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Test Series - 5/IITJEE - 2013

07/10/2012
PAPER - 1
M.M. : 270
10:00 A.M. - 01:00
TEST CODE :
TIME : 3.00 Hrs
P.M.
ACEG
Read the following Instructions very carefully before you proceed.

1.
The question paper consists of 3 parts (Part I : Chemistry, Part II : Physics, Part III :
Mathematics).
2.
Part I (Chemistry) contains 30 Straight objective type questions. Each question has
4 choices (A), (B), (C) and (D), out of which only one is correct.
3.
Part II (Physics) contains 30 Straight objective type questions. Each question has 4
choices (A), (B), (C) and (D), out of which only one is correct.
4.
Part III (Mathematics) contains 30 Straight objective type questions. Each question
has 4 choices (A), (B), (C) and (D), out of which only one is correct.
5.
For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately.

Please fill your
Test Code, Roll No. and Group Properly in the space given in
the ANSWER SHEET.
6.
For each question in All Parts, you will be given 3 Marks if you have darkened only the
bubble corresponding to the correct answer and zero mark if no bubble is darkened. In all
other cases,
minus ONE (1) marks (NEGATIVE MARKING) will be given.
7.
A blank space has been provided on each page for rough work. You will not be provided
with any supplement or rough sheet. However some blank pages for rough work are
given at the end of this paper.
8.
The use of log tables, calculator and any other electronic device is strictly prohibited.
VMC/IITJEE-2013/ACEG
Test Series - 5/Paper-1
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PART - I (CHEMISTRY)
90 MARKS
STRAIGHT OBJECTIVE TYPE

This Part contains 30 Multiple Choice Questions. Each Question has 4 choices A, B, C
& D, out of which
Only One is Correct :
1.
2.
The ionic mobility of alkali metal ions in aqueous solution is maximum for :
(A)
Na+
(B)
K+
(C)
Rb+
(D)
For the reaction, CO(g) + Cl2(g) COCl2(g) the Kp/Kc is equal to :
(A)
3.
Li+
RT
(B)
RT
(C)
1/RT
(D)
1.0
One mole of magnesium nitride on the reaction with excess water gives :
(A)
two moles of nitric acid
(B)
one mole of nitric acid
(C)
two moles of ammonia
(D)
one mole of ammonia
SPACE FOR ROUGH WORK
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4.
The decomposition temperature is maximum for :

(A)
MgCO3
(B)
SrCO3
(C)
CaCO3
(D)
BaCO3
5.
The two particles A and B have de-Broglie wavelengths 1 nm and 5 nm respectively. If mass of A is four times
the mass of B, the ratio of kinetic energy of A and B would be :
(A)
5:1
(B)
25 : 4
(C)
20 : 1
(D)
1:5
6.
An unknown sample oxides of nitrogen is reddish brown and paramagnetic at room temperature but it
decolourises and also loses its paramagnetism on freezing it. The sample at room temperature is :
(A)
Pure NO2
(B)
Pure N2O4
(C)
equilibrium mixture of N2O4 and NO2 (D)
N2O5
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7.
The correct ionic radii order is :

(A)
N 3 O 2 F Na
(B)
N3- > Na+ > O2- > F-
(C)
Na O 2 N 3 F
(D)
O 2 F Na N 3
8.
Which one of the following compounds gives only 2 monochlorination products ?

(A)
n-hexane
(B)
isohexane
(C)
2, 3-dimethyl butane
(D)
2, 2-dimethyl butane
9.
A sudden large jump between the values of second and third ionisation energy of an element would be
associated with the electronic configuration :
(A)
1s2 2s2 2p6 3s1
(B)
1s2 2s2 2p6 3s2 3p1
2
2
6
2
2
(C)
1s 2s 2p 3s 3p
(D)
1s2 2s2 2p6 3s2
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10.
The case of electrophilic substitution in the above compounds follows the order :
(A)
IV > V > III > II > I
(B)
I > IV > V > III > II
(C)
I > V > IV > III > II
(D)
IV > V > III > I > II
11.
If an endothermic reaction is non-spontaneous at its freezing point and becomes feasible at its boiling point,
then :
(A)
(B)
H is ve , S is +ve
H and S both are +ve
(C)
(D)
H and S both are ve
H is +ve, S is ve
12.
Arrange the following compounds in order of ease of dehydrohalogenation :
The correct choice is :

(A)
I < II < III < IV (B)
I < IV < II < III (C)
I < II < IV < III (D)
III < IV < I < II
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13.
14.
15.
The oxidation numbers of oxygen in KO2, OF2, H2O2 are respectively :

1
2, 2, 2
2, 1, 1
(A)
(B)
(C)
, 2, 1
2
(D)
1
, 2, 1
2
When borax (Na2B4O7) dissolved in water, then :

(A)
Only B(OH)3 is formed
(B)
(C)
Both B(OH)3 and [B(OH) 4 ] are formed (D)
Only [B(OH) 4 ] is formed

Both B(OH)3 and B2O3 are formed
Assuming that Hunds rule is violated, the bond order and magnetic nature of the diatomic molecule
B2 will be :
(A)
1 and diamagnetic
(B)
0 and diamagnetic
(C)
1 and paramagnetic
(D)
0 and paramagnetic
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16.
Statement : 1
Methylene cyclohexane reacts with NBS/CCl4 to give
CH2Br
as one of the products.

Statement : 2
The stability of alkyl free radicals follows the order : 3 > 2 > 1 via hyperconjugation.
(A)
Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for Statement-1.
(B)
Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation for
Statement-1.
(C)
Statement-1 is True, Statement-2 is False.
(D)
17.
Statement-1 is False, Statement-2 is True.
Two systems PCl5 PCl3 (g) Cl 2 (g) and COCl 2 (g) CO(g) Cl 2 (g) are simultaneously in
equilibrium in a vessel of fixed volume. If some CO is introduced into the vessel, then at the new equilibrium,
the concentration of :
(A)
PCl5 is greater
(B)
PCl3 remains unchanged
(C)
PCl5 is less
(D)
Cl2 is greater
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18.
Select correct adsorption isobars for chemisorption and physisorption respectively : (where
x
m
= extent of
adsorption, T = temperature)
19.
(A)
(B)
(C)
(D)
At what temperature will hydrogen molecules have same K.E. as helium molecules have at 35C ?
35C
280C
140C
265C
(A)
(B)
(C)
(D)
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20.
The hydrolysis constant for an aqueous solution of 0.1 M ZnCl 2 will be :

(A)
21.
Kh
Kw
Kb
(B)
Kh
K 2w
Kb
(C)
Kh
K 2w
K 2b
(D)
Kh
Kb
Kw
Which of the following statement are true for a solution saturated with AgCl and AgBr. If their solubilities in
mol lit 1 in separated solution are x and y respectively.
22.
(A)
[Ag ] x y
(B)
[Cl ] [Br ]
(C)
[Ag ] [Br ] [Cl ]
(D)
[Ag ] [Br ] [Cl ]
Statement 1 : Addition of non-volatile solute causes a depression in vapour pressure.

Statement 2 : Vapour pressure of a solution is directly proportional to mole fraction of solvent.
(A)
Statement-1 is True, Statement-2 is True and Statement-2 is a correct explanation for Statement-1
(B)
Statement-1 is True, Statement-2 is True and Statement-2 is NOT a correct explanation for Statement-1
(C)
Statement-1 is True, Statement-2 is False
(D)
Statement-1 is False, Statement-2 is True
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23.
Which of the following has greatest flocculation value for a negatively charged solution ?
(A)
Mg2+
(B)
Ca2+
(C)
Fe3+
(D)
Na+
24.
Given : NH 3 g 3Cl 2 g NCl 3 g 3HCl g ;

N 2 g 3H 2 g 2NH 3 g ;
H1
H 2
H 2 g Cl 2 g 2HCl g ;
H 3
The heat of formation of NCl3 g in the terms of H1 , H 2 and H3 is ?
25.
(A)
Hf H1
(C)
H f H1
H 2 3
H 3
2
2
H 2 3
H 3
2
2
(B)
H f H1
(D)
None of these
H 2 3
H 3
2
2
The time taken for a certain volume of gas to diffuse through a small hole was 2 min. Under similar conditions
an equal volume of oxygen took 5.65 min to pass. The molecular mass of the gas is :
(A)
32.0
(B)
11.33
(C)
4.0
(D)
8.0
CH3O
CH = CH
CHO
10
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26.
When
CH3O
is treated with HBr, the major product obtained is :

CH 2 C H
|
Br
CHO
CH3O
C H CH 2
|
Br
(A)
CH3O
CH CH
|
|
Br
Br
(B)
CHO
CH3O
(C)
27.
CHO
CBr2CBr2
CHO
(D)
In which of the following compounds delocalisation is not possible :

(A)
1, 4-pentadiene (B)
1, 3-butadiene (C)
1, 3, 5-hexatriene
(D)
benzene
11
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28.
X will be :
(A)
(B)
(C)
(D)
29.
For a first order reaction, nA B whose concentration vs time curve is as

shown in the figure. If half-life for this reaction is 24 minutes. Find out the
value of n.
(A)
1
(B)
2
(C)
3
(D)
4
30.
Highest heat of combustion is observed in :

(A)
n-hexane
(C)
3-methylpentane
(B)
(D)
2-methylpentane
2, 2-3-trimethylbutane
PART - II (PHYSICS)
90 MARKS
12
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& D, out of which
uu
r uu
r uur
31.
Assuming the gravity to be in negative z-direction, a force F v A is exerted on a particle in addition to
ur
uur
the force of gravity where v is the velocity of the particle and A is a constant vector in positive
xdirection. With what velocity of minimum magnitude, a particle of mass m be projected so that it continues to
move undeflected with constant velocity :
A
A
mg
mg
j
j
j
j
(A)
(B)
(C)
(D)
mg
mg
A
A
32.
A sonometer wire resonates with a given tuning fork forming standing waves with five antinodes between the
two bridges when a mass of 9 kg is suspended from the wire. When this mass is replaced by a mass M, the wire
resonates with the same tuning fork forming three antinodes for the same positions of the bridges. The value of
M is :
(A)
25 kg
(B)
5 kg
(C)
12.5 kg
(D)
1/25 kg
33.
An open pipe is suddenly closed at one end with the result that the frequency of third harmonic of the closed
pipe is found to be higher by 100 Hz then the fundamental frequency of the open pipe.
The
fundamental frequency of the open pipe is :
(A)
200 Hz
(B)
300 Hz
(C)
240 Hz
(D)
480 Hz
13
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34.
Two spherical black bodies of radii r1 and r2 and with surface temperatures T1 and T2 respectively radiate the
r1
same power.
must be equal to :
r2
(A)
35.
T1

T2
(B)
T2

T1
(C)
T1

T2
T2

T1
(D)
A resistance R and a capacitor C are joined to a source of AC of constant emf and variable frequency.
The potential difference across C is V. If the frequency of AC is gradually increased, V will :
(A)
Increase
(B)
Decrease
C
R
(C)
Remain constant
(D)
First increase and then decrease
V
36.
4H
Find VA VB in steady state

(A)
8V
(B)
16 V
(C)
24 V
(D)
Data is insufficient
2A
2
3
A
2H.2
14
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37.
A conducting wire frame is placed in a magnetic field, which is directed

into the paper. The magnetic field is increasing at a constant rate. The
directions of induced currents in wires AB and CD are :
(A)
A to B and C to D
(B)
B to A and C to D
(C)
A to B and D to C
(D)
B to A and D to C
C
A
B
D
38.
Two electric bulbs A and B are designed for the same voltage. Their power ratings are P A and PB respectively,
with PA > PB. If they are joined in series across a V-volt supply,
(A)
A will draw more power than B
(B)
B will draw more power than A
(C)
The ratio of powers drawn by them will depend on V
(D)
A and B will draw the same power
39.
A ball falls vertically onto a floor, with momentum p, and then bounces repeatedly. The coefficient of restitution
is e. The total momentum imparted by the ball to the floor is :
(A)
p (1 + e)
(B)
p
1 e
(C)
p 1
e
(D)
1 e
p
1 e
15
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40.
An impulse 10 Ns is applied on ring of mass m = 2 kg as shown in figure. The ring is placed on rough horizontal
surface. Then linear velocity of centre of ring once it starts rolling without slipping :
(A)
5 m/s
(B)
2.5 m/s
J = 10Ns
(C)
1.25 m/s
(D)
1.66 m/s
41.
A gas bubble of diameter D rises steadily through a solution of density at the rate of v.
coefficient of viscosity of the solution is :
(A)
42.
D2 g
9v
(B)
D2 g
18v
(C)
2D2 g
9v
(D)
The
D2 g
v
A liquid of density is filled in a vessel of cross-sectional area A upto height h. A block of mass M and crosssectional area a is made to float on it as shown in figure. The pressure at the bottom of the vessel will be :
Mg
P0 h g
P0 h g
(A)
(B)
a
a
P0
M
Mg
Mg
P0 h g
h g
(C)
(D)
h
A
A
16
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43.
A transverse wave is passing through a string shown in figure. Mass density of the string is 1 kg/m3 and cross
section area of string is 0.01 m2. Equation of wave in string is y 2 sin 20t 10 x cm where t in sec and x in
m. The hanging mass is (in kg)
(A)
40
(B)
0.2
(C)
0.004
(D)
None of these
44.
Electric charge is uniformly distributed along a long straight wire of radius

1 mm. The charge per cm length the wire is Q coulomb. Another cylindrical surface
of radius 50 cm and length 1 m symmetrically enclose the wire as shown in the
figure. The total electric flux passing through the cylindrical surface is
Q
100 Q
(A)
(B)
0
0
(C)
10 Q
0
(D)
1m
100 Q
0
50 cm
6V
45.
B is a 1.5 V, 0.30 A, 5.0 torch bulb working properly in the circuit

shown. The combined resistance of R and B, between the points X and
Y, is :
0.45
1.0
(A)
(B)
3.0
5.0
(C)
(D)
3
B
17
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A long hollow metallic cylinder of radius R has a current I ampere flowing through it. The magnetic field
induction at a distance r from the axis varies as shown in figure :
I.
II.
III.
R r
(A)
47.
IV.
(B)
Rr
R r
R r
II
(C)
III
(D)
IV
Q
P
A circuit ABCD is held perpendicular to uniform magnetic field of
B 5 102 T extending over the region PQRS and directed into the
plane of the paper. The circuit is pulled out of the field at a uniform
speed of 0.2 ms
0.5 m
for 1.5 s. During this time, the current in the 5
resistor is :
(A)
0.6 mA from B to C
(C)
0.9 mA from C to B
48.
0.3 m
46.
0.2 ms 1
C
(B)
(D)
0.9 mA from B to C
0.6 mA from C to B
A, B, C, D, P and Q are Points in a uniform electric field. The potentials at these

1m
points are V A 2 volt V(P) = V(B) = V(D) = 5 volt V(C) = 8 volt. The
magnitude of electric field is :
(A)
5 2V / m
(B)
5 13V / m
(C)
3 26V / m
(D)
15 2 V / m
P
A
Q
D
0.2 m
18
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49.
The circuit shown in figure is used to compare the emfs of two cells E1
and E2 E1 E2 . The null point is at C when the galvanometer is
connected to E1 . When the galvanometer is connected to E2 , the null
point will be
(A)
to the left of C (B)
(C)
at C itself
(D)
to the right of C
nowhere on AB
50.
In the figure shown the masses of block A and B are

10 kg and 20 kg respectively. Find the maximum mass of
block C so that block B does not move.
(A)
20 kg
(B)
30 kg
(C)
40 kg
(D)
50 kg
51.
A rod of length l rotates with angular velocity in a perpendicular field of induction which is parallel to the
axis of rotation passing through at a distance of l / 4 from one of its end. Find the potential difference across the
ends of the rod.
(A)
B l 2
(B)
B l 2
2
(C)
B l 2
4
(D)
5B l 2
16
19
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52.
The figure shows three circuits with identical batteries, inductors and resistances. Rank the circuits according to
the currents through the battery just after the switch is closed, greatest first.
(A)
i2 > i3 > i1
(B)
i2 > i1 > i3
(C)
i1 > i2 > i3
(D)
i1 > i3 > i2
53.
The value of alternating emf E in the given circuit will be :

(A)
220 V
(B)
140 V
(C)
100 V
(D)
20 V
54.
When the current changes from + 2A to 2 A in 0.05 s, an emf of 8V is induced in a coil. The coefficient of selfinduction of the coil is :
(A)
0.2 H
(B)
0.4 H
(C)
0.8 H
(D)
0.1 H
20
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55.
A straight wire of mass 200 g and length 1.5m carries a current of 2A. It is suspended in mid-air by a uniform
horizontal magnetic field B. The magnitude of B (intesla) is :
(A)
2
(B)
1.5
(C)
0.55
(D)
0.65
56.
The current passing through the ideal ammeter in the circuit given below is :
(A)
57.
1.25 A
(B)
1A
(C)
0.75 A
(D)
0.5 A
A potentiometer wire of length 10 m and resistance 20 is connected in series with a 15 V battery and an
external resistance 40 . A secondary cell of emf E in the secondary circuit is balanced by 240 cm long
potentiometer wire. The emf E of the cell is :
(A)
2.4 V
(B)
1.2 V
(C)
2.0 V
(D)
3V
21
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58.
In the given network, the value of C, so that an equivalent capacitance between A and B is 3 F , is :
(A)
36 F
(B)
(C)
(D)
59.
48 F
31
F
5
1
F
5
A hollow cylinder has a point charge q coulomb within it at the centre of the axis. If
is the electric flux in unit of voltmeter associated with the curved surface B, the
flux linked with the plane surface A in unit of voltmeter will be :
(A)
60.
1 q

2 0
(B)
q
2 0
(C)
(D)
Dipole is placed parallel to the electric field. If W is the work done in rotating the dipole by 60 , then work
done in rotating it by 180 is :
(A)
2W
(B)
3W
(C)
4W
(D)
W/2
22
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PART - III (MATHEMATICS)
90 MARKS

& D, out of which
61.
2
The complete set of values of a for which the point a, a , a R lies inside the triangle formed by the lines
x y 2 0 , x y 2 and x-axis is :
(A)
2, 2
(B)
1, 1
(C)
(0, 2)
(D)
2, 0
Paragraph for Q.62 - 64

Suppose you do not know the function f (x), however some information about f (x) is listed below. Read the following
carefully before attempting the questions.
I.
f (x) is continuous and defined for all real numbers.
II.
f 5 0 ; f 2 is not defined and f 4 0 .
III.
5, 12
IV.
f 2 is undefined, but f x is negative everywhere else.
V.
62.
is a point which lies on the graph of f (x).
The signs of f x is given below :

On the possible graph of y = f (x), we have :
x 5 is a point of relative minima
(A)
(B)
x = 2 is a point of relative maxima
(C)
x = 4 is a point of relative minima
(D)
Graph of y = f (x) must have a geometrical sharp corner
23
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63.
From the possible graph of y = f (x), we can say that :

(A)
There is exactly one point of inflection on the curve
(B)
f (x) increases on 5 x 2 and x > 4 and decreases on x 5 and 2 x 4
(C)
The curve is always concave down
(D)
Curve always concave up
64.
Possible graph of y = f (x) is :
24
Vidyamandir Classes
65.
x2
(A)
dx
1 x is equal to :
1 x
C
4
34
14
(B)
1 x
4
(C)
1 x4
x
66.
34
(D)
None of these
If 1 k tan 2 x 4 tan x 1 k 0 has real roots tan x1 and tan x2 , then :

I.
k2 5
III.
For k 2, x1
The correct choice is :

(A)
I, II
(B)
67.
14
II, III
II.
tan x1 x2 2
IV.
For k 1, x1 0
(C)
I, III, IV
(D)
I, II, III, IV
(C)
(D)
x 1
x 1
sin 1
dx equals to :
x 2
x 2
sin 1
(A)
(B)
25
Vidyamandir Classes
68.
69.
dy
is :
dx
1
The solution of the differential equation x y cos
(B)
cot
x y
xC
2
(D)
tan
(C)
0I
cot
(C)
tan
If
x y
xC
2
x y
x C
2
0 1 x6 dx , then :
(A)
70.
x y
xC
2
(A)
I 1
4
(B)
1<I<2
(D)
I2
3
The expression x 2 4 px q 2 0 for all real x and also r 2 p 2 qr , then the range of f x
xr
,
x qx p 2
2
is :
(A)
p q
2r , 2r
(B)
0,
(C)
, 0
(D)
26
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71.
Which of the following is a non-real complex number ?

(A)
72.
(B)
(B)
(C)
The positive value of x for which the function f x

(A)
73.
ii
(C)
2
t
0 1 t e
x
(D)
2 2
dt has an extremum is :
(D)
x
Point A lies on the curve y e x and has the coordinates x, e
2
The period of sin

is :
(A)
12
None of these
where x > 0. Point B has the coordinates
(x, 0). If O is the origin, then the maximum area of the AOB is :
1
1
1
(A)
(B)
(C)
2e
4e
e
74.
None of these
(D)
1
8e
x
x
x
, where [x] represents the greatest integer less than or equal to x,
cos
tan
12
4
3
(B)
(C)
(D)
24
27
Vidyamandir Classes
75.
Find the number of ways in which ten candidates A 1, A2, . . . . . A10 can be ranked such that A1 is always
above A10.
10
10
10
(A)
(B)
(C)
(D)
None of these
2
10
76.
The value of
(A)
77.
The value of
4x
dx , where [.] denotes the greatest integer function.

5
7
3
(B)
sq. units (C)
sq. units (D)
sq. units
4
4
4
1
sin x
dx , is :
3 2
1 x2

2
e
1
(B)
3
6
3 4 sin x
12
(A)
e
2
6
3 3
(C)
e
4
6
3 3
(D)
28
Vidyamandir Classes
78.
The tangent lines for the curve y
0 2 t
dt , which are parallel to the bisector of the first quadrant angle
are :
(A)
(C)
79.
(B)
(D)
3
1
, y x
4
4
y x 1, y x 1
y x
The value of n in the equation of curve y a1 n x n , so that subnormal may be of constant length is :
(A)
80.
1
3
, y x
4
4
2 y 2 x 1, 2 y 2 x 3
y x
(B)
3
2
(C)
If chord AB of circle x 2 y 2 16 passes through
1
2
(D)
6 , 6 and is inclined at angle 135 with x-axis then the
equation of circle with AB as diameter will be :

(A)
x2 y2 9
(B)
x 1 2 y 2 5
(C)
x2 y2 2 6x 2 6 y 5 0
(D)
x 2 y 2 16
29
Vidyamandir Classes
81.
If the normal to the curve y f x at x = 0 be given by the equation 3x y 3 0 , then the value of
lim x 2 f x 2 5 f 4 x 2 4 f 7 x 2
x0
1
3
(A)
82.
(B)
is :
1
3
(C)
1
5
(D)
1
4
If the chord of contact of tangents from a point P x1 , y1 to the circle x 2 y 2 a 2 touches the circle
x a 2 y 2 a 2 , then the locus of x1 , y1

(A)
83.
a circle
(B)
is :
a parabola
(C)
an ellipse
(D)
a hyperbola
x
x
If I1 xe sin x cos x dx and I 2 e sin x dx , then I1 + I2 equals to :
(A)
xe x cos x C
(B)
xe x sin x C
(C)
e x cos x C
(D)
e x sin x C
30
Vidyamandir Classes
84.
The range of the function y f x
1 1
2 , 2
(A)
85.
86.
1 x x
1
0, 2
(B)
is :
(C)
1 1
,
2 2
The remainder when 55n 2 29n 1 16n is divided by 13, is :

(A)
2
(B)
3
(C)
7
2
The function f x x 1
(A)
87.
x x
(B)
(D)
[0, 1)
(D)
x 2 6 x 5 cos x is not differentiable at :

0
(C)
(D)
The product of common difference of all possible APs which are made from values of x satisfying
1
1
x cos 2
x 1 , is :
2
cos 2
(A)
4 2
2 2
(B)
(C)
2 2
2 2
(D)
None of these
31
Vidyamandir Classes
88.
Consider the function f x x cos x sin x , then identify the statement which is correct ?
(A)
(C)
89.
(B)
(D)
f is monotonic decreasing at x = 0
f has a minima at x
The area of the smaller portion enclosed by the curves x 2 y 2 9 and y 2 8 x is :

(A)
(C)
90.
f is neither odd nor even

f has a maxima at x
2 9 9
1
sin 1
3
4 2
3
(B)
2 9 9 1 1
sin
4 2
3
3
(D)
2 9 9 1 1
sin
4 2
3
3
2 9 9
1
sin 1
3
4 2
3
In a small village, there are 87 families, of which 52 families have atmost 2 children. In a rural development
programme 20 families are to be chosen for assistance, of which atleast 18 families must have atmost 2
children. In how many ways can the choice be made ?
(A)
52
C2 . 35C18
(C)
52
C2 . 35C18
52
C1 . 35C19
35
C20
(B)
52
C18 . 35C2
(D)
52
C18 . 35C2
52
C19 . 35C1
52
C20
32
Vidyamandir Classes
33
Vidyamandir Classes
* * * * * *End of Test Series - 5/JEE-2013/Paper - 1* * * * * *
34

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Vidyamandir Classes

Test Series - 5/IITJEE - 2013

10:00 A.M. - 01:00

TIME : 3.00 Hrs

Read the following Instructions very carefully before you proceed.

For answering a question, an ANSWER SHEET (OMR SHEET) is provided separately.

Test Series - 5/Paper-1

STRAIGHT OBJECTIVE TYPE

SPACE FOR ROUGH WORK

Test Series - 5/Paper-1

The decomposition temperature is maximum for :

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Test Series - 5/Paper-1

The correct ionic radii order is :

N3- > Na+ > O2- > F-

Which one of the following compounds gives only 2 monochlorination products ?

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Test Series - 5/Paper-1

IV > V > III > II > I

I > IV > V > III > II

I > V > IV > III > II

IV > V > III > I > II

Arrange the following compounds in order of ease of dehydrohalogenation :

The correct choice is :

I < IV < II < III (C)

I < II < IV < III (D)

III < IV < I < II

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Test Series - 5/Paper-1

The oxidation numbers of oxygen in KO2, OF2, H2O2 are respectively :

When borax (Na2B4O7) dissolved in water, then :

Only B(OH)3 is formed

Both B(OH)3 and [B(OH) 4 ] are formed (D)

Only [B(OH) 4 ] is formed

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Test Series - 5/Paper-1

Methylene cyclohexane reacts with NBS/CCl4 to give

as one of the products.

Statement-1 is False, Statement-2 is True.

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Test Series - 5/Paper-1

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Test Series - 5/Paper-1

The hydrolysis constant for an aqueous solution of 0.1 M ZnCl 2 will be :

[Ag ] [Br ] [Cl ]

[Ag ] [Br ] [Cl ]

Statement 1 : Addition of non-volatile solute causes a depression in vapour pressure.

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Test Series - 5/Paper-1

Given : NH 3 g 3Cl 2 g NCl 3 g 3HCl g ;

The heat of formation of NCl3 g in the terms of H1 , H 2 and H3 is ?

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Test Series - 5/Paper-1

is treated with HBr, the major product obtained is :

In which of the following compounds delocalisation is not possible :

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Test Series - 5/Paper-1

For a first order reaction, nA B whose concentration vs time curve is as

Highest heat of combustion is observed in :

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Test Series - 5/Paper-1

STRAIGHT OBJECTIVE TYPE

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