Академический Документы
Профессиональный Документы
Культура Документы
Volume 9
Sponsored by:
Volume 9:
Electronic Properties
of Composite Materials
Maurice A. Leeds
This document has been approved for public release and sale;
its distribution is unlimited. Sponsored by U.S. Defense Supply
Agency, Defense Electronics Supply Center, Dayton, Ohio.
Under Contract No. DSA 900-72-C-1182
1972
CONTENTS
INTRODUCTION .
CERAMIC MATRIX
Aluminum Phosphate Reinforced with S-994 Fiberglass . . . . . .
FIBERS
Boron [Tungsten Core] . . . . . . . . . . .
Graphite and Carbon . . . . . . . . . . . .
Graphite-Polyacrylanitrile [PAN] Precursor
Glass . . . . . . .
Glass Fabric . . . .
High Silica Content Glass
Quartz. . . .
Quartz Fabric . . .
7
7
9
10
10
11
13
13
GLASS
Glass Aluminum. . . . . . . . . . . . . . . . . . . . . . . . .
LAMELLATE
Glass-Metal
15
19
LAMINATES
Carbon/Graphite-Epoxy
Carbon/Graphite-Polyester
Boron-Epoxy . . . . . . .
Fiberglass-Amide-Imide . .
Fiberglass-Diphenyl Oxide
Fiberglass-Acrylic. . . .
Fiberglass-Diallyl Isophthalate (DAIP).
Fiberglass-Diolefin
Fiberglass-Nylon . .
Fiberglass-Epoxy . .
Fiberglass-Phenplic
Fiberglass-Polybenzimidizole (PBI).
Fiberglass-Polybenzothiazoles (PBT)
Fiberglass Polyester.
Fiberglass-Polyimide.
Fiberglass-Silicone .
Fiberglass-Teflon . .
Polyester (Fiber)-Epoxy, Phenolic, Polyester.
PRD 49-Epoxy . . . .
PRD 49-Polyimide.
Quartz-Epoxy . . .
Quartz-Phenolic .
Quartz-Polybenzimidizol (PBI)
v
20
26
26
27
27
27
28
30
32
33
41
42
47
48
55
61
63
66
67
71
72
72
73
CONTENTS (CONT'D)
LAMINATES (Cont'd)
Quartz-Polyester
Quartz-Polyimide
Quartz-Silicone
Quartz-Teflon
77
78
80
80
METALLIC MATRIX
Unidirectionally Solidified Eutectics
Dispersion-Strengthened Nickel and Aluminum
Tungsten Fiber Reinforced Copper
Fiberglass Reinforced Aluminum . . . . . . .
MOLDED COMPOSITE
Asbestos-Polyester
Dacron-Diallyl Phthalate (DAP)
Fiberglass-Epoxy . .
Fiberglass-Melamine
Fiberglass-Nylon . .
Fiberglass-Phenolic
Fiberglass-Polybutadine
Fiberglass-Polyimide . .
Fiberglass-Polycarbonate
Fiberglass-Polyester
Fiberglass-Teflon
81
81
82
83
85
86
88
89
90
91
92
92
93
94
95
MISCELLANEOUS
Concrete Pavement
Asphalt Pavement
97
98
REFERENCES
99
vi
INTRODUCTION
Composites are the fastest growing class of structural material.
Consequently, electronic properties are often difficult to find. This
report was prepared in order to present a compilation of reliable data
on the electronic and electrical properties of composites.
Composites provide an opportunity to tailor the properties to the
application; a factor that allows designers an unlimited variety of
new materials for new uses. It is this feature that has contributed
to the rapid growth of composites.
The electrical properties of a composite can be of vital importance
in the use or application of the material in a system. The designer
therefore, must be able to obtain the necessary electrical or electronic
property data to guide him in the materials selection. It is the
purpose of this report to assist the designer and engineer in fulfilling
that requirement.
Properties This report provides a compilation of the most commonly
required electronic properties data of structural composites. Thermal
properties often influence electrical design; consequently several of
these properties are included. The specific properties tabulated are:
Arc Resistance
Arc Tracking Resistance
Dielectric Constant
Dissipation Factor
Electrical (Volume) Resistivity
Electrical (Volume) Conductivity
Thermal Conductivity
Linear Thermal Expansion
Coefficient
Other electrical and thermal properties are compiled as the data was
made available.
Materials The first requirement of a material for inclusion was
compliance with the definition adopted for composites. Structural
composites are defined as:
A homogeneous combination of two or more materials,
resulting in structural properties of the composite
superior to those of either constituent. Each phase
shall be identifiable on a microscopic or greater
scale.
Further classification was accomplished by the list of general types
included and specifically excluded as follows:
Included
Fiber/Polymer Matrix
Fiber/Metal Matrix
Fiber/Ceramic Matrix
Lamellates
Aligned Eutectics
Dispersion Strengthened Alloys
Mixtures (high impact strength)
Excluded
Metal Alloys
Non-structural composites
Solid State Electronic Devices
Electrical Contact Materials
A few other classes were included though not listed above because no
electrical data were available, i.e. Whisker/Matrix and Flake/Polymer
Matrix.
When selecting a material for this report, a major consideration
was that it be primarily useful as a structural component and that
electrical properties be secondary. For example, concrete or asphalt
for a highway is a structural material. However, the electronic
properties become important when high frequency electronic detectors
are embedded in order to monitor and control traffic. Boron and
graphite fiber/polymer matrix composites are excellent structural
materials, used in many applications including aircraft. In this
regard, electrical properties become very important with the possibility
of lightning strikes. Tungsten wire reinforced copper was developed
as a high strength material suitable for structural applications
(Reference 47). However, the excellent conductivity of this composite
makes it a suitable contender for power transmission.
Occasionally, composite materials with a borderline compliance
to the above criteria are included. This resulted when unusual or
unique materials were uncovered during the search and the electronic
properties were available. On the other hand, in a class of composites
having a large population of similar materials, a few representative
examples were selected from more than one readily available source.
In addition to the data itself, other information is provided.
With most citations a brief statement clarifying important parameters
is given. Additional material descriptions seemed superfluous
because it was assumed the engineer is familiar with the material
he is considering. Standard test methods stated in the reference
are included in the compilation because the author believes the value
of the data is greatly enhanced when the test method is given. Nonstandard test methods described in the reference are noted in tables
by an "R" or foot note. Where a "U" appears in the table, or no
reference to test methods is given, the reader may assume that they
are not known.
Data Sources A variety of literature provided the data for this
compilation. Included were reports from conferences, journals and
periodicals, books, government research reports and sales literature
from materials manufacturers.
ASSESSMENT OF DATA
The prec~s~on and accuracy* of the data in this report must be
carefully weighed by designers and engineers when determining the
degree of applicability to specific projects. Several factors that
should be considered are discussed below.
Composites are multiphase materials with two or more constituents.
Therefore, within a given class with more than one available source
for the constituents, the composite properties depend upon the constituents used. In addition, it is highly probable that the composite's
properties will vary from lot to lot of the constituents.
The process by which a composite is manufactured has many factors,
such as time, temperature, pressure, etc., each of which could influence
the properties. A feature of many composites is the ability to fabricate
the final shape with few or no intermediate operations. The tooling
used for this shaping could influence the properties. Very often
property data is determined on specimens of standard shapes formed in
special tools. The same material formed into a different shape may
have different values for the same property. This phenomenon is
characteristic of many composites because of the high incidence of
anisotropy.
Measurement accuracy is.dependent upon the test method, especially
when determining electrical properties. Accuracy is also influenced
by the care in application of the method and the equipment used.
Property data is also affected by other variables such as
Thermal and environmental history
Properties of constituents
Distribution of constituents
Presence of foreign matter including voids
Finally, reported values are influenced by material sampling techniques
and statistical analysis methods.
This report should be useful to the designer and engineer as a
guide to the electrical properties of composites. For design data,
however, closer contact to the references and other sources is advisable.
Many new composites are finding expanded use, yet electrical
property data is scarce. The references in this report identify the
sources of recent and current activity for a rapidly expanding and
changing information field.
CERAMIC MATRIX
Ref. 7
Thickness
030 inch
Dielectric
Constant
Loss
Tangent
3.44
0.0062
Ref. 8
1. 73
44.2
2.60
42.7
6.00
47.5
10.00
44.4
Ref. 54
DENSITY gm/ cm 3
HMG-50
HMS
YARN
TOW
1.68
1.84
1.35 x 10- 3
RESISTIVITY ohm-em
SPECIFIC HEAT cal/gm;oC
0.3
0.83 x 10- 3
0.3
Ref. 44
Carbon content
Unit
KCF-IOO
KGF-200
99.5
99.8
7.5 x 10- 3
ohm-em
Electric resistance
Thermal conductivity*
Coefficient of thermal expansion
Kcal/m hroC
1O-6;oC
3.0 x 10- 3
15.4
30-40
1.7
1.5
Ref. 5
20
60
40
80
Ref. 56
1-22
I
I-IS e-
'"81-14
~'"
'"
r:f 1-10
1-06
1000
2000
3000
HTT <."el
1000
3000
Ref. 30
GLASS
Material
Dielectric constant
(Hz)
Dissipation factor
tan 0
(Hz)
Surface
resistivity
(ohm/em)
6.43 at 10 2
6.11 at 10 10
0.0042 at 10~
0.006 at 10 10
10 15 *
6.8 at 5 x 105
0.007 at 5 x 105
10 12
"E" glass
fibers
"A" glass
fibers
Ref. 55
GLASS FABRIC
Frequency 1000 Hz
TOC
Dielectric
Constant
Dissipation
Factor
25
6.3
0.0037
10
Ref. 39
:!:I~ 1.5
,
:I:
::>'
tiiE:
b
':;:
:::J
u
c;;
1.0~-------+--------+_~~~+--~~--;_------~
'"
.c:
I-
'">
] O.5~-------+~.-=---+--------;---------r------~
i:i:i
O~------4~OO------~8~070----~1~20~O~--~1~6700~--~2~OOO
MEAN TEMPERATURE - of
B-)1
--...:=========== C100-48
500
-==========r;;i/C-100.28
N-Ya
- - - - - - - . - . : . . B-24
Cloth
C10028
C10048
Sleeving Thickness
Series B)1
.050
,013
Series NYa
Series B24
.007
0~--~~--~~--~~--~~--~2~500
TEMPERATURE - of
11
Thickness
.015
:027
Ref. 39
All Forms
~ VO~lume
Temp.
Resistivity
80F.
5 X lOB
1 X 10 14 *
5 X 1012
5 X 109
500F.
900F.
DIelectric
Constant
1.3 - 2.3*
1.5
1.5
Power Factor
Frequency
.001- .004-
60 cycle - 1 MC
.002
.001
60 cycle - 1 MC
1 KMC
'Depending on moisture content. The dielectric constant of pure non-porous silica is about 3.8.
12
QUARTZ
Ref. 61
K'
tan 0
25*
3.02
.0054
25
2.98
;0019
98
2.97
.0018
198
2.96
.0016
307
2.95
.0015
418
2.95
.0014
497
2.945
.0014
591
2.95
.0016
729
2.96
.0022
828
2.975
.0029
905
2.99
.0035
995
3.01
.0042
QUARTZ FABRIC
Ref. 55
Frequency 1000 Hz
TOC
Dielectric
Constant
Dissipation
Factor
25
3.7
0.0001
13
01
.....
"
10
20
" ....
--
30
-0-
\\\~ .
,, .,
,
"
'
'\~
\~
"
~
VOL.% OF GLASS
50
60
70
"
80
90
'\
"''!\
.0.
~,.~
'. ,
"
. "
~ ." ,
.. "
.~
CABAL (1.0CaO.2.0B 2 0 3 1 A1 20 3 )
""' '~,
.....
.......
~
ts.
---n, __
- -:::...... .
.........
--0
' .......
--_
."4 . . ~
~
40
---{]
0-._. --0
0- -
8 ~
10 ~
12 ~
14
16 ~
18 ~.
20 ~
22 ~
X 10-6
100
S
'"d
(J)
rt
1-"
(J)
(1)
p..
(1)
(l
1-"
!3
(1)
Pl
rt
(1)
p..~
()qo'
H1~
p..(l
p..
(1)
(1)
rt 1-"
1-"
(J)
!3 1-"
(J)
(l rt
0
!3 0
'"dt-n
Pl
(l'"d
rtO
(1) :E:
p..p..
!3 (l
1-" 0
(1)
H(J)
Pl
p..
Pl 0
(J)
Pl (l
(J) 0
()q
::r
(1)
I-j
:;.::l
t-n
(1)
:s::
c::
3::
c::
;J>
t"""
CIl
CIl
G'l
s;:
\~
....
0-
*'
..I
a:
xw
c..
en
.20
.40
.60
.80
400
TEMPERATURE,OF
600
800
200
1000
1.00 ~,-------------------------------------------------------------------------------------,
-1=
C1l
Ii1
'-'
t:::l
o
~
r-..
;J>
CJ)
CJ)
s;:
G')
......
::J
0
I-
>
u
I-
>-'
E
L:
0
'71
100
0.2
0.4
0.6
0.8
1.0
1.2
1.4 l-
1.6 l-
1.8 I.\-
2.0 X 10 5
\.
90
\.
\.
80
50
40
ALUMINIUM VOL. PERCENT
60
30
70
20
10
(.Jl
t-n
::0
(!)
'-...J
t::I
'-l
r--.
~
H
;J;>
t-<
(fl
(fl
s;:
CJ
LAMELLATE
Ref. 63
GLASS-METAL
Glassed Steel
Crys talli zed
Glass
Layer
Amorphous
Glass
Layer
Thermal conductivity
Ceramic component only.
Btu-in/hr f t 2 0p
Composite, 0.05 in. ceramic plus
11/16 in. steel, k/l
Typical chemical service. (liquid
product, steam jacketed
vessel), overall "U"
123
98
87
74
735
700
8.24
8.02
Dielectric strength
Volts per mil, room temp .
60 cycle
Dielectric constant
f = 10 6 cps
19
LAMINATES
Ref. 43
CARBON/GRAPHITE-EPOXY
1.18 x 10 3
Transverse
2.76 x 10 6
Longitudinal
16
Transverse
Thermal conductivity
(Btu./hr./ft. 2 /op/ft.)
Longitudinal
28
Transverse
0.8
20
0.21
....,
64.9
1.38
66.1
0.88
9.6
0.58
11.30
0.67
12.6
0.71
11.7
0.67
60% Type I ) L
S. Treated ) T
50% Type I ) L
Untreated ) T
40% Type II ) L
S. Treated ) T
50% Type II ) L
S. Treated ) T
60% Type II ) L
S. Treated ) T
50% Type II ) L
Untreated
) T
345
2.7
413
5.8
347
3.1
253
1.2
556
2.6
667
5.1
526
3.7
457
2.3
8.97
0.63
9.80
0.60
6.70
0.46
11. 70
0.30
15.40
0.65
9;87
0.50
C1010N/m2)
131
47
18
18
17
16
128
71
112
211
214
142
53
75
119
a:r
50
-*
-_ .. _-
51.1
0.96
50% Type I ) L
S. Treated) T
39.3
0.79
40% Type I
S. Treated
Composites
Sample
(W.m-l.oC-l)
-0.37
49.5
-0.18
57.0
19.5
-0.20
54.0
15.5
17.0
-0.035
73.5
17.0
1.41
1.44
1.40
1.30
1. 47
1.57
-1. 22
49.5
-0.47
57.0
1.48
1.38
Density
(kg.m- 3 x10- 3 )
-1.18
54.0
-1.06
73.5
a@100C
(0C- l x10- 6)
19.5
17.0
15.5
17.0
a@25C
(OC- l x10- 6)
5.1
7.0
6.0
9.2
4.2
1.9
3.4
5.8
Voids
%
M'l
;:;:l
(1)
'-'
>-1
,....,
><
-<
'"C
rr:
t:1
>-1
>-
:;c
Cl
t:l:'
n
>:;c
....en
>
..,>
.., ....
300
~
':' 400
51n28
c::
::s
::s
1-'0
rt
III
::srt
(1)
1-'-
I-j
I-j
(1)
0-
'Tl
1-'-
.....
III
::s
1-'0
rt
oj:>.
.....
H1
::0
(1)
'-'
I-j
(1)
0
Z
(")
1-'-
P.
1-'-
,....,
0-(
'"><
tT1
tT1
~
"0
::r:
I-t
.........
tx:I
@
C'l
--y
,--
(")
>
::0
Co)
'"
500
, = ANGLE
100
200
lAJ300
ex:
.....
en
en
t:400
>
>
..;'6
&00
SOOr
I-'
i-t)
::0
(J)
'-"
,-..
><
><
tTl
"0
tTl
~
"0
::r:
H
C'"l
Z
........
;t>
::0
tI::l
"'"
t-)
40
n.
x
Z
4
(/)
= ANGLE
../'
-10L------------------------------------------------------------------~
z 20t-
bJ
t&.
I&.
u 30
bJ
t-
(J
('")
......
.r::.
I-h
(1)
"
'-'
t:1
('")
r--
0-<
'"
~
ttl
ttl
1-1
~
::r:
C)
S;
CARBON/GRAPHITE-POLYESTER
Ref. 19
Resistivitr
ohm-cm 10Thermal Conductivity
.04 (25C)
BORON-EPOXY
Ref. 43
26
3.94 x 10 3
3.94 x 10 12
2.5
7.9
1.1
0.6
0.28
t-.)
til
30
"'"
><
n.
-1~~----------------------------------------------------------------------
10
Cii
z 20
0"'"
IlL
IlL
z 40
!!l
<.0
70
I-'
.j:::..
CD
H,
::0
'-'
,.-..
>-<
o
><
tTl
"0
tTl
I-f
~::c:
C)
..........
::0
FIBERGLASS-AMIDE-IMIDE
Test
Temperature,
Resin
Amide-imide
of
75
300
400
500
Ref. 55
Dielectric
Constant,
K'
4.29
4.37
4.31
4.53
Dissipation
Factor,
tan <5
0.018
0.016
0.016
0.038
Loss
Index
0.0772
0.0699
0.0690
0.1721
FIBERGLASS-DIPHENYL OXIDE
Resin
Test
Temperature,
of
Dipheny1-oxide*
75
300
400
500
Ref. 55
Dielectric
Constant,
K'
4.83
4.98
5.06
5.20
Dissipation
Factor
tan <5
0.024
0.023
0.027
0.027
Loss
Index
0.1159
0.1145
0.1366
0.1404
FIBERGLASS-ACRYLIC
Resin
Acrylic
Ref. 55
Test
Temperature,
of
75
300
400
Dielectric
Constant,
K'
3.88
4.63
4.63
Dissipation
Factor
tan <5
0.027
0.013
0.047
Loss
Index
0.1048
0.0602
0.2176
27
Ref. 55
Resin
DAIP
Test
Temperature
Dielectric
Constant,
of
K'
75
300
400
500
Dissipation
Factor,
tan <5
4.16
4.21
4.24
4.29
0.010
0.0-14
0.017
0.029
w
~ 4.5 c:
.!:!
~ 4.0
0.0416
0.0589
0.0721
0.1244
5.0
Loss
Factor
----------~~
0--
0;
o Diallyl Isophthalate
100
200
300
500
Temperature, OF
28
0.04
Ref. 55
o Oiallyl Isophthalate
0.01
100
200
300
Temperature. of
400
500
0.12
.0
Oiallyl Isophthalate
100
200
0.10
c:
~
X
-",
..: 0.08
.s
~
30.06
004
300
Temperature. of
400
500
29
Ref. 60
Poly-Preg
P 681**
Poly-Preg
P 680*
Dielectric Constant
3.9
9.3 GHz
10 6 Hz
10 3 Hz
4.1
4.4
Dissipation Tangent
0.014
0.013
0.016
9.3 GHz
10 6 Hz
10 3 Hz
FIBERGLASS-DIOLEFIN
Resin
Diolefin
Ref. 55
Test
Temperature
of
75
300
400
500
Dielectric
Constant,
K'
3.41
4.08
4.20
4.63
Dissipation
Factor,
tan 0
Loss
Factor
0.0120
0.0104
0.0086
0.0068
0.0409
0.0424
0.0361
0.0315
30
FIBERGLASS-DIOLEFIN (CONT'D)
Ref. 55
5.0
-w
~ 4.5
t::
'-'
4.0-
Ol
100
500
300
200
Temperature, OF
0.04
(; DioJefin
.0
c:
~ 0.03
c:
,g 0.02
~
.~
'"
100
200
300
Temperature, of
400
500
31
FIBERGLASS-DIOLEFIN (CONT'D)
Ref. 55
o1 4 , - - - , - - , - - - - , - - - , - - - - - , - _ - - - ,
0.12
I>
<0
Diolefin
0.10
-w
~.
0.08
~
~
0.06
0.04
100
200
300
Temperature. OF
400
500
FIBERGLASS-NYLON
Ref. 48
on Fiberglass
Dielectric Constant
Dissipation Factor
Dry
16 Hrs
100% RH/120F
Dry
16 Hrs
100% RH/120oC
4.5
8.3
0.035
5.2
Silane Y-5l08
4.2
4.2
0.035
0.53
Silane Y-4087
4.7
5.2
0.037
0.50
None
32-
MIL-R-9300
MIL-R-9300
Test
Method
Dissipation
Factor
10 3 Hz
* Flame resistant
Dissipation
Factor
10 6 Hz
Dissipation
Factor
MIL-R-9300
9.37 Hz
Dry
Dissipation
Factor
MIL-R-9300
9.37 Hz
Wet
Dielectric
Constant
10 6 Hz
Dielectric
w Constant
w
10 3 Hz
Dielectric
Constant
9.37 GHz"
Wet
Dielectric
Constant
9.37 GHz
Dry
Property
0.010
4.55
F155
(28)
.012
.011
4.4
4.4
F16l
(28)
0.007
0.016
4.82
4.76
Poly-Preg
E-705
(60)
"-
0.018
4.68
Poly-Preg
E-741D
(60)
0.022
4.7
Poly-Preg
E-777
(60)
0.005
0.012
5.15
4.86
Poly-Preg *
E-780
(60)
0.167
4.6
F-153
(28)
1-'-
Ii
I-f)
00
.....
(I)
'<
H
rt
Vl
1-'Vl
p..
(I)
Vl
s::
Vl
Vl
$I)
OQ
H
Ii
(I)
0'
1-'-
I-f)
(I)
::f
>-<
><
'"0
ttl
(f.l
(f.l
s;:
CJ
:;0
gJ
'Tl
FIBERGLASS-EPOXY (CONTID)
Resin
Test
Temperature,
of
Ref. 55
Dielectric
Constant,
K
Dissipation
Factor
tan 0
Loss
Index
Epoxy 1
75
300
400
500
4.06
4.30
4.39
4.44
0.015
0.033
0.037
0.042
0.0609
0.1419
0.1624
0.1865
Epoxy 2
75
300
400
500
4.78
4.61
5.28
5.43
0.015
0.018
0.021
0.025
0.0717
0.0830
0.1109
0.1358
Epoxy
novo1ac 1
75
300
400
500
4.65
4.61
4.99
0.019
0.023
0.050
0.0884
0.1060
0.2495
Epoxy
novo lac 2
75
300
400
500
4.68
4.97
5.31
0.013
0.022
0.061
0.0608
0.1093
0.3239
Epoxy
acrylate
75
300
400
500
4.59
5.16
0.025
0.042
0.1148
0.2167
34
Ref. 43
FIBERGLASS-EPOXY (CONT'D)
S-Glass Fabric
Electrical resistivity (microhm-in.)
Longitudinal
3.94 x 10 19
Transverse
3.94 x 10 19
Longitudinal
11.4
Transverse
Thermal conductivity
(Btu-in. jhr ft 2 F
Longitudinal
0.17
Transverse
0.12
0.24
Ref. 61
.'
0 ,0)
F-~4..'-i
. I-"-H.f--+
' :l'--l'4-1-""-1' -l-',.-+~
,.J....j.=~~J- TOe
~FF-.-
1-- 1"
,
"
i;.
Elap.ed
tlm~(mtn.)
11
)0
~
6l
SO
81
99
II )
1 )0
0-
3.0
100
TEMPERATURE f'J of
'TJ
III
0'
::r
til
1-"
::I
'TJ
1-"
C/l
1-"
Ii
......
...J
.....
(I)
'<
.....
C/l
C"+
til
til
III
.....
VI
I-h
;:0
(I)
'-'
0-3
~
I
G)
(j
,.-..
><
tTl
C/l
C/l
tTl
to
'TJ
C/l
00
3.5
4.0
4.5
'5.0
U
W
0::
u
u
z
~
en
z
5.5
6.0 --~~~~~~r-r-r-r-~~
Co)
.....
.021
(J)
(J)
o
100
t'V
700
TEMPERATURE
of
.003
.006
.009
.012
~ .015
zc::{
LLJ) . 018
c
....
Z
.024
.027
.0301r---~--~--~--~--~----~--~--~--~--~----~~
'Tl
(N
I-h
:::0
<D
o....J
,......
0-<
ttl
"tJ
en
en
G")
:::0
tx:l
ttl
FIBERGLASS-EPOXY (CONT'D)
Ref. 30
Cycles
~ 8
<{
IUJ
U 7
Q:
I-
W
...J
06
4~
40
________
~~
80
________
~~
________
120
TEMPERATURE(OC)
~~
160
______
~~
200
38
Ref. 30
FIBERGLASS-EPOXY (CONT'D)
10
0.6
0.2
Z
<f
f-
0.1
lLJ
--'
(') 0.06
<f
V>
V>
..J
0.02
0.01
0.006
39
Ref. 30
FIBERGLASS-EPOXY (CONTID)
E1012
.;
w
u
z
0V!
V!
a:
108~------~1~0~O----------------~2~0~0~--------------~30C
TEMPERA TURE(O F)
40
Ref. 55
FIBERGLASS-PHENOLIC
Resin
Phenolic
Test
Temperature
of
K'
Dissipation
Factor
tan 0
Loss
Index
4.26
4.59
4.67
5.13
0.022
0.039
0.042
0.096
0.0937
0.1790
0.1961
0.4925
Dielectric
Constant
75
300
400
500
Ref. 28
1 Megacycle
5.92
5.92
0.021
0.024
3000 Megacycles
4.23
---
0.083
---
2.05
5.55
4.60
5.55
41
x
x
x
x
10 13
10 12
10 13
10 12
Ref. 55
FIBERGLASS-POLYBENZIMIDIZOLE (PBI)
Resin
of
75
300
400
500
Polybenzi
midazole
K'
Dissipation
Factor
tan 0
Loss
Index
4.02
3 . 94
4.08
4.20
0.0120
0.0080
0.0096
0.0087
0.0482
0.0315
0.0392
0.0365
Dielectric
Constant
Test
Temperature
Ref. 61
..
. ..
!: l; :~ . .
~
i'i +:tGP
::.~'t'H
~~ttt:dl-tttmM
4.8H-l-+,;'F'4
.- '~
" I--.. +-:-I!-":+.:. F.
...+.;:.,.
.. ('-+++-1~
F+==t-.j....J,,"",
l:-+__--I-+-I~--1
K'
~4
-+.,+'....
."1":+.'. 1-.'+ ;.' F' ...j-/i,,
' "$..=-+. ++
';il-' +-1-+-+-+-1-:+4 -=+=
-~::jo...,J..-t-:
...
,;
i' I;'!,
....
Ii';':
r--..
I;';,,:,;
!1-'
w... H
V
Hi
:iii
1'"
.. .
ji
Y-
; / ":
i:'
i-
.:i'L
Temperature (Oe)
42
Ref. 3
C/)
o
(,)
(,)
0:::
~
(,)
UJ
.....J
UJ
3.6
3.5
3.4
3.3
3.2
3.0~--------~----------~--------~----------~--~
50
100
150
200
43
~
~
(/)
(/)
(!)
IJJ
....
Z
100
AF -R-IOO/E GLASS
TEMPERATURE rv of
200 300 400 500 600 700 800 900 1000 1200 1400
JJ
.003
.006
.009
.012
.015
.018
.021
@ 8.5 KMc
t-
.024
--1
.027~
.030
('I)
tN
I-t)
:::0
'-'
t-j
,.....,
I-<
"0
ttl
r-.
t'""'
tTl
I-<
I-<
3:
I-<
zN
t'T1
o::l
o-<
t-
"0
CIl
(IJ
s;:
&S
t'T1
o::l
'"r:I
I-<
t;
5.0
o-r--_
O-Q
AF-R-IOO/E GLASS@8.5KMc -0-.-----0
TEMPERATURE ~ of
100 200 300 400 500 600 700 800 900 1000 1100 1200
3.0
UJ 3.5
...J
IU
UJ
~
en 4.5
z
0
u
u
~ 4.0
.z
5.5
6.0.r----T---~----~----~--~----~----r_--~----~--~~--_r----~~
(l)
(".I
Jot,
::0
'>..J
t:1
>-i
(")
,.....,
'>..J
'"'"
,.....,
t""
tTl
t:1
3::
0<
t""
'"o
CIl
~
~
'Tj
H
Ref. 3
.0122
.0114
.-----,------.--------,.-------r-----,
o
o
~----Jo...I...----------------
.0106
PBI/S-994
.0098
.0090
.0082
I-
ILl
(!)
.0074
.0066
~
en .0058
en
0
...J
.0050
.0042
.0034
.0026
.0018
PBI AF-R-IOO
.0010
.0002
100
50
150
200
FIBERGLASS-POLYBENZOTHIAZOLES (PBT)
Ref. 3
.016
~
.014 I -
IJJ
t!)
(/)
(/)
0
..J
.012
I-
~~
.010 ! -
.008
'-
.006 0
100
200
300
I
400
500
600
100
200
300
400
500
600
5.0
~
<4
I"-
4.9
Z
0
4.8
u
(.)
:l:
~
4.7
lLJ
..J
i.LJ
4.6
4.5 0
TEMPERATURE,...., of
47
FIBERGLASS POLYESTER
Composition is mineral filled polyester resin reinforced
with random fiberglass mat.
Glastic
TSF
(25)'"
Glastic
UTS
Flame
Retard
(25) *
Glastic
Rod
Stock
(24) *
400
350
150
250
250
150
(150C)
40
15
40
15
10
3.0
2.5
5.0
Property
Test
Method
Dielectric Strength, ST
Condition A
ASTM
D 229
V/mil
Dielectric Strength, ST
After 200 hrs at 200C
ASTM
D 229
V/mil
Parallel Dielectric
Strength, SS
Condition A
D48/50
ASTM
D 229
kV
Power Factor
60 cycles
ASTM
D 150
Dielectric Constant
60 cycles
ASTM
D 150
Arc Resistance
Condition A
ASTM
D 495
seconds
Arc Tracking
Resistance
ASTM
D 2302
minutes
Thermal
Conducti vi ty
ASTM
l;oF
C 177 ~tu/hr/ft2/i
Thermal Expansion
Coefficient
ASTM
D 690
Units
5.0
in/inoC
120
120
120
120
25
2.0
48
2 x 10- 5
Ref. 55
FIBERGLASS-POLYESTER (CONT'D)
Resin
Dissipation
Factor
tan 0
Dielectric
Constant
Test
Temperature
of
K'
Loss
Index
Polyester 1
75
300
400
500
4.15
4.23
4.36
4.40
0.012
0.021
0.025
0.036
0.0498
0.0888
0.1090
0.1584
Polyester 2
75
300
400
500
4.68
4.73
4.70
5.01
0.011
0.025
0.035
0.0515
0.1183
0.1645
TAC polyester
75
300
400
500
4.35
4.37
4.41
4.46
0.015
0.017
0.016
0.018
0.0653
0.0743
0.0706
0.0803
"E" glass style 181 fabric with approximately 35 percent resin content.
Properties measured at 9.35 GHz.
O.
14.----,----,,-------,----,---,---~
0.12 .
o Tae Polyester
""
0.10
-w
..: 0.08
~
3 006
004
100
200
300
Tem~erature.
OF
400
500
49
FIBERGLASS-POLYESTER (CONT'D)
Ref. 55
5.0
-",
___
~ 4.5 c:
o
u
0------
--n-~~----~&---~-
~ 4.00;
DTac Polyester
100
200
300
Temperature, OF
500
0.04
D Tae Polyester
00
~. 0.03
0.02
.~
-----------~~---~
0-
0.01
100
200
300
400
Temperature, OF
500
FIBERGLASS-POLYESTER (CONT'D)
Property
Dielectric Constant
9.36 GHz
Dry
Wet
Test
Method
MIL-R-7575
F14l
(28)
F149
(28)
Poly-Preg
P 603
(60)
Poly-Preg
646
(60)
3.99
4.25
4.33
4.31
Dielectric Constant
10 6 Hz
Dry
Wet
FSTM
406
Dielectric Constant
10 3 Hz
Dissipation Factor
9.36 GHz
Dry
Wet
FSTM
406
MIL-R-7575
FSTM
406
Dissipation Factor
10 3 Hz
FSTM
406
4.48
0.0106
o.Oll
0.0096
0.0120
0.012
0.008
51
Dissipation Factor
10 6 Hz
Dry
Wet
4.27
2.4
2.5
0.015
0.016
FIBERGLASS-POLYESTER (CONT'D)
Ref. 48
Temperature c
20
37
87
137
187
237
260
20
Dielectric Constant
Loss Tangent
4.49
4.60
4.69
4.74
4.70
4.72
4.75
4.47
.014
.015
.018
.018
.018
.018
.020
.Oll
52
FIBERGLASS-POLYESTER (CONT'D)
I-
I-
<{
I-
'"U
W
l?f:g;;
VJ
-' Z
W 0
-0
Ref. 30
:1
o. 2
/
V
o.1
0.0 7
0.0 5
0.0 3
." 0.02
<{
0.0 1 _
0.007
0.005
0.003
-80
-40
f--
---.?::-
80
~...c::.
40
1
1
160
120
TEMPERATURE(OC)
Electrical Properties *
Arc Resistance, sec .....
Dielectric Strength
Perpendicular, S.T., volts/mil.
Perpendicular, S.S., volts/mil.
Parallel, S.T., kv.. . ........ .
Parallel, S.S., kv ....
Dielectric Strength, wet.
Perpendicular, S.T., volts/mil
Perpendicular, S.S., volts/mil..
Parallel, S.T., kv.
. ..
Parallel, S.S., kv.
. ... .
Power Factor, 100 cycles, 'Yo ..... .
])i('lcctrie Constant
....... .
Volume I{esistivity, ohm-em.
Surface Resistivity, ohm ........ .
Insulation Resistance, ohm .... .
Track Resist., inclined plane, min.
As Molded
(2.5 min at 240F)
(0.5% USP-245)
Post Cured
(16 hrs at 135C)
( 2 hrs at 180C)
( 2 hrs at 200C)
Aged
(10 days at 220C)
170-180
175-185
185-195
470-480
450-460
65-70
60-65
485-495
460-470
60-65
55-60
495-505
470-480
55-60
50-55
0.85-1.05
4.1-4.3
1.0-1.2
4.1-4.3
lAS X 10'
1.0 X 10"
1.0 X 10"
650-700
lAO X 10'0
>
>
750-850
485-495
470-480
55-60
50-55
1.4-1.6
4.1-4.3
0040 X 10'
1.0 X 10"
> 1.0 X 10'"
>
FIBERGLASS-POLYESTER (CONTID)
Ref. 16
70
60
a:: 50
....0
~ 40
a::
~
Q.
30
t!- 20
10
0
0
50
100
150
200
250
300
TEMPERATURE, "C
54
<.n
<.n
3.5t-
~
CJ)
oZ
lLI
frl
...J
a::
(.)
(.)
3.2'
3.31-
3.4t-
3.61
3.71
I
600
400
I
800
200
1000
(N
I-t)
::tl
(\)
ttl
t:l
3:
><
H
t""'
"d
C/)
I
>C/)
t""'
tJ:I
ttl
'T1
Ot
0.
fI)
fI)
LIJ
...Z
"Z~
200
400
600
.00400
.ooeol-
.0060 ....
TIME AT 600F,..,HOURS
800
1000
OO7
'
-I
.00801-
.0090 1
'Tl
VI
H)
(1)
::tl
'-'
t:l
>-3
,-..
tTl
t:l
:s:
0
t.0-<
."
en
en
I
G)
::tl
tI:I
tTl
Ref. 3
FIBERGLASS-POLYIMIDE (CONTID)
.010r-------~------~--------~------~------~------~
z
w
(!)
~ .008
en
en
o
..J
.007
.0060
.....
z
~
en
z
100
200
300
400
500
600
100
200
300
400
500
600
4.3
4.2
(,)
4.1
u
a:::
....
4.0
IJJ
..J
IJJ
0
3.9
(,)
3.8 0
TEMPERATURE
I"oJ
of
57
FIBERGLASS-POLYIMIDE (CONT'D)
Resin
Test
Temperature
of
Ref. 55
Dielectric
Constant,
K'
Dissipation
Factor
tan <5
Loss
Index
Po1yimide 1
75
300
400
500
3.81
3 . 88
3 . 89
4.01
0.0075
0.0117
0:0075
0.0111
0.0286
0.0454
0.0292
0.0445
Po1yimide 2
75
300
400
500
4.20
4.30
4.34
4.34
0.0071
0.0082
0.0110
0.0150
0.0298
0.0353
0.0477
0.0651
Ref. 61
Glass Fabric
4,6
4. 6
"
"
4.1
' ,1
0.010
..
0.010
....
0.0 16
....
0.01'
o.OIl
0.012
0.00 1
0. 00'
IS
4.
10J
197
I.
))Z
41 .
Sl9
409
195
'OJ
91
107
IZO
...
55
>69
70
71
IS
0 . 004
'00
ZOO
100
400
soo
600
TOe
58
* ASTM
0.015
0.014
0.018
0.013
0.010
0.015
3.74
3.74
3.74
3.74
3.74
3.70
100C
150C
200C
250C
300C
Room Temperature
50C
Dissipation Factor
4.81
.01650
4.30
.00639
32,000
16,000
D 48/S0*
D 24/23*
0.016
Dielectric Constant
ASTM D618-61
55,000
38,000
179
140
4.10
.00445
1.9 x 10 7
2.47 x 1015
3.35 x 10 14
As is
Laminates *
3.74
Temperature
conditioning procedures,
Dielectric strength
Short time parallel to laminate (volts)
Step-by-step parallel to laminate (volts)
Short time (volts/mil)
Stepwise (volts/mil)
Dielectric Constant (lMC)
Dissipation Factor (lMC)
Insula~ion resistance (megohms)
Volume Resistivity (ohm-ems)
Surface Resistivity (ohms)
Property
Skybond 700
1.4 x 10 2
1.16 x lOll
2.90 x 10 10
C96/3S/90*
V1
(1)
"H1
'-'
n
~
otTl
1-1
3:
o
t""
-<
1-1
"tl
en
5:en
~
~
1-1
'T.I
FIBERGLASS-POLYIMIDE (CONT'D)
Property
Test
Method
Dielectric
Constant
8.5 GHz
Dielectric
Constant
10 6 Hz
Dissipation
Factor
8.5 GHz
Dissipation
Factor
10 6 Hz
Thermal
Conductivity
Thermal
Expansion
Coefficient
_70 to 90C
90 to 170C
170 to 400C
Units
F170 *
(28)
Fl7l *
(28)
3.74
Pyralin **
Pyralin ***
Cll)
(ll)
3.76
3.9
3.9
0.016
0.015
0.014
4.1
0.016
0.0044
cal/cm secoC
in/in;oC
4.36 x 10- 4
0.74 x 10- 5
0.34 x 10- 5
0.69 x 10- 5
60
Ref. 55
FIBERGLASS-SILICONE
Resin
Silicone
Test
Temperature
of
75
300
400
500
Dielectric
Constant
K'
3.98
4.17
4.31
4.46
Dissipation
Factor
tan 0
Loss
Index
0.0081
0.0069
0.0066
0.0070
0.0322
0.0288
0.0284
0.0312
61
FIBERGLASS-SILICONE (CONT'D)
Test
Method
Property
Dielectric
Constant
9.36 GHz
Dry
Dielectric
Constant
9.36 GHz
Wet
Dielectric
Constant
10 6 Hz
Dry
Dielectric
Constant
10 6 Hz
Wet
Dissipation
Factor
9.36 GHz
Dry
Dissipation
Factor
9.36 GHz
Wet
Dissipation
Factor
10 6 Hz
Dry
Units
MIL-R-25506
F130*
(28)
F13l*
(28)
3.946
MIL-R-25506
F130**
(46)
POly-Preg
5860*
(60)
3.60
4.17
0.002
0.013
4.021
MIL-R-25506
MIL-R-25506
MIL-R-25506
4.03
3.9
4.12
4.0
0.0082
MIL-R-25506
0.0106
MIL-R-25506
0.0019
0.002
0.0075
0.010
Dissipation
Factor
10 6 Hz
Wet
MIL-R-25$06
Dielectric
Strength
9.37 GHz
V/mil
100
Arc ResistaI ce
9.37 GHz
seconds
244
* E glass
** D glass
62
Ref. 57
FIBERGLASS-TEFLON
ASTM Method
Test Values
D149-55T
D153l-58T
D153l-58T
MIL-P-13949
MIL-P-13949
D257-57T
300
2.35
0.0005
2.35
.0012
63
D495-56T
U
3.0 x 10 14
3.0 x 10 14
2.0 x 10 13
2.0 x 10 13
No track up
to melting
at 180 sec.
1.6
4.0
10.0
1.0
2.0
10.1
1.8
FIBERGLASS-TEFLON (CONT'D)
Ref. 57
----- ~----
RT/dUlid 5870
--
2.30
2.20
106
107
108
10 10
.0010
.0005
I""""""'
----'~....----' """"
107
108
64
,,'"
1010
FIBERGLASS-TEFLON (CONT'D)
Ref, 61
F1uorg1ass E 650/2-1200
E
Freq. , GHz
TOe
8,5
23
-195
.L
II
tan 0
tan 0
2.505
.0014
2.847
.0036
2.533
.00082
2.896
.00172
DiC1ad-522
All values of tan
E 1. sheet
TOe
25
100
250
-78
-195
-269
10 2
10 3
10 4
105
10 6
10 7
2.739
8.6
2.740
7.0
2.738
6.7
2.737
6.1
2.735
6.3
2.734
6.95
2.733
7.7
<5
2.710
11.1
2.705
8.10
2.704
8.25
2.698
7.17
2.696
7.07
2.683
7.7
<5
2.554
79.0
2.534
36.3
2.522
20.35
2.503
14.9
2.502
11.6
2.49
10.6
<5
2.796
4.2
2.793
5.9
2.790
6.8
2.784
7.1
2.78
7.7
2.78
9.8
K
<5
1 tan
K
1 tan
K
1 tan
<5
2.801
.0005
2.799
2.2
2.794
4.5
2.792
5.1
2.787
5.4
<5
2.789
.0003
2.789
1.2
2.784
2.0
2.783
2.2
2.780
2.1
1 tan
K
1 tan
* Ca.pper
multiplied by 10 4
10
Freq, (Hz)
1 tan
<5
25
cavity
100
250
-54
-195
Freq. (Hz)
3xl0 8
3.155
28
tan
<5
2.4x10 1O
3.146
40
3.133
48
3.127
52
3.03
36
<5
3.17
35
3.13
39
<5
3.22
28
3.12
31
tan
1.4x10 1O
<5
tan
8.5x10 9
3.11
39
tan
3x10 9
3.152
33
<5
tan
10 9
3.153
30
65
2.732
10.0
9xl0 7
3.14xl0
2.731
11. 7
2.712
22.5
2.680
31
2.752
17
2.758
12
E II sheet
TOe
5.5xl0 7
9~
8:
Dielectric Constant
(1 mc)
Dielectric Str. Perp. St
Par. SXS kv
Insulation Resistance
Surface Resistance
vpm
kv
m ohm
m ohm
Units
048/50
C-96/35/90
C-96/35/90
024/23
Condo
3.2-3.4
3.3-3.6
917
80-110
10 9 -10"
10 8 -10"
Epoxy
Matrix
75
10 9
10 8
3.9
4.0
XXXP
Phenolic
Matrix
10 9
90
4.0
4.0
X
Phenolic
Matrix
70
10 9
lOll
3.1
3.1
Polyester
Matrix
"0
ffi
.....
V1
(I)
I-t)
::0
::0
tTl
~
~
t'"""
"0
t'"""
"0
o
><
0-<
"0
rn
'--'
::0
'Tl
r--..
::0
rn
rn
t'"""
0-<
~
77
315
Epon-828
"
54
"
"
"
77
"
"
"
"
49- I II
(120 Style)
77
"
"
"
"
P5289-25
315
"
"
"
"
---
---
After 24 hrs
in H2O
After 315 of
measurement
---
---
"
"
"
---
77
BP-907
Condition
58
of
Temp.
Resin
vlo
Fiber
"
49-111
(120 Style)
Fiber
"
P5289-l8A
Sample
4.05
3.68
to E
to E
to E
to E
to E
II
II
II
3.88
3.45
3.65
3.67
to E
3.25
1 to E
II
II
II
Dielectric
Constant
Fiber
Orientation
0.0406
0.0159
0.0186
0.0167
0.0509
0.0127
0.00995
Loss
Tangent
'"tl
......
I-t)
::0
CD
tTl
'"tl
\.0
.;:.
::0
Ref. 10
v/o
Fiber
Thermal Conductivity
Btu/hr1ft 2 F/ ft
46
0.123
46
Parallel to wrap
0.525
0.122
Unidirectional
59.5
54.0
Transverse to fibers
0.087
Unidirectional
54.0
Parallel to fibers
1. 01
Fiber Form
68
Ref. 59
9.3 GHz FREQUENCY
-I
4.0
\
~
PRD49-1/BP907
---
OIELECTRIC
CONSTANT
EPOXY RESIN SYSTEM GOOD
ONLY TO 3000 F
3.0
200
100
TEMPERATURE DEGREES F
0.02 ,...-------,--------...----,
PRD49-1/BP907
LO$
TANGENT
~.01 It-___~~~..==~~~~
181 E-GLA$/POL YMIDE
0.001
100
200
TEMPERATURE DEGREES F
69
300
......
+41.0 (+23)
-3.2 (-1.80)
+41. 0 (+23)
-5.8 (-3.22)
+56.0 (+31)
-7.6 (4.22)
+93.0 (+52)
+61.0 (+34)
90
(0)
+30.0 (+17)
+20.0 (+11)
+38.0 (+21)
-4.95 (2.75)
+101.0 (+56)
+45.0 (+25)
90
+1.0 (+0.56)
-6.6 (-3.7)
-3.68 (-2.0)
Composite
C>
Test
Direction
Coefficient of Thermal Expansion for Unidirectional PRO 49-1 Fiber Reinforced/Epoxy Composites
Unidirectional Fiber Orientation
'"0
N
\D
t-t,
(1)
::0
'-'
t:J
t-3
r---
o
><
0-<
tTl
'"0
\D
PRD 49-POLYIMIDE
Ref. 59
RESIN
POLYIMIDE
(P13N)
Vf %
TEMP.
(OF)
48
70
100
200
225
275
300
400
500
600
3.40
3.42
3.47
3.46
3.42
3.39
3.40
3.45
3.52
0.00645
0.00727
0.00792
0.00775
0.00726
0.00717
0.00973
0.0148
0.0210
36
70
100
200
250
300
400
500
600
3.28
3.29
3.31
3.32
3.30
3.31
3.39
3.45
0.00505
0.00555
0.00621
0.00654
0.00660
0.00889
0.0132
0.0194
71
DIELECTRIC
CONSTANT
LOSS
TANGENT
Ref. 55
QUARTZ-EPOXY
Resin
Reinforcement
Epoxy
novo1ac 1
120 glass
503 quartz
Dielectric
Constant,
K'
4.55
3.46
Dissipation
Factor,
tan <5
0.0865
0.0519
0.019
0.015
Loss
Index
Property
Fabric Description
Epoxy
Epon 828/CL
Oz/sq yd
Weave
Finish
Dielectric constant
X-band, dry-room temp
(9,375 megacycles)
Loss tangent
X-band, dry-room temp
8.4
8H satin
AlIOO
Ref. 46
3.470
0.0092
QUARTZ-PHENOLIC
Ref. 46
Property
Fabric Description
Phenolic
V-204
Oz/sq yd
Weave
Finish
Dielectric constant
X-band, dry-room temp
(9,375 megacycles)
Loss tangent
X-band, dry- room temp
8.4
8H satin
AlIOO
72
3.86
0.040
QUARTZ-POLYBENZIMIDIZOL (PBI)
Ref. 46
Property
Fabric Description
PBI
AF-R-IOO
Oz/sq yd
Weave
Finish
Dielectric constant
X-band, dry-room temp
(9,375 megacycles)
Loss tangent
X-band, dry room temp
8.4
8H satin
AIIOO
3.360
0.0034
Ref. 3
.0066
.0058
.0050
t-
lLJ
.0042
C)
z
~
en
en
0
PBI/Quartz
.0034
.0026
..J
o PBI
.0018
.0010
.0002
50
100
150
200
3.0
3.5
4.0
4.5
5.0
o
100
9.375 KMc
TEMPERATURE f ' I of
200 300 400 500 600 700 800 900 1000 1100 1200
000
AF-R-IOOIQUARTZ
t.aJ
...J
t.aJ
0
(,)
(,)
(,)
~
CJ)
5.5
ao.--~~~~~r-r-III1I1I1~
(1)
().:I
I-t!
::0
'-'
0:1
'"......
o
t""
,.....,
t:I
......
3:
......
......
o
t""
><
'"
>
'8
til
LaJ
..J
LaJ
-a::
....0
CJ)
FZ
50
150
PBI/Quartz
T I ME AT 600F"-I HOURS
100
3.0
3.2
3.3
3.4
200
PBI AF-R-IOO
3.7 -.-----~----_r_-----r___----~-__,
VI
I-i)
::tI
(1)
1-1
'-'
'"I::l
,-.
t""
1-1
t:l
:s:
1-1
1-1
g;
><:
t""
'"I::l
>-
'8
CJ)
CJ)
t=!
(!)
lLJ
o
100
'"
TEMPERATURE "-I of
200 300 400 500 600 700 800 900 1000 1200 1400
AF - R- 100/ QUARTZ
@ 9.375 KMc
.003
.006~
.009
.012
.015
.018
.- .021
.024
.027
.030
::0
CD
VI
I-t)
'-'
'1:::l
tI:1
r"\
t"'"
:s::
to(
t"'"
'1:::l
QUARTZ-POLYESTER
Ref. 55
Dielectric
Constant
Dissipation
Factor,
tan 0
Resin
Reinforcement
Polyester 1
503 quartz
3.45
0.005
0.0173
TAC polyester
503 quartz
3.19
0.010
0.0319
Resin
DAIP
Reinforcement
503 quartz
Resin
Reinforcement
Diolefin
503 quartz
K'
Loss
Index
Dielectric
Constant
K'
3.40
Dissipation
Factor,
tan 0
0.005
Loss
Index
0.0170
Dielectric
Constant
K
2.81
Dissipation
Factor,
tan 0
0.0039
77
Loss
Index
0.0110
QUARTZ-POLYIMIDE
Ref. 55
Dielectric
Constant
Reinforcement
Resin
Polyimide
KI
503 quartz
Dissipation
Factor
tan 0
Loss
Index
0.0049
0.0155
3.16
Polyimide PBI-373.
Ref. 2
A-730-2
A-714-1
.54
.28
Specific Gravity
1.64
1.68
35.0
34.8
5.7
5.5
3.27/.008
Thickness, in.
3.17/.003
500F
2.21/.003
600F
3.00/.004
400op-500F
500F-600op
Spec. 1
2.31
2.50
1.50
1.77
3.25
1. 75
2.23
2.2.5
1. 75
Avg
2.10
2.67
1.67
Temp. Range
. j"1n 0p :
CTE 10- 6 1n
Laminate #A-714-1.
QUARTZ-POLYIMIDE
Ref. 2
I,
3.40
I
1-----!
i
:z:
(!J
,....,
1.0
r;
0\
3.30t--+-~~~-+---+-
e
+0)
s::
is 3. 10 t--+'
.008
:z:
(!J
+-----+---+----+1--
!!
+0)
.004
t:
QJ
0)
t:
....
ttl
VI
VI
-'
.002
.000
i
~!
i-
-r---
I
t
-t-i- !
t----- I -----,
Lh
I
0\
I -
--i---J-T~k ~ -r---j--+--L
----- ---
,...., .006
1.0
M
"
300 400
500
600
700
Test Temperature, of
I i -+- -900
Ref. 46
QUARTZ-SILICONE
Property
Fabric Description
Silicone
Oz/sq yd
Weave
Finish
Dielectric constant
X-band, dry-room temp
(9,375 megacycles)
Loss tangent
X-band, dry-room temp
8.4
8H satin
None
2.93
0.00098
Ref. 46
QUARTZ -TEFLON
Property
Fabric Description
Teflon
Oz/sq yd
Weave
Finish
Dielectric constant
X-band, dry-room temp
(9,375 megacycles)
Loss tangent
X-band, dry-room temp
80
8.4
8H satin
Teflon
2.47
0.0007
METALLIC MATRIX
Ref. 20
pohm-cm
Sb
InSb
InSb-Sb eutectic
with 4.3 rods
4.4 X
1~
10....
35
-325
0.18
0.16
X
X
X
X
X
X
10'"
104
1010'"
10'"
10'"
lo-a
4.0 X 10-1
-18
-71
-12
-53
-8.2
-28
214
5.4 X 104
18
22
25
45
55
65
3.05
33.0
3.0
33.0
3.15
34.0
2.2 X lo-a
Kw/cmo
Qp.v/o
n
n
II Sb rods
0.11
0.08
0.12
0.09
0.14
0.10
0.02
1.
Sb
Sb
Sb
Sb
Sb
rods
rods
rods
rods
rods
II growth
(20 C)
(40 C)
(60 C)
(20 C)
(40 C)
(60 C)
rectlon
1.
dl-
growth dlrectlon
Ref. 62
Alloy
TD NickelHigh Purity
Nickel"
TDNICb
Aluminumo
SAP
M257
M486 d
Density
Thermal
Conductivity
at 70 0 F.
Btu(fthr_OF)-1
2% ThO.
None
0.322
0.320
50.0
54.5
7.6
7.0
2% ThO.
None
13% AI.O.
8% AI.O.
Intermetallic
Compound
0.306
0.097
0.100
0.098
0.104
8.3
120.0
100.0
110.0
60.0
108.0
2.9
4.2
3.4
6.7
Dlspersold
81
Electrical
Resistivity
(microhm-em)
.6
I~
EI~ctric~1
~ ~ndUCtiVity
.5
E
Ref. 47
~
_ .4 - c:';'
i.... "
'"
fo,....<; ~
Id'
~p
"'"
,1
iL>".....
f<!'
20
40
Electrical
resistiVit'y -
~I.
cV
J.
60
80
"1~
-
100
82
Ref. 64
ELECTRICAL RESISTIVITY
Glass Fiber: "E" - . 0006" Dia. -Parallel Oriented
Coating Alloy: 2% Zn 0.2% Cd 1100 Al
Matrix Alloy: 2014 Al
Vacuum Injection Casting
Heat Treatment: Solutioned and Aged
Percent Glass
By Volume
0
15
15
15
15
15
19
19
19
19
19
22.5
22.5
30
30
30
30
Resistivity
(microhm-cm)
6.42
6.45
6.54
6.43
6.64
6.66
6.30
6.29
6.64
6.48
6.50
6.55
6.50
6.45
6.30
5.71
Av. Resistivity
(microhm-cm)
Calculated
Resistivity
(mi cron -cm)
3.13
3.13
6.49
3.69
6.47
3.86
6.525
4.00
6.42*
4.47
5.74**
4.47
83
Ref. 64
--AI:..
L
75
161
300
502
715
1030
1054
407
75
.0023
.0004
-.0008
Second Cycle
75
990
75
0
.0029
0
Third Cycle
70
207
357
484
688
960
764
574
413
227
70
0
.0005
.0013
.0020
.0023
.0027
.0020
.0018
.0012
.0005
70
303
670
942
562
222
70
0
.0013
.0022
.0024
.0017
.0003
-.0002
First Cycle
Fourth Cycle
84
0
.0004
.0011
.0020
.0024
--
--
MOLDED COMPOSITE
ASBESTOS-POLYESTER
Ref. 48
7.3
6.1
Powder Factor:
@ 1 KHz
@ 10 KHz
0.22
0.014
Volume Resistivity:
@ 500 Vdc, ohm-em
1.2 x 10 12
85
Ref. 53
Test
Method
FTMS 406
Property
125
4011
> 397
4031
3.7
4021
3.8
4021
3.5
4021
3.5
4021
0.014
4021
0.015
4021
0.016
4021
0.020
4021
86
0.06 x 10 6
MIL-M-14 F
'I
00
FTMS
4064021
FTMS
4064021
FTMS
4064021
Dielectric
Constant
10 3 Hz;
Dry
Wet
Dissipation
Factor
10 6 Hz
Dry
Wet
Dissipation
Factor
10 3 Hz
Dry
Wet
* F lame retardant
Arc
Resistance
Electrical
Resistance
(Volume)
Humidity + Dew
U
MIL-P
19833
FTMS
4064021
Dielectric
Constant
lOb Hz
Dry
Wet
Dielectric
Strength, SS
Wet
Test
Method
Property
seconds
10 12 ohms
V/mi1
Units
J 25
0.17
38-420
0.008
0.008-0.010
0.013-0.010
0.015-0.012
4.4
4.4
4.2
4.3
1030 (53)
and
Poly-Dap
6130 (60)
DAP
125
0.14
397-424
0.007-0.009
0.007-0.017
0.010-0.017
0.014-0.017
4.3-4.1
4.3-4.1
4.2-3.9
4.2-4.0
1030 * F (53)
and
Poly-Dap
6l30F (60)
125-150
0.08
391-425
0.009
0.008-0.011
0.012
0.014
4.2
'4.2
4.0
4.0
lM30 (53)
and
Poly-Dap
6230 (60)
DAIP
125
0.20
389-410
0.008
0.008-0.011
0.014-0.011
0.015
4.3-4.1
4.3
4.3-4.0
4.3-4.1
lM30F (53)
and
Poly-Dap
6230F (60)
'Tl
'--'
"CI
'--' ,-.,
"CI
~[T1
~2:3
,-., t""'
[T15S
~~
;;t""'
t""'''CI
2n~
0>"CIt""'
(flH
HO
(fl
(fl
I
>-
e:l
t""'
[T1
t:7:1
00
00
FTMS
4064021
FTMS
4064021
FTMS
4064021
Dielectric
Constant
10 6 Hz
Dry
Wet
Dielectric
Constant
10 3 Hz
Dry
Wet
Dissipation
Factor
10 6 Hz
Dry
Wet
Dissipation
Factor
10 3 Hz
Dry
Wet
Thermal
Expansion
Coefficient
FTMS
4064011
FTMS
4064031
Thermal
Conductivity
Arc
Resistance
Electrical
Resistivity
(Volume)
Dielectric
Strength, SS
Dry
Wet
FTMS
4064021
Property
Dielectric
Strength, ST
Dry
Wet
Test
Method
in/in;oC
cal/sec/cm 2 /oC/cm
seconds
ohm-em
V/mi!
V/mil
Units
186
376
368
0.013
0.016
0.019
0.021
5.4
5.5
5.1
5.1
EM7I02
(60)
1.1 x 10- 5
(-30 to + 30C)
10 x 10- 4
180
1 x 10 16
380
5.1
E7111 *
(18)
390
420
0.017
0.02 (170C)
5.8
6.0 (170C)
E260 *
(18)
380
400
0.0015
0.02 (170C)
4.5
4.8 (170C)
E360 *
(18)
---
0.9 x 10- 5
1.2 x 10- 5
(-30 to + 200C) (-30 to + 200C)
I
I
I
,
H
>-<
o
><
tTl
"0
C/'l
C/'l
t""'
;J>
es
tTl
t;:I
'Tl
Ref. 18
FIBERGLASS-MELAMINE
Property
Dielectric
Constant
10 6 Hz
Dissipation
Factor
10 6 Hz
Dielectric
Strength, ST
Dry
Wet
Test
Method
M-2880
M-2037
ASTM
D150
6.2
8.0
ASTM
D150
0.020
0.030
V/mil
300
275
230
150
V/mil
250
250
220
135
seconds
180+
180+
Units
ASTM
D149
Dielectric
Strength, SS
Dry
Wet
Arc
Resistance
ASTM
D495
Thermal
Conductivity
ASTM
Cl77
cal-cm/sec cm2 C
10 x 10- 4
Thermal
Expansion
Coefficient
ASTM
D696
in/in;oC
1.6 x 10- 5
89
1.6 x 10- 5
'0
ASTM
D149
ASTM
D149
Dielectric
Strength, ST
Dielectric
Strength, SS
A.rc
Resistance
Thermal
Conductivity
Thermal
Expansion
Coefficient
ASTM
D696
CencoFitch
ASTM
D495
ASTM
D257
ASTM
D150
Dissipation
Factor
10 6 Hz
Electrical
Resistivity
(Volume)
Dry
Wet
ASTM
D150
ASTM
D150
ASTM
D150
Dissipation
Factor
60 Hz
Dissipation
Factor
10 3 Hz
Dielectric
Constant
10 6 Hz
Dry
Wet
ASTM
D150
ASTM
D150
Dielectric
Constant
60 Hz
Dielectric
Constant
10 3 "Hz
Dry
Wet
Test
Method
Property
in/in;oF
Btu-in/hr ft 2F
seconds
ohm-cm
V/mil
V/mil
Units
1.3 x 10- 5
4.7x10 15
2.3 x 10 9
440
530
0.0221
0.0199
3.73
10.7
4.52
25.0
ZYTEL
7010-33
(9)
1.0 x 10- 5
4.0 x 10 14
3.0 x 10 9
510
630
0.0177
0.0185
3.38
4.22
ZYTEL
7110-33
(9)
2.1 x 10- 5
1.5
148
5.5 x 10 15
400
sod
0.017
0.022
0.018
3.4
3.9
4.0
(17)
NYLAFIL
G-l/30
c _
1.4 x 10- 5
3.3
100
2.6 x 10 15
400
480
0.018
0.011
0.009
4.1
4.4
4.4
NYLAFIL
G-IO/40
(17)
"T:I
t:"'"
>-<
(f)
(f)
I
;t>
2i
t:"'"
tTl
t7j
L--_ _ _ _ _ _ _ _ _ _ .__
9 x 10- 4
1.5 x 10- 5
10 x 10- 4
ASTM D696
ASTM Cl77
Ex~ansion, in.jin.jOC
-30 C to +30C
Thermal Conductivity, CaljSecjCm 2 jOCjCm
Coefficient of Linear
6.0
0.025
320
300
260
180
1 x 10 13
1.8 x 10- 5
5.0
0.02
380
320
380
300
FM 5064
1 x 10 13
ASTM D257
Dry
Dry
Wet
Wet
ASTM D150
ASTM D150
ASTM D149
FM 4030-190
()O
I-h
(1)
:;0
t"'"
'"gjz
(fl
(fl
I
tx:1
'T.I
Ref. 18
FIBERGLASS-POLYBUTADINE
PBD-l60
Dielectric Constant
RT, 1 mc
4.2
Dielectric Constant
170C 1 mc
4.25
Dissipation Factor
RT 1 mc.
.003
Dissipation Factor
170C 1 mc
.0035
420 +
420 +
1.3 x 10- 5
Ref. 18
FIBERGLASS-POLYIMIDE
PI-560
Dielectric Constant
RT, 1 mc
4.9
Dielectric Constant
170C 1 mc
4.9
Dissipation Factor
RT 1 mc
.005
Dissipation Factor
170C 1 mc
.0045
380
350
260C hrs.
.6 x 10- 5
5000
92
ASTM
D150
ASTM
D150
ASTM
D149
ASTM
D149
Dissipation
Factor
10 3 Hz
Dissipation
Factor
10 6 Hz
Dielectric
Strength, ST
Dielectric
Strength, SS
Thermal
Expansion
Coefficient
Thermal
Conductivity
V/mil
V/mil
ASTM
D696
CencoFitch
in/in-oF
Btu-in/hr/ft 2 F
seconds
ASTM
D150
Dissipation
Factor
60 Hz
ASTM
D495
ASTM
D150
Dielectric
Constant
10 6 Hz
ohm-cm
ASTM
D150
Dielectric
Constant
10 3 Hz
Units
ASTM
D257
ASTM
D150
Dielectric
Constant
60 Hz
Electrical
Resistivity
(Volume)
Arc
Resistance
Test
Method
Property
1.8 x 10- 5
0.522
70
1.5 x 1015
435
475
0.009
0.006
3.3
3.7
Polycarbafil
G-50/20
(17)
1.2 x 10- 5
0.374
100
1.5 x 1015
422
482
0.008
0.002
0.003
3.7
3.8
3.8
Polycarbafil
G-50/40
(17)
2.1 x 10- 5
2.3
120
6 x 1015
490
0.0079
0.0011
0.0008
3.26
3.31
3.31
Thermocomp
DF-1004
(45)
2.9 x 10- 5
2.7
120
6 x 1015
465
0.0072
0.0014
0.0012
3.61
3.68
3.66
Thermocomp
DF-1004
(45)
'T.I
tTl
g;
::0
;J>
o
r-'
><
n
"0
en
en
r-'
;J>
tTl
H
t):I
ASTM
D2303
ASTM
Cl77
ASTM
D696
**ASTM D 149
Arc
Tracking
Thermal
Conductivity
Thermal
Expansion
Coefficient
*ASTM D 150
LP4064011.2
LP4064031
Dielectric
Strength, SS
Dry
Wet
Arc
Resistance
LP4064031
LP4064021
L1:'4064021
LP4064021
LP4064021
Test
Method
Dielectric
Strength, ST
Dry
Wet
Dissipatioll
Factor
10 3 Hz
Dry
Wet
Dissipation
Factor
10 6 Hz
Dry
Wet
Dielectric
Constant
10 3 Hz
Dry
Wet
Dielectric
Constant
10 6 Hz
Dry
Wet
Property
***ASTM D 495
in/in;oC
ca1-cm/sec cm 2 C
minutes
seconds
V/mi1
V/mi1
Units
----
184
307
315
335
401
***
**
**
0.012
0.051
6.1
7.0
S-6300
(18)
14.9 x 10- 4
------
1. 59 x 10- 5
1.40 x 10- 4
191
290
400
390
410
0.0152
0.0082
0.0083
0.0113
5.07
4.88
5.42
5.43
S-642
(18)
***
**
**
2.02 x 10- 5
14.9 x 10- 4
191
351
389
380
475
0.009
0.0106
4.95
5.03
****
S-6400
(18)
300-600
180-350
300-350
***
**
Type
E1ectr. Grade
(27)
I
tTl
ttl
t-<
0-(
"0
en
en
es
"Ij
H
I:!'
ttl
FIBERGLASS-TEFLON
Ref. 57
Property
ASTM Method
Units
Condition
Typical
Value
2.38 .05
2.38 .05
Dielectric Constant
Perpendicular to
molding direction
Dl53l
2.5 GHz
10.0 GHz
Dissipation Factor
D153l
2.5 GHz
10.0 GHz
.0025
.0025
Coefficient of Thermal
Expansion x 10- 6 MD
D696
-73 to 20C
20 to 25C
25 to 100C
120
54
149
-73 to 20C
20 to 25C
25 to 100C
49
76
54
23 to 100C
2.5
in/in;oC
CMD
Thermal Conductivity
cal-cm/hr cm 2 C
MD - molded direction
CMD - perpendicular to molded direction
95
MISCELLANEOUS
CONCRETE PAVEMENT
Sample
Density
Sl
Dry
Ref. 61
(MHz)
K
tan 0
Sl
Wet
0.1
10
9.05
7.97
7.01
.0946
176.5
.0913
69.2
.822
tan 0
1.088
.0730
23.5
.734
100
6.57
.0536
13.2
.485
0.1
0.1
0.335
2.14
2.21
0.453
2.04
2.81
Various
Various
Face 1
Face 1,
Face 2
Face 2,
Face 1
Face 1,
Face 2
Face 2,
97
90
90
90
90
5.03-5.06
5.06-5.17
5.21
5.20
5.30
5.26
4.71
4.60
4.70
4.55
.026-.029
.034-.030
.059
.0612
.0509
.0505
.0470
.0455
.0487
.0487
ASPHALT PAVEMENT
Sample
Density
Dry
Ref. 61
(Hz)
K
tan
S
Wet
Dry
Wet
10 8
4.51
4.34
4.21
4.14
14.48
6.54
.444
.233
4.70
.0158
4.61
.0123
9.28
.0121
6.65
.280
.368
.0198
9.03
4.73
.0187
(3
.0181
.638
4.79
(3
.0221
17.7
.875
(3
tan
10 7
42.0
tan
10 6
.0280
(3
tan
10 5
6.01
.190
.104
Thickness Density
No.
(cm)
1
2
3
4
5
0.1
0.1
0.1
0.1
0.91
(gj cm 3 )
H2 O
Orientation
tan
(3
(%)
Independent
Independent
2.35
K'
.754
Face
Face
Face
Face
98
1
1, 90
2
2, 90
4.73
4.62
5.03
5.48
6.02
5.53
5.37
5.44
.0114
.0103
.0120
.0095
.021
.052
.204
.102
REFERENCES
1.
MATERIALS
2.
3.
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4.
5.
6.
7.
8.
9,'
DuPONT.
Advanced Engineering
Polyester Glass - Dilecto
Sept. 1969.
10.
DuPONT. DuPont's New High Modulus Organic Fiber for Plastics Reinforcement
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11.
DuPONT.
12.
BRELAND, J.G., JR. et al. Lightning Protective Coatings for Boron and
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13.
14.
MATERIALS ENGIN-
15.
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17.
lB.
19.
20.
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23.
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27.
2B.
HEXCEL AEROSPACE.
29.
30.
HOLLIDAY, L.
31.
Fiberfi1
Aug.
Composite Materials.
Composite Materials.
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100
32.
33.
34.
35.
36.
37.
38.
39.
40.
HYDE, J.K. Glass Fibre Laminates in the Electrical Field. In: Glass
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41.
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42.
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43.
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46.
47.
McDANELS, D.L. Electrical Resistivity and Conductivity of Tungsten-FiberReinforced Copper Composites. TRANS. OF THE ASM, v. 59, 1966. p. 994-997.
101
MATERIALS
Oct. 4,
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48.
49.
50.
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51.
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52.
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55.
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58.
SHAFFER, T.B. and C.K. JUN. The Elastic Modulus of Dense Polycrystalline
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MASS.
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103