Вы находитесь на странице: 1из 3

Unit-Test

Subject

Duration

Class

Marks

Chemistry

1.5 hr

XII

44

1 Marks
1. For an amine RNH2, write an expression to indicate its basic strength [1]
2. Give one use of quaternary ammonium salts. [1]
3. Give one example of Hoffmann Bromamide reaction [1]
4. Distinguish between ethylamine and aniline. [1]
5. The IUPAC name of secondary amine having lowest molecular mass is _________.
[1]
6. Give an example of diazotization [1]
7. What is denatured alcohol?
8.Mention two important uses of methanol.
9. Explain the following giving one example. Friedel-Crafts acetylation of anisole
10. Illustrate the following reaction by giving a chemical equation.Williamson's
synthesis.
12. Phenyl methyl ether reacts with HI to give phenol and methyl iodide and not
iodide benzene and methyl alcohol. Why?
13.Give chemical tests to distinguish between phenol and benzoic acid.
14. Illustrate the following reaction giving a suitable example: Decarboxylation.
15.Draw the structure of the following compound. Hexane-1, 6-dioic acid.
16.Illustrate the following name reaction giving suitable example; Hell-VolhardZelinsky reaction.

17.How would you complete the following observation? Write the complete
equation. Benzoic acid to m-nitrobenzyl alcohol.
18.Write the structure of 2-(2-chlorophenyl)-1-iodooctane.

19.Write the structure of the following compound 1-bromo-4-sec butyl-2-methyl


benzene.
20.Write the structure of the following organic compound 2-chloro-3methylpentane.

21.Which will react faster in SN2 displacement, 1-bromopentane or 2bromopentane and why?
22.Write the structure of the following compound 3-(4-chlorophenyl)-2-methyl
propane.
2 marks
1. Write the structure of 2-(2-chlorophenyl)-1-iodooctane.
2. Write the structure of the following compound 1-bromo-4-sec butyl-2-methyl
benzene.
3. Write the structure of the following organic compound 2-chloro-3methylpentane.
4. Which will react faster in SN2 displacement, 1-bromopentane or 2bromopentane and why?
5. Write the structure of the following compound 3-(4-chlorophenyl)-2-methyl
propane.
6. Explain the mechanism of add catalysed hydration of an alkene to form
corresponding alcohol.
7. How would you obtain
(i)
picric acid from phenol?
(ii)
2-methyl propanol from 2-methyl propene?
8. Account for the following
(i)
Propanol has higher boiling point than butane.
(ii)
Ortho-nitrophenol is more acidic than ortho-methoxy phenol
(iii)
Explain the mechanism of a nucleophilic attack on the carbonyl group of
an aldehyde or a ketone.
(iv)
Although phenoxide ion has more number of resonating structures than
carboxylate ion, carboxylic acid is a stronger acid than phenol. Give two
reasons.
9. How will you carry out the following conversions?
(i) Acetylene to acetic acid
(ii) Toluene to m-nitrobenzoic Acid
10.It is difficult to prepare pure amines by ammonolysis of alkylhalides. [2]
11. Amines have higher boiling points than hydrocarbons of similar molecular
mass.[2]

Вам также может понравиться