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Index.
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1. Compound 1
common name - common salt
emprical formula - NaCl
structural formula -
2. Compound 2.
common name - glucose
systematic name - 2,3,4,5,6-pentahydroxyhexanal
emprical formula - CHO
structural formula
glucose powder
or
CHOHCH(OH)CH(OH)CH(OH)CH(OH)CHO
or
Cations
1+ ions
2+ ions
3+ ions
hydrogen
lithium
sodium
potassium
silver
copper(I)
ammonium
H
Li
Na
K
Ag
Cu
NH
magnesium
Mg2
calcium
Ca2
iron(II)
Fe2
copper(II)
zinc
Cu2 blue
Zn2
barium
Ba2
hydronium
HO
tin(II)
Sn2
lead(II)
Pb2
manganese(II)
Mn2pale pink
nickel
Ni2
cobalt(II)
Co2pink
or hydroxonium
pale green
aluminium
scandium
iron(III)
Al
Sc
Fe
yellow/brown
chromium(III) Cr
green or blue
green
Anions
1- ions
2- ions
hydroxide
OH
hydrogencarbonate HCO
hydrogensulfate
HSO
nitrate
NO
nitrite
NO
fluoride
F
chloride
Cl
bromide
Br
iodide
I
oxide
permanganate
MnO
purple
various colours
CO2
sulfate
SO2
sulfite
SO2
sulfide
S2various colours
manganate
MnO2
ClO or OCl
ClO
BrO
IO
CHCOO
Al(OH)
or AlO
green
HPO2
HPO
nitride
phosphide P
carbonate
monohydrogenphosphate
dihydrogenphosphate
hypochlorite
chlorate
bromate
iodate
ethanoate
aluminate
O2
3- ions
phosphate
dichromate CrO2orange
chromate
CrO2yellow
zincate
Zn(OH)2
or ZnO2
PO
2.
Na NO
Ca SO
NH CO
Al O
NaNO
CaSO
(NH)CO
AlO
3.
a.Zinc carbonate
.................
b. Potassium fluoride
.................
d. Copper oxide
.................
e.Lead hydroxide
.................
e. Sodium oxide
.................
f. Aluminium chloride
.................
g. Silver chloride
.................
h. Potassium sulphide
.................
i. Copper nitrate
.................
j. Ammonium sulphate
.................
k. Calcium iodide
.................
l. Sodium phosphate
.................
.................
n. Barium nitrate
.................
o. Zinc nitride
.................
q. Iron(II) sulphate
.................
.................
s. Aluminium sulphide
.................
t. Magnesium ethanoate
.................
u. Sodium zincate
.................
v. Ammonium dichromate
.................
w. Calcium dihydrogenphospate
.................
.................
Molecular formulae
a) Molecular substances contain only non metal atoms. These are substances
where the atoms are held together by covalent bonds.
b) Sometimes the name gives a clue as to the formula.
c) Other formulae need to be learnt. LEARN AS MANY AS POSSIBLE !!
Name
1.
Water
2.
Hydrogen peroxide
3.
Carbon monoxide
4.
Carbon dioxide
5.
Methane
6.
Ethane
7.
Ethene
8.
Ethyne
9.
Sulphur dioxide
10. Ammonia
Formula
HO
HO
CO
CO
CH
CH
CH
CH
SO
NH3
NO
12. Nitrogen
80% of air
13. Hydrogen
14. Oxygen
15. Ozone
16. Chlorine
Cl
17. Glucose
18. Iodine
19. Sulphur
yellow solid
20. Phosphorus
21.
22.
23.
24.
Hydrochloric acid
Sulphuric acid
Nitric acid
Ethanoic acid
25. Carbon
26. Glucose
27. Ethanol
Properties
a colourless liquid at room temp
a colourless liquid used as a bleach
a colourless poisonous gas
a colourless gas turns limewater milky
natural gas used as a fuel gas
a gas found in LPG
a gas used to make plastics
a gas mixed with O to weld iron
a pollutant gas formed when sulfur burns
strong smelling gas, used as a cleaner
graphite or charcoal.
CHO white solid, the simplest of the sugars
ethanol
aluminium potassium sulphate 24-hydrate
aluminium oxide
sodium hydrogen carbonate
ore containing aluminium oxide
calcium chloride hypochlorite
copper sulphate pentahydrate
sodium chloride solution/seawater
silicon carbide
potassium hydroxide
sodium hydroxide
calcium carbonate
graphite, amorphous carbon
sodium nitrate
sodium chloride
sodium aluminium fluoride
carbon
carbon dioxide solid
magnesium sulphate heptahydrate
diethyl ether
sublimed sulphur
iron sulphide
sodium sulphate decahydrate
glycerol (from soap manufacture)
crystalline carbon sheets
calcium sulphate dihydrate
nitrous oxide
calcium hydroxide solution
lead monoxide
magnesium oxide
triferric tetroxide, mixed iron oxide
calcium carbonate
magnesium hydroxide suspension
naphthalene
potassium nitrate
glyceryl trinitrate
sulphuric acid
calcium sulphate hemihydrate
silicon dioxide
calcium oxide
mercury
triplumbic tetroxide, mixed lead oxide
sodium chloride
ammonium chloride
ammonium carbonate
potassium nitrate
silicon dioxide
calcium hydroxide solid
sodium carbonate
sucrose
trinitrotoluene
sodium carbonate decahydrate
methanol
CHCHOH
Al(SO).KSO.24HO
AlO
NaHCO
AlO ( FeO + SiO )
CaCl(OCl)
CuSO.5HO
NaCl
SiC
KOH
NaOH
CaCO
C
NaNO
NaCl
NaAlF
C
CO
MgSO.7H0
CHCHOCHCH
S
FeS
NaSO.10HO
CH(OH)CH(OH)CHOH
C
CaSO.2HO
NO
Ca(OH)
PbO
MgO
FeO
CaCO
Mg(OH)/HO
CH
KNO
CH(NO)CH(NO)CHNO
HSO
CaSO./HO
SiO
CaO
Hg
PbO
NaCl
NHCl
(NH)CO
KNO
SiO
Ca(OH)
NaCO
CHO
CH(NO)
NaCO.10HO
CHOH
The following are of interest , but are not as important as those listed above.
Aqua fortis
Aqua regia
Borax
Brimstone
Cinnabar
Corrosive sublimate
Cream of tartar
Dolomite
Green vitriol
Halite
Hypo
Lye
Marsh gas
Muriatic acid
Prussic acid
White vitriol
nitric acid
nitric acid and hydrochloric acid
sodium tetraborate decahydrate
liquid sulphur
mercury(II) sulphide
mercury(II)chloride
potassium hydrogen tartrate
calcium and magnesium carbonate
ferrous sulphate heptahydrate
sodium chloride
sodium thiosulphate pentahydrate
sodium hydroxide
methane
hydrochloric acid
hydrocyanic acid
zinc sulphate heptahydrate
HNO
HNO/HCl
NaBO.10HO
S
HgS
HgCl
KHCHO
CaCO.MgCO
FeSO.7HO
NaCl
NaSO.5HO
NaOH
CH
HCl
HCN
ZnSO.7HO
Colours in Chemist ry
Year 1 1 level
SOLIDS
1 . Whit e solids
(unless anion
is coloured)
2 . Whit e Precipit at es
3 . Whit e precipit at es
t hat dissolve
Al, Zn , Pb , Sn
in excess NaOH
AgCl, Zn(OH)
in ammonia
all carbonates (any colour)
in acids
all hydroxides (any colour)
in acids
4 . Yellow solids
5 . Black solids
Charcoal / graphite
CuO, CuS,
PbS
FeO, FeO
MnO (or brown)
6 . Brown solids
PbO, AgO
FeCl anhydrous is dark brown crystals
FeCl.6HO is yellow brown crystals
FeO is red brown, rusty
7 . Red solids
8 . Grey solids
9 . Orange solids
1 0 . Purple solids
KMnO
1 1 . Green solids
1 2 . Blue solids
CuSO.5HO, Cu(NO).3HO
anhydrous CoCl
CoCl.6HO
Mn salts are very pale pink
1 4 . Green precipit at es
CuCO.Cu(OH) from Cu + CO
FeCO and Fe(OH) (both darken on standing in air)
1 5 . Blue precipit at es
AgO from
Ag + OH
1 8 . Red
Br
Fe , Ni , Cr, MnO
Cu (sometimes green/blue)
MnO, I in non-polar organic solvents eg. hexane
CrO
Br solutions, I in polar solvents eg. propanone , I (I + I)
Fe, CrO
GASES
2 0 .Colourless
2 1 .Coloured
Cl green/yellow
2 2 .Coloured vapours
F pale yellow
NO brown
maximum
number of
electrons in
shell, 2n
18
32
50
electron shell, n
nucleus
contains neutrons and
protons
Atoms 1 - 20
Period 1
He
Period 2
Li
Be
flO
Period 3
Na
Mg
Al
Si
Ne
Period 3
fiCl
Ar
Period 4
Ca
fiSc
He
Ne
Ar
Kr
18
!Xe
18
18
Rn
18
32
18
18
32
50
72
98
18
32
50
72
Li
Na
Rb
18
!!Cs
18
18
Fr
18
32
18
98
2n
Cl
!Br
18
!I
18
18
!At
18
32
chlorine gas
18
32
bromine liquid
50
72
98
iodine solid
18
32
Ca
Sc
Ti
10
11
Cr
13
!Mn
13
Fe
14
Co
15
Ni
16
Cu
18
Zn
18
Ga
18
Scandium metal
Vanadium metal
50
72
98
Manganese metal
Other elements
2n
18
32
Cu
18
Ag
18
18
Au
32
18
18
32
21
!Am
18
32
25
Rg
18
32
32
18
50
Americium-241
in a smoke alarm
72
98
cubes of Uranium
2. Covalent bond -
3. Metallic bond
4. Intermolecular bond
between metals,
metal cations and their valence electrons
between molecules or atoms of Noble Gases
[ H - bonds, permanent dipoles, temporary or induced dipoles ]
types of bond
Cl
Cl
Cl
a non-polar bond
a pair of electrons shared between two
non-metal atoms with the same
electronegativity ens Cl = 3.0
a polar bond
a pair of electrons shared
unequally between two non-metal
atoms with different electronegativities
ens Cl = 3.0, H = 2.1
an ionic bond
Cl
Na
a metallic bond
Na
Na
Structure
Types of structure that you should be familar with
i.e. you should know about
a. particles holding structure together
b. types of force holding particles together
c. the relative strengths of these forces
d. the physical properties involved with these
structures.
TYPES OF SOLIDS
Forces of Attra ction in Crystalline Solids
Crystalline solids have an ordered array of atoms or molecules. This array is called a
lattice. The atoms or molecules in solids are held together in four different ways and
these are:
Molecular Solids: Molecules are held together by relatively weak forces (van
der Waals, hydrogen bonding) so molecular solids have low melting points and in
many cases only form solids at low temperatures. e.g. ice, solid CO. Most of the
non-metal elements e.g. chlorine and neon, form solids of this type. The forces
between the molecules are weak BUT within the molecule e.g. CO there are strong
forces holding the atoms together.
Ionic Solids: The lattice is made up of positive and negative ions. The force of
attraction between the oppositely charged ions is strong compared to molecular
solids. They have high melting points. Each ion is surrounded by neighbours of
opposite charge and there are no separate molecules. Ions are not easily moved from
their lattice sites, so typical ionic solids are hard and rigid, though brittle [If an ion is
displaced, it moves closer to an ion of like charge which repels it, thus breaking the
lattice]. They shatter easily and cannot be shaped by hammering and bending. The
electrons are localized on the ions and ionic solids only conduct electricity when they
are molten and the ions are free to move. Examples are NaCl [sodium chloride] and KI
[potassium iodide].
diamond
graphite
Metallic Solids: The metal atoms occupy regular lattice sites, however the valence
electrons can move throughout the entire solid. These delocalized electrons
readily carry heat and electricity throughout the solid. The mobile electrons produce
the typical sheen or metallic lustre characteristic of metals. Since the force of
attraction is not localised, the metal atoms can slide from one lattice site to another,
making metals malleable (shaped by hammering) and ductile (drawn into wire). The
strength of the metallic bond is quite variable as indicated by the range of melting
points from tungsten, 3422 0C to mercury, !39 0C.
This table summarises some of the facts about the four types of solids.
TYPE of SOLID
METALLIC
IONIC
MOLECULAR
COVALENT
Entity
atoms
ions
molecules
atoms/molecules
Force of Attraction
metallic
bond
ionic bond
Van der
Waals
covalent bond
variable
strong
weak
strong
Texture
soft
hard /
brittle
soft
very hard
Conductor of
Heat or Electricity
conductors
insulators
[conduct
when
molten]
insulators
insulators
(except graphite)
Melting Point
variable mp
-39 to
4000C
high mp
600 to
3000C
low mp
-272 to 400
C
very high mp
1200 to 4000C
Solubility
insoluble in
water/organ
ic
soluble in
water
soluble in
organic
solvents
insoluble
Examples
Fe
Pb
Sn
NaCl
MgO
Na2SO4
sugar
CH4
CO2
diamond
graphite
quartz
Amorphous Solids
An amorphous solid is not crystalline as the atoms or molecules are not arranged
in a regular lattice and is formed when the shape of the molecule is too complex, the
molecules are frozen too rapidly or when impuriites prevent a regular lattice. They
include glass, rubber and plastics. Amorphous solids can be considered to be
supercooled liquids of high viscosity.
9. Precipitation
Example :
sodium chloride + silver nitrate sodium nitrate + silver chloride
a white ppt.
10. Combination
soluble
insoluble
CO
Na,K and NH
the rest
OH
Na,K, NH,
Ca and Ba slightly
the rest
the rest
Cl, Br, I
the rest
Ag,Pb also Cu
SO
the rest
HCO
------------
NO
------------
CHCOO
------------