SPM Chemistry Skema Set 1 paper 1

SECTION A
BAHAGIAN A

1 (a)
(b)

(i)
(ii)

ZnCl2
Zn(NO3)2

1
1

(i)

Silver nitrate and zinc chloride

argentum nitrat dan zink klorida
Silver chloride and zinc nitrate
argentum klorida dan zink nitrat
2AgNO3 + ZnCl2
2AgCl + Zn(NO3)2

(ii)
(iii)
(c)

(i)

From the chemical equation,

Daripada persamaan tindak balas :
2 mol of AgNO3 produces 2 mol of Ag and 1 mol of
O2
2 mol AgNO3 menghasilkan 2 mol Ag dan 1 mol O2
Hence,
Maka,
1 mol of AgNO3 will produce 1 mol of Ag and 0.5
mol of O2
1 mol AgNO3 akan menghasilkan 1 mol Ag dan
0.5 mol O2

(ii)

No. of mol of AgNO3

Bilangan mol AgNO3

1
1

0.5 mol

1
From the chemical equation,
Daripada persamaan tindak balas, didapati :

Hence,
Maka,
0.5 mol of AgNO3 will produce 0.5 mol of NO2
0.5 mol AgNO3 akan menghasilkan 0.5 mol NO2

85 g / 170

2 mol of AgNO3 produces 2 mol of NO2

2 mol AgNO3 menghasilkan 2 mol NO2

SPM Chemistry Skema Set 1 paper 1

Volume of NO2
Isipadu NO2
= 0.5 x 24
= 12 dm3

10
..

(a)

39

(b)

(i)
(ii)
(iii)

(c)

1
3
2.8
Group / kumpulan 1

Low density
Low melting and boiling points
Conduct electricity
Soft metal
[any one correct]
ketumpatan rendah
takat lebur/didih rendah
mengkonduksikan elektrik
logam lembut
[ Mana-mana satu betul ]

1
1
1

(d) (i)
2M + Cl2

2MCl
1
(ii)
ionic bond /Ikatan ion
Atomic size/ atomic
radius of N atom bigger than M
Saiz /Jejari atom N lebih besar berbanding M
Valence
electron of atom N further away from nucleus //Nucleus attraction towards
valence electron of N is weaker than M
Elektron valens atom N semakin jauh dari nukleus //
Daya tarikan nukleus terhadap elektron valen N lebih lemah
berbanding M
1
3 N atom easy to release electron.
Atom N mudah melepaskan elektron

1
10

(a) Chemical to electrical

SPM Chemistry Skema Set 1 paper 1

Tenaga kimia kepada tenaga elektrik

(b)(i) Aluminium
1
(ii) Aluminium tends to donate electron //
Aluminium is more electropositive// Al is above Cu in ECS
Aluminium lebih cenderung menderma elektron//
Aluminium lebih elektropositif // Al lebih atas dalam SEK berbanding
kuprum
1
3+
(iii)
Al

Al
+ 3e
1
(c) (i)
copper plate becomes thicker// brown solid deposited
Kepingan kuprum menebal // Enapan perang
1
2+
(ii) Cu
+
2e
Cu
1
(d) 2Al + 3Cu2+
2Al3+
+ 3Cu
1
(e) Drawing arrow to show the movement of electron from Al to Cu
through external circuit.
Melukis anak panah menunjukkan pergerakan elektron
dari Al ke Cu melalui litar luar
1
(f)
(i)
Cu, Pb, Zn, Mg
1
(ii) 0.6 V
1
10

(a)

14.90,

15.10,

(b)

14.90

+ 15.10
3

(c)

pink to colourless /

(d)

2KOH

(e)

MasidVasid = 1
MalkValk
2

15.00
+ 15.00 cm3

H2SO4

1
=

15.00 cm3

merah jambu kepada tanpa warna

K2SO4

2H2O

Masid x 15/1000 = 1
0.5 x 20/1000
2
Masid = 0.33 moldm-3

1
1

SPM Chemistry Skema Set 1 paper 1

(f)

(i)

30.00 cm3
(ii)

HCl is monoprotic acid whereas H2SO4 is diprotic acid

1 mol of HCl ionises to produce 1 mol of H+
And 1 mol of H2SO4 produces 2 mol of H+ ion
Same number of H+
HCl asid monobes sementara H2SO4 asid dwibes//
1 mol HCl mengion menghasilkan 1 mol ion H+
dan 1 mol H2SO4 menghasilkan 2 mol ion H+
1
+
bil mol ion H sama
1
10

5 (a) (i)

Mg + 2HCl

MgCl2 + H2

(ii)

Label axes with units // All points are transferred correctly

Smooth graph
Paksi berlabel dan berunit // Semua titik dipindah dengan betul
Bentuk graf licin
1

(iii)

[step of calculation
Correct answer

(b)(i)

(ii)

Langkah pengiraan]
//

Jawapan betul ( 0.33

cm3s-1)

magnesium powder has larger total surface area

Serbuk magnesium mempunyai jumlah luas permukaan
lebih besar ,
1
number of collision between the particles increase
Bilangan perlanggaran antara zarah bertambah,
1
Frequency of effective collision increases / rate of reaction increases
frekuensi perlanggaran berkesan bertambah / kadar tindak
balas bertambah
1
increase the temperature / use catalyst
meningkatkan suhu /menggunakan mangkin

1
10

SPM Chemistry Skema Set 1 paper 1

6 (a) Mark the flow of electron correctly ( from A to B) through

external circuit / connecting wires
Tanda arah aliran elektron betul (dari A ke B) melalui litar luar
/ wayar penyambung
(b) to allow the flow of ion.
untuk membenarkan perpindahan ion melaluinya
(c) (i)
colourless to brown
tidak berwarna kepada perang
(ii)
2I + 2e
I2
1
(iii) Oxidation pengoksidaan
(d) (i) +3 to +2
+3 kepada +2
(ii) add sodium hydroxide solution / ammonia aqueous
dirty green precipitate formed.

1
1
1

Or
Add potassium hexasionoferate(III) / potassium thiocianate
Dark blue precipitate / red blood solution formed.
Tambahkan larutan natrium hidroksida/larutan ammonia.
Mendakan hijau kotor terhasil.
Atau
Tambahkan larutan kalium heksasionoferat(III) / kalium tiosianat.
Mendakan biru tua / larutan merah darah terhasil.
(e) i)

purple to colourless / purple colour is decolourised

ungu kepada tidak berwarna/ warna ungu dinyahwarna

ii)

x + 4(-2) = -1
x

=+7

1
10
SECTION B

BAHAGIAN B
2 (a)

[Can draw structural formula and name the corresponding isomer correctly.
Dapat melukis formula struktur dan menamakan isomer yang sepadan dengan
betul ]
Answer :
H H
H
I
I
I
H - C - C - C - OH
propan-1-ol / 1-propanol
I
I
I
H
H
H
H
H
I
I
H -C - C I
I
H
OH

(b)(i)

1
1

H
I
C - H
I
H

propan-2-ol / 2-propanol

[can write the molecular formula correctly

1+1

1+1

SPM Chemistry Skema Set 1 paper 1

Dapat menghitung formula molekul dengan betul]
Answer
Jawapan :
[ calculate the number of mol of carbon and hydrogen
mengira bilangan mol karbon dan hidrogen ]
1. no. of mol of carbon = 85.7 / 12 and no. of mol of hydrogen = 14.3/1
bil. Mol karbon = 85.7 / 12 dan bil mol hydrogen = 14.3/1
[determine the simplest ratio of CH
menentukan nisbah paling ringkas bagi CH]
2 Simplest ratio
nisbah paling ringkas C : H = 1 : 2
[ determine the empirical formula for CH
menentukan formula empirik bagi CH]

3 Empirical formula is
formula empiric ialah CH2
[use the empirical formula to determine the molecular formula
gunakan formula empirik untuk menentukan formula molekul ]
4

to get the number of atom in CH2

Untuk mendapat bilangan atom pada CH2
Answer / Jawapan :
( CH2 )n = 42 // n( CH2 ) = 42 // 12n + 2n = 42 // 14n = 42
[determine the molecular formula by replacing n value in CH2
menentukan formula molekul dengan menggantikan niali n pada CH 2 ]
(b)(ii)

(b)(iii)
(b)(iv)

5 C3H6 // CH3CHCH2
[can draw the structural formula and name the alkene correctly
Dapat melukis formula struktur dan menamakan alkena dengan betul]
6 structural formula is / formula strukur ialah :
H H
H
I
I
I
H- C - C = C - H
I
H
7 Name : propene / prop-1-ene
Nama : propena / prop-1- ena
[ can state the general formula of homologous series correctly
Dapat menyatakan formula am siri homolog dengan betul]

1
1

(c)

Answer / Jawapan :
8 general formula of homologous is CnH2n
Formula am siri homolog ialah CnH2n
[procedure
prosedur ]
1. Put 5 cm3 of alkene M and propane in two test tube
masukan 5 cm3 alkena M dan propana dalam dua tabung uji
2. drop/ add bromine water and shake
titis/ tambahkan air bromin dan goncang
[observation
pemerhatian ]
3. Brown colour of bromine water turns to colourless in test tube of alkene M
No change in test tube of propane
warna perang air bromin bertukar kepada tanpa warna dalam tabung uji
alkena M

1
1
1
1
1

SPM Chemistry Skema Set 1 paper 1

tiada perubahan dalam tabung uji propana
[conclusion
kesimpulan ]
4. Alkene M undergoes addition reaction
alkena M mengalami tindak balas penambahan
[labelled diagram
gambarajah berlabel]

(2)(d)

1. [functional diagram
gambarajah berfungsi ]:
water is shaded, rubber stopper outside the mouth of test tube, delivering
tube is not blocked, retort stand with clamp.
air berlorek, gabus diluar mulut tabung uji, salur penghantar tidak
dihalang, pengapit kaki retort,

1
1

2. [ label ] :
Alkene M gas, heat, porcelain chips, glass wool soaked with propanol
gas Alkena M, panaskan, serpihan porselin, kapas direndam propanol.
[ Procedur
prosedur ]
3. Heat the porcelain chips strongly / until glowing
panaskan serpihan porselin dengan kuat / sehingga membara
4. Warm the glass wool soaked with propanol
Hangatkan kapas yang direndam propanol

1
1

SECTION C
BAHAGIAN C
3

(a) Heat released when 1 mol of H+ ion reacts with 1 mol of OH- ion to form 1 mol of
water
Haba yang dibebaskan apabila 1 mol ion H+ bertindak balas dengan
1 mol ion OH- membentuk 1 mol air
11
(b)(i) Hydrochloric acid is strong acid, undergoes complete ionisation when
dissolve in water.
Ethanoic acid is weak acid, undergoes partial ionisation when
dissolve in water.
Some of the heat released is absorbed to break the bond in the acid molecule.
Asid hidroklorik adalah asid kuat, mengalami pengionan
lengkap apabila larut dalam air
1
Asid etanoik adalah asid lemah, mengalami pengionan separa
apabila larut dalam air
1
Sebahagian haba dibebas diserap untuk memutuskan ikatan
yang terdapat dalam molekul asid
13
(ii) x value is 57 kJ mol-1 [same as reaction 1]
sulphuric acid is strong acid, undergoes complete ionisation when dissolve in
water
reaction involved 1 mol of H+ and 1 mol of OH- /
H+ + OH- H2O
nilai x ialah 57 kJ mol-1 [sama seperti tindak balas 1]
1
Asid sulfurik adalah asid kuat, mengalami pengionan lengkap
apabila larut dalam air
1
Tindak balas melibatkan 1 mol H+ dan 1 mol OH- /
H+ + OH- H2O
1..3

SPM Chemistry Skema Set 1 paper 1

(c)

apparatus:
Polystyrene cup, thermometer, measuring cylinder
Radas :
Cawan polistirena, termometer, silinder penyukat.

Procedure
Kaedah :
1 100cm3 of sodium hydroxide solution 2 moldm-3 is measured using
measuring cylinder and is added into polystyrene cup
100cm3 larutan natrium hidroksida 2 moldm -3 disukat menggunakan
silinder penyukat dan dimasukkan ke dalam cawan polistirena
2 initial temperature is recorded
Suhu awal dicatat
1
3 100cm3 of hydrochloric acid 2 moldm-3 is measured using measuring
cylinder
100cm3 asid hidroklorik 2 moldm-3 disukat dengan silinder
penyukat
1
4 initial temperature of acid is recorded
Suhu awal asid dicatat
1
5 hydrochloric acid is quickly poured into sodium hydroxide solution
Asid hidroklorik dituang dengan cepat ke dalam larutan natrium
hidroksida
1
6 the mixture is stirred
Campuran dikacau.
1
7 maximum temperature achieved is recorded
Suhu maksimum yang dicapai dicatat.
1
8 Step 1 to 7 is repeated using ethanoic acid.
Langkah 1 7 diulangi dengan asid etanoik.
1
Result
Keputusan :
Hydrochloric acid
Asid hidroklorik

Ethanoic acid
Asid etanoik

Initial temperature of
NaOH/oC
Suhu awal NaOH /oC
Initial temperature of
acid/oC
Suhu awal asid /oC
Maximum temperature/oC
Suhu maksima /oC
1
Calculation
Penghitungan :
Heat released
Haba dibebaskan = 200 x 4.2 x
No. of mol / Bilangan mol HCl / CH3COOH = / 0.2 mol
Heat of neutralisation
Haba peneutralan = 200 x 4.2 x kJ mol-1
0.2 x 1000

1
1
1
..13
20

SPM Chemistry Skema Set 1 paper 1

4

(a)

Reinforced concrete
Consist of steel rod in concrete pillar
It can withstand high pressure / withstand compression
Does not corrode
Uses : to make construction outline, bridges, road / high buildings
Konkrit yang diperkukuhkan
terdiri daripada batang keluli dalam tiang konkrit
sifatnya tahan terhadap tekanan yang tinggi / tahan mampatan
tidak berkarat
kegunaanya : membuat rangka pembinaan, jambatan, jalan raya
/ bangunan yang tinggi
OR
ATAU

1
1
1
1
15

Reinforced plastic with glass

Consists of molten glass added with resin fibre
It is light/not ductile / not miscible / electrical insulator /
corrosion resistant / inflammable
uses : racket, vehicle body/ aeroplane body/ angler rod
construction panel
Plastik yang diperkukuhkan dengan kaca
terdiri daripada kaca lebur dicampur dengan gentian damar
sifatnya ringan/tidak rapuh/tidak telap air/penebat elektrik/
tahan kakisan/ tidak mudah terbakar
kegunaannya raket/ rangka kenderaan/ rangka kapal/ rod pancing/ panel pembinaan/
OR
ATAU
Photochromic glass
Consists of silver bromide/chloride in the glass structure
It sensitive to light
Transparent
To make spectacles
Kaca fotokromik
terdiri daripada argentum bromida/klorida dalam struktur kaca
sifatnya peka terhadap cahaya
lutsinar
membuat cermin mata

(b) Material
Dilute sulphuric acid, ammonia solution, phenolphthalein indicator
Bahan :
Asid sulfurik cair, larutan ammonia, penunjuk fenoftalein
Apparatus:

SPM Chemistry Skema Set 1 paper 1

Beaker, Bunsen burner, retort stand, glass rod, tripod stand,
Wire gauze, filter funnel, filter paper
Alat radas :
Bikar, buret, penunu Bunsen, kaki retort, rod kaca, tungku kaki tiga,
kasa dawai, corong turas, kertas turas

procedure/ method:
Prosedur / Kaedah :
1
2
3

5
6
7

(c) 1
2
3
4
5

50 cm3 of ammonia solution is measured and poured into a conical flask

50 cm3 larutan ammonia disukat lalu dimasukkan ke dalam kelalang kon
1
A few drops of phenolphthalein indicator is added into the conical flask
Beberapa titik penunjuk fenoltalein ditambahkan ke dalam kelalang kon
1
dilute sulphuric acid is added from the burette into the conical flask
While conical flask is swirled
Asid sulfurik cair ditambah daripada buret ke dalam kelalang kon
1
sambil kelalang kon digoncang
1
The addition of dilute sulphuric acid is continued until the colour of phenolphthalein indicator change
from pink to colourless
Penambahan asid sulfurik cair diteruskan sehingga warna penunjuk
fenolftalein bertukar warna daripada merah jambu kepada tidak berwarna 1
the product is heated until saturated
Hasil dipanaskan sehingga tepu
1
then it cooled
Kemudian dibiarkan sejuk
1
the product is filtered and dried using two pieces of filter paper
Hasi dituras dan dikeringkan menggunakan dua kertas turas
1..10
Aspirin is acidic / aspirin is acetylsalicylic acid
Aspirin bersifat asid / aspirin ialah asid asetilsalisilik
to help to relieve fever
membantu meredakan deman
to treat arthritis disease / to reduce ankle soreness
merawat penyakit artritis/ mengurangkan pembekakan sendi
to reduce blood clot / to prevent the heart attack
mengurangkan pembekuan darah/ mencegah serangan jantung
overdose can cause stomach bleeding and can be death.
penggunaan secara berlebihan mengakibatkan pendarahan dalam perut
dan boleh membawa maut
1.5

1
1
1
1