7 - BTS - (12th) - JEE Adv. (Paper-II) - 29-11-2015 - All

Date: 29-112015
BYJ
US
CLASSES
Code:
B
Time: 12:30pm
Think & Learn Pvt. Ltd.
TEST No.7
JEE Advanced (PAPER-2)
BYJUS Test Series (BTS)
CLASS : 12th (PCM)
Time: 3 Hours
Maximum Marks: 240
Topics Covered:
Physics
: Ray Optics, Wave Optics, Dual nature of matter and Radiation,
Atoms and Nuclei

Chemistry : Solid State, Solutions, p and d-block elements, coordination
Compounds, Metallurgy
Maths
Calculus Complete, Matrices, and Determinants
Important Instructions:
1. Attempting all the questions are compulsory.
2. Use Blue/Black Ball point pen only.
3. There are 60 questions in the paper (20 Questions in each subject) .
4. Section-1 contains 8 questions. The answer to each question is a single digit integer
ranging from 0 to 9
(Both inclusive).
Marking scheme : +4 for correct answer and 0 in all other cases.
5. Section-2 contains 8 multiple choice questions with one or more than one correct option.
Marking scheme : +4 for correct answer, 0 if not attempted and 2 in all other cases.
6. Section-3 contains 2 Paragraph type questions. Each paragraph describes an
experiment, a situation or a problem. Two multiple choice questions will be asked based
on this paragraph. One or more than one option can be correct.
Marking scheme : +4 for correct answer, 0 if not attempted and 1 in all other cases.
7.
8.
Use of calculator and other electronic devices is not allowed during the exam.
No extra sheets will be provided for any kind of work.
BYJUS CLASSES : 1st Floor, K-40, Outer Circle, Opposite PVR Plaza, Connaught Place, New Delhi110001
[1]
Name of the Student : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Roll No.: . . . . . . . . . . . . . . . . . . .

Fathers Name : . . . . . . . . . . . . . . . . . . . . . . . . . Class : . . . . . . . . Signature : . . . . . . . . . . . . . . . .
Centre Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Contact No : . . . . . . . . . . . . . . . . . . . .
[2]
PART-I :
SECTION-1 (MAXIMUM MARKS : 32)
1.
This section contains EIGHT questions

The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
For each equation, darken the bubble corresponding to the correct integer in the ORS
Marking scheme:
+4
If the bubble corresponding to the answer is darkened
0 In all other cases
A thin lens of refractive index 1.5 is silvered as shown in the figure. Radius of silvered surface is 20cm and the other
surface is 10cm. An object is placed at a distance of 20cm from this combination. If the distance of image from the
object is 10 x cm. Find the value of x.
O
20cm
2.
The image of a real object, formed by a plano-concave lens at a distance of 4m from the lens, is virtual and one-third of
2
3
the size of the object. The speed of light inside the lens is times the speed in free space. The radius of the curved
surface of the lens is (in meter).
3
d
2
3.
Two sources are placed on x-axis at a separation

, where is the wavelength of light of both the sources. An
observer starts moving from A on a circular track of radius R. Find the total number of dark points that he observes in
one revolution.
R
S1
S2
d
2
d
2
A x
4.
Light corresponding to the transition n=4 to n=2 on He + ion falls on copper metal (work function 4.5eV). If the
maximum kinetic energy of the emitted photoelectrons is XeV. Find [x] where [ ] represents greatest integral part.
5.
How many different wavelengths may be observed in the spectrum from a hydrogen sample if the atoms are excited to
states with principal quantum number 4?
8p
9q
6.
For a metal ratio of wavelength of k and k characteristic X-rays is

Value of (p-q) is
where p and q are smallest possible integers.
Space for Rough Work
[3]
2
3
7.
Three harmonic waves of equal frequencies and equal intensities. I o have phase angles 0,
superposed, the intensity of the resulting wave is mI 0. The value of m is.
and
. When they are
8.
The activity of a freshly prepared radioactive sample is 10 12 disintegrations per second, whose mean life is 10 9s. The
mass of an atom of this radioactive isotope is 10-23kg. The mass of the radioactive sample is 10xmg. Find x?
9.

Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are)
correct
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme:
+4
If the bubble(s) corresponding to all the correct option(s) is(are) darkened
0 If none of the bubbles is darkened
Read the statements carefully and choose the correct alternative (s).
(A) For short range (<10-15m), nuclear force is the strongest force of nature.
(B) Nuclear density is almost independent of the mass number.
(C) Mass of positron is same as that proton.
(D) Mass of positron is same as that of electron
10. In an experiment to determine the focal length (f) of a concave mirror by the u- method, a student places the object
pin A on the principal axis at a distance x from the pole P. The students looks at the pin and its inverted image from a
distance keeping his/her eye in line with P . When the student shifts his/her eye towards right, the image appears to
the left of the object pin. Value of x can not be equal to
5f
3f
4f
7f
2
2
3
3
(A)
(B)
(C)
(D)
11. A tank contains three layers of immiscible liquids as shown in the figure. Top layer is of water. A bird and a fish watch
the bottom of the tank. Bird is flying just above the water-air interface whereas fish is floating just below the water-air
interface. Choose the correct alternative (s).
8cm
=4/3
9cm
= 3/2
4cm
=2
(A) Apparent depth of the tank is 14cm as seen by the bird.

(B) Apparent depth of the tank is 8cm as seen by the fish.
(C) Apparent depth of the tank is 16cm as seen by the fish
(D) Apparent depth of the tank is 18.6cm as seen by the fish.
12. Read the following statements carefully and choose the incorrect alternative (s).
(A) Penetrating power of alpha ray is lower than that of Beta and gamma ray.
(B) Gamma ray has the greater ionizing power as compared to Beta ray.
(C) Alpha ray cannot be deflected by an electric field
(D) Gamma ray cannot be deflected by electric field
[4]
[5]
13. During an experiment it is found that green light does not eject photoelectrons from a metal. Now which of the
following colours of light is/are certainly not able to eject photoelectrons as per the given information.
(A) Yellow
(B) Blue
(C) Orange
(D) Indigo
14. Which of the following statements are correct about the optical components.
(A) For concave mirror, velocity of image is always opposite to the velocity of object.
(B) For convex lens minimum distance between the object and its real image is 4 | f |.
(C) Concave lens can never form a real image of a real object.
(D) If the incidents beam is convergent, image will always be real.
15. An object and a plane mirror are approaching towards each other with each having speed of 3m/s w.r.t lab. Choose the
correct alternative (s)
(A) Velocity of image w.r.t. lab is 3 m/s
(B) Velocity of image w.r.t. lab is 9 m/s
(C) Velocity of image w.r.t. lab is 6 m/s
(D) Velocity of image w.r.t. mirror is 6 m/s
16. In a Youngs double slit experiment, the separation between the slits is 0.10 mm, the wavelength of light used is 600
mm and the interference pattern is observed on a screen 1.0 m away. Choose the correct alternative (s).
(A) The separation between the successive bright fringes is 6 mm.
(B) The separation between the successive dark fringes is 9 mm.
(C) Total number of maxima observed on the screen is 333.
(D) Total number of minima observed on the screen is 332.
This section contains TWO paragraphs

Based on each paragraph, there will be TWO questions
correct.
Marking scheme:
+4
If only the bubble(s) corresponding to all the correct match(s) is(are) darkened
Paragraph1
When light of sufficiently high frequency is incident on a metallic surface electrons are emitted from the surface. These
electrons are called photoelectrons and this effect is called photoelectric effect. Max. K. E. of photoelectrons is (hv )
where v is frequency of incident light and is work function of the metal. Reverse of photo-emission produces X-rays
in a Coolidge Tube. Min wavelength of X-rays depends on potential difference applied across the Coolidge Tube.
17. A monochromatic light is used in a photoelectric experiment. The stopping potential
(A) Depends on wavelength (B) Depends on frequency
(C) Depends on intensity
(D) Depends on max. K. E.
18. If potential difference across a Coolidge tube is increased then
(A) min will increase
(B) min will decrease
(C) min will remain unchanged
(D) Wavelength of characteristic x-rays will change.
Paragraph-2
When a monochromatic light coming from two slits, integer on a screen, alternate dark and bright fringes are formed
I a12 a 22 2a1a 2 cos
on screen. Assume that intensity at a point on the screen is
where a1 and a2 are amplitudes of
interfering waves and is phase difference between the waves at that point. Give that the maximum intensity on the
I0 ,a1 2a
a 2 3a.
screen is
and
Answer the following
[6]
19. If wavelength is
Io
4
(A)
then intensity at a point having a path different

13I0
25
(B) Zero
(C)
will be
Io
(D)
20. If the slits are arranged as shown below then ratio of intensities at A and at B wil be (B is on perp. Bisector)
Graph
(A) 0
(B) 1:1
(C) 1:13
(D) 1:25
PART-II :

Marking scheme:
+4
21. If radius ratio is less than 0.155, the co-ordination no. is.
22. Number of second nearest neighbours in body centred lattice is.
23. Co-ordination no. of Cs+ in CsCl is..
24. In HCP arrangement of atoms, co-ordination no. of atoms in the middle layer is.
25. Total number of rings formed in a bis- (dimethyl glyoximato) nickel (II) complex are
26. A solution containing 2.665 gm of CrCl 3.6H2O is passed through AgNO3 solution and gives 2.87 gm of AgCl ppt.
Determine the number of ions in aqueous solution
27. The number of geometrical isomers possible for complex [Pt Cl Br I (NH 3)] would be
28. Sodium thiosulphate is used to remove the unexposed AgBr from photographic films by forming a complex. In this
complex of silver, the coordination number of silver is:

correct
Marking scheme:
+4
29. In the electrolysis of alumina, cryolite is added to

(A) Lower the melting point of alumina
(C) Minimize the anode effect
(B) Increase the electrical conductivity

(D) Remove impurities from alumina
30. Which of the following statements are not correct?

(A) A mineral is an ore but an ore may not be a mineral
(B) In the blast furnace, temperature rises as one moves from bottom to top
(C) In the blast furnace involving the reduction of ferric oxide, the main reaction occurring in the zone of fusion is
CO 2 C 2CO.
(D) The zone of reduction in the blast furnace involving the metallurgy of iron lies in the middle portion of the furnace
[7]
[8]
31. Which of the following statements are correct?

(A) In extractive metallurgy of zinc partial fusion of ZnO with coke is called sintering and reduction of the ore to the
molten metal is called smelting
(B) A mineral from which a metal can be profitably extracted is known as ore
(C) The principal ore of iron from which it is extracted is haematite
(D) Air is blown in blast furnace through water-jacketed pipes called tuyers
32. When a non-volatile solute is added to a pure solvent, the
(A) Vapour pressure of the solution becomes lower than that of the pure solvent
(B) Rate of evaporation of the pure solvent is reduced
(C) Solute does not affect the rate of condensation
(D) Rate of evaporation of the solution is equal to the rate of condensation of the solution at a lower vapour pressure
than that in the case of the pure solvent.
33. Which of the following combinations are correct for a binary solution, in which the solute as well as the solvent are
liquid?
H so ln 0;
Vso l 0
(A) C6H6 and C6H5CH3;
H so ln 0;
Vsol 0
(B) CH3COCH3 and CHCl3;
H so ln 0;
Vsol 0
(C) H2O and HCl;
H so ln 0;
Vsol 0
(D) H2O and C2H5OH;
34. The azeotropic solutions of two miscible liquids
(A) Can be separated by simple distillation
(B) May show positive or negative deviation from Raoults law
(C) Are supersaturated solutions
(D) Behave like a single component and boil at a constant temperature
(PBenzene
42mm of Hg)
(PToluene
36mm of Hg)
35. 1 mole of benzene

and 2 mole of toluene
(A) Positive deviation from Raoults law
(B) Negative deviation from Raoults law
(C) Total vapour pressure 38 mm
(D) Mole fraction of vapours of toluene above liquid mixture is 12/19
will have
36. In which of the following pairs, both the complexes have the same geometry?
(A) [NiCl4]2, [Ni(CN)4]2
(B) [CoF6]3, [Co(NH3)6]3+
2
(C) [Ni(CO)4], [Ni(CN)4]
(D) [Cu(NH3)4]+, [Ni(NH3)4]2+

correct.
Marking scheme:
+4
[9]
Paragraph1
Transition metal and their compounds are used as catalysts in industry and in biological system. For example, in the
VO 3
contact process, vanadium compounds in the +5 state (V2O5 or
) are used to oxidize SO2 to SO3:
1
V2 O5
SO 2 O
SO3
2
2
It is thought that the actual oxidation process takes place in two stages. In the first step, V 5+ in the presence of oxide
ions converts SO2 to SO3. At the same time, V5+ is reduced to V4+.
2V 5 O 2 SO 2 2V 4 SO3
In the second step, V5+ is regenerated from V4+ by oxygen:
1
2V 4 O2 2V5 O 2
2
The overall process is, of course, the sum of these two steps:
1
SO 2 O 2 SO 3
2
37. Transition metals and their compounds catalyse reactions because:
(A) They have completely filled s-subshell
(B) They have a comparable size due to poor shielding of d-subshell
(C) They introduce an entirely new reaction mechanism with a lower activation energy
(D) They have variable oxidation states differ by two units
38. During the course of the reaction:
(A) Catalyst undergoes changes in oxidation state
(C) Catalyst is regenerated in its original form
(B) Catalyst increases the rate constant

(D) All are correct
Paragraph2
When degenerate d-orbitals of an isolated atom/ion come under influence of magnetic field of ligands, the degeneracy
eg (d x 2 y2 , d z2 )
t 2g (d xy ,d yz ,d xz )
is lost. The two set
and
It can be expressed diagrammatically as:
are either stabilized depending upon the nature of magnetic field.
eg
t 2g
(CFSE)
t 2g
eg
Octahedral field
Tetrahedral field
Value of CFSE depends upon nature of ligands and a spectrochemical series has been made experimentally, for
0
tetrahedral complexes, is about 4/9 times to

(CFSE for octahedral complex). This energy lies in visible region and
i.e., why electronic transition are responsible for colour. Such transition are not possible with d 0 and d10 configuration.
0
39. The value of CFSE (
(I) [Co(NH3)6]3+
(A) I < II < III
) for complexes given below follow the order:

(II) [Rh(NH3)6]3+
(III) [Ir(NH3)6]3+
(B) I > II > III
(C) I < II > III
(D) I = II = III
40. For an octahedral complex, which of the following d-electron configuration will given maximum CFSE ?
High spin d 6
Low spin d 4
Low spin d 5
High spin d 7
0.4 0
(A)
1.6 0
(B)
2.0 0
(C)
0.8 0
(D)
[10]
[11]
PART-III :

Marking scheme:
+4
sin t
dt
t
0
f (x)
41. The number of points of extremum of the function
in (0, 16) is
a 2 k b,
42. Let f : R R given by f(x) = x3 + ax2 + bx + c is a bijection. If
then the value of k is _______.

f
y Df .
43. Let f be a real valued function such that f(x + y) = f(x) f(y), x,
If f(0) = 0; then
is equal to _______.
2
1 x2
2
44. If S is area bounded by the curves y = x and y =
, then the values of [S], where [] stands for greatest integer
function, is equal to________.
2 3
n
lim tan tan tan .........tan

n
2n 2n
2n
2n
45. The value of
46. If
1
n
is equal to ______.
1
9
f n 1 f (n)
,n N
2
f (n)
and f(n) > 0 ,
lim f (n)
. Then
is equal to _______
4 4 x 82/3( x 2) 52 22(x 1)
47. The smallest positive integer in the domain of f(x) =
1 cos 4x
x2
16 x 4
48. Let f(x) =
is.
; x0
; x0
; x0
. If f is continuous at x = 0, then a is equal to _______.

correct
Marking scheme:
+4
49. The points of extremum of function

x
(x) e
t2
2
{1 t 2 }dt
are
[12]
x
(A) x = 0
(B) x = 1
1
2
(C)
(D) x = 1
[13]
50. If line ax + by + c = 0 is a normal to curve xy = 1, then

(A) a > 0, b > 0
(B) a > 0, b < 0
(C) a < 0, b > 0
(D) a < 0, b < 0
51. Let A, B and C be 2 2 matrices with entries from set of real numbers and I be an identity matrix of order 2. Define *
1
(AB BA)
2
as A * B =
, then
(A) A * B = B * A
(B) A * A = A2
(C) A * I = A
(D) A * (B + C) = A * B + A * C
1; x is rational
0; x is irrational
(x)
52. Consider a function
defined as
, then the period of the function is

22
7
(C)
(D)
2
5
(A) 1
(B)
2
f a x b b3 1 3b 2 .f x 3b f x
bR
53. Let a,
be fixed positive numbers such that
x R
Then
(A) 2a is the period of the function
(C) 9a is the period of the function
f x
1
3
(B) 3a is the period of the function

(D) 4a is the period of the function
54. The cardinal number of set A is 6, the total number of symmetric relations is
(A) 230
(B) 221
(C) 220
8
9
1
1
1 x
1 x
I1
dx and I 2
dx.
4
3
1
x
0
01 x
55. Let
Then
I1 1
I2 1
I1 I 2 1
(A)
(B)
(C)
(D) 219
I 2 I1 1
(D)
56. Consider the curve a2x2 = y2(a2 y2), then

(A) The given curve consists of two loops symmetrical about y-axis
2a 2
3
(B) The area of a loop of the curve is
sq. units
4a 2
3
(C) The area enclosed by the given curve is
sq. units
(D) The area of the curve is equal to the half of the area included between the parabola x 2 = 4ay and its latus rectum y=a

correct.
Marking scheme:
+4
If f(x) is continuous on the interval
axb
Paragraph-1
but is discontinuous at x = b, we define
[14]
bh
f (x)dx lim
f (x)dx
h 0
(Provided that limit exists). If f(x) is continuous on internal
axb
, but is discontinuous at
x = a, we define.
b
ah
f (x)dx lim
f (x)dx
h 0
(Provided that limit exists)
axb
If f(x) is continuous for all values of x on the interval

b
c h
except x = c, where a < c < b, we define
f (x)dx hlim
f (x)dx hlim
f (x)dx
0
0
c h
(Provided that both limit exists). Using above concept solve following
questions.
3
dx
9 x2
57.
is equal to
(A)
(B)
(C)
3
(D)
x2
1 x2
58. The area between the curve y2 =

and its asymptotes is
(A) 1square units
(B) 2 square units
(C) 4 square units
(D) 16 square units
Paragraph-2
One of the application of maxima and minima of a function is to find the largest term of a given sequence by replacing
nth term by f(x) and n by x, then answer the following questions.
1
4
9 16
,
,
,
,..........is
201 208 227 264
59. The largest number of the sequence defined as
29
43
453
543
(A)
(B)
36
416
(C)
49
543
(D)
x2
x 3 200
60. The function f(x) =

(A) Increases for all x
x (400)
(C) Has a maxima at
(B) Decreases for all x

1
3
(D) Increases in [0, 9]

[15]

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Date: 29-112015

Think & Learn Pvt. Ltd.

Maximum Marks: 240

: Ray Optics, Wave Optics, Dual nature of matter and Radiation,

Atoms and Nuclei

Calculus Complete, Matrices, and Determinants

Name of the Student : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Roll No.: . . . . . . . . . . . . . . . . . . .

This section contains EIGHT questions

Two sources are placed on x-axis at a separation

For a metal ratio of wavelength of k and k characteristic X-rays is

where p and q are smallest possible integers.

Space for Rough Work

. When they are

SECTION-2 (MAXIMUM MARKS : 32)

This section contains EIGHT questions

(A) Apparent depth of the tank is 14cm as seen by the bird.

SECTION-3 (MAXIMUM MARKS : 16)

This section contains TWO paragraphs

then intensity at a point having a path different

This section contains EIGHT questions

SECTION-2 (MAXIMUM MARKS : 32)

This section contains EIGHT questions

29. In the electrolysis of alumina, cryolite is added to

(B) Increase the electrical conductivity

30. Which of the following statements are not correct?

31. Which of the following statements are correct?

35. 1 mole of benzene

SECTION-3 (MAXIMUM MARKS : 16)

This section contains TWO paragraphs

Space for Rough Work

(B) Catalyst increases the rate constant

are either stabilized depending upon the nature of magnetic field.

tetrahedral complexes, is about 4/9 times to

) for complexes given below follow the order:

Space for Rough Work

This section contains EIGHT questions

41. The number of points of extremum of the function

42. Let f : R R given by f(x) = x3 + ax2 + bx + c is a bijection. If

then the value of k is _______.

45. The value of

and f(n) > 0 ,

SECTION-2 (MAXIMUM MARKS : 32)

This section contains EIGHT questions

49. The points of extremum of function

Space for Rough Work

50. If line ax + by + c = 0 is a normal to curve xy = 1, then

(C) a < 0, b > 0

(D) a < 0, b < 0

52. Consider a function

, then the period of the function is

(B) 3a is the period of the function

56. Consider the curve a2x2 = y2(a2 y2), then

SECTION-3 (MAXIMUM MARKS : 16)

This section contains TWO paragraphs

If f(x) is continuous on the interval

If f(x) is continuous for all values of x on the interval

except x = c, where a < c < b, we define

58. The area between the curve y2 =

(D) 16 square units

60. The function f(x) =

(B) Decreases for all x

(D) Increases in [0, 9]

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