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All substances either are simple molecules, or have a giant structure. In this topic we will
consider how the type of bonding and forces between atoms, ions and molecules gives rise
to different physical properties, including the shapes and arrangements of atoms and ions
within substances.
Properties of simple molecules
Many substances, especially organic substances, consist of individual molecules with
strong covalent bonds holding the atoms together within the molecule and weak
intermolecular forces holding one molecule to another. To change the state of such
substances from solid to liquid to gas we have to overcome the forces that hold the
molecules to one another, but we do not break any of the covalent bonds the molecules
are identical regardless of their physical state.
Characteristic
Bonding
Boiling and melting points
Electrical conductivity
Solubility
Electrical
conductivity
Solubility
Yes
Sea of delocalized electrons
are mobile and act as charge
carriers
EXCEPT
Graphite has one delocalized
electron per C atom which is
free to act as charge carrier
Insoluble
Insoluble
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Silicon
Graphite is a soft substance. The layers are held one to another by weak Van der Waals
forces, which means that the layers can easily slide over each other making graphite
slippery and good for use as a lubricant. Pencils leave their marks on paper because the
graphite 'lead' in the pencil leaves layers of graphite stuck to the paper.
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Graphite has a very high melting point (and boiling point) and is insoluble. To melt or
dissolve graphite would require the layers to be broken down, and this means large
numbers of very strong covalent bonds have to be broken requiring lots of energy.
iii) Graphene
Graphene is a two-dimensional material. Each carbon
atom in graphene is covalently bonded to 3
neighbouring atoms. Each atom has four outer shell
electrons. Three of these are involved in single covalent
bonds to adjacent carbon atoms, and a fourth electron
from each atom is delocalised and free to move
throughout a conjugated network that extends
throughout the lattice. This arrangement means that
carbon-carbon bonds in graphene are extremely strong.
Thanks to this structure, graphene has some unusual properties:
Huge surface area to weight ratio, up to 2630 m 2/g
High electrical conductivity
Exceptionally stiff: Young's modulus about 1 TPa
Strong - fracture strength approximately 130 GPa
The highest thermal conductivity of all known materials
These unique properties mean that graphene could prove valuable in many application
areas. Some examples include:
Transparent conductive films, e.g. for touchscreen displays
Chemical, biological and mechanical sensors, e.g. for detecting nerve agents,
diseases and strain
Additives for composite materials, e.g., for aircraft, car tyres and prosthetics
Inert coatings for protecting materials from harsh environments
The first thorough investigations of graphene properties were reported in 2004, based on
material produced by micromechanical exfoliation, also known as the 'sticky tape' method.
Despite producing high-quality material, this approach is laborious and is only capable of
providing small-area samples. There are now many scalable methods for graphene
production e.g. chemical vapour deposition (CVD) that have been developed for the
industrial production of graphene.
iv) Sodium Chloride a typical giant ionic lattice
Sodium chloride has a regular 3D lattice structure in
which sodium ions and chloride ions alternate. The
electrostatic attraction between the ions is nondirectional so every sodium ion attracts chloride ions
all around it above, below and on each side.
Similarly each chloride ion attracts six sodium ions.
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The formula NaCl does not indicate that sodium and chloride ions "go around in pairs", but
that there is a ratio of one sodium ion for every chloride ion in the lattice it is an empirical
formula.
Because the electrostatic attractions between the oppositely-charged ions run throughout
the lattice, sodium chloride is hard and brittle. These attractions are strong, and must be
overcome before the lattice can be broken down to form a liquid, which requires a lot of
energy. Sodium chloride thus has a high melting and boiling point.
Sodium chloride dissolves in polar solvents such as water. The energy needed to break
down the lattice so the ions can be in solution is offset by the energy released when bonds
are formed between the ions and the water molecules.
Once in solution (or melted), the sodium and chloride ions are free to move around. They
are charge carriers, so in these states sodium chloride is able to conduct electricity. When
solid the ions are locked in place in the lattice and although they are charged, they are
unable to move and carry the electrical charge. This means that solid sodium chloride does
not conduct electricity.
v) Iodine a simple molecular lattice
Iodine has a simple molecular structure. Iodine atoms
are bonded in pairs by covalent bonds, so the formula
is I2.
In the solid state, the weak intermolecular forces
between the iodine molecules hold them together in a
3D lattice structure. This is a simple molecular lattice.
There are no delocalized electrons in iodine, and no
ions, so there are no charge carriers and iodine cannot
conduct electricity.
Iodine has the unusual property that when heated it
goes directly from being solid to being a gas. This
property is called sublimation. It does this at a low
temperature (114C) because only weak intermolecular forces hold the iodine molecules
together and these take little energy to overcome. Iodine vapour still consists of I 2
molecules no bonds have been broken in turning iodine into a gas.
Being non-polar iodine dissolves readily in most non-polar organic solvents such as hexane
or trichloromethane. It is almost completely insoluble in water because to dissolve in water
the hydrogen bonds between the water molecules have to be broken, and there are no new
bonds formed between iodine and the water so the energy cannot be offset by any
released energy.
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Shapes of Molecules
There are a variety of basic shapes and bond angles:
LINEAR
NON-LINEAR (BENT)
e.g. 104.5 in H2O
TRIGONAL PLANAR
PYRAMIDAL
TRIGONAL BIPYRAMIDAL
TETRAHEDRAL
OCTAHEDRAL
The shapes of real molecules are determined by the outer shell electrons of the atoms
which are bonded together. A dot-cross diagram is the essential starting point for working
out shape. What we need to know is how many lone pairs and how many bonding pairs
surround the central atom in each molecule.
Valence Shell Electron Pair Repulsion theory (VSEPR)
The shapes of molecules are caused by the mutual repulsion electron pairs (bonding pairs
and lone pairs). As a result of this repulsion the bonds and lone pairs arrange themselves
as far apart as possible.
Lone pairs repel more strongly than bonding pairs, so a lone pair will push bonding pairs
away from itself, closing the bond angle between bonding pairs by about 2.5 per lone pair.
To determine the shape of a molecule, we have to work out the spatial arrangement of the
lone pairs and bonding pairs and the bond angles (angles between the bonding pairs).
Then we match the positions of the atoms to the various shapes, above.
We will find that particular shapes correspond to particular numbers of lone pairs and
bonding pairs.
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BeCl2
Central Be atom:
bonds = 2
lone pairs = 0
The two bonding pairs repel as far as possible from one another, giving a bond angle of
180. The lone pairs on Cl have no effect on the shape. The molecule is LINEAR.
CO2
Central C atom:
bonds 2 (doubles)
lone pairs = 0
The fact that the bonds are double has no effect on shape the two double bonds repel
each other as far as possible. The bond angle is 180and the molecule is LINEAR.
For the purpose of working out shapes (only) we dont consider double or triple bonds any
differently than single bonds.
BF3
Central B atom:
bonds = 3
lone pairs = 0
CH4
Central C atom:
bonds = 4
lone pairs = 0
PF5
Central P atom:
bonds = 5
lone pairs = 0
Page 7
SF6
Central S atom:
bonds = 6
lone pairs = 0
NF3
Central N atom:
bonds = 3
lone pairs = 1
There are four bonds/lone pairs repelling each other, so the arrangement around the
central N atom is tetrahedral but the lone pair repels the bonding pairs more than the
bonding pairs repel each other so the bond angle between the N-F bonds is reduced from
109.5 to 107 degrees. The positions of the atoms match the PYRAMIDAL shape.
H2S
Central S atom:
bonds = 2
lone pairs = 2
There are four bonds/lone pairs repelling each other, so the arrangement around the
central S atom is tetrahedral but the two lone pairs reduce the bond angle by 2.5 each, so
the H-S bond angle is 104.5. The positions of the atoms match the NON-LINEAR or
BENT shape.
NH4+
Central N atom:
bonds = 4
lone pairs =0
It doesnt matter that its an ion shapes work just the same. It doesnt matter that one bond
is dative. Covalent and dative bonds are identical once they are formed. The central N has
four bonds and no lone pairs, so the shape is TETRAHEDRAL and the bond angle 109.5.
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sulphur trioxide
v)
ozone
CH3CHO
Page 9
non linear
tetrahedral
linear
trigonal planar
non-linear
104.5
109.5
180
120
117.5
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