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MCassignments
Review
pastdueassignments:
methodofinitialratestodeterminetheorder
ofreaction
integratedratelaws
LT16
due3/23at1pm
LT17
due3/25at1pm
LT18
due3/30at1pm
availableassignments:
LT19/20
dueFri4/3atmidnight
HWCh14
dueSat.4/4atmidnight
firstorder
secondorder
zeroorder
halflifet
upcomingassignments:
LT21
due4/8at1pm
Lecture18:Mondayofweek11
I_____thelecturenotesDr.Irmihas
postedbeforelectures.
Chapter14.5 14.6
FridayinRecitation:
79
Quiz12,
Laboratory:
NextExam:
Wednesdayevening,Apr.15,6:45 7:45pm
FinalExam:http://www.registrar.iastate.edu/students/exams/springexams#alpha
Wednesdayevening,May6,7 9pm
1. like
2. donotlike
3. dontknowanything
about
49
23
putawayalldistractions
setyourclickertoChannel17or27
1.
Thisweathermakesit______tocome
toclass.
2.
3.
66
1. easier
2. harder
3. nodifference
56
93
40
1.
2.
3.
4.
101.6
44.1
0.74
1.69
60
12
4
1.
2.
3.
1.
2.
3.
4.
4/1/2015
N2O5(g)4NO2(g)+O2(g)
Thereactionisfirstorderandk =6.82x103 s1 at70C
Youstartwith0.0250molN2O5(g)in2L
After6.76min,howmuchN2O5(g)isleft?
N2O5(g)4NO2(g)+O2(g)
Thereactionisfirstorderandk =6.82x103 s1 at70C
Youstartwith0.0250molN2O5(g)in2L
Howmanyminuteswillittakeuntilonly0.10molisleft?
119
1.
2.
3.
4.
0.0125
6.25x103
3.13x103
1.56x103
25
135
1.
2.
3.
4.
24
2.2
1.1
4.4
6.6
19
7
2
1.
2.
3.
4.
halflifeofasecond orderreaction
1
1.
2.
3.
4.
Howfastdochemicalreactions
proceed?
Speedsdependon
Physicalstate,
Homogeneous orheterogeneous mixtures
dependsontheinitialconcentration
rateconstantsforisomerizationof
methylisonitrile toacetonitrile
CH3NC CH3CN
Reactantconcentration,
Reactiontemperature
Presenceofacatalyst
Demo?
Atmolecularlevel:
Frequency,energy,andorientation ofcollisions
graphicaldeterminationofthe
activationenergy
therateconstantincreases withincreasing
temperature
thereactionproceedsfaster athigher
temperatures
theArrhenius equationshowsthetemperature
dependenceoftherateconstantk:
Ea
R
T
A
Activationenergy
gasconstant8.13J/molK
absolutetemperature
preexponentialfactor
linearequation;
graphoflnk over1/T
fromtheslope:
ArrheniusPlot
4/1/2015
Afirstorderreactionwas
studiedattwodifferent
startingconcentrations
andtwodifferent
temperatures.
Whichofthethreegraphs
weretakenatthesame
g
startingconcentration?
Afirstorderreactionwas
studiedattwodifferent
startingconcentrations
andtwodifferent
temperatures.
Whichofthethreegraphs
weretakenatthesame
p
temperature?
1. 1and2
2. 2and3
3. 1and3
1. 1and2
2. 2and3
3. 1and3
151
156
19
1
1.
2.
3.
Afirstorderreactionwas
studiedattwodifferent
startingconcentrations
andtwodifferent
temperatures.
Whichgraph(s)wastaken
atthelowertemperature?
1.
2.
3.
WhatistheActivationEnergy?
EnergyProfileoftheReaction
initialstate:CH3NCmolecule
addenergy:bendthemolecule
1. 1and2
2. 1only
3. 3only
158
atthemaximumoftheenergycurve:
activatedcomplex,or
transitionstate
energyisreleased:newbondis
formed
7
1.
finalstate:CH3CNmolecule
8
2.
3.
Wheredoestheenergycomefrom?
forareactiontoproceed,the
activationenergyhastobeaddedto
themolecule
Thermalenergyofthemoleculescan
supplythisenergy
kineticmoleculartheoryshowsthis
nicelyforgasses
atagiventemperatureafraction of
moleculeshaveakineticenergythat
exceedstheactivationenergy.
atahighertemperaturemore
moleculeshaveenoughkinetic
energy
thefractionofmoleculesthathaveakinetic
energythatexceedstheactivationenergyis
thisisalmosttheArrhenius equation
preexponentialfactorA:
noteverycollision issuccessful
hastheproperunits
4/1/2015
usesofArrheniusequation
determinetheactivationenergyofareaction
ReactionMechanisms
Whatgoesonatthemolecularlevel?
somebondsarebroken
otherbondsareformed
theremaybeintermediates
measurementofk atdifferenttemperatures
useslope ofArrheniusplot
determinetherateconstantatadifferent
temperature
ElementaryReactions
stepbystep reactions
one,two,orthree moleculesinvolved
molecularity oftheelementaryreaction
eachelementaryreactionproceedsatitsownrate
TeamScores
molecularityofelementaryreactions
amoleculefallsapartABA+B
unimolecular
rate=k[AB]
Points
Team
5.33
5.27
easier
nodifference
5.15
harder
Points
Team
twomoleculescollide:C+DCD
bimolecular
rate=k [C][D]
threemoleculescollide:D+E+FDEF
termolecular (veryrare)
rate=k [E][D][F]