Nguyn Hong Tn (CECEIU11027) | Rxn Rate&Eq_Wed (ONLINE) v1 | Completed 11/22/2012 3:24

PM | 14/14 (100%)
Student's Answer
a1)

Correct

Incorrect

Partial Credit

When writing equilibrium-constant expressions for chemical reactions involving a

pure solid the concentration of the pure solid is
a) not included in the equilibrium constant expression
b) represented by the density of the pure solid
c) determined by a series of volume and mass experiments
d) is treated as an aqueous solution
.

a2)

Consider the reaction 2N2O(g) + 3O2(g) = 2N2O4(g), which is an endothermic

reaction. What is the effect of increasing the concentration of N2O?
a) [O2] will decrease
b) [N2O4] will decrease
c) [O2] will increase
d) there will be no effect
.

a3)

For the equilibrium CO(g) + 3H2(g) = CH4(g) + H2O(g) the value of Kc = 0.176
at 1500C. What is the value of Kp at 1500C?
a) 5.00x10-9
b) 8.31x10-6
c) 1.16x10-5
d) 2.67x10-3
.

a4)

Which of the following statements is CORRECT? At equilibrium, ______

a) the reaction ceases
b) the forward and reverse rates are equal
c) all of the reactants have been converted to product
d) the rate constants for the forward and reverse reactions are equal
.

a5)

An equilibrium mixture for the reaction N2(g) + 3H2(g) = 2NH3(g) has the
following concentrations: [N2] = 0.075 mol/L, [H2] = 0.150 mol/L, and [NH3] =
0.0550 mol/L. What is the value of the equilibrium constant?
a) 71.1
b) 11.95
c) 0.011
d) 0.0141
.

a6)

Q. 4. Which of the following correctly describes a relation between the equilibrium

constant (K) and the equilibrium quotient (Q)?
a) Q > K: reaction shifts to products
b) Q < K: equilibrium established
c) Q = K: reaction shifts to reactants
d) Q > K: reaction shifts to reactants
.

Nguyn Hong Tn (CECEIU11027) | Rxn Rate&Eq_Wed (ONLINE) v1 | Completed 11/22/2012 3:24

PM | 14/14 (100%)
a7)

Consider the A = B reaction for which Kc = 0.798 mol/L. Which of the following
statements about the equilibrium is CORRECT?
a) the reaction essentially goes to completion
b) the rates of the forward and reverse reactions are not equal
c) there are slightly more products than reactants in the mixture
d) there are slightly more reactants than products in the mixture
.

a8)

If Keq = 8.13 for A + 2B = 2C , then for 2C = A + 2B

Keq =_____________
a) 13.88
b) 0.123
c) 6.48
d) -8.13
.

a9)

Which of the following statement is TRUE about catalyst?

a) Catalyst increases the reaction rate
b) Catalyst remains unchanged during a reaction
c) Catalyst has no effect on the equilibrium compostion of a reaction mixture
d) All of the listed items
.

a10)

Given the 2nd order reaction 2NO2(g) = 2NO(g) + O2(g). If k = 0.543 M-1s-1
and concentration of NO2 is 0.0079 M, what is the rate in M/s?
a) 4.3x10-3
b) 3.4x10-5
c) 1.5x10-2
d) 69
.

a11)

The rate law for a reaction A = B is rate = k[A]. Which of the following graphs will
give a straight line?
a) ln[A] vs. time
b) [A] vs. time
c) 1/[A] vs. time
d) ln[A] vs 1/T
.

a12)

For the reaction NH4+(aq) + NO2-(aq) = N2(g) + 2H2O(l) The rate law has
been found to be Rate = k[NH4+][NO2-]. In one experiment where initial [NO2-]
was 0.0400 and initial [NH4+] was 0.200, the observed initial rate was 2.15x10-6
M/s. What is the value of k in M-1s-1?
a) 1.72x10-8
b) 3.72x10+3
c) 2.69x10-10
d) 2.69x10-4
.

Nguyn Hong Tn (CECEIU11027) | Rxn Rate&Eq_Wed (ONLINE) v1 | Completed 11/22/2012 3:24

PM | 14/14 (100%)
a13)

Which of the following is TRUE about a/the rate-determining step?

a) The rate-determining step is the slowest step in the reaction mechanism
b) The rate-determining step limits the rate of the overall reaction
c) The rate law of the rate-determining step represent the rate law fro the
overall reaction
d) All of the listed items
.

a14)

2NO(g) + 2H2(g) = N2(g) + 2H2O(g) with the rate expression as follows:

Rate = k*[NO]^2*[H2] The reaction order with respect to H2 is __________
a) 0
b) 1
c) 2
d) 3
.