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This print-out should have 16 questions.


Multiple-choice questions may continue on
the next column or page find all choices
before answering.
001 10.0 points
Pick the name and formula that do NOT
match.

003 10.0 points


Which one of the following pairs of acids
and their conjugate bases is INCORRECTLY
matched?

1. NH+
4 : NH2 correct

2. HF : F

1. H2 CrO4 : chromic acid

3. H3 O+ : H2 O

2. HBrO4 : perbromic acid

4. HClO : ClO

3. HCN : hydrocyanic acid

5. H2 O : OH

4. H2 PO4 : phosphoric acid correct


Explanation:
Phosphoric acid is H3 PO4 .
Bromic acid is HBrO3 . P erbromic acid
has one more oxygen atom, so its formula is
HBrO4 .
HCN is hydrogen cyanide. In aqueous solution, HCN is known as hydrocyanic acid.
CrO2
is the chromate ion. H2 CrO4 is
4
chromic acid.
002 10.0 points
Which of the following is NOT a property of
bases?

Explanation:
An acid is a proton donor and a base is a
proton acceptor. The only difference between
the acid and its conjugate base is that the
base has one less H atom. NH
2 has two
+
fewer H atoms than the NH4 ; therefore, it is
incorrectly matched.
004

10.0 points

Identify the Lewis Base in the reaction


SO2 + BF3 O2 SBF3 .
1. O2 SBF3

1. Bases make indicators change colors.

2. SO2 correct

2. Bases feel slippery.

3. BF3
Explanation:
b b

b b
b
b

b b

Explanation:
Bases have a bitter taste and have a slippery feel. They also react with acids to form
salts. Both acids and bases give chracteristic colors with indicators. However, bases
produce hydroxide ions, OH , in aqueous solution, not hydrogen ions, H+ .

5. Bases produce hydrogen ions, H , when


added to water. correct

b b

4. Bases react with acids.

b b

b
b

3. Bases taste bitter.

F
b

b
b

SO2 has a lone pair of electrons which it


shares in a coordinate covalent bond with the
electron-poor BF3 .
005 10.0 points
Most common acids are
1. electron pair acceptors and proton donors.
correct

2
2. Cannot tell from the information given.
2. electron pair donors and proton acceptors.
3. electron pair donors and proton donors.
4. electron pair acceptors and proton acceptors.

3. F
4. NH3 correct
5. Neither F1 nor NH3 would be bases.
Explanation:

Explanation:
006 10.0 points
HCN is classified as a weak acid in water.
This means that it produces
1. 100% of the maximum number of possible
hydronium ions.

009 10.0 points


Which pH represents a solution with 1000
times higher [OH ] than a solution with pH
of 5?
1. pH = 1
2. pH = 7

2. a relatively large fraction of the maximum


number of possible hydronium ions.
3. a relatively small fraction of the maximum
number of possible hydronium ions. correct

3. pH = 4
4. pH = 8 correct
5. pH = 5000

4. no hydronium ions.
Explanation:
In water only a small percentage of a weak
acid hydrolyzes, producing H3 O + ions.
007 10.0 points
Which of the following is a strong acid?
1. HF

6. pH = 0.005
7. pH = 6
8. pH = 2
9. pH = 3
Explanation:
pH = 5

2. HCl correct
pOH = 14 pH = 14 5 = 9
3. CH3 COOH

[OH ] = 10pOH = 109 M

4. NaCl
Explanation:
CH3 COOH and HF are weak acids. NaCl
is a salt. HCl is the only strong acid listed.
008 10.0 points
HF is a stronger acid than NH+
4 . Which base
would be stronger: F or NH3 ?
1. Both bases would be equal in strength.

[OH ]x = 1000 [OH ] = (103 )(109 M)


= 106 M
pOHx = log(OHx ) = 6
pHx = 14 pOHx = 14 6 = 8
010 10.0 points
Sea water has a pH = 8.1. What is its hydronium ion concentration?

3
1. 1.3 106 M

6. 0.000178 g

2. 5.9 M

7. 1.36 g

3. 8.0 101 M

8. 0.0112 g

4. 7.9 109 M correct

9. 5.49 g
Explanation:
pH = 3.75
MM = 63.1 g/mol

5. 1.0 108 M
Explanation:
011 10.0 points
What is the pH of a solution for which [OH ]
equals 6.7 1010 M?

V = 11.5 L

[H+ ] = 10pH = 103.75 = 0.000177828


Since HNO3 is a strong acid,

Correct answer: 4.82607.


Explanation:
[OH] = 6.7 1010 M

HNO3 (aq) H+ (aq) + NO


3 (aq) .
pH = ?

[H3 O+ ][OH ] = 1.0 1014 M2


1.0 1014 M2
[H3 O+ ] =
[OH ]
1.0 1014 M2
=
6.7 1010 M
= 1.49254 105 M
pH = log[H3 O+ ]
= log(1.49254 105 )
= 4.82607

One HNO3 one H+ , so


[H+ ] = [HNO3 ] = 0.000177828 M and
(11.5 L)

0.000177828 mol HNO3


1L
= 0.00204502 mol HNO3 .

Thus
63.1 g HNO3
(0.00204502 mol HNO3 )
1 mol HNO3
= 0.129041 g HNO3
013 10.0 points
What is the pH of a 0.006 M KOH solution?
1. 11.78 correct

012 10.0 points


How many grams of HNO3 are needed to give
a pH of 3.75 in an 11.5 L tank? The molar
mass of HNO3 is 63.1 g/mol.
1. 0.00204 g
2. 0.129 g correct
3. 0.466 g
4. 2.19 g
5. 0.0000324 g

2. 5.12
3. 8.88
4. 2.22
5. 7.00
Explanation:
[KOH] = 0.006 M
KOH is a strong base which completely
dissociates in aqueous solution:
KOH OH + K+

[OH] = [KOH] = 0.006 M

4
2. 105 M HCl

[H3 O+ ] =

1 1014

Kw
=
M
[OH ]
0.006
= 1.66667 1012 M

pH = log[H3 O+ ] = 11.7782
014 10.0 points
What is the pH of 500 mL of solution containing 6.20 mg of Ca(OH)2 (74.1 g/mol)?
1. 10.83
2. 9.68
3. 10.52 correct
4. 3.48
5. 3.77
6. 3.17
7. 10.22
Explanation:
015 10.0 points
Which substance is NOT a soluble, strong
base?
1. Ba(OH)2
2. LiOH
3. KOH
4. NaOH
5. Zn(OH)2 correct
Explanation:
All are stong bases except for Zn(OH)2 .
016 10.0 points
Select the solution with the highest pH.
1. 105 M Ca(OH)2

3. 103 M H2 SO4
4. 103 M Ca(OH)2 correct
5. 103 M HCl
6. 105 M NaOH
7. 103 M NaOH
Explanation:
A solution with a high pH is a basic solution
so you can eliminate all the acid solutions.
Now you are looking for the solution that
produces the largest number of moles of OH .
103 M is more concentrated than 105 M.
Ca(OH)2 produces twice as many moles of
OH than NaOH. Therefore 103 M Ca(OH)2
will have the highest pH.

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