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Y energy
A 4
Z 2
4
2
Beta-minus Decay:
A
Z
Y energy
A
Z 1
0
1
Beta-plus Decay:
A
Z
Y energy
A
Z 1
0
1
Conservation of Mass Energy: The total massenergy of a system must not change in a
nuclear reaction.
Y Q
A 4
Z 2
4
2
A4
K .E.
Q
A
4
K .E. Q
A
Rate of decay
dN/dt = -l*N
where
l is the decay constant
N is the number of nuclei present in a sample of
radioactive nuclide at a certain time ( number of
undecayed nuclei)
The minus sign comes from the fact that dN/dt is
DECREASING rather than growing.
dN/dt = -l*N
We can solve this differential equation for N(t):
dN/N = -l dt , or ln (N) = -l t + ln (No)
ln (N/No) = -l t , or N(t) = No e-lt
The rate of decay for radioactive substances can be
expressed in terms of the activity A:
A = lN = lNoe-lt = Aoe-lt
A = Aoe-lt
This means that the activity decreases exponentially
with time also
Half Life
N(t) = No e-lt
The number of radioactive atoms decreases with
time.
Half Life
After two half lives, is the number now down to
zero?
NO. After a second half life, we only have half as
much as we did after the first half life:
N(t = 0) = No
N(t = 1 half life) = No
A=Aoe-lt
Review:
N(t) = No e-lt
A = lN = Aoe-lt
Table N provides us
with a list of various
nuclides, their decay
modes, and their halflifes.
Using Table N, what is
the decay mode and
half-life for Radium226?
Radium-226 undergoes
alpha decay.
Radium
Radon
Using Half-life
Table N also tells us that Radium-226 has a
half-life of 1600 years.
Starting with a
100g sample, after
1 half-life (or 1600
years), 50g remain.
After another
1600 years, half of
the 50g will remain
(25g).
Example 1:
A 10 gram of sample of Iodine-131 undergoes
decay, what will be the mass of iodine remaining
after 24 days?
From Table N, the life of iodine is determined
to be approximately 8 days.
Example 2:
The percent of C-14 is found to be 25% of what the original
C-14 concentration was. What is the age of the sample?
First, lets analyze how many half-lives have taken place.
Nuclear Reactions
It is possible to alter the structure of a nucleus
by bombarding it with small particles. Such
events are called nuclear reactions:
x+XY+y
General Reaction:
N H O
14
7
1
1
17
8
H Li He X energy
7
3
4
2
A
Z
Charge before = +1 + 3 = +4
Charge after = +2 + Z = +4
Z=42=2
(Helium has Z = 2)
Nucleons before = 1 + 7 = 8
Nucleons after = 4 + A = 8 (Thus, A = 4)
1
1
H 37 Li 42 He 42 He Q
The energy released or absorbed is called the Qvalue and can be found if the atomic masses are
known before and after.
1
1
H 37 Li 42 He 42 He Q
Q 11 H 37 Li 42 He 42 He
1
1
H 1.007825 u
7
3
Li 7.016003 u
4
2
He 4.002603 u
4
2
He 4.002603 u
Q =17.3 MeV
1. Spontaneous Fission
Heavy nuclei are highly unstable and decay
spontaneously by splitting into 2 smaller nuclei.
Such spontaneous decays are accompanied by the
release of neutrons.
2. Induced Fission
Nuclear fission can be induced by bombarding
atoms with neutrons.
The nuclei of the atoms then split into 2 equal parts
Induced fission decays are also accompanied by the
release of neutrons.
Example:
235
U
n
+
92
0
141
92
Ba
Kr
n
3
+
+
56
36
0
1
0n
235
92 U
1
0n
235
92 U
1
0n
235
92 U
1
0n
235
92 U
236
92 U
1
0n
92
36 Kr
1
0n
1
0n
92
36 Kr
1
0n
reaction.
Fission
produces
a chain
reaction
235
92
U +0n
138
96
Cs + 37Rb+ 20n
55
Element
Atomic Mass (kg)
235 U
-25
3.9014
x
10
92
138 Cs
-25
2.2895
x
10
55
96 Rb
-25
1.5925
x
10
37
1 n
1.6750 x 10-27
0
The total mass before fission (LHS of the equation):
3.9014 x 10-25 + 1.6750 x 10-27 = 3.91815 x 10-25 kg
= 2.65 x 10-28 kg
E = 2.385 x 10-11 J
The energy released from this fission reaction
does not seem a lot because it is produced from
the fission of a single nucleus.
Fission
Process of splitting
a nucleus into
smaller nuclei
Both
Reactions
produce
energy
2 small, light
nuclei combine to
form one larger,
heavier nucleus
H
H
+
1
1
Energy
He
n
+
+
2
0
2
1H
3
1H
2
1H
3
1H
2
1H
3
1H
2
1H
3
1H
1
0n
4
2 He
1
0n
4
2 He
4
2 He
4
2 He
H
H
+
1
1
Element
2 H
1
3 H
1
4 He
2
1 n
0
Energy
He
n
+
+
2
0
Atomic Mass (kg)
3.345 x 10-27
5.008 x 10-27
6.647 x 10-27
1.6750 x 10-27
E = 2.79 x 10-12 J
The End