SOLUTIONS

61.

62.

A semi molar solution is the one, which contains

1. One mole solute in 2 litres

2. 2 moles solute in 2 litres

3. 0.1 mole solute in 1 litre

4. 0.2 mole solute in 2 litres

The solution having lowest molar concentration is

1. 1.0N HCl

63.

2. 0.4 N

Normality of 0.1 M
1. 0.2N

64.

3. 0.1N

3. 0.033N

4. 0.05N

2. 0.1 M

3. 0.2 M

4. 0.3 M

When an oxide

M 2O3

is oxidized to

M 2O5

2. M. W/2

its equivalent weight is

3. M. W/4

FeSO . NH
4

67.

The equivalent weight of Mohrs salt

equal to its

SO4 .6 H 2O

2. Atomic weight/2

3. Molecular weight/3

4. Molecular weight

In an oxidation-reduction reaction,
KMnO4

1. 0.02

MnO4

ion is converted to

during redox reaction is

Mn 2

(mol.wt=158) present in 250ml of 0.04 M

2. 0.05

. What is the number of

KMnO4

solution?

3. 0.04

4. 0.07

3. Molality

4. Mole fraction

Which of the following has no units?

1. Molarity

69.

4 2

4. M. W/8

1. Molecular weight/2

equivalents of

68.

4. 1N NaOH

Molarity of 0.1N oxalic acid is

1. m. W/1

66.

Na2CO3

is

2. 0.30N

1. 0.05 M
65.

H 3 PO3

H 2 SO4

2. Normality

Molarity of 4%(w/v) solution of NaOH is

1. 0.1

Sec: COMING SR.IPL-CT

2. 0.5

3. 0.001

4. 1.0
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SOLUTIONS

70.

250 ml of a sodium carbonate solution contains 2.65 grams of

solution is added to x ml of water to obtain 0.001M
in ml?(Molecular weight of
1. 1000

71.

Na2CO3

2. 990

Na2CO3

Na2CO3

. 10ml of this

solution. What is the value of x

=106)
3. 9990

4. 90

(A): Any part of the solution has identical chemical and physical properties
(R) : Solution is always a homogeneous mixture
1. Both (A) and are (R) are true and (R) is the correct explanation of (A)
2. Both (A) and (R) are true and (R) is not the correct explanation of (A)
3. (A) is true but (R) is false
4. (A) is false but (R) is true

72.

LIST 1

LIST 2

A) Gaseous solution

1) German silver

B) Liquid solution

2) Milk

C) Solid solution

3) Sand in water

D) Colloidal solution

4) Aqueous Alcoholic solution

5) Air

A B C D

73.

A B C D

1. 5 4 1 2

2. 1 3 2 5

3. 4 2 5 1

4. 2 3 1 4

In the reaction

2 NaOH H 3 PO4 Na2 HPO4 2 H 2O

1. 49
74.

2. 98

3. 32.6

, the Equivalent weight of the acid is

4. 36.5

Which of the following acid has the same molecular weight and equivalent weight
H 3 PO2

1.
Sec: COMING SR.IPL-CT

2.

H 3 PO3

3.

H 3 PO4

4.

H 2 SO4
Page 2

SOLUTIONS

75.

M is the molecular weight of

according to the equation

1. M/2
76.

KMnO4

. The equivalent weight of

KMnO4

when it reacts

2 KMnO4 3H 2 SO4 5H 2C2O4 K 2 SO4 2MnSO4 8H 2O 10CO2

2. M/3

3. M

4. M/5

To change the molal conc. To one half, one of the following should be adopted
1. weight of the solute should be doubled
2. Weight of the solvent should be doubled
3. volume of the solvent should be doubled
4. Weight of the solution should be doubled

77.

100 ml of an aqueous solution contains

6.023 1021

solute molecules. The solution is diluted

to 1 lit. The number of solute molecules present in 10ml of the dilute solution is
1.
78.

6.0 1020

2.

6.0 1019

3.

6.0 1018

4.

6.0 1017

100 ml of 1M HCl, 200ml 2M HCl and 300 ml 3M HCl are mixed . The molarity of the
resulting solution is
1. 1M

79.

3. 2.33 M

4. 4.25 M

A 20%(w/w) solution of NaOH is 5 M. The density of the solution is

1. 1 g. ml-1

80.

2. 2.66 M
2. 2 g.ml-1

3. 0.5 g. ml-1

4. 0.25gml-1

10.6 g of a substance of molecular weight 106 was dissolved in 100 ml. 10ml of the this
solution was pipetted out into a 1000 ml flask and made up to the mark with distilled water.
The molarity of the resulting solution is
102

1. 1 M
81.

2.

3.

103

4.

The concentration of a 100 ml solution containing x grams of

104

Na2CO3

is yM. The value

of x and y are
1. 2.12, 0.05
82.

2. 1.06, 0.2

The number of millmoles of

1. 500

Sec: COMING SR.IPL-CT

2. 1000

H 2 SO4

3. 1.06, 0.1

4. 2.12, 0.1

present in 5 litres of 0.2 N

3. 250

H 2 SO4

4. 0.5

solution is

103
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SOLUTIONS

83.

The volume of 0.025M

H 3 PO4

solution which can neutralise 100ml of

104

is

1. 10ml
84.

Ca OH 2

2. 60ml

3. 0.6ml

4. 2.8ml

The molarity of 200 ml of HCl solution which can neutralise 10.6 g.of anhydrous

Na2CO3

Is
1. 0.1 M
85.

2. 1 M

The Normality of 0.98% (w/v)

1. 0.1 N

86.

Molarity of 3N

H 2 SO4

2. 0.2 N
H 3 PO4

1. 9 M
87.

3. 0.6 M

4. 0.75M

solution is
3. 0.4 N

4. 1N

3. 6M

4. 1M

solution is

2. 1.5 M

Which of the following aqueous solution is more concentrated [Assume the density of the
solution as 1g/ml]
1. 1M Glucose

88.

4. 0.5 M Glucose

2. 0.35m

3. 0.25m

4. 0.45m

6 g. of Urea is dissolved in 90g. of water . The mole fraction of solute is

1. 1/5

90.

3. 0.5m Glucose

The molarity of 2% (w/w) NaCl solution nearly

1. 0.02m

89.

2. 1m Glucose

2. 1/50

3. 1/51

4. 1/501

The mole fraction of solvent in 0.1 molal aqueous solution is

1. 0.9982

2. 0.0017

3. 0.017

4. 0.17

21. Liquids A and B form an ideal solution and the former has stronger intermolecular forces. If X A and
X A'

are the mole fractions of A in the solution and vapour phase in equilibrium, then

X 'A
1
X
A
A)

X 'A
1
X
A
B)

X 'A
1
X
A
C)

D) X ' A X A 1

22. Which of the following are correct about molal elevation constants (Kb ) order

Sec: COMING SR.IPL-CT

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SOLUTIONS
A). n-butyl alcohol >Isobutyl alcohol > tert-butylalcohol
B) propyl alcohol > n-butyl alcohol > n-pentyl alcohol
C) tert-butylalcohol > Isobutyl alcohol > n-butyl alcohol
D) n-pentyl alcohol > n-butyl alcohol > propyl alcohol
23. Which of the following statements is/are correct
A) minimum boiling azeotropic mixture boils at temperature lower than either of the two pure
components.
B) miximum boiling azeotropic mixture boils at temperature higher than either of the two pure
components
C) minimum boiling azeotropic mixture shows positive deviation from Raoults law
D) miximum boiling azeotropic mixture shows negative deviation from Raoults law
24. Which of the follwing curves repesents the Henry's law?

logm

A)

B)

logm
logp

C)

logm
logp

D)

logp

25. The ratio of lowering of vapour pressure of 0.1 M aqueous solutions of KCl, CuSO4 & Na2SO4 is
A) 1:2:3

B) 2:2:3

C)1:1:1

D) 3:2:1

26. Which of the following show deviation from raoults law.

A) C2H5OH & H2O

B) HNO3 & H2O

C) CHCl3 & CH3COCH3

D) C6H6 & C6H5CH3

27. 4 mole of pure liquid A and 6 mole of pure liquid B are mixed.

PA0 100mm

and

PB0 200mm

respectively. The vapour pressure of the resulting solution is found to be 90 mm of Hg then

A) It is an ideal solution
B) The solution shows negative deviation from Raoult's law
C) The solution is formed by the absorption of heat.
D) The solution will boil at higher temperature than expected
28. Which of the following statement is not correct about Henrys law
A) It is applicable only when pressure is high
Sec: COMING SR.IPL-CT

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SOLUTIONS
B) It is applicable only when temperature is very high
C) It is applicable only when gas reacts with the solvent
D) KH (Henrys constant) is a function of the nature of the gas

SECTION - II
(COMPREHENSION TYPE)

This section contains 4 groups of questions. Each group has 2 multiple choice
questions based on a paragraph. Each question has 4 choices A), B), C) and D) for its
answer, out of which ONLY ONE is correct.

Paragraph for Question 29 and 30

Lowering of vapour pressure is determined by Ostwald and Walner dynamic method. It is based on
the principle, when air is allowed to pass through a solvent or solution, it takes up solvent vapour
with it to get itself saturated with vapours at that temperature.
dry air

solution

PA

solvent

PA

Anhy.CaCl2

air

A and B are weighed separately before and after passing dry air. Loss in weight of each set, gives
the lowering of vapour pressure. The temperature of air, the solution and the solvent is kept constant.
29. Loss in weight of solvent will be pro portional to
O
A

A) P -PA

B) PA P

O
A

C)

PA
PAO

O
D) PA PA

30. Dry air was passed through 5 g of solute in 80g of water and then through pure water. The loss in
weight of solution was 2.5g and that of pure water was 0.04g. The molecular weight of solute is
A) 7.143 g mol1

B) 71.43 g mol1

C) 74.3 g mol1

D) 714.3 g mol1

Paragraph for Question 31 and 32

At any fixed temperature, the vapour phase is always richer in more volatile component as compared
to the solution phase. In other words, mole fraction of more volatile component is always greater, in
vapour phase than in solution phase. We can also say that vapour phase is relatively richer in the
component whose addition to liquid mixture results in an increases in total vapour pressure.
31. If 2moles of A and 3 moles of B are mixed to from an ideal solution, vapour pressures of A and B are
120 and 180 mm of Hg respectively, the total vapour pressure of solution will be
Sec: COMING SR.IPL-CT

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SOLUTIONS
A) 48 mm Hg

B) 108 mm Hg

C) 156 mm Hg

D) 15.6 mm Hg

32. From the statement in question 31, the composition of A and B in the vapour phase when the first
traces of vapours are formed is :
A) A = 0.407, B = 0.592

B) A = 0.8, B = 0.1

C) A = 0.109, b = 0.791

D) A = 0.307, B = 0.692

Paragraph for Question 33 and 34

In a mixture of closely related liquids (such as benzene and toluene), the Raoult law states that the
ratio pA is proportional to the mole fraction of A in the liquid, PA = PA xA Mixtures that obey the
law throughout the composition ranges from pure A to pure B are called ideal solutions. In ideal
solution the solute also obeys Raoults law. Then the total pressure is given by P total = P0AxA+
P0BxB
33. Each of the following solution obeys Raoults law
A) n-hexane + n-heptane
B) Methanol + Ethanol
C) carbon tetrachloride+carbon disulphide
D) chloroform + Acetone
34. For the solution which obeys Raoults law, which of the following is incorrect?
A) Vmix = 0

B) Hmix= 0

C) Smix = 0

D) Ptotal = P0AxA+ P0BxB

Paragraph for Question 35 and 36

Two pure liquids A & B which can form ideal solution have vapour pressures 300 torr & 800 torr.
In mixture the mole fraction of A is 0.25.A mixture of the vapour of A & B

slowly compressed at

temperature T.
35. The total pressure when first drop of condensate formed will be
A) 575 torr

B) 475 torr

C) 375 torr

D) 675 torr

36. The molefraction of A in this first drop of condensate is :

Sec: COMING SR.IPL-CT

Page 7

SOLUTIONS
A) 0.11

B) 0.22

C) 0.33

D) 0.44

SECTION III
(MATRIX MATCH TYPE)

This section contains 4 questions. Each question contains statements given in 2 columns which have to be
matched. The statements in Column I or labeled choices A, B, C and D, while the statements Column- II
are labeled p,q,r,s and t.
37. Column I

Column - II

P) PoA = 200; PoB = 300

1) P = 250; XA = 0.5

Q) PoA = 300; PoB = 200

2) P = 325; XA = 0.25

R) PoA = 100; PoB = 400

3) P = 264; XA = 0.33

S) PoA = 400; PoB = 100

4) P = 290; XA = 0.1

CODE:
A)
B)
C)
D)
38. Column - I
Gas at 298 K
P) Carbon dioxide
Q) Argon
R) Vinyl chloride
S) Methane
CODE:
A)
B)
C)
D)

1
2
3
1

3
1
4
2

P
3
2
3
1

Q
1
1
1
2

39. Column I
Solvent
P) Water
Q) Ethanol
R) Acetone
S) Carbon tetrachloride
Sec: COMING SR.IPL-CT

4
2
4
3
2
1
3
4
Column II
KH (henrys constant) in Kbar
1) 40.3
2) 1.67
3) 0.413
4) 0.611
R
S
4
2
4
3
2
4
3
4

Column II
Kb (molal elevation constant)
1) 5.02
2) 1.70
3) 0.52
4) 1.20
Page 8

SOLUTIONS
CODE:
P
A)
1
B)
2
C)
3
D)
4
40. Column - I
P) Vapour pressure of the solution
Q) Lowering of Vapour pressure
of the solution
R) Acetone-CHCl3 solution
S) Hexane ethanol solution
CODE:
P
A)
1
B)
2
C)
3
D)
1

Sec: COMING SR.IPL-CT

Q
3
1
4
3

Q
3
1
1
2

R
S
4
2
4
3
2
1
2
1
Column - II
1) mole fraction of the solute
2) mole fraction of the solvent
3) Hmix = + ve
4) Hmix = -ve
R
4
4
2
3

S
2
3
4
4

Page 9