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ABSTRACT
Calcium Hydroxide (Ca(OH)2) is a salt that is sparingly soluble. In this
experiment, molar solubility of this salt was observed and calculated obtaining
data from titration. After the collection of molar solubility, the K sp was calculated
with the use of the [OH-] and [Ca2+] in the aliquot after being titrated. The media,
where temperature was observed, was used to construct a Vamt Hoff plot which
yielded a function which is y = 4135.6x - 24.946 with an r2 of 0.8238. With this, a
Ksp of 1.560x10-5 was calculated at 298 K. Comparing it to the literature value for
Ksp Ca(OH)2 which is 5.5x10-6, it yielded a percent error of 83.4%.the Using this
function also, the enthalpy ( H) and entropy (S) of the salt was calculated which
yielded a result of 34.38 kJ/mol and -207.4 j/mol*K respectively, each having the
percent error of 104.3%( H) and 148.7% (S).
be contextualized by the equilibrium
constant for reactions like these.
INTRODUCTION
A solution is a homogeneous mixture
that has no visible components in it1.
Deconstructing a solution shows its
two main components: solvent and
solute. Solvent is a dissolving
substance and solute is the thing that
dissolves in a solvent1. Salt is an
example of a solute, which forms due
to the reaction of an Arrhenius acid
and base1. A kind of salt that partially
dissociate in water is a sparingly
soluble salt.
(1)
K sp=[A y+ ] x [Bx- ]y
Where
Ksp=
Constant
(2)
Solubility
Product
[A y+ ] , [Bx- ] =
Concentration, in M
x,y= coefficient in the reaction
lnK= -
H S
+
RT R
(3)
METHODOLOGY
The media, where Calcium hydroxide
(Ca(OH)2)
was
dissolved,
was
prepared in a 250-mL beaker. The
components and condition of the
media was specified in table 1.
Media
A
Solution
Condition
50 mL
Room
distilled
temperatu
H2 O
re
B
50 mL
Heated
distilled
H2 O
C
50 mL
In cold
distilled
water bath
H2 O
D
50 mL
Room
0.10 M
Temperatu
CaCl2
re
E
50 mL
Room
0.50 M
temperatu
KCl
re
F
45 mL
Room
distilled
temperatu
H2O+ 5
re
mL 95%
ethanol
Table 1. Media where Ca(OH)2 is to be
dissolved
The temperature for media A, B, and
C were recorded before adding
Ca(OH)2.
Calcium hydroxide was added to the
media while stirring vigorously until it
was saturated. The deposition of the
solid compound at the bottom of the
beaker indicated that the solution was
already saturated. The solution was
lnK vs 1/T
-9.5
-100
-10.5
-11
-11.5
-12
-12.5
-13
In media E, the presence of K+ and Clions gives the Ca(OH)2 a higher molar
solubility because of the diverse ion
effect or commonly known as salt
effect. Since there are other ions
present in the media which can
associate with each other, the amount
of the reactant/salt present will
dissociate into Ca2+ and OH-. A
decrease of reactants will push the
reaction to dissociate further to attain
equilibrium thus causing an increase
in the molar solubility.
CONCLUSION
y = 4135.6 298
APPENDIX
- 24.946.
y= -11.6= e-11.6=1.560x10-5
Sample calculations
d)
H
=4135.6
RT
a)Media A
Vtitrant
10.5 mL +10.8 mL
2
10.65mL
[OH-]
e) S=(-24.946)(R)
S= -207.4 j/mol*K
( 0.1 M ) (10.65 mL )
25 mL
0.0426M
[Ca2+] = s =
0.0426 M
2
= 0.0213M
b) Ksp= [Ca2+][OH-]2
Ksp=(0.0213)(0.0426)2=1.933x10-5
c) y = 4135.6x - 24.946.