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NATIONAL
CHEMISTRY OLYMPIAD
NATIONAL EXAM PART I
Prepared by the American Chemical Society Olympiad Examinations Task Force
Sherry Berman-Robinson, Consolidated HS, Orland Park, IL (retired) Preston Hays, Glenbrook South HS, Glenbrook, IL
Seth Brown, University of Notre Dame, Notre Dame, IN
60 questions
8 questions
2 lab problems
single-answer multiple-choice
problem-solving, explanations
laboratory practical
1 hour, 30 minutes
1 hour, 45 minutes
1 hour, 30 minutes
A periodic table and other useful information are provided on page 2 for student reference. Students should be permitted to use nonprogrammable calculators.
DIRECTIONS TO THE EXAMINEEPART I
DO NOT TURN THE PAGE UNTIL DIRECTED TO DO SO. Answers to questions in Part I must be entered on a Scantron
answer sheet to be scored. Be sure to write your name on the answer sheet; an ID number is already entered for you. Make a record
of this ID number because you will use the same number on both Parts II and III. Each item in Part I consists of a question or an
incomplete statement that is followed by four possible choices. Select the single choice that best answers the question or completes the
statement. Then use a pencil to blacken the space on your answer sheet next to the same letter as your choice. You may write on the
examination, but the test booklet will not be used for grading. Scores are based on the number of correct responses. When you
complete Part I (or at the end of one hour and 30 minutes), you must turn in all testing materials, scratch paper, and your Scantron
answer sheet. Do not forget to turn in your U.S. citizenship statement before leaving the testing site today.
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
Distributed by the ACS DivCHED Examinations Institute, Iowa State University, Ames, IA.
All rights reserved. Printed in U.S.A.
amount of substance
ampere
atmosphere
atomic mass unit
atomic molar mass
Avogadro constant
Celsius temperature
centi prefix
coulomb
electromotive force
energy of activation
enthalpy
entropy
equilibrium constant
CONSTANTS
M
M
mol
h
P
k
Q
s
c
T
t
V
V
R = 8.314 Jmol1K1
R = 0.0821 Latmmol1K1
1 F = 96,500 Cmol1
1 F = 96,500 JV1mol1
NA = 6.022 1023 mol1
h = 6.626 1034 Js
c = 2.998 108 ms1
0 C = 273.15 K
EQUATIONS
E = Eo !
1
1A
1
H
RT
ln Q
nF
"k % E " 1 1 %
ln$$ 2 '' = a $$ ( ''
# k1 & R # T1 T2 &
18
8A
2
He
3
Li
2
2A
4
Be
13
3A
5
B
14
4A
6
C
15
5A
7
N
16
6A
8
O
17
7A
9
F
6.941
9.012
10.81
12.01
14.01
16.00
19.00
20.18
11
Na
12
Mg
13
Al
14
Si
15
P
16
S
17
Cl
18
Ar
22.99
24.31
26.98
28.09
30.97
32.07
35.45
39.95
19
K
31
Ga
32
Ge
33
As
34
Se
35
Br
36
Kr
1.008
4.003
10
Ne
20
Ca
3
3B
21
Sc
4
4B
22
Ti
5
5B
23
V
6
6B
24
Cr
7
7B
25
Mn
8
8B
26
Fe
9
8B
27
Co
10
8B
28
Ni
11
1B
29
Cu
12
2B
30
Zn
39.10
40.08
44.96
47.88
50.94
52.00
54.94
55.85
58.93
58.69
63.55
65.39
69.72
72.61
74.92
78.96
79.90
83.80
37
Rb
38
Sr
39
Y
40
Zr
41
Nb
42
Mo
43
Tc
44
Ru
45
Rh
46
Pd
47
Ag
48
Cd
49
In
50
Sn
51
Sb
52
Te
53
I
54
Xe
85.47
87.62
88.91
91.22
92.91
95.94
(98)
101.1
102.9
106.4
107.9
112.4
114.8
118.7
121.8
127.6
126.9
131.3
55
Cs
56
Ba
57
La
72
Hf
73
Ta
74
W
75
Re
76
Os
77
Ir
78
Pt
79
Au
80
Hg
81
Tl
82
Pb
83
Bi
84
Po
85
At
86
Rn
132.9
137.3
138.9
178.5
180.9
183.8
186.2
190.2
192.2
195.1
197.0
200.6
204.4
207.2
209.0
(209)
(210)
(222)
87
Fr
88
Ra
89
Ac
104
Rf
105
Db
106
Sg
107
Bh
108
Hs
109
Mt
110
Ds
111
Rg
112
Uub
114
Uuq
(223)
(226)
(227)
(261)
(262)
(263)
(262)
(265)
(266)
(269)
(272)
(277)
(2??)
58!
Ce
Page 2
59
Pr
60
Nd
61
Pm
62
Sm
63
Eu
64
Gd
65
Tb
66
Dy
67
Ho
68
Er
69
Tm
70
Yb
71
Lu
140.1
140.9
144.2
(145)
150.4
152.0
157.3
158.9
162.5
164.9
167.3
168.9
173.0
175.0
90
Th
91
Pa
92
U
93
Np
94
Pu
95
Am
96
Cm
97
Bk
98
Cf
99
Es
100
Fm
101
Md
102
No
103
Lr
232.0
231.0
238.0
(237)
(244)
(243)
(247)
(247)
(251)
(252)
(257)
(258)
(259)
(262)
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
DIRECTIONS
When you have selected your answer to each question, blacken the corresponding space on the answer sheet using a soft, #2
pencil. Make a heavy, full mark, but no stray marks. If you decide to change an answer, erase the unwanted mark very carefully.
There is only one correct answer to each question. Any questions for which more than one response has been blackened will not
be counted.
Your score is based solely on the number of questions you answer correctly. It is to your advantage to answer every question.
(B) CaO
(C) CO
(D) SO2
(B) N2
(C) NH3
(D) CH4
(B) blue
(C) green
(D) yellow
7. What is the
Formula Weight, g
mass percent
UO2(C2H3O2) 2.NH4C2H3O2.6H2O
of oxygen in the compound
UO2(C2H3O2) 2NH4C2H3O26H2O?
(A) 5.58%
(B) 16.8%
(C) 22.3%
573
(D) 39.1%
reported concentration
(A) increased
too low
(B) increased
too high
(C) decreased
too low
(D) decreased
too high
(A) 2.9
(B) 3:1
(C) 4:1
(C) 18
(D) 36
(B) 5
(C) 6
(D) 8
(A) 2:1
(B) 7.2
(B) 80.0%
(C) 90.0%
(D) 100.%
(D) 3:2
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
Page 3
(B) N2H4
(C) H2O2
(D) HCl
(B) 1.15 g
(C) 1.61 g
(D) 2.30 g
(B)
2: 1
(D)
323 :
298
(B) II only
(B) II only
Hf, kJ.mol-1
H2O(g)
NH3(g)
2NO(g) + 3H2O(g). NO(g)
(A)! 105.4
(B) 226.3
(C) 452.6
241.8
46.1
90.3
(D) 637.0
(B) 33.9
(C) 29.5
(D) 23.2
(B) 3.71
(C) 19.2
(D) 44.2
Page 4
(B) 6
(C) 12
(D) 16
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
catalyst
intermediate
(A) SO2(aq)
H2O(l)
HSO3(aq), H3O+(aq)
(B) SO2(aq)
HSO3(aq)
S2O72(aq)
S2O72(aq)
HSO3(aq)
! HI(g) to a
32. A 1.0 L evacuated tank is charged with
pressure of 1.0 atm at 793K.
! Some of the HI(g) forms
H2 (g) and I2(g) according to the equilibrium;
2HI(g) s H2(g) + I2(g)
Kp = 0.016
What is the pressure (in atm) of HI at equilibrium?
(A) 0.11
(B) 0.13
(C) 0.80
(D) 1.6
(B) 1.6105
(C) 6.31010
(D) 6.31011
(B) 4.70
(D) 8.95
HSO3(aq), S2O72(aq)
29. For the reaction; H2(g) + I2(g) r 2HI(g), the rate law is
Rate = k[H2][I2].
Which of the mechanisms given is consistent with this
rate law?
I.
II.
I2 s I + I
(fast)
I2 s I + I
(slow)
H2 + I + I r 2HI (slow)
H2 + I + I r 2HI (fast)
(A) I only
(B) II only
(C) Either I or II
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
Page 5
(A) 3, 2, 0
(B) 3, 1, 1
(C) 2, 0, 0
(D) 1, 1, 0
(A) size
(B) shape
(C) occupancy
(D) orientation
(A) 2.10 V
(B) 1.54 V
(C) 1.26 V
(D) 0.42 V
(A) Na
(B) 2.03 V
(C) 1.97 V
(D) 1.94 V
(B) 12
(C) 14
(D) 16
E = 0.80 V
Ag+(aq) + e r Ag(s)
E = 0.13 V
Pb2+(aq) + 2e r Pb(s)
reduction potentials, what is the free energy change (in
kJ.mol-1) for the reaction
Pb(s) + 2Ag+(aq) r Pb2+(aq) + 2Ag(s)?
(A) 180
(B) 90
(C) 90
(D) 180
(B) 96.5
(C) 64.3
(D) Si
47. The energies of the 3s, 3p and 3d orbitals in a multielectron atom increase in that order. To which factor(s)
can this order be attributed?
I. the relative penetrations of these orbitals near the
nucleus
II. the relative average distance of the electron from the
nucleus
(A) I only
(B) II only
(B) Si
(C) P
(B) +1
(D) S
O
H O N O
(C) +3
(D) +5
(B) KCl
(D) 32.2
(A) 156
Page 6
(B) Mg
(B) 99
(C) MgI2
(D) BaS
(D) 156
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
(B) NCl3
(C) CO32
(D) I3
I. PCl3
II. COCl2
III. SF4
(A) I only
(B) two
(C) three
I.
II.
III.
IV.
(B)
(C)
(D)
(D) four
amide
amine
ether
ester
(A) II only
H
H
(A) identical.
(D) enantiomers.
OH
CH3
(C) CH3CH2 CH2OH
(B)
OH
(B) 17.5
(C) 175
(D) 1750
NO2
END OF TEST
(D) (CH3)3COH
Not valid for use as an USNCO Olympiad National Exam after April 29, 2009.
Page 7
Number
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
Answer
D
C
D
B
B
A
D
A
B
C
B
A
D
C
B
C
C
A
A
D
C
C
D
D
C
B
C
D
A
D
Number
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.
42.
43.
44.
45.
46.
47.
48.
49.
50.
51.
52.
53.
54.
55.
56.
57.
58.
59.
60.
Not for use as a USNCO Local Section Exam after April 29, 2009
Answer
A
C
B
A
D
B
A
D
B
D
A
A
C
D
D
B
A
C
B
A
B
C
A
C
C
B
B
A
A
B