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4/1/2015

MCassignments

Review

pastdueassignments:

methodofinitialratestodeterminetheorder
ofreaction
integratedratelaws

LT16
due3/23at1pm
LT17
due3/25at1pm
LT18
due3/30at1pm
availableassignments:

LT19/20

dueFri4/3atmidnight

HWCh14

dueSat.4/4atmidnight

firstorder
secondorder
zeroorder

halflifet

upcomingassignments:
LT21
due4/8at1pm

Lecture18:Mondayofweek11

I_____thelecturenotesDr.Irmihas
postedbeforelectures.

Chapter14.5 14.6
FridayinRecitation:

79

Quiz12,

Laboratory:
NextExam:
Wednesdayevening,Apr.15,6:45 7:45pm

FinalExam:http://www.registrar.iastate.edu/students/exams/springexams#alpha
Wednesdayevening,May6,7 9pm

1. like
2. donotlike
3. dontknowanything
about

49

23

putawayalldistractions
setyourclickertoChannel17or27
1.

Thisweathermakesit______tocome
toclass.

2.

3.

N2O5(g) 4NO2(g) +O2(g)


Thereactionisfirstorderandk =6.82x103 s1 at70C
whatist1/2inmin?

66

1. easier
2. harder
3. nodifference

56
93

40

1.
2.
3.
4.

101.6
44.1
0.74
1.69

60

12
4

1.

2.

3.

1.

2.

3.

4.

4/1/2015

N2O5(g)4NO2(g)+O2(g)
Thereactionisfirstorderandk =6.82x103 s1 at70C
Youstartwith0.0250molN2O5(g)in2L
After6.76min,howmuchN2O5(g)isleft?

N2O5(g)4NO2(g)+O2(g)
Thereactionisfirstorderandk =6.82x103 s1 at70C
Youstartwith0.0250molN2O5(g)in2L
Howmanyminuteswillittakeuntilonly0.10molisleft?

119

1.
2.
3.
4.

0.0125
6.25x103
3.13x103
1.56x103

25

135

1.
2.
3.
4.

24

2.2
1.1
4.4
6.6
19
7

2
1.

2.

3.

4.

halflifeofasecond orderreaction
1

1.

2.

3.

4.

Howfastdochemicalreactions
proceed?
Speedsdependon
Physicalstate,
Homogeneous orheterogeneous mixtures

dependsontheinitialconcentration

rateconstantsforisomerizationof
methylisonitrile toacetonitrile
CH3NC CH3CN

Reactantconcentration,
Reactiontemperature
Presenceofacatalyst

Demo?

Atmolecularlevel:
Frequency,energy,andorientation ofcollisions

graphicaldeterminationofthe
activationenergy

therateconstantincreases withincreasing
temperature
thereactionproceedsfaster athigher
temperatures
theArrhenius equationshowsthetemperature
dependenceoftherateconstantk:
Ea
R
T
A


Activationenergy
gasconstant8.13J/molK
absolutetemperature
preexponentialfactor

linearequation;
graphoflnk over1/T
fromtheslope:

ArrheniusPlot

4/1/2015

Afirstorderreactionwas
studiedattwodifferent
startingconcentrations
andtwodifferent
temperatures.
Whichofthethreegraphs
weretakenatthesame
g
startingconcentration?

Afirstorderreactionwas
studiedattwodifferent
startingconcentrations
andtwodifferent
temperatures.
Whichofthethreegraphs
weretakenatthesame
p
temperature?

1. 1and2
2. 2and3
3. 1and3

1. 1and2
2. 2and3
3. 1and3

151

156

19

1
1.

2.

3.

Afirstorderreactionwas
studiedattwodifferent
startingconcentrations
andtwodifferent
temperatures.
Whichgraph(s)wastaken
atthelowertemperature?

1.

2.

3.

WhatistheActivationEnergy?
EnergyProfileoftheReaction
initialstate:CH3NCmolecule
addenergy:bendthemolecule

1. 1and2
2. 1only
3. 3only

158

atthemaximumoftheenergycurve:
activatedcomplex,or
transitionstate
energyisreleased:newbondis
formed

7
1.

finalstate:CH3CNmolecule

8
2.

3.

Wheredoestheenergycomefrom?
forareactiontoproceed,the
activationenergyhastobeaddedto
themolecule
Thermalenergyofthemoleculescan
supplythisenergy
kineticmoleculartheoryshowsthis
nicelyforgasses
atagiventemperatureafraction of
moleculeshaveakineticenergythat
exceedstheactivationenergy.
atahighertemperaturemore
moleculeshaveenoughkinetic
energy

thefractionofmoleculesthathaveakinetic
energythatexceedstheactivationenergyis

thisisalmosttheArrhenius equation
preexponentialfactorA:
noteverycollision issuccessful
hastheproperunits

4/1/2015

usesofArrheniusequation
determinetheactivationenergyofareaction

ReactionMechanisms
Whatgoesonatthemolecularlevel?
somebondsarebroken
otherbondsareformed
theremaybeintermediates

measurementofk atdifferenttemperatures
useslope ofArrheniusplot

determinetherateconstantatadifferent
temperature

ElementaryReactions
stepbystep reactions
one,two,orthree moleculesinvolved
molecularity oftheelementaryreaction
eachelementaryreactionproceedsatitsownrate

userateconstantk atT1 andEa

TeamScores

molecularityofelementaryreactions
amoleculefallsapartABA+B
unimolecular
rate=k[AB]

Points

Team

5.33
5.27

easier
nodifference

5.15

harder

Points

Team

twomoleculescollide:C+DCD
bimolecular
rate=k [C][D]

threemoleculescollide:D+E+FDEF
termolecular (veryrare)
rate=k [E][D][F]

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