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Question1.
Thealkenethatexhibitsgeometricalisomerismis:
[A]
[B]
[C]
[D]

2methy1propene
2butene
2methy12butene
propene

Question2.
Whichofthefollowingstatementisnotcorrectregardingbondingmolecularorbitals?
[A]
[B]
[C]
[D]

Bondingmolecularorbitalspossesslessenergythantheatomicorbitalsfromwhichtheyareformed
Bondingmolecularorbitalshavelowelectrondensitybetweenthetwonuclei
Electroninbondingmolecularorbitalcontributestotheattractionbetweenatoms
Theyareformedwhenthelobesofthecombiningatomicorbitalshavethesamephase

Question3.
Whichofthefollowingstatementsabouttheelements,
[A]
[B]
[C]
[D]

andcompoundsistrue?

Solubilityofthehydroxidesinwaterincreaseswithincreasingatomicnumber
Thermalstabilityofthecarbonatesincreaseswithincreasingatomicnumber
Allgivenelementsreactwithsteamtogivehydrogen
Metalchloridesareallliquidsatroomtemperature

Question4.
Considerthefollowingstatementsandchoosethecorrectoption(s):
[A]
[B]
[C]
[D]

Alkeneismorereactivethanalkyneforelectrophilicadditionreaction
Alkynegivesnucleophilicaswellaselectrophilicadditionreaction
Alkyneismorereactivethanalkenefornucleophilicadditionreaction
Noneofthese

Question5.
Whichofthefollowingstatements(s)is(are)correct?
[A]
[B]
[C]

TheentropyinisolatedsystemwithPVworkonly,isalwaysmaximizedatequilibrium
Itispossiblefortheentropyofclosedsystemtodecreasesubstantiallyinanirreversibleprocess
Entropycanbecreatedbutnotdestroyed
iszeroforreversibleprocessinanisolatedsystem

[D]

Question6.
Nodalplanesof

bond(s)in

arelocatedin:

[A]

Allareinthemolecularplanecontainingthe

[B]

Twoinmolecularplaneandoneinaplaneperpendiculartomolecularplanewhichcontains

[C]

Oneinmolecularplaneandtwoinplaneperpendiculartomolecularplanewhichcontains

[D]

Twoinmolecularplaneandoneinaplaneperpendiculartomolecularplanewhichbisects

atrightangle

Question7.
Whichofthefollowingareopticallyactive?

[A]

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[B]

[C]

[D]

Question8.
When

isreactedwithHBrthentheproductformedisAandwhen

istreatedwith

thentheproductformedisC.Hencehere:

[A]

[B]

[C]

[D]

Question9.
ThevapourpressureoftwopureliquidsAandBwhichformanidealsolutionare500and800torrrespectivelyat300K.AsolutionofA
andB,forwhichthemolefractionofAis0.60,iscontainedinacylinderclosedbyapistononwhichthepressurecanbevaried.The
solutionisslowlyvaporizedat300Kbydecreasingtheappliedpressure.

Thecompositionofvapourwhenfirstbubbleformedis:
[A]
[B]
[C]
[D]

Question10.
ThevapourpressureoftwopureliquidsAandBwhichformanidealsolutionare500and800torrrespectivelyat300K.AsolutionofA
andB,forwhichthemolefractionofAis0.60,iscontainedinacylinderclosedbyapistononwhichthepressurecanbevaried.The
solutionisslowlyvaporizedat300Kbydecreasingtheappliedpressure.

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Whatisthecompositionoflastdropletofliquidremaininginequilibriumwithvapour?
[A]
[B]
[C]
[D]

Question11.
Molarconductivity

isdefinedasconductingpoweroftheionsproducedby1moleofanelectrolyteinasolution.
where

isconductivityandCismolarconcentration.

Themolarconductivityof0.4Msolutionof
areaand0.50cmapartisfilledwith

Conductanceof

is

at298K.Acellwithelectrodesthatare2.0cm2insurface

solution.

solutionis:

[A]
[B]
[C]
[D]

32S
0.032S
Noneofthese

Question12.
Molarconductivity

isdefinedasconductingpoweroftheionsproducedby1moleofanelectrolyteinasolution.
where

isconductivityandCismolarconcentration.

Themolarconductivityof0.4Msolutionof
areaand0.50cmapartisfilledwith

is

at298K.Acellwithelectrodesthatare2.0cm2insurface

solution.

Howmuchcurrentwillflowwhenthepotentialdifferencebetweentheelectrodesis5.0V?
[A]
[B]
[C]
[D]

156.25A
0.16A
160A
Noneofthese

Question13.
5.6litresofanunknowngasatNTPrequires12.5caloriestoraiseitstemperatureby
atomicityofthegascanbe____________.
(Hint:

atconstantvolume.Thenminimum

f=degreeoffreedom,CV,m =molarheatcapacity)

Question14.
Solubilityproductof
saturatedsolutionat

.Kf forwateris2KKg

.WhenPbCl2isdissolvedinwatertomakeits

,findthedecreaseinfreezingpoint(inKelvin).[Expresstheanswerintermsof

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Question15.
Howmanyofthefollowingcanformchainisomers?

Question16.
Positroniumisaspeciesconsistingofanelectronboundtoapositron.Iftheradiusofits2ndorbitis

(whereR0istheradiusof1st

Bohrorbitofhydrogen).Thenthevalueofxis_____.

Question17.
Thecellreaction:
=1.70V.Assuming

worksat

with

tobeconstantinthistemperaturerange,calculate

=1.2Vandat

withthe

inkJ/K.[Assume

coulombs].

Question18.
Forstrongelectrolytesthevaluesofmolarconductivityatinfinitedilutionaregivenbelow:

ThenequivalentconductanceofBa(OH) 2atinfinitedilutionis

.Valueofxis______.

Question19.
1000mloftapwatercontainingCa(HCO 3) 2wastitratedwithN/50HClwithmethylorangeasindicator.If300mlofHClwererequired,
thentemporaryhardnesswillbe

ppm.Findx.

Question20.
Ahypothetical'Xeton'atrestwithmassequivalenttoaHenucleusabsorbs(n)photonsoffrequency
waslaterfoundtobe

.ItsdeBrogliewavelength

(m=massofproton),thenthevalueofnis_____.

Question21.
Fourpointmassesarefastenedtothecornersofaframeofnegligiblemasslyinginthexyplaneasshowninfigure.Let
angularspeedofrotation.Then:

bethe

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[A]

Rotationalkineticenergyassociatedwithagivenangularspeeddependsontheaxisofrotation

[B]

Rotationalkineticenergyaboutyaxisisindependentofmanditsvalueof

[C]

Rotationalkineticenergyaboutzaxisdependsonmanditsvalueis

[D]

Rotationalkineticenergyaboutzaxisindependentofmanditsvalueis

Question22.
AballAcollideselasticallywithanotheridenticalballBinitiallyatrestandAismovingwithvelocityof10m/satanangleof60ofromthe
linejoiningtheircentres.Selectthecorrectalternatives:
[A]
[B]
[C]
[D]

VelocityofballAaftercollisionis5m/s
VelocityofballBaftercollisionis
m/s
VelocityofballAaftercollisionis7.5m/s
VelocityofballBaftercollisionis5m/s

Question23.
Currentflowsthroughuniform,squareframesasshown.Inwhichcaseisthemagneticfieldatthecentreoftheframezero?

[A]

[B]

[C]

[D]

Question24.
Earthhasanelectricfieldofmagnitude100Vm1radicallyinwardsinatmospherearoundit.Afterwhattimeintervalmustlighteningoccur
successively,suchthatelectronspresentonsurfaceofearthdonotgobeyondadistanceof(20/91)kmfromsurfaceofearth?
(Assumewhenlighteningoccurs,electronsinatmosphereimmediatelyfallbacktosurfaceofearth)
[A]
[B]
[C]
[D]
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Question25.
Aboatexperiencesaresistiveacceleration=2vm/s 2duetothewater.Iftheboatstartsfromrest,anditsengineisprovidingaforward
pushwithanaccelerationof10m/s 2,then:
[A]
[B]
[C]
[D]

Maximumspeedwhichtheboatcanachieveis5m/s
Maximumspeedwillbeafter10s

Question26.
Threecapacitorseachhavingcapacitance
closed,

[A]
[B]
[C]
[D]

areconnectedwithabatteryofemf30Vasshowninfigure.WhentheswitchSis

Theamountofchargeflownthroughthebatteryis
Theheatgeneratedinthecircuitis0.6mJ
Theenergysuppliedbythebatteryis0.6mJ
TheamountofchargeflownthroughtheswitchSis

Question27.
Inthecircuitasshowninthefigure

[A]
[B]
[C]
[D]

Question28.
Whichofthefollowingfunctionsofxandtrepresentsaprogressivewave?
[A]

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[B]

[C]
[D]

Question29.
AsmallballBofmassmissuspendedwithlightinelasticstringoflengthLfromablockAofsamemassmwhichcanmoveonsmooth
horizontalsurfaceasshowninthefigure.Theballisdisplacedbyangle
fromequilibriumpositionandthenreleased.

Maximumvelocityoftheblockduringsubsequentmotionofthesystemafterthereleaseoftheballis:
[A]
[B]
[C]
[D]

Informationaresufficienttodecide

Question30.
AsmallballBofmassmissuspendedwithlightinelasticstringoflengthLfromablockAofsamemassmwhichcanmoveonsmooth
horizontalsurfaceasshowninthefigure.Theballisdisplacedbyangle
fromequilibriumpositionandthenreleased.

ThedisplacementofcentreofmassofA+Bsystemtillthestringbecomesverticalis:
[A]

Zero

[B]
[C]
[D]

Noneofthese

Question31.
Thegraphsinfigureshowthataquantityyvarieswithdisplacementdinasystemundergoingsimpleharmonicmotion.

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Whichgraphsbestrepresentstherelationshipobtainedwhenyis:

Thetotalenergyofthesystem?
[A]
[B]
[C]
[D]

I
II
III
IV

Question32.
Thegraphsinfigureshowthataquantityyvarieswithdisplacementdinasystemundergoingsimpleharmonicmotion.

Whichgraphsbestrepresentstherelationshipobtainedwhenyis:

Thetime?
[A]
[B]
[C]
[D]

I
II
III
IV

Question33.
Acylindricalvesselofheight500mmhasanorifice(smallhole)atitsbottom.Theorificeisinitiallyclosedandwaterisfilledinitupto
heightH.Nowthetopiscompletelysealedwithacapandtheorificeatthebottomisopened.Somewatercomesoutfromtheorificeand
thewaterlevelinthevesselbecomessteadywithheightofwatercolumnbeing200mm.Findthefallinheight(inmm)ofwaterleveldue
toopeningoftheorifice.(Takeatmosphericpressure
N/m2,densityofwater=1000kg/m3andg=10m/s 2.Neglectany
effectofsurfacetension).

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Question34.
Aparticleofmassmissubjectedtoanattractivecentralforceofmagnitudek/r 2,kbeingaconstant.Ifattheinstantwhentheparticleis
atanextremepositioninitsclosedorbit,atadistanceafromthecentreofforce,itsspeedis(k/2ma),ifthedistanceofotherextreme
positionis'b'.Finda/b.

Question35.
Twoidenticalconductingrods,infirstcaseconnectedindependentlytotwovessels,onecontainingwaterat100oCandtheother
containingiceat0oC.Inthesecondcase,rodsarejoinedendtoendandareconnectedtothesamevessels.Ifq1andq2(ing/s)arethe
ratesofmeltingoficeintwocases,thenfindtheratioofq1/q2.

Question36.
Avesselcontains1moleO 2gasatatemperatureT.AnidenticalvesselcontainsonemoleofHegasatatemperature2T.Findtheratio
oftheirpressure(HetoO 2).

Question37.
Asmallbodyofmassmisconnectedtotwohorizontalspringsofelasticconstantk,naturallengthoftheeachspringis3d/4.Inthe
equilibriumpositionbothspringsarestretchedtolengthd,asshowninfigure.
Whatwillbetheratiooftimeperiodofthemotion(Tb/Ta)ifthebodyisdisplacedhorizontallybyasmalldistancewhereTaisthetime
periodwhentheparticleoscillatesalongthelineofspringsandTbistimeperiodwhentheparticleoscillatesperpendiculartotheplaneof
thefigure?(Neglecteffectsofgravity).

Question38.
Auniformmagneticfield

existsinaspace.Aparticleofmassmandchargeqisprojectedtowardsnegativexaxiswithspeed

vfromtheapoints(d,0,0).Themaximumvaluevforwhichtheparticledoesnothittheyzplaneis=

.Find'n'.

Question39.
Inthesystemshowninthefigurethereisnotfrictionanywhere.TheblockCgoesdownbyadistancex 0=10cmwithrespecttowedge
Dwhensystemisreleasedfromrest.ThevelocityofAwithrespecttoBwillbe(g=10m/s 2).

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Question40.
Aflexiblechainoflength2mandmass1kginitiallyheldinverticalpositionsuchthatitslowerendjusttouchesahorizontalsurface,is
releasedfromrestattimet=0.Assumingthatanypartofchainwhichstrikestheplaneimmediatelycomestorestinstantlyandthatthe
portionofchainlyingonhorizontalsurfacedoesnotformanyheap,theheightofitscentreofmassabovesurfaceatanyinstant
(beforeitcompletelycomestorest)isn/4,where'n'is_________.

Question41.
Thefunction

is:

[A]

Continuouseverywhere

[B]

Discontinuousatthepoints

[C]

Notdifferentiableat

[D]

Notdifferentiableat

Question42.
Ifthepoint

liesinsidethetriangleformedbythelines

andthexaxis,thenthevalueof

canbeequalto:
[A]
[B]
[C]
[D]

1.5
0.5

Question43.
Thesequence

isdefinedby

and

.Now,if[.]denotesthegreatestintegerfunction,thenwhichof

thefollowingoptionsis(are)correct?
[A]

[B]

[C]

[D]

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Question44.
Letnbeapositiveintegerwith

andP(x),Q(x)bepolynomialsinxsuchthat
then:

[A]
[B]
[C]
[D]

Question45.
If

and

then:(

arepositiveintegersand

is

minimum)
[A]
[B]
[C]
[D]

A=80
B=180
C=199
C=119

Question46.
If

and

,thenwhichofthefollowingoptionsis(are)correct?

[A]
[B]
[C]
[D]

Question47.
Whichofthefollowingis(are)correct?
[A]

Domainof

isnullset

[B]

Domainof

is

[C]

Domainof

is

[D]

Domainof

is

[cos1,1]

Question48.
ConsiderthecirclesS1:
[A]
[B]
[C]
[D]

andS2:

.Whichofthefollowingstatementsis(are)correct?

Numberofcommontangentstothesecirclesis2
IfthepowerofavariablepointPw.r.t.thesetwocirclesissame,thenPmovesontheline
Sumoftheyinterceptsofboththecirclesis6
ThecirclesS1andS2areorthogonal

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Question49.
LetA1,G 1,H1denotethearithmetic,geometricandharmonicmeans,respectively,oftwodistinctpositivenumbers.For
and

hasarithmetic,geometricandharmonicmeansas

,let

respectively.

Whichofthefollowingstatementsis(are)correct?
[A]
[B]
[C]
[D]

G 1>G 2>G 3>.......

G 1=G 2=G 3=.....
A1>A2>A3>.....
A1>A3>A5>......andA2>A4>A6>.....

Question50.
LetA1,G 1,H1denotethearithmetic,geometricandharmonicmeans,respectively,oftwodistinctpositivenumbers.For
and

hasarithmetic,geometricandharmonicmeansas

,let

respectively.

Whichofthefollowingis(are)notcorrect?
[A]
[B]
[C]
[D]

H1>H2>H3>....
H1<H2<H3<.....
H1>H3>H5>.....andH2<H4<H6<....
H1<H3<H5<......andH2>H4>H6>.....

Question51.
TwocurvesC1:

andC2:

Satisfying

[Hint:Generalsolutionto

and

is

whereP(x)andQ(x)arefunctions

ofx].

ThenthecurvesC1andC2are:
[A]
[B]
[C]
[D]

circle
parabola
ellipse
straightline

Question52.
TwocurvesC1:

andC2:

Satisfying

[Hint:Generalsolutionto

and

is

whereP(x)andQ(x)arefunctions

ofx].

TheareaboundedbyC1andC2(insq.units)is:
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[A]
[B]
[C]
[D]

Question53.
Iff(x)andg(x)aretwopolynomialssuchthatpolynomial

isdivisibleby

,thenthevalue

ofg(1)is____________.

Question54.
LetTnwhere

representfourdistinctpositiverealnumbersotherthanunitysuchthat

pointonacirclewhosecentreliesonYaxis,thenthelargestintegerxsuchthat

representsa

isalwaysgreaterthanxis__________.

Question55.

If

then

isequalto_________.

Question56.
Letx>0,thenthevalueof

isequalto____________.

Question57.
If

aretherootsof

for

where

and

,thenkisequalto___________.

Question58.
Letf:

definedby

bestrictlyincreasingonR,thenthelargestintegralvalueof

'c'is__________.

Question59.

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QuestionRevision

is___________.

Question60.
Let

of

.Then,thenumberofelementsintherange

is______.(where[]denotesthegreatestintegerfunction).

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