2008 9

......................................................................................1
......................................7
.................................................................... 11
........................................................19
........................................39
1
............................................................................................................41
2 .............................................45

2002
Globally Harmonized System for Classification and Labelling of
Chemicals GHS

LabellingMaterial Safety Data Sheet

MSDS/SDS

Food and Agriculture

Organization of the United NationsFAOWorld
Health OrganizationWHO 2002
GHS
FAO 2006 GHS

GHS
GHS

GHS
GHS /

/ MSDS/SDS
1

/
97
GHS MSDS/SDS
100 GHS
http://pesticide.baphiq.gov.tw/ghs/
MSDS/SDS

MSDS/SDS
/
GHS
MSDS/SDS

International Chemical
Safety CardsICSCs WHOInternational
Labour OrganizationILOUnited Nations
Environment ProgrammeUNEP
International Programme for Chemical SafetyIPCS

1613 2007 12 ICSCs

/
/
2

ICSCs
MSDS/SDS
ICSCs MSDS/SDS

WHO FAO Pesticide

Data SheetsPDSs
PDS
123
45
IPCS INCHEM
http://www.inchem.org/pages/pds.html
PDSs PDSs

GHS MSDS/SDS

Identification

Hazard(s) identification

Composition/information on ingredients

First-aid measures

Fire-fighting measures

Accidental release measures

3

Handling and storage

Exposure controls/personal protection

Physical and chemical properties

10 Stability and reactivity

11 Toxicological information
12 Ecological information
13 Disposal considerations
14 Transport information
15 Regulatory information
16 Other information

ISO MSDS/SDS

1.

GHS GHS GHS

2.

MSDS/SDS
3.

/
4.
/

GHS MSDS/SDS

MSDS/SDS

MSDS/SDS

MSDS/SDS

MSDS/SDS

MSDS/SDS

GHS MSDS/SDS

MSDS/SDS

MSDS/SDS
(1)

(2)

(3)

(4)
MSDS/SDS

(5)

93 GHS
8

MSDS/SDS

10

MSDS/SDS
MSDS/SDS

MSDS/SDS

(1) CAS No.

Chemical Abstracts Service
CA
CAS No.
1969 71 CA
CAS No.

(2)

closed-cupopen-cup

11

(3)
Lower Explosion LimitLEL
Upper Explosion LimitUEL

propagation

%
g/m3
UEL
LEL

(4)

(5)

ppm
mg/m3 ppm
mg/m3
12


c TWA
TWATime-Weighted Average

d (STEL)
STELShort-Term Exposure Limit
15

e CELING

CELING

(6)

13

(7) pH
0 ~ 14
pH 7 pH 7
pH 0 ~ 3 pH 11 ~ 14

(8)

760 mmHg

(9)

(10)

2.5 ~ 3

14

(11)
20
mmHg
psi
(12)

(13)

1300
(14) =1

28.8

1
1

15

(15) =1
4
1

0.7

(16)
20
% 100

(17) /log Kow

/log Kow

(18)

16

(19) LD50
mg/kg
14 50% LD50Median
Lethal Dose mg/kg

LD50

(20) LC50
( 1 ~ 4 )
14 50% Median
Lethal Concentration ppm
LC50

(21) UN No.

UN No. UN No.
UN No.

17

18

MSDS/SDS

MSDS/SDS

4.1
4.1.1
MSDS/SDS
//

MSDS/SDS

4.1.2
(1)
MSDS/SDS

19

(2) //

(3)

4.1.3
Chlorpyrifos

4.2
4.2.1

GHS

4.2.2
(1) GHS

20

(2) GHS

4.2.3
3
3

2 1
1

4.3
4.3.1

21

4.3.2
(1)
CAS No.

(2)

chemical nature

4.3.3

Chlorpyrifos
ChlorpyrofosChloropyrofosChlorpyrophosO,O-Diethyl
O-3,5,6-Trichloro-2-Pyridyl Phosphorothioate2-Pyridinol,3,5,6-Trichloro-,
O-Ester With O, O-Diethyl PhosphorothioatePhosphorothioic Acid, O,
O-Diethyl O-(3,5,6-Trichloro-2-Pyridyl) EsterBrodanChlorpyrifos-Ethyl
ChloropyriphosChlorpyriphos-EthylDetmolEthion DryDursbanEradex
LorsbanPyrinex
CAS No.2921-88-2

100

4.4
4.4.1

22

4.4.2
(1)

MSDS/SDS
(2)
2-PAM

(3)

4.4.3

1.2.
3.4.

1.2.
3.4.
5.
1.2.
3.

1.2.
3.
4.

23

4.5
4.5.1

4.5.2
(1)

(2)

4.5.3

1.
2.

1.2./

1.2.3.4.
5.6.
7.8.
9.10.11.
12.13.

24

4.6
4.6.1

4.6.2
(1) MSDS/SDS
y

(2)

4.6.3
1.2.

1.2.

25


1.2.3.
4.
5
1.2.3.
4.5.
6.7.
8.
9.

1.2.

1.2.3.

4.7
4.7.1

4.7.2
(1) MSDS/SDS

(2)

26

4.7.3
1.2.3.
4.5.
6.7.8.
9.10.11.
12.

1.2.
3.4.
5.6.7.8.
9.10.
11.

4.8
4.8.1

4.8.2
(1) MSDS/SDS

(2)

27

(3) American Conference of

Governmental Industrial HygienistsACGIH
Deutsche ForschungsgemeinschaftDFG
biological monitoring guidelines
biological exposure indicesBEIs
Biological Tolerance ValuesBAT
MSDS/SDS BEIs
MSDS/SDS
NsSc
BNq
Sq

4.8.3
1.

TWA

STEL

CEILING

BEIs

1.2.
3.
4.
5.

6.

1.

28

1.2.

1.
1.
2.
3.4.

4.9
4.9.1

4.9.2
(1) pH

%
100
g/100g 100

20
(2)

60.5

29

4.9.3

41-42

pH /

//

0.0000187 mmHg@25

1.398@43=1

2 ppm@25

/log Kow

4.10
4.10.1

4.10.2
(1)

(2)

30

4.10.3
1. 1302.
1.
2.
1.2.

4.11
4.11.1

4.11.2
(1)
LD50 LC50
(2)

International Agency for Research on

CancerIARCAmerican
Conference of Governmental Industrial HygienistsACGIH

(3) MSDS/SDS

31

4.11.3

1.

2. 12

3.

4.

5.
6.

1.2.
3.4.
2-3 12 5.
6. 25 mg/kg 12

1.

2.3.
0.1 mg/kg 4
1.
2.3.
4.5.
5 7.125 mg 25
39.8% 15.9%
LD50
82 mg/kg
LD50
202 mg/kg
LC50
200 mg/m3/4H
1.
2.

3.

32


4.

5.

6.
7.
8.

9.

4.12
4.12.1

4.12.2
(1)

(2)

4.12.3
LC50
4.5 g/L/96HAtherinops affinis
0.3 g/L/48HDaphnia longispina
EC50
BCF100-4667

33


1.
81
2. 16-179
25 62 pH 4.735 pH 6.922 pH 8.1
3.
4

4.13
4.13.1

4.13.2
(1)

(2) MSDS/SDS

4.13.3

1.
34

2.
3.
4.

4.14
4.14.1
UN No.

UN No.

4.14.2
(1) UN No.
60
UN 1993
(2) UN No.
14
A
UN No. 1
(3) /
IMDG Code

35

4.14.3
2783

6.1
III
/

4.15
4.15.1

4.15.2
(1) MSDS/SDS

(2)

4.15.3

1.

2.

3.

4.

36

4.16
4.16.1

4.16.2
(1)
MSDS/SDS

(2)

4.16.3
1. RTECS TOMES PLUS Vol.682006

2. ChemWatch 2006-1
3. OHS MSDS 2006
4. HSDB TOMES PLUS Vol.682006

96.10.31

37

38

MSDS/SDS

MSDS/SDS

MSDS/SDS

y MSDS/SDS

y MSDS/SDS

y
y

y
y
y
y CAS No.

y
y
/
y

39

 GHS MSDS/SDS

MSDS/SDS 3 ~ 5

GHS MSDS/SDS

CAS No.

40

 1
A

UN No.

6.1

2758

23

6.1

2760

23

6.1

2762

23

6.1

2764

23

6.1

2772

23

6.1

2776

23

6.1

2778

23

6.1

2780

23

6.1

2782

23

6.1

2784

23

6.1

2787

23

6.1

3121

23

6.1

3124

23

6.1

3346

23

6.1

3350

23

6.1

2588

6.1

2757

6.1

2759

6.1

2761

6.1

2763

6.1

2771

6.1

2775

6.1

2777

41

UN No.

6.1

2779

6.1

2781

6.1

2783

6.1

2786

6.1

3027

6.1

3345

6.1

3349

6.1

2902

6.1

2992

6.1

2994

6.1

2996

6.1

2998

6.1

3006

6.1

3010

6.1

3012

6.1

3014

6.1

3016

6.1

3018

6.1

3020

6.1

3026

6.1

3348

6.1

3352

6.1

2903

23

6.1

2991

23

6.1

2993

23

6.1

2995

23

6.1

2997

23

6.1

3005

42

UN No.

23

6.1

3009

23

6.1

3011

23

6.1

3013

23

6.1

3015

23

6.1

3017

23

6.1

3019

23

6.1

3025

,
23

6.1

3347

23

6.1

3351

23

43

44

45


1 /6

P007

Chlorpyrifos

3 3 2
1 1

Chlorpyrifos
ChlorpyrofosChloropyrofosChlorpyrophosO,O-Diethyl O-3,5,6-Trichloro-2-Pyridyl
Phosphorothioate2-Pyridinol,3,5,6-Trichloro-, O-Ester With O, O-Diethyl Phosphorothioate
Phosphorothioic Acid, O, O-Diethyl O-(3,5,6-Trichloro-2-Pyridyl) EsterBrodan
Chlorpyrifos-EthylChloropyriphosChlorpyriphos-EthylDetmolEthion DryDursbanEradex
LorsbanPyrinex
CAS No.2921-88-2
100

46

1.2.3.
4.

1.2.3.
4.5.
1.2.3.

1.2.
3.4.

1.
2.

1.2./

1.2.3.4.
5.6.7.
8.9.10.
11.12.13.

1.2.

1.2.

1.2.3.
4.5

1.2.3.
4.5.6.
7.
8.9.

47


3 /6

P007
1.2.

1.2.3.

1.2.3.4.
5.6.7.
8.9.10.
11.12.

1.2.
3.4.5.6.7.
8.9.
10.11.

1.

TWA

STEL

CEILING

BEIs

1.2.
3.
4.
5.

6.

1.
1.2.
1.
1.2.
3.4.

48

41-42

pH /

//

0.0000187 mmHg@25

1.398@43=1

2 ppm@25

/log Kow

1. 1302.
1.
2.
1.2.

1.
2.
12

3.

4.
5.
6.

1.2.3.
4. 2-3 12
5.6. 25 mg/kg 12

1.
2.
49


5 /6

P007

3. 0.1 mg/kg 4

1.2.
3.4.
5. 5 7.125 mg
25 39.8% 15.9%
LD5082 mg/kg
LD50202 mg/kg
LC50200 mg/m3/4H
1.2.

3.4.

5.

6.7.
8.

9.

LC504.5 g/L/96HAtherinops affinis

EC500.3 g/L/48HDaphnia longispina
BCF100-4667

1.
81
2. 16-179 25
62 pH 4.735 pH 6.922 pH 8.1
3.
4

50

1.
2.
3.
4.

2783

6.1
III
/

1.

2.

3.

4.

1. RTECS TOMES PLUS Vol.682006

2. ChemWatch 2006-1
3. OHS MSDS 2006
4. HSDB TOMES PLUS Vol.682006

96.10.31

51

MSDS/SDS
GHS http://pesticide.baphiq.gov.tw/ghs

062939371 062938810
E-Mailcustomer@sahtech.org