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Summer 2013
GCE Chemistry 6CH08/01
Chemistry Laboratory Skills II
Alternative
Summer 2013
Publications Code US035580
All the material in this publication is copyright
Pearson Education Ltd 2013
/ means that the responses are alternatives and either answer should receive full
credit.
( ) means that a phrase/word is not essential for the award of the mark, but helps
the examiner to get the sense of the expected answer.
[ ] words inside square brackets are instructions or guidance for examiners.
Phrases/words in bold indicate that the meaning of the phrase or the actual word is
essential to the answer.
ecf/TE/cq (error carried forward) means that a wrong answer given in an earlier part
of a question is used correctly in answer to a later part of the same question.
Full marks will be awarded if the candidate has demonstrated the above abilities.
Questions where QWC is likely to be particularly important are indicated QWC in the mark
scheme BUT this does not preclude others.
Question
Number
1(a)(i)
Question
Number
1(a)(ii)
Acceptable Answers
Reject
Mark
Green
IGNORE qualifications of green such as
light / dark / emerald
(1)
Blue-Green
Turquoise
Reject
Mark
Carbon dioxide
ALLOW CO2
(1)
CO32
ALLOW HCO3
(1)
Acceptable Answers
[NiCl4]2
ALLOW
-2 for 2NiCl42- [Ni(Cl)4]2[Ni(H2O)2Cl4]2[NiCl6]4-
Question
Number
1(a)(iii)
Question
Number
1(a)(iv)
Ni(Cl)42-
Acceptable Answers
Reject
Ni(OH)2 / Ni(H2O)4(OH)2 /
Ni(OH)2 (H2O)4 /
[Ni(H2O)4(OH)2] /
[Ni(OH)2 (H2O)4]
Acceptable Answers
Reject
Mark
1
Blue-green
OR
(Green) precipitate dissolves
Mark
Precipitate dissolves to
give incorrect coloured
solution
Question
Number
1(b)(i)
Acceptable Answers
Reject
Mark
2
(1)
Question
Number
1(b)(iii)
Acceptable Answers
Reject
Mark
4 or more SF
Acceptable Answers
Reject
Mark
(1)
2
More needed to react
with unspecified
impurity
Question
Number
2(a)
Acceptable Answers
Reject
Mark
White smoke
Acceptable Answers
Reject
Mark
Just OH group
Hydroxide group
Acceptable Answers
Reject
Mark
Either aldehyde or
ketone on its own
Reject
Mark
ALLOW C=O
Question
Number
2(b)(iii)
Acceptable Answers
X is a ketone
Acceptable Answers
Reject
Mark
Hydrogen atoms in
phenol
Question
Number
2(c)(ii)
Acceptable Answers
Reject
OR
(b)
OR
(c)
(1)
triplet
triplet
singlet
(1)
(1)
ALLOW
If the side chain is (b) the triplet CH2
next to the C=O correctly labelled
scores one mark
Mark
3
O
CH 2
C
CH 2
CH3
(1)
triplet
If the side chain is (c) the triplets,
both labelled, score the mark.
O
C H2 C H2 C
triplet triplet
Question
Number
2(c)(iii)
(1)
Acceptable Answers
Reject
OR
O
CH2
CH2
CH3
Mark
Question
Number
2(d)
Acceptable Answers
Reject
Mark
(1)
Question
Number
3(a)(i)
Acceptable Answers
Burette /
(graduated / volumetric) pipette
Reject
Mark
2
(1)
(1)
Acceptable Answers
Reject
Mark
2
Pink / purple
(1)
Lilac
To colourless
(1)
Acceptable Answers
Reject
Mark
Acceptable Answers
Reject
Mark
OR
Electrical conductivity
pH meter
OR
So the concentration of each reactant
is proportional to the volume used
Question
Number
3(a)(iv)
Just titrate
Question
Number
3(a)(v)
Acceptable Answers
Reject
Mark
3
Acceptable Answers
Reject
Mark
3
(1)
IGNORE units
Points plotted correctly
(1)
(1)
Question
Number
3(b)(ii)
Acceptable Answers
Reject
Mark
Gradient = 10300
ALLOW any value in the range
-9600 to -11000
Positive gradient
Reject
Mark
Acceptable Answers
EA = (-) gradient from b(ii) x 8.31
2
(1)
Negative EA
Correct value:
EA = -(-10300) x 8.31
= 85593 J mol1 / 85.6 kJ mol1
Correct answer with no working scores
both marks
Gradient
-9600
-9700
-9800
-9900
-10000
-10100
-10200
-10300
-10400
-10500
-10600
-10700
-10800
-10900
-11000
EA/ kJmol-1
79.8
80.6
81.4
82.3
83.1
83.9
84.8
85.6
86.4
87.3
88.1
88.9
89.7
90.6
91.4
Total for Question 3 = 15 Marks
Question
Number
4(a)(i)
Acceptable Answers
Reject
Mark
3
(1)
(1)
Acceptable Answers
Reject
Mark
Sulfuric acid
KOH
NaOH
Heat with drying agent
Dry with filter paper
Reject
Mark
Acceptable Answers
Carry out in fume cupboard / hood /
chamber / well ventilated lab
(1)
IGNORE gas / face masks
Wear (protective) gloves
(1)
Question
Number
4(b)(ii)
Acceptable Answers
Reject
Mark
Just evaporate
Acceptable Answers
Reject
Mark
Acceptable Answers
Reject
85 mg = 0.085 g
(1)
Mark
2
% caffeine>100%
Acceptable Answers
Reject
Recrystallization
Mark
1
Distillation
Total for Question 4 = 12 Marks
Total for Paper = 50 Marks