Академический Документы
Профессиональный Документы
Культура Документы
ABSTRACT
CO2 anthropogenic pipeline transportation has been pointed out as
one of the most promising way to gather captured CO2 from power
plant to permanent underground storage sites for final sequestration or
for Hydrocarbon Enhanced Recovery. A lot of efforts have been, till
now performed, to develop economically feasible capture systems
applicable either on existing (Post Combustion) or new generation
(Oxyfuel and Precombustion) electric coal or gas fired power plant;
furthermore funds were allocate to individuate and perform deep
studies on the geo-stability of underground sink storage (mainly in
Aquiferi loci) to be selected by avoiding leaks or to exploit oil recovery
from mature wells. Unfortunately few efforts have been put in place to
fill the existing gaps of knowledge in CO2 handling and transportation
in a safely, efficient and convenient manner.
Up to now it was thought to transfer the existing know how based on
CO2 pipelines transportation for enhanced oil recovery (these pipelines
are in service since the 70 in North America) to anthropogenic carbon
dioxide, but this approach could be questionable if specific issues arent
properly faced. This paper will address the main differences in terms of
issues related to the transportation of these two apparently alike fluids.
Furthermore many of the integrated energy Companies around the
world recently have decided to sponsor collaborative activities to define
guidelines and recommended practices for line design and material
procurement as well as to define how to cope with operation and
maintenance pipeline issues. There are some relevant technicalfeasibility issues to be addressed for an emerging CO2 safe
transportation as:
x
-Pipeline integrity, that is fracture propagation avoidance and
control as well as environmental assisted cracking prevention
(Corrosion and stress-corrosion including the selection of
proper material for internal painting/coating);
x
-Safety, that is a deeper understanding of the carbon dioxide
release/dispersion phenomenon. This need forces to collect
data to validate model(s) to asses the carbon dioxide release
(area of interest and consequences) in case of an unlike event
of pipeline leak or rupture;
x
-Operational, that is how to avoid hydrate formation.
All these issues are strongly related on actual CO2 composition due to
243
244
Figure 3 CO2 lake in the Amiata region (Tuscany ,Italy) . The gas
accumulation has been made visible by igniting a smoke bomb in the
morphological depression. The yellow colour highlights the zone where
CO2 concentration is lethal. The manifestation caused a fatality on the
20th November 2003.
Impurities are addressed as the main driving difference in EOR
from anthropogenic CO2.
Dense phase carbon dioxide transportation needs to meet reservoir
specifications; it is compressed to a high pressure enough to overcome
the frictional and static pressure drops and to deliver the CO2 at a high
enough pressure to avoid flashing of gas, so that two-phase flow is
avoided. Furthermore, depending on the capture source and method, the
level of impurities (SOx, NOx, H2S, CH4, N2, H2, H2O, Ar) present in
CO2 mixture could be different.
245
The impurities in the CO2 change the phase envelope shape, as shown
in Fig. 5, they increase the region of two phase slugs (gas and liquid),
they affect the operating parameters of the pipeline and increase
compressor-power.
Figure 5 CO2 Phase diagram for the three different capture streams and
EOR pipeline specification. (Downie, Race, Seevam , 2007)
When the impurities are present with a large extent, higher operating
pressures will be needed to maintain dense phase (see Fig. 5), so an
increase of decompression pressure should lead to a higher crack
driving force to propagate fracture further; as can be seen from see Fig.
10.
246
the possible presence of free water in the CO2 for reduced operational
periods. The role of chemical composition of CO2 and service
conditions on corrosion resistance in terms of general corrosion,
localized corrosion (also on girth welds) and hydrogen assisted
cracking phenomena, stress corrosion cracking and corrosion fatigue
should be investigated for various steel grades and welds, since no data
are available for anthropogenic carbon dioxide mixtures. The likelihood
and severity of these different corrosion mechanisms not only depends
on the level of respective impurities in the CO2, but also on the partial
pressure of each impurity, which is governed by the total system
pressure. Presence of atomic hydrogen can lead to environmental
assisted cracking. Furthermore the presence of liquid impurities as
water, amine, HCl, HNO3 and NaOH (Ayello.,Evans, Sridhar, Thodla,
2010) has a deep impact on the corrosion steel rate when free water
may be present.
Corrosion Issues
Corrosion and stress corrosion studies utilizing CO2 at high pressure
and corresponding field experiences suggest that corrosion on carbon
steel in pure and dry CO2 is negligible. But it is well known that at low
to medium CO2 partial pressure severe corrosion damage will occur if a
water-enriched phase is present. This issue should be balanced with the
economical considerations for the power plant capture system design to
reduce the amount of water down to acceptable level for transportation
needs. Moreover impurities as H2S, CO, SOx, NOx and probably even
H2 could lead to corrosion phenomena like hydrogen assisted cracking,
and stress corrosion cracking and corrosion fatigue. These examples
shown here clearly points out that a specific experience on the
anthropogenic CO2 behaviour is missing. It is known that severe
corrosion damage may occur if free phase water is present; it must be
remembered that water solubility in carbon dioxide (Fig. 11) depends
on temperature and pressure, on the other hand, CO2 pipelines operated
without free water dont show any corrosion phenomena on the inner
wall surface (Fig. 12).
247
monitoring the noise evolution and propagation around the nozzle area.
Chemical sensors are applied to monitor the oxygen concentration and
distribution. All this instrumentation is foreseen to collect as much as
possible information from the experimental activities to supply useful
information in terms of safety health and environment congruence to
such an event. Moreover all the recorded data can be used to fine tune
modelling.
For the ductile fracture propagation has been studied and selected a
specific plant with a pumping system of the following characteristics: a
flow capacity 8 metric ton/hour and maximum pressure of 15 MPa.
As an ultimate device can be mentioned the weather condition station.
In fact a very important key issue is the monitoring of the weather
condition by means of a local station. It can gives the boundary
condition of the ambient parameters as wind speed, solar heat flux,
temperature, pressure, atmospheric stability etc. these can useful be
used in simulation or recorded and associated to a specific test.
CONCLUSIONS
CO2 anthropogenic pipeline transportation has been recognized as one
of the most promising way to gather captured CO2 from power plants to
permanent underground storage sites for final sequestration or for EOR
applications.
While a lot of efforts have been put in place to develop economically
feasible capture and storage systems, a limited effort has been spent so
far to fill the existing gaps of knowledge in CO2 handling and
transportation in a safely, efficient and convenient manner.
The straightforward application of the know how (design criteria,
material requirements, etc.) developed over the years for natural gas
transmission pipeline as well as the experience gained (especially in
USA) on pure CO2 pipelines for oil recovery applications; this is an
interesting starting point but it is not the final solution, since significant
differences exist when anthropogenic carbon dioxide is transported in
particular due to the effect of the impurities on structural integrity
related issues, particularly fracture control and corrosion-stress
corrosion prevention.
Several projects have been recently launched or are about to be
launched to fill gaps on a tight timeline, with the final aim to issue
guidelines and recommended practices to soon feed the standardization
bodies.
With this scenario several companies have launched an integrated
research approach which for the experimental part is strongly centred
on the new carbon dioxide devoted facilities that CSM is going to
realize in its full scale testing laboratory in Sardinia. These devices are
designed to allow release and leakage as well as fracture propagation
testing involving large amount of CO2 representative of a real pipeline
failure. Specific effort is being spent on design and installation of
suitable instrumentation able to capture all the main parameters of the
event under consideration so to allow, through the test data post
processing, significant improvement of modelling.
REFERENCES
Ayello F.,Evans K, Sridhar N., Thodla R. (2010), Effect of liquid
impurities on corrosion of carbon steel in supercritical CO2,
Proceedings of the 8th International Pipeline Conference IPC2010
September 27-October 1, 2010, Calgary, Alberta, Canada. pp 3-4.
Downie M., Race J., Seevam P.,(2007) Transport of CO2 for Carbon
Capture and Storage in the UK, Anglo French scientific discussion
seminar 27-09-2007, slide n6.
Hopman,J.(2008), TNO CASTOR - ENCAP - CACHET
DYNAMIIS Common Technical Training CASTOR-SP2 Workshop,
Lyon
2008
(available
at
web
address:
248
http://www.encapco2.org/papers.htm
Le Thiez, P., Mosditchian1 G., Tore Torp, Feron P.TNO-MEP,
Zweigel P,Lindeberg E. (2004), An innovative European integrated
project: Castor - CO2 from capture to storage, Presentation Vancouver
2004 (available at web address http:/www.castor.com/publication pp 14)
Lucci A, CSM Rome, Spinelli C.M. eni g&p , Tudori P. CCTS (Carbon
Capture Transportation & Storage) Transportation issue,(2011) The 21st
International Offshore (Ocean) and Polar Engineering Conference,
, Maui, Hawaii, USA, ISOPE, Vol 4, www.isope.org
249