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ElectricArcFurnaceSteelmaking
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ElectricArcFurnaceSteelmaking
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ByJeremyA.T.Jones,NuproCorporation
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FURNACEOPERATIONS
Theelectricarcfurnaceoperatesasabatchmeltingprocessproducingbatchesofmoltensteelknown"heats".Theelectricarcfurnace
operatingcycleiscalledthetaptotapcycleandismadeupofthefollowingoperations:
Furnacecharging
Melting
Refining
Deslagging
Tapping
Furnaceturnaround
Modernoperationsaimforataptotaptimeoflessthan60minutes.Sometwinshellfurnaceoperationsareachievingtaptotaptimesof
35to40minutes.
FurnaceCharging
Thefirststepintheproductionofanyheatistoselectthegradeofsteeltobemade.Usuallyascheduleisdevelopedpriortoeach
productionshift.Thusthemelterwillknowinadvancethescheduleforhisshift.Thescrapyardoperatorwillpreparebucketsofscrap
accordingtotheneedsofthemelter.Preparationofthechargebucketisanimportantoperation,notonlytoensurepropermeltin
chemistrybutalsotoensuregoodmeltingconditions.Thescrapmustbelayeredinthebucketaccordingtosizeanddensitytopromote
therapidformationofaliquidpoolofsteelinthehearthwhileprovidingprotectionforthesidewallsandrooffromelectricarcradiation.
Otherconsiderationsincludeminimizationofscrapcaveinswhichcanbreakelectrodesandensuringthatlargeheavypiecesofscrapdo
notliedirectlyinfrontofburnerportswhichwouldresultinblowbackoftheflameontothewatercooledpanels.Thechargecaninclude
limeandcarbonorthesecanbeinjectedintothefurnaceduringtheheat.Manyoperationsaddsomelimeandcarboninthescrapbucket
andsupplementthiswithinjection.
Thefirststepinanytaptotapcycleis"charging"intothescrap.Theroofandelectrodesareraisedandareswungtothesideofthe
furnacetoallowthescrapchargingcranetomoveafullbucketofscrapintoplaceoverthefurnace.Thebucketbottomisusuallyaclam
shelldesigni.e.thebucketopensupbyretractingtwosegmentsonthebottomofthebucket.Thescrapfallsintothefurnaceandthe
scrapcraneremovesthescrapbucket.Theroofandelectrodesswingbackintoplaceoverthefurnace.Theroofisloweredandthenthe
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electrodesareloweredtostrikeanarconthescrap.Thiscommencesthemeltingportionofthecycle.Thenumberofchargebucketsof
scraprequiredtoproduceaheatofsteelisdependentprimarilyonthevolumeofthefurnaceandthescrapdensity.Mostmodernfurnaces
aredesignedtooperatewithaminimumofbackcharges.Thisisadvantageousbecausechargingisadeadtimewherethefurnacedoes
nothavepoweronandthereforeisnotmelting.Minimizingthesedeadtimeshelpstomaximizetheproductivityofthefurnace.Inaddition,
energyislosteverytimethefurnaceroofisopened.Thiscanamountto1020kWh/tonforeachoccurrence.Mostoperationsaimfor2
to3bucketsofscrapperheatandwillattempttoblendtheirscraptomeetthisrequirement.Someoperationsachieveasinglebucket
charge.ContinuouschargingoperationssuchasCONSTEELandtheFuchsShaftFurnaceeliminatethechargingcycle.
Melting
ThemeltingperiodistheheartofEAFoperations.TheEAFhasevolvedintoahighlyefficientmeltingapparatusandmoderndesignsare
focusedonmaximizingthemeltingcapacityoftheEAF.Meltingisaccomplishedbysupplyingenergytothefurnaceinterior.Thisenergy
canbeelectricalorchemical.Electricalenergyissuppliedviathegraphiteelectrodesandisusuallythelargestcontributorinmelting
operations.Initially,anintermediatevoltagetapisselecteduntiltheelectrodesboreintothescrap.Usually,lightscrapisplacedontopof
thechargetoaccelerateborein.Approximately15%ofthescrapismeltedduringtheinitialboreinperiod.Afterafewminutes,the
electrodeswillhavepenetratedthescrapsufficientlysothatalongarc(highvoltage)tapcanbeusedwithoutfearofradiationdamageto
theroof.ThelongarcmaximizesthetransferofpowertothescrapandaliquidpoolofmetalwillforminthefurnacehearthAtthestartof
meltingthearciserraticandunstable.Wideswingsincurrentareobservedaccompaniedbyrapidmovementoftheelectrodes.Asthe
furnaceatmosphereheatsupthearcstabilizesandoncethemoltenpoolisformed,thearcbecomesquitestableandtheaveragepower
inputincreases.
Chemicalenergyisbesuppliedviaseveralsourcesincludingoxyfuelburnersandoxygenlances.Oxyfuelburnersburnnaturalgasusing
oxygenorablendofoxygenandair.Heatistransferredtothescrapbyflameradiationandconvectionbythehotproductsofcombustion.
Heatistransferredwithinthescrapbyconduction.Largepiecesofscraptakelongertomeltintothebaththansmallerpieces.Insome
operations,oxygenisinjectedviaaconsumablepipelanceto"cut"thescrap.Theoxygenreactswiththehotscrapandburnsironto
produceintenseheatforcuttingthescrap.Onceamoltenpoolofsteelisgeneratedinthefurnace,oxygencanbelanceddirectlyintothe
bath.Thisoxygenwillreactwithseveralcomponentsinthebathincluding,aluminum,silicon,manganese,phosphorus,carbonandiron.
Allofthesereactionsareexothermic(i.e.theygenerateheat)andsupplyadditionalenergytoaidinthemeltingofthescrap.Themetallic
oxidesthatareformedwillendupintheslag.Thereactionofoxygenwithcarboninthebathproducescarbonmonoxide,whicheither
burnsinthefurnaceifthereissufficientoxygen,and/orisexhaustedthroughthedirectevacuationsystemwhereitisburnedand
conveyedtothepollutioncontrolsystem.AuxiliaryfueloperationsarediscussedinmoredetailinthesectiononEAFoperations.
Onceenoughscraphasbeenmeltedtoaccommodatethesecondcharge,thechargingprocessisrepeated.Oncethefinalscrapcharge
ismelted,thefurnacesidewallsareexposedtointenseradiationfromthearc.Asaresult,thevoltagemustbereduced.Alternatively,
creationofafoamyslagwillallowthearctobeburiedandwillprotectthefurnaceshell.Inaddition,agreateramountofenergywillbe
retainedintheslagandistransferredtothebathresultingingreaterenergyefficiency.
Oncethefinalscrapchargeisfullymelted,flatbathconditionsarereached.Atthispoint,abathtemperatureandsamplewillbetaken.
Theanalysisofthebathchemistrywillallowthemeltertodeterminetheamountofoxygentobeblownduringrefining.Atthispoint,the
meltercanalsostarttoarrangeforthebulktapalloyadditionstobemade.Thesequantitiesarefinalizedaftertherefiningperiod.
Refining
Refiningoperationsintheelectricarcfurnacehavetraditionallyinvolvedtheremovalofphosphorus,sulfur,aluminum,silicon,manganese
andcarbonfromthesteel.Inrecenttimes,dissolvedgases,especiallyhydrogenandnitrogen,beenrecognizedasaconcern.
Traditionally,refiningoperationswerecarriedoutfollowingmeltdowni.e.onceaflatbathwasachieved.Theserefiningreactionsareall
dependentontheavailabilityofoxygen.Oxygenwaslancedattheendofmeltdowntolowerthebathcarboncontenttothedesiredlevel
fortapping.Mostofthecompoundswhicharetoberemovedduringrefininghaveahigheraffinityforoxygenthatthecarbon.Thusthe
oxygenwillpreferentiallyreactwiththeseelementstoformoxideswhichfloatoutofthesteelandintotheslag.
InmodernEAFoperations,especiallythoseoperatingwitha"hotheel"ofmoltensteelandslagretainedfromthepriorheat,oxygenmay
beblownintothebaththroughoutmostoftheheat.Asaresult,someofthemeltingandrefiningoperationsoccursimultaneously.
Phosphorusandsulfuroccurnormallyinthefurnacechargeinhigherconcentrationsthanaregenerallypermittedinsteelandmustbe
removed.Unfortunatelytheconditionsfavorableforremovingphosphorusaretheoppositeofthosepromotingtheremovalofsulfur.
Thereforeoncethesematerialsarepushedintotheslagphasetheymayrevertbackintothesteel.Phosphorusretentionintheslagisa
functionofthebathtemperature,theslagbasicityandFeOlevelsintheslag.AthighertemperatureorlowFeOlevels,thephosphoruswill
revertfromtheslagbackintothebath.Phosphorusremovalisusuallycarriedoutasearlyaspossibleintheheat.Hotheelpracticeis
verybeneficialforphosphorusremovalbecauseoxygencanbelancedintothebathwhileitstemperatureisquitelow.Earlyintheheatthe
slagwillcontainhighFeOlevelscarriedoverfromthepreviousheatthusaidinginphosphorusremoval.Highslagbasicity(i.e.highlime
content)isalsobeneficialforphosphorusremovalbutcaremustbetakennottosaturatetheslagwithlime.Thiswillleadtoanincreasein
slagviscosity,whichwillmaketheslaglesseffective.Sometimesfluorsparisaddedtohelpfluidizetheslag.Stirringthebathwithinert
gasisalsobeneficialbecauseitrenewstheslag/metalinterfacethusimprovingthereactionkinetics.
Ingeneral,iflowphosphoruslevelsarearequirementforaparticularsteelgrade,thescrapisselectedtogivealowlevelatmeltin.The
partitionofphosphorusintheslagtophosphorusinthebathrangesfrom5to15.Usuallythephosphorusisreducedby20to50%inthe
EAF.
Sulfurisremovedmainlyasasulfidedissolvedintheslag.Thesulfurpartitionbetweentheslagandmetalisdependentonslagchemistry
andisfavoredatlowsteeloxidationlevels.RemovalofsulfurintheEAFisdifficultespeciallygivenmodernpracticeswheretheoxidation
levelofthebathisquitehigh.Generallythepartitionratioisbetween3and5forEAFoperations.Mostoperationsfinditmoreeffectiveto
carryoutdesulfurizationduringthereducingphaseofsteelmaking.Thismeansthatdesulfurizationisperformedduringtapping(wherea
calciumaluminateslagisbuilt)andduringladlefurnaceoperations.Forreducingconditionswherethebathhasamuchloweroxygen
activity,distributionratiosforsulfurofbetween20and100canbeachieved.
Controlofthemetallicconstituentsinthebathisimportantasitdeterminesthepropertiesofthefinalproduct.Usually,themelterwillaim
atlowerlevelsinthebaththanarespecifiedforthefinalproduct.Oxygenreactswithaluminum,siliconandmanganesetoformmetallic
oxides,whichareslagcomponents.Thesemetallicstendtoreactwithoxygenbeforethecarbon.TheywillalsoreactwithFeOresultingin
arecoveryofironunitstothebath.Forexample:
Mn+FeO=MnO+Fe
Manganesewilltypicallybeloweredtoabout0.06%inthebath.
ThereactionofcarbonwithoxygeninthebathtoproduceCOisimportantasitsuppliesalessexpensiveformofenergytothebath,and
performsseveralimportantrefiningreactions.InmodernEAFoperations,thecombinationofoxygenwithcarboncansupplybetween30
and40%ofthenetheatinputtothefurnace.Evolutionofcarbonmonoxideisveryimportantforslagfoaming.Coupledwithabasicslag,
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CObubblesaretappedintheslagcausingitto"foam"andhelpingtoburythearc.Thisgivesgreatlyimprovedthermalefficiencyand
allowsthefurnacetooperateathigharcvoltagesevenafteraflatbathhasbeenachieved.Buryingthearcalsohelpstopreventnitrogen
frombeingexposedtothearcwhereitcandissociateandenterintothesteel.
IftheCOisevolvedwithinthesteelbath,ithelpstostripnitrogenandhydrogenfromthesteel.Nitrogenlevelsinsteelaslowas50ppm
canbeachievedinthefurnacepriortotap.Bottomtappingisbeneficialformaintaininglownitrogenlevelsbecausetappingisfastanda
tighttapstreamismaintained.Ahighoxygenpotentialinthesteelisbeneficialforlownitrogenlevelsandtheheatshouldbetappedopen
asopposedtoblockingtheheat.
At1600C,themaximumsolubilityofnitrogeninpureironis450ppm.Typically,thenitrogenlevelsinthesteelfollowingtappingare80
100ppm.
Decarburizationisalsobeneficialfortheremovalofhydrogen.Ithasbeendemonstartedthatdecarburizingatarateof1%perhourcan
lowerhydrogenlevelsinthesteelfrom8ppmdownto2ppmin10minutes.
Attheendofrefining,abathtemperaturemeasurementandabathsamplearetaken.Ifthetemperatureistoolow,powermaybeapplied
tothebath.Thisisnotabigconcerninmodernmeltshopswheretemperatureadjustmentiscarriedoutintheladlefurnace.
DeSlagging
Deslaggingoperationsarecarriedouttoremoveimpuritiesfromthefurnace.Duringmeltingandrefiningoperations,someofthe
undesirablematerialswithinthebathareoxidizedandentertheslagphase.
Itisadvantageoustoremoveasmuchphosphorusintotheslagasearlyintheheataspossible(i.e.whilethebathtemperatureisstill
low).Thefurnaceistiltedbackwardsandslagispouredoutofthefurnacethroughtheslagdoor.Removaloftheslageliminatesthe
possibilityofphosphorusreversion.
Duringslagfoamingoperations,carbonmaybeinjectedintotheslagwhereitwillreduceFeOtometallicironandintheprocessproduce
carbonmonoxidewhichhelpsfoamtheslag.Ifthehighphosphorusslaghasnotbeenremovedpriortothisoperation,phosphorus
reversionwilloccur.Duringslagfoaming,slagmayoverflowthesilllevelintheEAFandflowoutoftheslagdoor.
ThefollowingtableshowsthetypicalconstituentsofanEAFslag:
Component
Source
CompositionRange
CaO
Charged
4060%
SiO2
Oxidationproduct
515%
FeO
Oxidationproduct
1030%
MgO
Chargedasdolomite
38%
CaF2
Chargedslagfluidizer
MnO
Oxidationproduct
25%
Absorbedfromsteel
Oxidationproduct
Tapping
Oncethedesiredsteelcompositionandtemperatureareachievedinthefurnace,thetapholeisopened,thefurnaceistilted,andthesteel
poursintoaladlefortransfertothenextbatchoperation(usuallyaladlefurnaceorladlestation).Duringthetappingprocessbulkalloy
additionsaremadebasedonthebathanalysisandthedesiredsteelgrade.Deoxidizersmaybeaddedtothesteeltolowertheoxygen
contentpriortofurtherprocessing.Thisiscommonlyreferredtoas"blockingtheheat"or"killingthesteel".Commondeoxidizersare
aluminumorsiliconintheformofferrosiliconorsilicomanganese.Mostcarbonsteeloperationsaimforminimalslagcarryover.Anew
slagcoveris"built"duringtapping.Forladlefurnaceoperations,acalciumaluminateslagisagoodchoiceforsulfurcontrol.Slagforming
compoundsareaddedintheladleattapsothataslagcoverisformedpriortotransfertotheladlefurnace.Additionalslagmaterialsmay
beaddedattheladlefurnaceiftheslagcoverisinsufficient.
FurnaceTurnaround
Furnaceturnaroundistheperiodfollowingcompletionoftappinguntilthefurnaceisrechargedforthenextheat.Duringthisperiod,the
electrodesandroofareraisedandthefurnaceliningisinspectedforrefractorydamage.Ifnecessary,repairsaremadetothehearth,slag
line,tapholeandspout.Inthecaseofabottomtappingfurnace,thetapholeisfilledwithsand.Repairstothefurnacearemadeusing
gunnedrefractoriesormudslingers.Inmostmodernfurnaces,theincreaseduseofwatercooledpanelshasreducedtheamountof
patchingor"fettling"requiredbetweenheats.Manyoperationsnowswitchoutthefurnacebottomonaregularbasis(2to6weeks)and
performthehearthmaintenanceoffline.ThisreducesthepowerofftimefortheEAFandmaximizesfurnaceproductivity.Furnaceturn
aroundtimeisgenerallythelargestdeadtime(i.e.poweroff)periodinthetaptotapcycle.Withadvancesinfurnacepracticesthishas
beenreducedfrom20minutestolessthan5minutesinsomeneweroperations.
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