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JOURNAL OF
COMPOSITE
M AT E R I A L S
Article
chsner2 and
Morteza Farsadi1, Andreas O
2
Moones Rahmandoust
Abstract
This paper studies the extent to which the effective stiffness of composite materials can be impacted by the characteristic
waviness of nanotubes embedded in polymers. A three-dimensional finite element model is used to investigate the effect
of volume fraction and waviness on mechanical properties, i.e. Youngs modulus and Poissons ratio, of composites
reinforced with waved carbon nanotubes. According to the obtained results, the nanotube waviness causes a decrease
in the longitudinal and transverse Youngs modulus of composites, compared to the straight nanotube reinforcement, but
the change in the value of transverse Youngs modulus (Eyy) is less remarkable than the longitudinal Youngs modulus (Exx).
Furthermore, the effect of fiber curvature on Poissons ratio has also been studied. The results show that the curvature
has not much effect on Poissons ratio and when a fiber curvature changes, Poissons ratio value almost remains
unchanged. In addition, the effect of fiber volume fraction on the longitudinal Youngs modulus and major Poissons
ratio has been studied. As the mesh density may have a significant role in evaluating the model, several different meshes
have been generated in order to predict their effect on the mechanical properties of the composite.
Keywords
Carbon nanotube, composite materials, elastic properties of composite, fiber waviness, FEM
Introduction
When a material is composed of one or more discontinuous phases incorporated in a continuous phase, it is
termed a composite where the discontinuous phase is
the reinforcing material (ber) and the continuous
phase is the matrix. The bers have been used as stiening and strengthening agents since 800 BC by ancient
Egyptians who blended straw and clay to make reinforced bricks. Since their discovery by Iijima in 1991,1
signicant research has focused on carbon nanotubes
(CNTs) as bers. CNTs have exceptional mechanical
properties in addition to their outstanding electronic
and thermal properties.2 Experimental and theoretical
investigations show that the strengths of CNTs is 10 to
100 times greater than the strongest steel at a fraction
of the weight and that its elastic modulus is larger than
1 TPa, in comparison with 0.2 TPa for steel and
0.07 TPa for aluminum.3
Because of the signicant mechanical properties of
CNTs, reinforcement of various matrices by the use of
Corresponding author:
Morteza Farsadi, University of Applied Science and Technology (UAST),
Provincial Branch, PO Box 97179-11487, Birjand, Iran.
Email: morteza.farsadi@gmail.com
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Farsadi et al.
1427
perpendicular to the ber. Since composite parts in different industries are under loading in dierent directions, studying changes in mechanical properties
under loading in ber direction and in perpendicular
direction to it is very important in optimal design.
Furthermore, the eect of ber volume fraction Vf on
the longitudinal Youngs modulus and major Poissons
ratio has been studied.
FE analysis
The FE method is a powerful tool to model the eective
response of embedded wavy inclusions of CNTs inside
a matrix. To determine the eective reinforcing modulus (E) of an embedded wavy nanotube, the commercial
FE code MSC.Marc was used to create and analyze a
three-dimensional FE model of a single, wavy nanotube
shape of the form z a cos2x=L, where L is the
sinusoidal wavelength and x is the ber axial direction
(Figure 2). In order to generate the three-dimensional
models, eight-node, isoparametric hexahedral elements
with trilinear interpolation functions were used for the
matrix and ber. The matrix and the ber were rst
meshed as individual solids. Then, assuming perfect
bonding and by merging the nodes of the two constituents in the contact region, the interface between matrix
and ber has been modeled. Since only elastic properties were evaluated within this contribution, static
linear-elastic analyses were performed with the commercial code.
For the FE simulations where the loading was in
direction of the ber, i.e. the x-direction, reective symmetry conditions were prescribed on the x 0 (ux 0),
y 0 (uy 0), and z 0 (uz 0) plane. In addition, a
small displacement (ux L) was applied to all nodes
of the model at x L in the x-direction. For the cases
where the loading was perpendicular to the ber, i.e.
the y-direction, reective symmetry conditions were
prescribed on the x 0 (ux 0), y 0 (uy 0), and
z 0 (uz 0) plane and a small displacement
(uy L) was applied to all nodes of the model at
y b/2 in the y-direction. Thus, pure tensile tests were
realized in both directions where bending was excluded
due to the applied displacement boundary conditions.
Youngs modulus and Poissons ratios which were
assigned for the CNT and matrix are given in Table 1.
In the linear-elastic range, Youngs modulus is
dened as follows:
P
Eii
Fi L
A L
i x, y
P
where
Fi is the sum of reaction forces on the displaced plane, A is the cross-sectional area of the cell,
and L is a small displacement. Since the curve radius
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Figure 2. Schematic representation of the composite model reinforced with waved carbon nanotube for axial displacement.
CNT
Matrix
Youngs modulus
Poissons ratio
1.03 TPa
3.8 GPa
0.063
0.4
P
(a) has direct eect on F, Youngs modulus (E) will
be majorly dependent on a parameter called the waviness ratio (w a/L). A systematic analysis of the impact
of this parameter on E was undertaken and the key
results will be presented in the following section.
Farsadi et al.
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Figure 5. Longitudinal Youngs modulus (Exx) as a function of nanotube waviness ratio (w a/L).
Effect of Vf
Figure 8 shows the longitudinal Youngs modulus as a
function of Vf, for dierent curvatures. As can be seen,
with an increase in the Vf, longitudinal Youngs modulus increases as well. Because the ber is stier than the
matrix, by increasing the Vf, the eect of the presence of
ber in the model compared to the matrix becomes
more signicant; consequently the composite will be
stier and longitudinal Youngs modulus will increase.
In order to validate the results, the classical HalpinTsai equations (see Appendix) have been employed for
straight bers. As shown in Figure 8, results obtained
from Halpin-Tsai are equal to the results obtained for
the model with straight bers.
The straight bers have the highest longitudinal
Youngs modulus and with an increase in the curvature,
longitudinal Youngs modulus decreases. Therefore,
the curves related to wavy bers will be placed under
that with straight bers.
Farsadi et al.
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Conclusion
Mechanical properties of composite material with ber
waviness have been investigated as a three-dimension
FE model by means of the commercial software
Farsadi et al.
1433
Conflict of interest
None declared.
References
1. Iijima S. Helicoidal microtubes of graphitic carbon. Nature
1991; 354: 5658.
2. Lu JP. Elastic properties of single and multilayered nanotubes. J Phys Chem Solids 1997; 58(11): 16491652.
3. Thostenson ET, Reng Z and Chou T. Advances in the
science and technology of carbon nanotubes and their
composites: a review. Compos Sci Technol 2001; 61:
18991912.
4. Krishnan A, Dujardin E, Ebbesen TW, et al. Youngs
modulus of single-walled nanotubes. Phys Rev B 1998;
58: 1401314019.
5. Wong EW, Sheehan PE and Lieber CM. Nanobeam mechanics: elasticity, strength, and toughness of nanorods and
nanotubes. Science 1997; 277: 19711975.
6. Xiao JR, Gama BA and Gillespie JW. An analytical
molecular structural mechanics model for the mechanical
properties of carbon nanotubes. Int J Solids Struct 2005;
42: 30753092.
7. Qian D, Wagner GJ, Liu WK, et al. Mechanics of Carbon
nanotubes. Appl Mech Rev 2002; 55: 495533.
1434
#f
#m
Mm
1 Vf
Mf
1
Mm
Mf
Mm
where:
Appendix
Halpin-Tsai equations are useful for the prediction of
the properties of composite materials. They are as
follows:27
Longitudinal modulus (Exx):
Exx Ef Vf Em 1 Vf
M
Mf
Mm
x
where:
Vf