MUNISH KAKARs INSTITUTE OF CHEMISTRY

TEST - FULL SYLLABUS (CLASS +1)

Time Allowed : 3 Hrs.

Maximum Marks : 70

General instruction :
(i) All questions are compulsory.
(ii) Marks for each question are indicated against it.
(iii) Question number 1 to 8are very short answer question and carry 1 mark each.
(iv) Question numbers 9 to 18 are short answer question and carry 2 marks each.
(v) Question numbers 19 to 27 are also short answer question and carry 3 marks each.
(vi) Question numbers 28 to 30 are long answer question and carry 5 marks each.
(vii) Use log tables if necessary, use of calculators is not allowed.
Q1

Which series of lines of the hydrogen spectrum lie in the visible region ?

Q2

What would be the IUPAC name and symbol for the element with atomic number 119 ?

Q3

Which of the following has maximum bond angle ?

Q4

Write van der Waals equation for one mole of a gas.

Q5

Predict the sign of S0 for the following reaction :

H2O, CO2, NH3, CH4

2H 2 S ( g ) 3O2 ( g ) 2H 2O( g ) 2SO2 ( g )

Q6

What is the oxidation number of Mn in KMnO4 ?

Q7

Name the alkali metal which shows diagonal relationship with magnesium.

Q8

Write structural formula of 3,4,4,5-tetramethylheptane.

Q9
Q10

Identify A and B in the following :

Na

CH CH

Red hot iron tube

873 K

The mass of an electron is 9.1 10-31 kg. If its K.E. (kinetic energy) is 3 10-25 j. Calculate
its velocity.

Q11

Give the main product of the reactions :

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CH C

Anhy,AlCl3
CH3Cl

(i)

(ii)

+
CH2 + H2O H

CH3

Q12

Give two difference between and bonds.

Q13

1g mixture of CaCO3 and MgCO3 on strong heating gave 0.96g of residue. What is
percentage by mass of CaCO3 and MgCO3 in mixture ?

Q14

Compare the relative stability of the following species on the basis of molecular orbitals
theory and indicate their magnetic properties : O2 , O2

Q15

Balance the following equations in basic medium by ion electron method :

Cl2O7 ( g ) H 2O2 (aq) ClO2 (aq) O2 ( g ).

Q16

Arrange the following :

+
+
+
(CH3)3C, CH3CH2CH, CH3CH2CH2CH2 [incresing order of stability]

(a)

CH3

(b) CH3COOH , H-COOH and CH3CH2COOH in increasing order of acidic strength.

Q17

Compare the alkali metals and alkaline earth metals with respect to :
(a) ionization enthalpy

Q18

(b) basicity of oxides.

Why CO2 is gas while SiO2 is solid at room temperature ?

OR
Write balanced equations for the reactions between :
(a) Na2O2 and water.

Q19

(b) Decomposition of LiNO3

In Carius method of estimations of halogen, 0.15 g of an organic compound gave 0.12 g of

AgBr. Find out the percentage of bromine in the compound.
[Molar mass of AgBr = 188 mol-1, At. Mass of Br = 80 g mol-1]

Q20

Write a brief note on the following environment terms :

(a) Acid rain,

Q21

(b) Greenhouse effect,

(c) Ozone layer depletion.

(a) What cause the temporary and permanent hardness of water ?

(b) Compare the structure of H2O and H2O2.

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Q22

(a) Write the conjugate acids for the Bronsted base NH 2 and HCOO-.
(b) The concentration of hydrogen ion in a sample of soft drink is 3.8 10 -3 M. What is its
pH ? [log 3.8 = 0.5798]
(c) Equilibrium constant for a reaction is 4.0, what will be the equilibrium constant for the
reverse reaction.

Q23

(a) Which has larger a value NH3 or CH4 ?

(b) Calculate the total pressure in a mixture of 8 g of oxygen and 4 g of hydrogen.
Confined in a vessel of 1 dm3 at 270C . R = 0.083 bar dm3K-1mol-1.

Q24

(a) Define principle quantum number (n).

(b) Write the electronic configuration of Cr. [Atomic number of Cr = 24]
(c) Define Paulis exclusion principle.

Q25

Give a brief account for the following :

(a) Anions are bigger in size than their parent atom.
(b) Oxygen has lesser first ionization enthalpy than nitrogen.
(c) Fluorine has less negative electron gain enthalpy than chlorine.

Q26

(a) The reaction quotient of a reversible reaction is Q c and the equilibrium constant is Kc.
what do you conclude for the reaction if Qc<Kc ?
(b) State Le Chateliers principle.
(c) What happens to the basic strength of NH4OH in presence of NH4Cl ?

Q27

(a) What type of isomerism is shown by pentane and 2-Methyl butane (isopentane).
(b) Why is an organic compound fused with sodium for testing halogen, nitrogen, sulphur
and phosphorus ?
(c) Write the I.U.P.A.C. name of CH2=CHCH2CH(OH)CH3

Q28

(a) How can you convert the following :

(i) Acetylene to nitrobenzene,

(ii) 2-Bromopropane to 1-Bromopropane

(b) Give a chemical test to distinguish between ethene and ethyne.

(c) Give a brief account for the following statements :
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(i) n-pentane has greater boiling point that isopentane.
(ii) CH4 cannot be synthesized by Wurtz reaction.
Q29

(a) State Hesss law.

(b) Give a brief note on the following thermodynamic terms :
(i) Standard enthalpy of combustion,
(c) For the reaction :

(ii) Standard enthalpy of formation.

2 A( g ) B( g ) 2D( g ) U0 = -10.5 kj and S0 = -44.1 jk-1 mol-1.

Calculate G0 for the reaction and predict whether the reaction

may occur

spontaneously.
OR
(a) For the reaction at 298 K 2A B C H = 400 kj mol-1 and S = 0.2 kj mol-1 K-1
At what temperature will the reaction become spontaneous considering H and S to be
constant over the temperature range.
(b) State first law of thermodynamics.
(c) Give one point to differentiate the following thermodynamic terms :
(i) Extensive properties and intensive properties,
(ii) Isothermal process and isobaric process.
Q30

(a) Account for the following :

(i) Boron trihalides (BX3) act as Lewis acids.
(ii) PbCl4 is a powerfuloxidising agent.
(iii) BeSO4 is more soluble in water than BaSO4 ?
(b) Complete the following reactions :

(ii) B2 H 6 6 NH3

(i) Na2 B4O7 2HCl 5H 2O

OR
(a) Draw the shape of B2H6 molecule.

(b) Give suitable reasons for the following :

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(i) [SiF6]2- is known whereas [SiCl6]2- not (ii) diamond is covalent, yet it has high melting
point.
(c) Complete the reactions :
strongly heated
(i) Na2 B4O7 .10H 2O

(ii) B2 H 6 3O2

S.C.O. No. 203, SECOND FLOOR, SECTOR 14, PANCHKULA. Phone : 9417655033, 9888019721