Академический Документы
Профессиональный Документы
Культура Документы
Daniel T. Watrous
Department of Electrical and Computer Engineering
University of Utah, Salt Lake City, Utah 84112 1
March 2, 2010
1
Special Thanks to Professor Mark Miller, Justin Jackson and Divesh Kapoor
Contents
0.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
0.2.2 Fabrication . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
0.4.3 SpinFET . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Interest in developing nano-scale devices that manipulate both the charge and spin of electrons has
fueled much research in recent years. To be commercially viable these devices will require proven
and reliable means of fabrication. One solution has been proposed in which a traditional MOSFET
device is modified to create a periodic potential in the inversion layer when actively biased. The
period of this potential is on the order of 10nm. The present research works to establish the
basis of the spin device by fabricating a suitable, small-scale NMOSFET and characterizing the
substrate, polysilicon, and oxide layers. An oxide thicknesses of less than 5nm was obtained.
Very high doping was applied to both the initial substrate on the order of 1.5 × 1020 cm−3 , and to
the polysilicon on the order of 1021 cm−3 . Both aluminum spiking after annealing and depletion
of the polysilicon layer were observed during characterization. Fabrication and characterization
details are presented along with some background NMOSFET and SpinFET theory.
0.1 Introduction 1
0.1 Introduction
This paper discusses the fabrication and characterization of a polysilicon MOSFET as a base
for a SpinFET device. The discussion begins with a review of the well established theory of
NMOSFET devices including schematics and processing steps. This analysis reviews the current
vs. voltage and capacitance vs. voltage characteristics. Polysilicon work function, and depletion
are discussed. Operating modes and surface conditions are considered. This section closes with a
discussion of the future of MOSFET fabrication, including projected feature sizes and timelines.
“Spin” MOSFET, or SpinFET theory is then discussed briefly. This discussion begins with
The properties of the resulting spin lattice are then analyzed, including magnetic properties,
electronic confinement and the resulting band structure for the inverted region at the Si -Si 02
Fabrication and characterization details are presented for the NMOSFET device. This sec-
tion includes images of the actual devices and the data that resulted from characterization mea-
surements. Complications in the fabrication process are analyzed and adjustments for future
This paper concludes with recommendations for future work and a summary of characteriza-
tion results.
Metal Oxide Semiconductor Field Effect Transistors (MOSFETs) are the building block of modern
Silicon due to the high quality oxide layer (Si O2 ) which is used as the dielectric for the MOS
Capacitor.
MOSFET devices are fabricated on both p-type (majority holes) substrates and n-type (ma-
jority electrons) substrates and become NMOSFETs and PMOSFETs respectively, where the N
and P indicate the type of inversion layer created when actively biased. The structure of these
devices is identical, but each device performs differently. A large difference in the mobility, µ,
0.2 Polysilicon NMOSFET Theory 2
between holes and electrons has a significant impact on the performance and characteristics of
each type of MOSFET. The remainder of this chapter discusses the NMOSFET. A schematic
MOS Capacitor
An MOS capacitor is at the heart of a MOSFET device. An MOS capacitor consists of three
layers, metal, oxide and semiconductor. In recent years, heavily doped poly-crystalline silicon
(polysilicon) is frequently substituted for the metal top gate to accommodate a self aligning
fabrication process. Since the metal layer has been replaced with polysilicon, care must be taken
to prevent depletion in the gate layer. A schematic for an MOS capacitor is shown in figure 2.
Several conditions are of interest with respect to a voltage, Vapp , applied to the device as
shown in figure 3. These conditions are accumulation, depletion and inversion (and sometimes
flatband). In accumulation a negative bias voltage is applied to the gate which causes the initial
concentration of holes a the surface due to doping to increase, thus accumulating additional holes.
Depletion is achieved by applying a positive voltage to the gate equal to the threshold voltage
Vth . This attracts electrons to the Si O2 interface in concentration equal to the concentration of
holes which gives charge neutrality at the interface. Inversion is achieved by applying a positive
voltage greater than the threshold voltage Vapp > Vth . At positive applied voltages higher than
the threshold voltage the potential at the interface is inverted, that is, an n-type channel is
created in the p-type material right at the Si O2 surface. This inversion layer can be modeled as
a 2D electron system. The band diagrams illustrating these conditions, including the flat band
The threshold voltage is proportional to the bulk potential, Ψb . The relationship between
threshold voltage and other device parameters is given in equation (1) [3].
p
2s qNa (2Ψb )
Vth = 2Ψb + (1)
Cox
Each of the bias conditions above has a different capacitance associated with it, such that as the
applied voltage changes so does the capacitance of the MOS capacitor. This is due to the changing
0.2 Polysilicon NMOSFET Theory 4
depletion width. There are also frequency considerations related to carrier mobility. In other
words, capacitance in a MOS capacitor depends on both the applied voltage and the frequency of
the applied signal. The small-signal capacitances at low frequency are calculated using equation
(2) [4]. The capacitance can be further separated into two parts, the first corresponding to the
oxide capacitance and the second to the capacitance across the silicon as shown in equation (3)
[4].
d(−Qs )
C= (2)
dVg
1 1 1
= + (3)
C Cox Csi
An NMOSFET is fabricated by placing two heavily doped n-type regions on either side of an
MOS capacitor (which has a p-type semiconductor base, see 0.2.1). An illustration is shown in
figure 1. A gate voltage greater than or equal to Vth will produce an inversion layer in the MOS
capacitor that connects the source and drain n regions. Current can then be drawn from source
to drain by applying a voltage, VD from source to drain. As the applied drain voltage changes, so
does the shape of the inversion layer at the Si -Si O2 interface. At high VD , the inversion layer has
the shape of a wedge and the edge of the inversion layer begins to separate from the n+ region
of the drain. This is referred to as pinch-off and has the result of keeping the drain current ID
constant past the saturation voltage, Vs . The resulting current is called the saturation current. A
plot of theoretical currents and voltages for an NMOSFET (5µm gate length) is shown in figure
4.
0.2.2 Fabrication
Current fabrication techniques and processes are well established and mostly consistent through-
out the semiconductor industry. A standard process involves masking certain areas of a silicon
wafer and adding dopant impurities or growing oxide layers. Small feature sizes make accurate
0.2 Polysilicon NMOSFET Theory 5
alignment critical to a successful fabrication process. One technique used to improve alignment
involves replacing the metal gate with polysilicon. This method allows for a self aligning process,
and can accurately produce devices with very small dimensions (currently on the order of 35nm).
Processing steps
The process steps and masks used for the present research were developed at the University of
Utah by Justin Jackson and Mike Sorenson [6]. The process includes four masks which accom-
modate oxide growth, well definition, polysilicon patterning, contact vias and a final metal layer
for probe and bond pads. An illustration of the process is shown in figure 5.
tium sponsored by the major semiconductor manufacturing associations around the world. Its
vices. A road map, which outlines projected device characteristics and scale, is one result of
this undertaking. The road map represents the scale and speed projections to be achieved by
companies in the semiconductor industry. Current projections lead out as far as 15 years.
Lithography
Lithography projections [1] extend out to the year 2020. In this report, the gate length is projected
to shrink to 6nm. The implications of this are significant for the semiconductor industry. In
relation to the research presented here, this indicates that the target geometry and feature sizes
of a SpinFET device (currently obtained using SEM lithography) will be manufacturing ready
Several attempts have been made to create spin polarized semiconductor devices using magnetic
materials at the contacts. The magnetic materials provide a spin polarization to the injected
electrons. One ferromagnetic material used with III/V semiconductors is Manganese (Mn) in
compounds such as (Ga,Mn)As. In order to experimentally test these devices, spin sensing is
required. Spin devices dealing both with electronic and optical applications have been fabricated
in research labs around the world. At the time of this paper there are not yet any commercial
This present research deviates from previous structures in that the SpinFET devices fabricated
will use carefully engineered confining potentials to create an artificially magnetic material rather
than introducing naturally magnetic materials. In such a device, an inversion layer (at the Si O2
0.3 SpinFET Theory 7
modes my modulating the applied gate voltage [9]. Analysis of the energy band structure in the
periodic inversion layer reveals striking similarities to that of high Tc superconducting materials.
The basis of the spin lattice is an MOS capacitor (see 0.2.1). As was discussed in a previous
section, an MOS capacitor can produce an inversion layer at the insulator/substrate interface.
In order to achieve the confining potentials that are required to localize electrons in the lattice,
further processing is required. The process developed for this research requires nanolithography
using a Scanning Electron Microscope (SEM). A pattern is written in a PMMA layer, developed
and the lattice etched. The etching process includes Reactive Ion Etch (RIE) and a quick Buffered
Oxide Etch (BOE), which etch the polysilicon and gate oxide layers respectively. RIE is used
to etch the polysilicon pattern with minimal broadening from lateral etching. The process is
illustrated in figure 6. The resulting lattice holes should etch slightly into the Silicon surface to
increase confinement.
NMOSFET Basis
The MOS capacitor used in this research was part of a polysilicon NMOSFET. The choice to
use an NMOSFET as the base was influenced in part by ease of testing. During the process, a
particular wafer containing a number of die with devices is diced into two separate half wafers.
0.3 SpinFET Theory 8
One half wafer is then processed to produce traditional NMOSFETs. These devices are then
characterized and processing parameters verified. The other half is further diced into individual
dies and patterned using SEM lithography. Once patterned, the processing is completed for these
devices. Characterization of these spin devices and careful comparison to the non-spin devices is
Magnetic Properties
Two measures of interest in current magnetic devices include weight and power efficiency. In an
effort to reduce weight and increase power efficiency, recent research attention has been given to
finding non-metal materials that exhibit magnetic properties. Until recently, a common problem
with non-metal materials found to exhibit magnetic properties was that they needed to be held at
very low temperatures (in the tens of Kelvin). Work published since 2000 by various researchers
has shown that carbon-60 with a rhombohedral structure is ferromagnetic at relatively high
temperatures [9]. The benefits of a device made from a material which is a natural electric
insulator and non-metal include lighter weight devices and increased power efficiency.
The spin lattice device, which is the subject of this report, is both non-metal and can be made
to electrically insulate. The calculated conduction band for a structure such as an antidot lattice
One theory predicts that spheres of radius 10nm, made of nonmagnetic semiconducting material
and connected by the same material to its nearest neighbor, will exhibit ferromagnetism when
there is exactly one electron trapped in each sphere. Ferromagnetism is believed to result from
Coulomb repulsion between adjacent electrons causing them to assume alternating spins. The
Coulomb repulsion is given in equation (4) (this discussion and equations follow directly from
[9]).
0.4 Fabrication and Characterization 9
e2 f
κb
u ≡ ~2 5.7985
2m∗ a2
a a m f
= (4)
a0 b m∗ 2.9κ
In the present research, a confining potential is produced at the Si02 surface by an applied gate
voltage. This is accomplished by etching lattice holes and thus producing localized potentials.
These potentials can be analyzed using Poisson’s equation in two or three dimensions. The
probability of an electron being found at a given lattice site is shown in figure 8. A more in depth
A Keithley 4200-SCS is available in the University of Utah Microfab for conducting probe tests
and was used throughout this research. Measurements presented in this section used this platform
almost exclusively.
0.4 Fabrication and Characterization 10
The polysilicon self-aligning gate fabrication process is explained in detail in a Standard Op-
erating Procedure (SOP) hosted on the Microfab website [6]. The details of the SOP will not
be reproduced here, but deviations and process adjustments will be noted. The purpose of this
Doping Profile
Measurements across multiple die were used to obtain an average resistivity. This was then used
Ω
to obtain the resistance in ohms per square ( ). The resistivity of the substrate was initially
Ω
R = 205 , which corresponds to an initial doping concentration of 2 × 1015 cm− 3. After doping
Ω
the resistivity dropped to R = 26.8 , which corresponds to a concentration of 1.5 × 1020 cm− 3.
The high concentration is due in part to the shallow depth of the doped boron layer.
0.4 Fabrication and Characterization 11
Gate Oxide
The target gate oxide thickness was 5nm. To accomplish this growth the wafer was placed in a
furnace at 1000◦ C under dry oxygen flow at 3.5 SLM for five minutes.
The actual device measured is shown in figure 9. The results of measurement are shown in
figure 10. Based on the area of the capacitor as shown, the resulting oxide thickness is calculated
ox
tox = A
Cox
= 0.295 × 67.5 × 10−12
= 1.344nm (5)
Figure 9: Optical microscope image of substrate to polysilicon capacitor across gate oxide with
height and width marks.
The calculated oxide thickness, x, of a silicon dioxide layer after t seconds of growth is given
by equation (6) [3], where C0 is the surface concentration of oxygen, C1 is the number of molecules
in the sample, κ is the surface reaction rate, and τ is used to account for any initial oxide present.
s
D 2C0 κ2 (t + τ )
x= 1+ − 1 (6)
k DC1
C0 κ
x= (t + τ ) (7)
C1
Using the above equations the calculated thickness is expected to be 7.34nm, nearly six times
larger than what was measured. closer examination of the C-V curves measured on the part and
shown in figure 10 indicate that the polysilicon layer may be depleting (see [3]). It is expected
that the oxide layer is closer to that which was calculated and the incorrect measurement is due
Polysilicon resistor
A polysilicon test resistor was included among the devices on each die. The test resistor can be
used to determine the quality and doping profile of the polysilicon layer. Shown in figure 11 is
Aluminum Diffusivity
The diffusivity of aluminum (Al) in silicon (Si) is very high. One characteristic of an Al-Si system
that causes high diffusivity is that it becomes eutectic [3]. This means that the melting point
of the system is lower than either material independently. Due to the shallowness of the n-type
wells, the Al can easily spike through the n-type well and into the high p-type substrate. The
result is that a resistance is measured across the MOSFET from source to drain. This scenario
is illustrated in figure 12. A discussion of the volume of Al consumed and the depth to which
it is consumed can be found in [3], page 392. This type of spiking was observed in the devices
Current vs. voltage characteristics (I-V) are a common measurement for MOSFET devices.
Shown in figure 13 is an actual device fabricated in the lab. The corresponding I-V characteristics
0.4 Fabrication and Characterization 14
are shown in figure 14. Note that these measurements were taken before annealing.
0.4.3 SpinFET
Initial results from Scanning Electron Microscope (SEM) lithography are promising and have
yielded a feature size of 100nm. An SEM image of a spin lattice patterned on top of a polysilicon
NMOSFET is shown in figure 15. Etch rates and methods for each layer, both polysilicon and
Figure 15: Spin Lattice Patterned Using SEM Lithography (Justin Jackson)
Interest in producing devices that harness both the charge and spin of electrons is growing. Such
devices present several potential benefits in theory, including reduced power consumption, faster
operating speeds and smaller design features which increases the density of components that can
be placed on a die. Commercially viable means for producing spin devices are not yet available.
Some of the fabrication techniques presented in this research make possible prototype devices.
Two benefits gained by choosing the NMOSFET as a basis for future spin devices. First is
the maturity of both research and commercial fabrication techniques and methods. Second, the
NMOSFET provides an integrated testing device with ample data for correlation of results.
Future work should include adjustments to the thickness of the polysilicon layer to limit
the effects of depletion. Lower substrate doping concentration will reduce the threshold voltage,
allowing the devices to turn on at a standard voltage (1-3V). Aluminum spiking can be eliminated
with the use of a barrier metal layer, such as TiN. In addition to the recommendations made
above, further exploration of optical lithography techniques for the spin lattice is needed. This
will ensure that once realized in the lab, these devices will be ready for commercial fabrication.
0.6 Ethical Appendix 16
Unfortunately, all too often the ethical consequences of modern research are outside the scope
of the microscope. The scale and precision required to fabricate nano-scale devices can be so
demanding that one hardly has time to consider the ultimate destination of the chemical byprod-
ucts produced during fabrication, or even their more immediate effect on the researcher. The
cleanroom environment with its endless hum of air purification equipment, conditioned light, and
restrictive clothing can be numbing. Ultimately, fabrication labor, distribution and real world
use are so far, in both space and time, from the labs of research that they might initially escape
The chemicals used in a modern nano-scale semiconductor fabrication laboratory can be dan-
gerous and even deadly. Chemicals in both liquid and gas form are used throughout a typical
fabrication process to make modifications to a silicon (or other semiconductor) wafer. The chem-
icals used to clean, dope, etch or otherwise process silicon are rarely consumed completely in
the process and must be disposed of. Some are released into the air, other contaminants may
be released into waterways. As the demand for semiconductor devices increases, so can the
Large scale production, like initial research, will take place in a clean room environment. The
precision and sensitivity of the machinery used to fabricate semiconductor devices often requires
that it operate continually in order to limit the frequency of costly calibration. This imposes an
indirect requirement on future laborers to work long shifts and a clean room environment. For
As labor demands increase and market forces push prices lower many companies look to
foreign labor to help cut costs. Foreign labor often represents less expense not only in wage,
but also in retirement, health and other benefits. This may mean that instead of creating new
jobs, the advancement in technology has actually reduced the number of jobs available to native
candidates.
Many of these considerations don’t apply uniquely to the semiconductor industry. They
0.6 Ethical Appendix 17
are, nevertheless, ethical considerations that accompany the development of new technologies.
Chemical byproducts, labor conditions and labor sources all represent ethical issues that arise
with the development of new technology, such as the SpinFET that is presented in this research.
A discussion of the impact of a new nano-scale semiconductor device is potentially premature and
challenging. What could James Clerk Maxwell have said would be the impact of his efforts to
unify electricity and magnetism. That single, marvelous feat has completely changed the world
While the subject of this research is not being compared to the novelty of Maxwell’s equations,
it still stands that as new semiconductor devices are created there will be an impact on society.
There will be labor issues, environmental issues and even implementation issues. Some people
will want to use technology for war, and others for peace.
The impact of the SpinFET devices, which are the subject of this research, could be used to
implement low power electronics, new ultra-fast communications and even quantum computing.
It is the hope of the author, that any discovery pertaining to his research would be used to make
[2] Simon M. Sze, Physics of Semiconductor Devices, Wiley-Interscience; 2nd edition September
1981
[3] Simon M. Sze, Semiconductor Devices, Physics and Technology, John Wiley & Sons, Inc.;
[4] Yuan Taur, Tak H. Ning Fundamentals of Modern VLSI DEVICES, Cambridge University
Press 1998
[5] Charles M. Wolfe, Nick Holonyak, Gregory E. Stillman Physical Properties of Semiconduc-
[7] D. C. Mattis, On the Origin of d-Wave Pair Functions in High-Tc Superconductivity, Inter-
[9] Daniel C. Mattis, Design of a Nanomagnet, Journal of Statistical Physics June 14, 2003