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Question1.
TheeneynethatproducesachiralcompoundupontreatmentwithH2inthepresenceofLindlar'scatalystis:

[A]

[B]

[C]

[D]

YourAnswer:

CorrectAnswer: B
Explanation:

Thisisacaseofchiralityintermsofdifferentsubstituentsonthebasisofgeometricalconfigurations(willbecoveredinmoredetailin
advancedstereochemistrysessions).

Question2.
At

,thesolubilityproduct(Ksp)ofCaF2inwateris

.Thesolubility(inmolperkgofwater)ofthesaltatthesame

temperatureis:
[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: D
Explanation:
Solutionofsparinglysolublesaltisdilutesolution.Fordilutesolution

Question3.
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Asolutionof0.1MNa2CO 3istitratedagainstHClusing(1)phenolphthaleinasanindicatorand(2)methylorangeasanindicator.The
valueof

isequalto:[(WherepH(1)ispHatendpointwithphenolphthaleinandpH(2)ispHatendpointwithmethyl

orange)(gasesareevolvedoffifany)][Given
[A]

[B]
[C]
[D]
YourAnswer:

CorrectAnswer: C
Explanation:

Question4.
Whatquantityisrepresentedbytheslopeofthelineinthegraphofthetemperaturedependenceofthenaturallogofanequilibrium
constant?

[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: D
Explanation:

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Question5.
Theplotof

versus

(whereXAandYAarethemolefractionsofAinliquidandvapourphases,respectively)islinearwith

slopeandinterceptrespectivelyaregivenas:
[A]

[B]

[C]
[D]

Noneofthese

YourAnswer:

CorrectAnswer: B
Explanation:

Question6.
19gofmoltenSnCl2iselectrolyzedforsometime,usinginertelectrodes.0.119gofSnisdepositedatthecathode.Ifnosubstanceis
lostduringtheelectrolysisthenfindwhichofthefollowingstatement(s)is(are)correct?[AtomicmassofSn=119,Cl=35.5]
[A]
[B]
[C]
[D]

EquivalentofSnCl2decomposedareequalto0.002
Equivalentofchlorineproducedareequalto0.002
EquivalentofSnCl4formedareequalto0.002
MassofSnCl2remainedafterelectrolysisis18.62g

YourAnswer:

CorrectAnswer: A,B,C,D
Explanation:

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Question7.
Acellutilizesthefollowingcellreaction:

WhichofthefollowingwillchangetheEMFofthecell?
[A]
[B]
[C]
[D]

WhenCo(II)nitrateisdissolvedinthecathodecompartment
WhenCo(III)nitrateisdissolvedinthecathodecompartment
WhenareaofZn(s)electrodeisdoubled
Whenadditionalwaterisaddedtotheanodecompartment

YourAnswer:

CorrectAnswer: A,B,D
Explanation:

If[Co2+]isincreased,Ecellwilldecrease
If[Co3+]isincreased,Ecellwillincrease
IfareaofZn(s)isdoubled,Ecellwillnotchange
Ifadditionalwaterisaddedinanodiccompartment,[Zn2+]willdecreaseandhenceEcellwilldecrease.

Question8.
ConsiderthefollowingBronstedacidbasereactionofsomeorganiccompoundsR1andR2.

Identifycorrectstatement(s):
[A]
[B]
[C]

R2,P1andP2arearomaticcompounds
HybridizationstateofNatominbothP1andP2issame
R1isantiaromatic

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[D]

QuestionRevision

BothR2andP1containsacloseloopofdelocalizable

YourAnswer:

CorrectAnswer: A,B,D
Explanation:
R1isnotantiaromaticitisnonaromatic.

Question9.
Usethestandardreductionpotentialstodeterminewhatisobservedatthecathodeduringtheelectrolysisofa1.0MsolutionofKBrthat
containsphenolphthaleinusinginertelectrodes.Whatobservationsis(are)made?

[A]
[B]
[C]
[D]

Solidmetalforms
Bubblesformandapinkcolourappears
DarkredBr 2(aq)forms
Bubblesformandthesolutionremainscolourless

YourAnswer:

CorrectAnswer: B
Explanation:
Reductionofwatertakesplaceatthecathode.

Bubblesformduetoevolutionof

andapinkcolourappearsduetoformationof

(Phenolphthaleinshowspinkcolourationinalkalinemedium).

Question10.
Whichofthefollowingplot(s)iscorrectforfirstorderreaction?(r=rateattime't'andr 0istheinitialrate,k=rateconstant,t=
temperature).

[A]

[B]

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[C]

[D]

YourAnswer:

CorrectAnswer: A,B,C,D
Explanation:

Question11.
Mercuriciodideisaddedtoanaqueoussolutionofpotassiumiodide.Identifythecorrectstatement(s).
[A]
[B]
[C]
[D]

Acomplexspeciesisformed
Numberofsoluteparticlesincrease
Freezingpointisraised
Boilingpointislowered

YourAnswer:

CorrectAnswer: A,C,D
Explanation:

Whencomplexionsareformedtheirsolutionsshowabnormallylowcolligativeeffectsthanexpectedbecausetheycontainfewer
particlesofsolutethanwouldotherwisebepresent.Whenalittle
isaddedtopotassiumiodidesolutionthenumberofsolute
particlesdecreases,andthereislowvalueofcolligativepropertiesi.e.freezingpointisraisedandboilingpointislowered.

Question12.
Considerthefollowingsequenceofreactionsandidentifycorrectstatement(s)

[A]

In

,NOgroupshowsI,+RandRelectroniceffects

[B]

In

groupshowsIandRelectroniceffects

[C]

In

groupshowsIand+Relectroniceffects

[D]

In

groupshowsIandRelectroniceffects

YourAnswer:

CorrectAnswer: B,C
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Explanation:
NOisadeactivatinggroup.

Question13.
Inthethreestependothermicreaction

thanwhichofthefollowingstatementsarecorrect?
[A]
[B]
[C]
[D]

StepIisfavouredbyhightemperatureandlowpressure
StepIIisfavouredbylowtemperatureandhighpressure
StepIIisfavouredbyhighpressureandhightemperature
StepIIIisfavouredbyhighpressureandhightemperature

YourAnswer:

CorrectAnswer: A,C,D
Explanation:
NA

Question14.
Equalvolumesoffollowingsolutionsaremixed,inwhichcasethepHofresultingsolutionwillbeaveragevalueofpHoftwosolutions?
[A]
[B]
[C]
[D]

pH=3(HNO 3)andpH=5(HNO 3)
pH=2(HNO 3)andpH=12(KOH)
pH=4.5(CH3COOH)andpH=9.5(NH3)(aq)[Ka(CH3COOH)=Kb(NH4OH)]
pH=3(HCN)andpH=11(NaOH)[KaofHCN=1010]

YourAnswer:

CorrectAnswer: B,C
Explanation:

Question15.
Whichofthefollowingstatementsis(are)correctabouthalflifeperiod?
[A]
[B]
[C]

Itisproportionaltoinitialconcentrationforzerothorder
Averagelife=1.44halflifeforfirstorderreaction
Timeof75%reactionisthriceofhalflifeperiodinsecondorderreaction

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[D]

QuestionRevision

99.9%reactiontakesplacein100minutesforthecasewhenrateconstantis0.0693min1

YourAnswer:

CorrectAnswer: A,B,C,D
Explanation:

Question16.
At298K,theEMFofthecell:
is0.7530V.Thestandardpotentialofthecalomelelectrodeis
0.2802V.ThepHofthesolutionis_____________.
YourAnswer:

CorrectAnswer: 8
Explanation:

Question17.
Howmany
bondelectronpairsarelocalizedintheplanarcyclicorganiccompound(P).

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YourAnswer:

QuestionRevision

CorrectAnswer: 2
Explanation:

2pairofelectrons(1eachforthespcarbonbonds)willremainlocalized.

Question18.
Amixture(X)ofisomericorganiccompoundhavingmolecularformulaC4H8,onreactionwithBr 2dissolvedinCCl4producesamixture
containingfiveisomericproductshavingmolecularformulaC4H8Br 2.Thenumberofisomericorganiccompoundsinthemixture(X)is
____________.
YourAnswer:

CorrectAnswer: 3
Explanation:

Question19.
Howmanystereocentresdoesthefollowingmoleculecontain?

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YourAnswer:

QuestionRevision

CorrectAnswer: 9
Explanation:

Question20.
Howmanymillimolesofgaseoussubstanceswouldbeformedduringelectrolysisofaqueous

usinginertelectrodeby

passingacurrentof10milliampwithcurrentefficiency50%for965min?(Assumenoreactionbetweenproductofelectrolysis,ifany).
YourAnswer:

CorrectAnswer: 6
Explanation:

Question21.
AtimevaryingforceF=2tisappliedonspoolasshowninfigureanditrollswithoutslidingasfrictionissufficient.Theangularmomentum
ofspoolattimetaboutbottomofspoolis:

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[A]

[B]
[C]
[D]

Insufficientdata

YourAnswer:

CorrectAnswer: C
Explanation:

Question22.
Thecurrentthrough

resistanceiszero.

ThevalueofEis:

[A]
[B]
[C]
[D]

24V
36V
42V
45V

YourAnswer:

CorrectAnswer: C
Explanation:
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and

areinparallel,socurrentin

isalsozero,theycanberemoved.Andthecurrentsareasshown:

Question23.
Att=0,astone(ofmassm)isreleasedfromthetopofabuildingofheighth.Attimet,kineticenergyoftheparticleis3timesthe
potentialenergyoftheparticlew.r.t.theground.Averagepowerdeliveredtotheparticlebetweent=0andt=tequals:
[A]

[B]

[C]

[D]

YourAnswer:

CorrectAnswer: A
Explanation:
Attimet,ithasfallthrough3/4thheightoftotalheighth

Averagepowerdelivered=

Averagepower=

Question24.
Aringofradius

hascharge

throughthecentreofasolidsphereofradius

uniformlydistributedonitscircumference.Theaxisoftheringpasses
whichhascharge

uniformlydistributedwithinitsvolume.Thedistance

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betweenthetwocentreoftheringandthesphereis

.ThereisaverythintunnelMNalongtheaxisoftheringthroughthe

centreofthesolidsphere.

Whatisthevalueof

sothatthereisanullpointatM.

[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: B
Explanation:

Question25.
Aringofradius

hascharge

throughthecentreofasolidsphereofradius
betweenthetwocentreoftheringandthesphereis

uniformlydistributedonitscircumference.Theaxisoftheringpasses
whichhascharge

uniformlydistributedwithinitsvolume.Thedistance

.ThereisaverythintunnelMNalongtheaxisoftheringthroughthe

centreofthesolidsphere.

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Withwhatminimumvelocity

shouldaparticleofmass20gmandcharge

shouldbeprojectedfromthecentreofthe

ringalongitsaxissothatitmaybeabletoenterthetunnel.
[A]
[B]
[C]
[D]

6m/s
60m/s
300m/s
500m/s

YourAnswer:

CorrectAnswer: B
Explanation:

Question26.
TwochargesQ 1andQ 2placedat(0,0,0)and(a,0,0)aresuchthatxcomponentoffieldiszeroat(a/2,a,0).ycomponentoffieldwill
bezeroat:
[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: A,B,C
Explanation:

Thexcomponentcannotbezeroiftheboththechangesareofoppositesign.]
Fromthefigure,itfollows

asxcomponentofE1andE2equal.

atallpointsinthexzplane,theycomponentoffieldwillbezero

Question27.
AnunchargedcapacitorhavingcapacitanceCisconnectedacrossabatteryofemfV.Nowthecapacitorisdisconnectedandthen
reconnectedacrossthesamebatterybutwithreversedpolarity.Then:
[A]

afterreconnection,thermalenergyproducedinthecircuitwillbeequalto2CV2

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[B]
[C]
[D]

QuestionRevision

afterreconnection,thermalenergyproducedinthecircuitwillbeequaltotwothirdofthetotalenergysuppliedbythebattery
afterreconnection,noenergyissuppliedbythebattery
afterreconnection,energyproducedbythebatteryisconvertedintoheat

YourAnswer:

CorrectAnswer: A,B,D
Explanation:

Question28.
Whentheterminalsofacellofemf1.5Vareconnectedtoanammeterofresistance
followingstatementsarecorrect?
[A]
[B]
[C]
[D]

,theammeterreads0.30amp.Whichofthe

Thecellisnonideal
Ifa
resistorisalsoconnectedacrossterminalsofthecell,theammeterwillread0.50amp
Ifa
resistorisalsoconnectedacrosstheterminalofthecell,onethirdoftheelectricalpowergeneratedwilldissipateas
heatwithinthecell
Ifavoltmeterofresistance
isusedtomeasurepotentialdifferencebetweenterminalsofthecell,itwillread1.2V

YourAnswer:

CorrectAnswer: A,C,D
Explanation:

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Question29.
Theelectricpotentialinaregionalongthexaxisvarieswithxaccordingtotherelation
[A]
[B]
[C]
[D]

.Then:

potentialdifferencebetweenthepointsx=1andx=2is15V
forceexperiencedbyaonecoulombchargeat
willbe10N
theforceexperiencedbytheabovechargewillbetowards+xaxis
auniformelectricfieldexistsinthisregionalongthe+xaxis

YourAnswer:

CorrectAnswer: A,B,C
Explanation:

Question30.
EandVonetheelectricfieldandelectricpotentialatOifthelinearchargedensityofthesystemis

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[A]

[B]

[C]

[D]

YourAnswer:

CorrectAnswer: A,C
Explanation:

Question31.
Fiveidenticalconductingplatesarefixedparalleltoandequidistantfromother.Givend=distancebetweenanytwosuccessiveplates
andA=areaofeitherfaceofeachplate.

[A]
[B]

Totalchargeonplate3is4timesthetotalchargeonplate1
Totalchargeonplate2isnegative

[C]

Chargeontheuppersurfaceofplate5is

[D]

Chargeonthelowersurfaceofplate1iszero

YourAnswer:

CorrectAnswer: A,B,D
Explanation:

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Chargedrawnfromthebattery=

Totalchargeonplate1=Chargeath
Totalchargeonplate2=Chargesatfandg(sum)

Totalchargeonplate3=chargesatdande=

=4

timesthetotalchargeonplate1

Question32.
Threeidenticalspheresareinastraightlineonatableandonemovestowardstheothertwowhichareatrestandnotincontact,if
,then:

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[A]
[B]
[C]
[D]

QuestionRevision

therearetwoimpactsbetweenthem
therearethreeimpactsbetweenthem
theratiooftheirfinalvelocitiesis13:15:63
theratiooftheirfinalvelocitiesis13:15:36

YourAnswer:

CorrectAnswer: B,D
Explanation:

ThirdcollisionbetweenAandB:

AandBwillcollideagain

and

BandCwillnotcollideagain

Ratiooffinalvelocities=

=13:15:36

Question33.
Asphereofmass2.8kgisrollingwithoutslippingonaninclinedplaneofangle
[A]

theminimumcoefficientoffrictionrequiredis

[B]
[C]

thetranslationalkineticenergyisalwaysgreaterthanrotationalkineticenergy
thefrictionforceonthesphereis4.8N

[D]

theaccelerationofthesphereis

YourAnswer:

fromhorizontal.Choosethecorrectstatement(s).

CorrectAnswer: B,C,D
Explanation:

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Question34.
Intheadjacentfigure,auniformrodoflength
andmassmiskeptatrestinhorizontalpositiononanelevatededge.Thevalueofx
(considerthefigure)issuchthattherodwillhavemaximumangularacceleration
,assoonasitissetfree.

[A]

xisequalto

[B]

isequalto

[C]

isequalto

[D]

xisequalto

YourAnswer:

CorrectAnswer: A,C
Explanation:

Question35.
Acapacitorof

ischargedtoapotentialof100V.Now,thischargedcapacitorisconnectedtobatteryof100Vwithpositive

terminalofbatteryconnectedtonegativeplateofthecapacitor.
Forthegivensituation,markthecorrectstatement(s).
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[A]

Thechargeflownthrough100Vbatteryis

[B]
[C]
[D]

Thechargeflownthrough100Vbatteryis
Heatdissipatedinthecircuitis0.1J
Workdoneonthebatteryis0.1J

YourAnswer:

CorrectAnswer: B,C
Explanation:
Changesuppliedbybattery=

Heat=

Question36.
Theresistivityofrodoflengthlandofuniformcrosssectionvarieslinearlyfrom
potentialdifferenceofVvoltsismaintainedacrosstherod.Theelectricfieldatadistance

YourAnswer:

fromoneendAtotheotherendB.A
fromendAis

.Findn.

CorrectAnswer: 6
Explanation:

Question37.
Asmallsphereofmassm=0.5kgcarryingapositivecharge

isconnectedwithalight,flexibleandinextensiblestringof

lengthr=60cmandwhiledinaverticalcircle.Ifaverticallyupwardelectricfieldofstrength

existsinthespace,

calculateminimumvelocityofsphererequiredathighestpointsothatitmayjustcompletethecircle.
YourAnswer:

CorrectAnswer: 6
Explanation:

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Question38.
ABisahorizontaldiameterofaballmassm=0.4kgandradiusR=0.10m.Attimet=0,asharpimpulseisappliedatBatangleof
withthehorizontal,asshowninfig.,sothatballimmediatelystartstomovewithvelocity

.Findthevelocityofthe

ballwhenslidingceasesandpurerollingbegins.

YourAnswer:

CorrectAnswer: 0
Explanation:

At

horizontalandverticalcomponentofimpulseareequal(=Ilet)

Byhorizontalcomponentofimpulse,I=mV0
Angularimpulsebyverticalcomponent=

Let

......(i)

bevelocityofcentreandangularvelocityrespectivelywhenpurerollingbeginsaftertimet

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ballwillstoppermanently

Question39.
Adisc'A'ofmassMisplacedatrestonthesmoothinclinesurfaceofinclination

.AballBofmassmissuspendedverticallyfrom

thecentreofthediscAbyalightinextensiblestringoflength

asshowninthefigure.IftheaccelerationofthediscBimmediately

afterthesystemisreleasedfromrestis

Thevalueofkis:

YourAnswer:

CorrectAnswer: 1
Explanation:

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Question40.
Inthecircuitshowninfigure,findthevalueof

YourAnswer:

inVolt.

CorrectAnswer: 8
Explanation:

Question41.
If

(Cbeingtheconstantofintegration).Then:

[A]

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[B]

iscontinuousforall

[C]

[D]

YourAnswer:

CorrectAnswer: C
Explanation:

Question42.
If
[A]
[B]
[C]
[D]

,thenthevalueof

isequalto:

0
2207
1

YourAnswer:

CorrectAnswer: D
Explanation:

Question43.
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Solutionoftheequation

[A]
[B]
[C]
[D]

isequalto:

2
3
4
5

YourAnswer:

CorrectAnswer: A
Explanation:

Question44.

Thevaluesofaandbforwhichthefunction

iscontinuousfor

,are:

[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: B
Explanation:

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Question45.
If

and

bothare

differentiableatx=0,theng(x)isnondifferentiableatxisequalto:
[A]
[B]
[C]
[D]

YourAnswer:

CorrectAnswer: B
Explanation:

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Question46.
Consideravariableline'L'whichpassesthroughthepointofintersection'p'ofthelines
meetingthecoordinateaxesatpointsAandB:
[A]

and

thenthelocusofmiddlepointofthesegmentABhastheequation
thenthelocusofthefeetoftheperpendicularfromtheoriginonthevariableline'L'hastheequation

[B]
[C]

LocusofthecentroidofthevariabletriangleOABhastheequation(where'O'istheorigin)

[D]

LocusofthecentroidofthevariabletriangleOABhastheequation(where'O'istheorigin)

YourAnswer:

CorrectAnswer: A,B,C
Explanation:

Question47.
Letx,yberealvariablesatisfythe

Leta=max

andb=min

,then:
[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: A,C,D
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Explanation:

Question48.
LetA,B,C,D,lieonalinesuchthatAB=BC=CD=1.ThepointsAandCarealsojoinedbyasemicirclewithACasdiameterandPisa
variablepointonthissemicirclesuchthat
.LetRistheregionboundedbyareAP,thestraightlinePDandline
AD
[A]

ThemaximumpossibleareaofregionRis

[B]

If'L'istheperimeterofregion'R',thenLisequalto

[C]

ThemaximumpossibleareaofregionRis

[D]

If'L'istheperimeterofregion'R',thenLisequalto

YourAnswer:

CorrectAnswer: A,B
Explanation:

Question49.
If
[A]
[B]
[C]
[D]

then:
numberofsolutionsis7
numberofsolutionsis6
numberofintegralsolutionsis5
numberofintegralsolutionsis6

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YourAnswer:

QuestionRevision

CorrectAnswer: A,C
Explanation:

Question50.
Iff(x)andh(x)areoddfunctionandg(x)isevenfunction,thenwhichofthefollowingisoddfunction:
[A]
[B]
[C]
[D]
YourAnswer:

CorrectAnswer: B,C,D
Explanation:

Question51.
Iff:

satisfiescondition

,then:

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[A]
[B]
[C]

QuestionRevision

f(x)isontofunction
f(x)isoneonefunction
f(x)isanoddfunction

[D]

and

YourAnswer:

areidentical

CorrectAnswer: A,B,C,D
Explanation:

Question52.
Letf:
[A]
[B]

andlet

[C]

f(x)isoneonefunction
f(x)isoddfunction
g(x)iscontinuousis

[D]

f(x)iscontinuousforall

YourAnswer:

,then:

CorrectAnswer: B,C,D
Explanation:

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Question53.
If

,thenwhichofthefollowingis(are)false?

[A]
inthedomainoff(x)

[B]
[C]

f(x)isidenticalto

[D]

Numberofrootsofequation

YourAnswer:

islessthan2

CorrectAnswer: A,D
Explanation:

Notethatx=0isnotindomainof

CaseI:Ifx>0,let

Nowlet

CaseII:x<0

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as

&usingCaseI

So,

doesnotexist

Alsonotethat

isnotindomainof

identicalto

Question54.
Thefunctionf(x)=
[A]
[B]
[C]
[D]

dtissuchthat:

itisdefinedontheinterval[1,1]
itisanincreasingfunction
itisanoddfunction
thepoint(0,0)isthepointofinflection

YourAnswer:

CorrectAnswer: A,B,C,D
Explanation:

Now

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Again

whichvanishedatx=0andchangessign

isinflectionsincefiswelldefinedin

Question55.
Forthefunctionf(x)=ln(1lnx)whichofthefollowingdonotholdgood?
[A]
[B]
[C]
[D]

Increasingin(0,1)anddecreasingin(1,e)
Decreasingin(0,1)andincreasingin(1,e)
x=1isthecriticalnumberforf(x)
fhastwoasymptotes

YourAnswer:

CorrectAnswer: A,B,C
Explanation:

f(x)=ln(1lnx)
Domain(0,e)

f"(1)=0whichisapointofinflectiongraphisasshownyaxisandx=earetwoasymptotes

Question56.
Let

YourAnswer:

,thenkisequalto_________.

CorrectAnswer: 8
Explanation:

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Put

inaboveintegraltoget:

Question57.
Let

.Ifx 1andx 2aretworootsoftheequation

,(where[.]denotesgreatestintegerfunction,{.}denotesfractionalpartofx).Let

discontinuityoff(x),

representsnumberofpointsofnondifferentiability.

in
representsnumberofpointsof
and

then

is_________.
YourAnswer:

CorrectAnswer: 6
Explanation:

(Wehavemade

Question58.
If

andif

,thennis________.

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YourAnswer:

QuestionRevision

CorrectAnswer: 8
Explanation:

Question59.
If

YourAnswer:

,then3kisequalto____________.

CorrectAnswer: 4
Explanation:
NA

Question60.
Let
YourAnswer:

thenfindthenumberofpositiveintegralvaluesofxwhichsatisfies

CorrectAnswer: 2
Explanation:

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