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Original Article
Received: 13.07.2012
Accepted: 09.10.2012
Published: 30.10.2012
Abstract
The biofuels debate in Zambia and the African continent at large sometimes lacks locally generated data. The blending of biodiesel with
fossil diesel for use in internal combustion engines has raised many questions on the final quality of the blended fuel. This study focused on
the effects of blending biodiesel obtained from Jatropha with fossil diesel on five parameters. The parameters were kinematic viscosity,
specific gravity, distillation temperature, flash point temperature and the calculated cetane index value. The blending ratios used were B5,
B10, B15 and B20. The methods used for analyses were based on American Society for Testing Materials (ASTM) standards for petroleum
products, lubricants and fossil fuels. The ASTM methods applied in this study were the existing and approved methods used to certify fossil
fuel quality in Zambia. The results indicated that the specific gravity, calculated cetane index, flash point temperature and the distillation
temperature parameters were all suitable for use in internal combustion engines for all the four blending ratios, while the kinematic viscosity
-6
results for B15 and B20 were above the highest allowable limit. The B20 blend recorded the highest value for kinematic index of 7.2 x 10
2 -1
-6 2 -1
m s , about 31 percent above the upper allowable limit of 5.5 x 10 m s .
Due to limited feedstock levels, it is recommended that Jatropha based biodiesel in Zambia will have to be blended with fossil diesel, up until
the feedstock levels improve. The proposed blending ratios are 5 percent for biodiesel and 10 percent for bio-ethanol, according to the
Zambian Government Sixth National Development Plan of 2010.
Keywords: Blending Ratio, Calculated Cetane Index; Kinematic Viscosity; Feedstock, Flash Point
Corresponding Author: J. Mundike, e-mail: Jhomu@cbu.ac.zm, Phone: +260 975 222 297, Fax: +260 212 228 319
INTRODUCTION
Even though Jatropha has been used for various
traditional purposes like medicinal, live hedges and cosmetics
for a long time in Zambia, its commercial value was realized
around 2004 onwards. Oval Biofuels Limited first
implemented production of biodiesel from Jatropha on small
scale and commercial production in Zambia, between 2005
and 2008.
The global biofuels debate has pushed second generation
biofuels using non-food feedstock firmly under the spotlight
with the hope commonly expressed that they will soon
become fully commercialized at the large production scaleand
will become cost competitive with first generation and
95
x500ml 475ml of mineral diesel
100
Theory
Blending means mixing or combining of two or more
substances, which in this case was between Jatropha derived
biodiesel with mineral diesel. Biodiesel can be used as B100
(neat) or in a blend with petroleum diesel. A blend of 20%
biodiesel with 80% petro-diesel, by volume, is termed B20.
A blend of 2% biodiesel with 98% petro-diesel is B2, and
so on (Gerpen et al. 2004).
Kinematic viscosity can be defined as the resistance to
the flow of the fuel (liquid). The denser the fuel is the higher
its viscosity and the greater its resistance to flow. Since
temperature influences the fuel fluidity, it is important to
indicate the temperature at which the viscosity was
determined.
Distillation temperature provides a measure of the
temperature range over which a fuel volatizes or turns into
vapor. Three key temperatures are generally considered,
Kinematic Viscosity
The recommended range of values for kinematic
viscosity, according to Zambia Bureau of Standards (ZDS
369), 2009, is between 2 to 5.5 centistokes. The International
System Units (SI Units) for kinematic viscosity is metersquared per second. According to Mott et al
stoke
m2
(2006), centistoke
. The blending ratios
1x10 6
100
s
of B15 and B20 were found to have kinematic viscosity
values above the recommended upper limit standard value of
5.5 x 10-6 m2s-1 for use in internal combustion engines.
Where:
G = API gravity, determined by test method D1298
M = Mid-boiling point temperature, (C), determined by
test method ASTM D86 and then corrected to standard
barometric pressure.
D = Density at 15C, (g/ml), determined by test method
ASTM D1298.
B = Mid-boiling temperature, (C), determined by test
method ASTM D86 and then corrected to standard
barometric pressure.
CCI = Calculated Cetane Index
Table 1 Results for Kinematic Viscosity, Specific Gravity, Calculated Cetane Index and Flash Point Temperature of the
Blended Biodiesel Samples
Kinematic Viscosity
Specific Gravity
Calculated Cetane Index Flash Point
-6
2 -1
(x
10
m
s
)
(Unit
less)
(Unit less)
(C)
Blend
Results
Standard
Results
Standard
Results
Standard
Results
Standard
2 5.5
0.82 0.87
>50
>60
B5
4.64
0.8486
50.85
94.4
B10
4.98
2 5.5
0.8542
0.82 0.87
50.78
>50
96.4
>60
B15
5.67
2 5.5
0.8576
0.82 0.87
50.11
>50
98.5
>60
B20
7.20
2 5.5
0.8652
0.82 0.87
50.04
>50
103.4
>60
Specific Gravity
The standard specific gravity values for diesel fuels range
between 0.8200 to 0.8700. From the results obtained in table
1 above, all the four-blended biodiesel samples were within
the acceptable range of values. However, it was observed that
as the blending ratio increased, the specific gravity values
also increased. More biodiesel in the mixture (blend)
increased the density of the final blended sample, hence the
increase in specific gravity.
Distillation Temperature
The results in table 2 below show the LBP, MBP and
UBP for each of the four blending ratios. During the
distillation and condensation process, the LBP is the
temperature at which the first vapors are collected and
condensed, while the MBP is the temperature at which half of
the fuel would have been evaporated and the UBP is the
temperature at which the last volume of fuel (95%) would
have been evaporated, (Speight 2008).The significance and
application for distillation temperature test is both in aviation
and automotive fuels, affecting starting, warm-up, and
tendency to vapour lock at high operating temperature or at
high altitude, or both, (Storer et al. 1994). From the results in
table 2 below, all the four blended samples had acceptable
values of distillation temperature, the lowest temperature
recorded was 162.5C while the highest was
395.5C.Distillation limits are often included in petroleum
product specifications, in commercial contract agreements,
process refinery/control applications, and compliance to
regulatory rules, (Storer et al. 1994). Volatility is the major
determinant of the tendency of a fuel mixture to produce
potentially explosive vapours. Therefore, the distillation test
(volatility) characteristics of a fuel play an important role on
their performance and safety. The boiling range of any fuel
gives information on the composition, the properties, and the
behavior of the fuel during storage and use. According to
Guthrie et al. (1960), the fuel volatility requirements depend
on the engine design, size, nature of the speed and load
variations, and starting and atmospheric conditions.
B20
Results
164.0
314.1
315.1
CONCLUSION
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Fuel Properties of Biodiesel and Its Blends at Various Temperatures.
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Chemical
Society
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Speight JG, 2008. The Chemistry and Technology of Petroleum, CRC Press,
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for Testing Materials (ASTM) Standards, Petroleum Products,
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Agroforestry
Centre
http://worldagroforestry.org/downloads/publications/PDFs/WP15396.P
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Manuscript
EE
04
004.
Vol.
VI.
http://journals.sfu.ca/cigr/index.php/Ejournal/article/view.pdf. Accessed
28 March 2012
Zambia
Bureau
of
Standards.
2009.
http://erb.org.zm/downloads/standards/drafts/DZS-369-2009
2ndEdition.pdf. Accessed 26 November 2010