Академический Документы
Профессиональный Документы
Культура Документы
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and students, to indicate the requirements of the
examination. It shows the basis on which Examiners were initially instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began. Any
substantial changes to the mark scheme that arose from these discussions will be recorded in the published
Report on the Examination.
All Examiners are instructed that alternative correct answers and unexpected approaches in candidates
scripts must be given marks that fairly reflect the relevant knowledge and skills demonstrated.
Mark schemes must be read in conjunction with the question papers and the Report on the Examination.
CIE will not enter into discussion or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the June 2005 question papers for most IGCSE and GCE Advanced
Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
Grade thresholds for Syllabus 9701 (Chemistry) in the June 2005 examination.
maximum
mark
available
Component 4
60
45
40
22
The thresholds (minimum marks) for Grades C and D are normally set by dividing the mark
range between the B and the E thresholds into three. For example, if the difference between
the B and the E threshold is 24 marks, the C threshold is set 8 marks below the B threshold
and the D threshold is set another 8 marks down. If dividing the interval by three results in a
fraction of a mark, then the threshold is normally rounded down.
June 2005
GCE A LEVEL
MARK SCHEME
MAXIMUM MARK: 60
SYLLABUS/COMPONENT: 9701/04
CHEMISTRY
Paper 4 (Structured Questions A2 Core)
Page 1
(a)
Mark Scheme
A LEVEL JUNE 2005
(i)
(ii)
(iii)
Syllabus
9701
Paper
4
Ammeter/galvanometer
[1]
[1]
[1]
Volume/amount of hydrogen/gas
[1]
Time
[1]
Current/amps/ammeter reading
(ignore extra measurements)
[1]
[1]
(i)
F=Lxe
[1]
(ii)
[1]
(a)
[1]
Part (a): [1]
(b)
(i)
[1]
[1]
[1]
(ii)
Rate = k [propanone][CN-]
(iii)
Mechanism B (or A see grid below), with the first (or second
see grid below) step being the slow step,
[1]
[1]
[1]
Page 2
(a)
Mark Scheme
A LEVEL JUNE 2005
(i)
(ii)
Syllabus
9701
Paper
4
[1]
[1]
[1]
[1]
Part (a): [5]
(b)
[1]
Part (b): [1]
(c)
[1]
Mr(2CO2) = 2 x 44 = 88
88
= 47.7%
184.4
Allow 48%. Also allow 48.8% if Mr = 184
% loss in mass = 100 x
(e.c.f. in 184.4)
[1]
Page 3
(a)
Mark Scheme
A LEVEL JUNE 2005
Syllabus
9701
Paper
4
(i)
(ii)
[1]
(i)
(ii)
[1]
[1]
[1]
[1]
[1]
(i)
(ii)
(e)
Reagent: I2 + OH-
[1]
Page 4
Mark Scheme
A LEVEL JUNE 2005
Syllabus
9701
Ka = [RCO2-][H+]/[RCO2H]
(a)
Paper
4
[1]
Part (a): [1]
(b)
(i)
The more chlorine atoms in the molecule, the stronger the acid,
[1]
(iii)
[1]
pH = -log10(0.0118)
1.93
[1]
1.26
Allow 1.3
e.c.f.
[1]
Part (b): [6]
(c)
(i)
[1]
(ii)
[1]
Either:
or:
or:
or:
or:
add Br2(aq)
phenol decolourises it, or gives a white ppt.
add FeCl3(aq) phenol give a purple colour
add NaOH(aq) phenol dissolves
add UI solution phenol goes yellow/orange (A stays green)
add diazoniumto solution in OHphenol gives orange/red colour
(in each case, A give no reaction)
or:
or:
or:
or:
Page 5
(a)
Mark Scheme
A LEVEL JUNE 2005
Syllabus
9701
Paper
4
(i)
[1]
(ii)
HNO3 + H2SO4
[1]
[1]
NO2+
[1]
(iii)
NO2
H
etc.
NO2
or
[1]
H+
[1]
Part (a): [6]
(b)
(i)
Reduction
[1]
(ii)
[1]
Part (b): [2]
(c)
PCl5/PCll3/SOCll2/POCl3
(+ heat)
aq negates
[1]
Part (c): [1]
(d)
(i)
(ii)
[1]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/04
Paper 4
This mark scheme is published as an aid to teachers and students, to indicate the requirements of the
examination. It shows the basis on which Examiners were initially instructed to award marks. It does
not indicate the details of the discussions that took place at an Examiners meeting before marking
began. Any substantial changes to the mark scheme that arose from these discussions will be
recorded in the published Report on the Examination.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the Report on the
Examination.
The minimum marks in these components needed for various grades were previously published with
these mark schemes, but are now instead included in the Report on the Examination for this session.
CIE will not enter into discussion or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2006 question papers for most IGCSE and
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 1
Mark Scheme
GCE A/AS Level May/June 2006
Syllabus
9701
[1]
[1]
Paper
04
[1]
k
=
=
=
units =
rate/([NO]2[O2])
0.020/(0.0052 x 0.005)
1.6 x 105
mol-2dm6sec-1
ecf [1]
ecf [1]
ecf [1]
[6]
[1]
(ii) NO + O2 NO2
SO2 + NO2 SO3 + NO
(SO3 + H2O H2SO4)
[2]
[3]
[Total: 9]
[1]
ecf [1]
ecf [1]
ecf from (ii) [1]
Mr(CaSO4) = 136.1
Thus mass(CaSO4) = 0.55 x 136.1 = 74.8g (0.55 x Mr)
(if the accurate [CaSO4] is held throughout the calculation, ans = 74.5g)
[1]
[5]
(b) (i) down the group: the Hsolution becomes more endothermic;
both lattice energy and Hhydration become less (exothermic);
due to ionic radius (of M2+) increasing;
but Hhydration changes more than lattice energy any three points
(ii) Ksp = [Ba2+][SO42-] = (9 x 10-6)2 = 8.1 x 10-11
[3]
NO ecf [1]
[4]
[1]
[1]
both points
[1]
[3]
[Total: 12]
Page 2
Mark Scheme
GCE A/AS Level May/June 2006
Syllabus
9701
Paper
04
(ii) [Ar]3d2
[1]
[2]
[1]
[1]
until the first permanent pink colour (or change from colourless to pink) [1]
repeat until two titres are within 0.1 cm3
[1]
[1]
[1]
[1]
[ignore any refs. to iron hydroxides]
[1]
[1]
[1]
[1]
[5]
[Total: 16 max 14]
Page 3
Mark Scheme
GCE A/AS Level May/June 2006
Syllabus
9701
Paper
04
[1]
[1]
[2]
(b) two rings only (1 ring around the -C of tyrosine & 1 around the -C of lysine) [1]
[1]
(c)
NH3CH2CO2-
[1]
[1]
[1]
[1] + [1]
[1] + [1]
[1]
[6]
(e)
O
H2N
CH2
O
NH
CH
NH
CH2
CH
CH2
CO2H
CH2
CH2
CH2
OH
NH2
structure [1]
at least one peptide group identified [1]
[2]
(f) (i) e.g.
CH2 NH
CO
CO NH CH2 CH2 NH
CO
CO NH CH2
CH2 NH
[1]
(ii)
HO2C
CO2H
H2N
CH2
CH2
NH2
or ClCO---------------COCl
[1]
[1]
[3]
[Total: 15 max 14]
Page 4
(a) I:
II:
Mark Scheme
GCE A/AS Level May/June 2006
Syllabus
9701
[1]
[1]
[1]
[1]
IV: CH3CH2OH
[1]
(or name)
+ c. H2SO4 + heat
Paper
04
[1]
[6]
(b)
CH3
CH3
CH3
+
H
NO2+
NO2
H+
NO2
intermediate, including
[1]
NO2+ at start and H+ at finish
[1]
(no marks for curly arrows, but if present, they must be in correct direction)
[2]
(c) (i) ester and (primary) amine
(ii) more basic: amine group is not adjacent to benzene ring
(or lone pair (on N) is not delocalised)
[2]
both points [1]
[3]
[Total: 11]
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2007 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
om
.c
s
er
Page 2
1
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
(a)
[1]
[1]
[1]
[1]
[1]
[1] [6]
(b)
conditions
ZnCl2(l)
ZnCl2(conc aq)
ZnCl2(dil aq)
product at anode
(chlorine)
chlorine [1]
oxygen [1]
product at cathode
zinc [1]
(H2 or zinc) (ignore)
hydrogen [1]
[1] for each product in correct place [4] [4]
(c)
LE
=BA
= 415 (131 + 908 + 1730) {244 + 2(349)}
[1]
[1]
= 415 2315
= 2730 (kJ mol1)
[1]
(correct answer = [3]: deduct [1] for each error) [3]
(d) (i)
instrumental method (e.g. spectrophotometer/colorimeter/conductance meter)
what is measured (e.g. absorbance/transmission at a stated wavelength
or by use of a suitable (green) filter or conductance/resistance)
measurement of time
relation of time to rate (e.g. gradient of absorbance/time graph, or rate 1/t)
repeat with different [Zn2+], (but the same [PAR])
relation of rate to [Zn2+] (either by a plot or by simple proportion)
(all 6 points are unconditional on each other) any 5 points [5]
(ii) e.g. add Br2(aq)
decolourises or produces a white ppt.
or add FeCl3(aq or neutral); purple colour produced
[1]
[1]
[1] + [1] [2]
[Total: 20]
UCLES 2007
Page 3
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
(or x )
(b) more stable down the group (or higher temperature needed)
(cat)ionic size/radius increases down the group
(or ionic charge density decreases)
distortion/polarisation of anion/nitrate (ion) decreases
(c) (i) 16 = O+
14 = N+
17 = OH+
16 = O+
A = H2O
18 = H2O+
28 = N2+ 30 = NO+
44 = N2O+
and B = N2O
[1] [1]
[1]
[1]
[1] [3]
(ignore charges)
all 3
all 5
any 4
(ignore charges) any 3
(or in equation below)
[1]
[3]
[2]
[1]
[1]
[1] [6]
[Total: 10 max. 9]
(or x )
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[1]
[5]
[1]
[1]
[Total: 8]
UCLES 2007
Page 4
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
(a)
(between axes)
[1]
[1]
[2]
[1]
[1]
[1] [3]
D = blue
[1] + [1]
[1] [3]
[Total: 8]
(a) I:
II:
III:
IV:
(b) I:
III:
Cl2 + AlCl3/Fe/etc
Cl2 + hf
KMnO4 + H+
SOCl2 or PCl5/PCl3 or P + Cl2
(for I, II and IV, deduct a mark ([1] only) for one or more mentions of (aq))
(for I, mention of hf negates the mark)
(for I and II, if Cl2 is omitted in one or both, deduct [1] mark only)
[1]
[1]
[1]
[1]
electrophilic substitution
oxidation or redox (NOT oxygenation)
[1]
[1] [2]
(c) H is C6H5-CH2CN
step V: NaCN/KCN
heat (or 50-80oC) + ethanol/alcohol
step VI: LiAlH4 or H2 + Ni/Pt/Pd/Rh or Na + ethanol
(d)
compound
cold water
[4]
[1]
[1]
[1]
[1] [4]
reagent
hot NaOH(aq)
no reaction
no reaction
no reaction
C6H5CH2OH
C6H5CO2H
C6H5CO2Na+
6 x [1] [6]
[Total: 16]
UCLES 2007
Page 5
6
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
[1]
[1] [2]
O- Na+
CH3
H
H
H
Na+O
HO
CH3
[1] + [1]
Br
(1, 2 or 3 bromines)
HO
Br
[1]
(iii) NaOH(aq)
HO
CH3
H
H
H
Na+ O
[1]
OCOCH3
H
H
H
H
CH3COO
[1]+ [1]
(v) hot acidified K2Cr2O7
CH3
H
H
HO
[1]
(if one or more OH groups have been omitted in (ii), (iii) or (v) deduct [1] mark) [7]
[Total: 9]
UCLES 2007
Page 6
7
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
(a) (i)
addition requires an unsaturated/double bond or alkene/C=C
condensation produces a small molecule or water as well as the polymer
or loss of mass occurs on polymerisation
the empirical formula of an addition polymer is the same as that of the monomer
any two [1] + [1]
(ii) minimum is:
O
NH2CH(CH3) C
N CH2CO2H
H
[1]
[1] [4]
(b) X = deoxyribose
Y = phosphate
Z = thymine
3 x [1] [3]
[2]
[1] [3]
[1]
[1]
[1] [3]
[Total: 13]
UCLES 2007
Page 7
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
(a) NH2 (or CO2) group can be protonated and the molecule moves towards
the cathode/negative
CO2H (or NH3+) group can lose a proton and the molecule moves towards
the anode/positive
[1]
[1]
[1]
[1] [2]
[1]
(ii)
[2]
[1]
(iii) D
[1]
(iv) C
[1] [5]
[Total: 10]
UCLES 2007
Page 8
9
Mark Scheme
GCE A/AS LEVEL May/June 2007
Syllabus
9701
Paper
04
(b) The (walls of) nano-sized test tubes consists of (rolled/single) sheets
of graphite
The ends are half a buckyball (buckminsterfullerene)
(c) Particles are similar in size to the wavelength of uv light
and reflect/deflect/scatter (NOT absorb) the harmful radiation
[1]
[1] [2]
[1]
[1] [2]
[Total: 7]
UCLES 2007
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2008 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
om
.c
s
er
Page 2
1
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
[1]
[1]
[1]
D is platinum/Pt
[1]
[1]
[1]
[1]
(since R.H. electrode is negative) electrons flow (from right) to left or to the chlorine
electrode or anticlockwise or from (beaker) E to (beaker) B
[1] [8]
(b) (i) H = 3 (167.2) + (48.5) (399.5)
= 150.6 or 151 (kJ mol1)
(correct ans [2])
(ii) 2Fe3+ + Cu 2Fe2+ + Cu2+
(or molecular: 2FeCl3 + Cu 2FeCl2 + CuCl2)
Eo = 0.77 0.34 = (+) 0.43 (V)
(no mark for 0.43V)
[1]
[1]
[1]
[1]
[4]
[Total: 12 max 11]
[1]
[1]
[1] [5]
(b) (i) coal-fired power stations; fuel in cars; car exhausts/gas emissions; other named use of a
fossil fuel; contact process; cement manufacture; brick manufacture; roasting of sulphide
ores; burning tyres
(any 2) [1]
(NOT volcanoes etc; NOT burning of natural gas)
(no marks for only 1 correct source)
(ii) causes acid rain
[1]
which lower pH of lakes; leaches aluminium from soils; kills fish/plants/rainforests;
dissolves/corrodes/damages buildings
(any 1) [1]
(NOT asthma etc since this is not environmental)
[3]
UCLES 2008
Page 3
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
[1]
[1]
[1]
ecf [1]
[1]
[1]
(words can substitute for one of the equations but not both. If two correct word
descriptions are given, in the absence of at least one correct equation, award [1] mark
only)
[8]
[Total: 16 max 15]
3
[1]
[1]
[2]
[1]
[1]
[2]
[both] [1]
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[3]
[Total: 11]
UCLES 2008
Page 4
4
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
(a) ester
Paper
04
[1] [1]
[1]
[1] [4]
[1]
(ii) HO2C-CO-CO2H
[1] [2]
[1]
ecf [1]
[2]
[1]
ecf from equ [2]
[3]
UCLES 2008
Page 5
5
(a) reaction I
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
electrophilic addition
[1]
[1]
[2]
[1]
Br CH2
CH2
H2C
or
CH2
Br
CH2
[1]
H2C
or
CH2
Br
Br
Br
[1]
H
Br
Br
or
Br
[1]
H
Br
or
[4]
(c) Delocalised ring of electrons (in benzene) is stable, (so is re-formed in second step in
benzene.)
or electrons in the ethene bond are localised/more available for reaction with electrophiles
[1] [1]
[Total: 7]
UCLES 2008
Page 6
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
6
CH3
CO2H
Br
CO2H
Br
CO2H
CO2H
NO2
NH2
5 x [1]
[deduct [1] mark if ring circle omitted more than once]
[allow ecf for E from structure of D]
[allow ecf for B from structure of A]
[allow -CO2 for E]
[5]
[Total: 5]
7
polymer
addition/condensation?
condensation
formulae of monomers
HO2C-CO2H or ClCO-COCl
NH2-CH2-CH2-NH2
HO-CH2-CH(C2H5)-CO2H
2
condensation
HO-CH2-CH(CH3)-CO2H
CH2=CH-CH3
CH2=CH-CONH2
CH2=CH-C6H5
addition
[2]
(2 correct: [1])
[6]
(6 correct: [5])
etc
(2 correct: [1])
(C=C bonds not needed, but penalise [1] if C-C drawn instead of C=C)
(if more than 7 formulae drawn, then penalise [1] for each formula in excess of 7)
[8]
[Total: 8]
UCLES 2008
Page 7
8
(a) primary:
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
[1]
[1]
[1]
[1]
[1]
[7]
(b) met-ala-gly-ala-gly-arg-val-lys
[2]
any possible sequence with more than 8 residues, that uses all 6 tripeptides (overlapping
or not), and that starts with met and ends with lys is worth [1] mark
any sequence that does not start with met or end with lys gets zero.
[2]
(c) CARE this is not about DNA!
candidates should describe TWO potential effects on tertiary or quaternary structures caused
by amino acid sidechains...
these include:
disruption of H-bonding
disruption of disulphide bridges
disruption of electrostatic/ionic attraction
disruption of van der Waals forces
(only allow effects on the secondary structure if proline is specifically mentioned)
2 x [1]
then award [1] mark each for two of the following bullet points:
a description of the amino acids involved in the above, (or a labelled diagram)
(award [1] mark for each example)
a description of an effect of interchanging amino acids, such as the..
unfolding of tertiary structure/different folding/different shape (NOT denatured)
inactivity of an enzyme or changing the active site
causing of a protein to become less soluble/coagulate (e.g. sickle cells)
2 x [1]
[4]
[Total: 13 max 12]
UCLES 2008
Page 8
9
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
[1]
CH3CH2CHO would show 3 (sets of) peaks since there are 3 different proton
environments
or there would be a peak at = 9.5 10.0 due to the CHO group
or a peak at = 0.9 due to CH3
or a peak at 1.3 due to CH2
[1]
(reasons needed for the marks. Salvage: if reasons are not given, but candidate states
that propanone will have one peak and propanal three, then award [1] mark)
(ii) different fragments:
CH3COCH3 would form fewer fragments (must be stated in words)
CH3COCH3 would form a fragment of CH3CO+ or at (m/e) 43
CH3CH2CHO would form a fragment of CH3CH2+ or CHO+ at (m/e) 29
CH3CH2CHO would form a fragment of CH3CH2CO+ or at (m/e) 57
[charges on fragments not required for mark]
any 3 points [3]
[5]
(c) (i) peaks at (m/e) 79 and 81 or at (m/e) 94 and 96
(ii) in chlorine the M and M+2 peaks are the ratio 3:1
whereas in bromine they are approx. 1:1
[1]
[1]
[1] [3]
[Total: 10 max 9]
UCLES 2008
Page 9
Mark Scheme
GCE A/AS LEVEL May/June 2008
Syllabus
9701
Paper
04
2 [1] [2]
(b) (i) spheres with a diameter of the order of nanometres/in the nanometre range/between 10
& 500 nm
[1]
(ii) it is (highly) acidic or low pH or contains HCl (NOT contains enzymes)
[1]
(iii) use hydrogels: of different (wall) thickness/strength (to release drug over time)
of different chemical composition (for different breakdown times)
incorporating pores/holes (in their walls)
(any two) [1] + [1]
[4]
(c) for the homopolymer, either using the amino acid the minimum is:
-CO-CHR-NH-CO-CHR-NH-CO-CHR-NHor using the hydroxyacid the minimum is:
CO2H
CO2H
CO2H O
or
O
CO2H
CO2H O
CO2H
O
O
O
O
O
(glycol)
O
O
or
(di-acid)
(glycol)
OH
OH
(glycol)
(di-acid)
(di-acid)
or using the amino acid and the di-acid, the minimum is:
(ester)
R
O
O
O
N
H
O
CO2H
R
or
N
H
(amide)
O
or
(ester)
O
O
CO2H
CO2H O
O
(amide)
(ester)
O
O
N
H
(amide)
H
N
N
H
O
or
CO2H
(amide)
CO2H O
H
N
O
(ester)
O
O
CO2H
(A heteropolymer incorporating all three monomers can also be drawn. This should include an ester
linkage between the glycol and one of the CO2H groups, and an amide linkage between the aminoacid and
another CO2H group. Deduct [1] mark from the whole of section (c) if complete compounds are shown
rather than sections of chains. Allow 4-monomer sections instead of 3. Allow [2] marks for a polymer
section even if one end is incomplete (e.g. is lacking an oxygen atom), but if both ends are incomplete
deduct [1])
([1] for each error) [2] [4]
[Total: 10 max 9]
UCLES 2008
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2009 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
om
.c
s
er
Page 2
Syllabus
9701
Paper
04
Section A
1
(a)
(b)
[1]
[1]
[2]
(i) more Cl atoms produce a stronger acid or the larger the Ka the stronger the acid
(NOT just the more Cl atoms, the larger the Ka must refer to acid strength) [1]
because the anion/RCO2 is more stable or the O-H bond is weaker/polarised [1]
due to the electronegativity/electron-withdrawing effect of Cl
[1]
(ii) [H+] = (Ka.c) = 0.0114 (mol dm3)
pH
= 1.94 (allow 1.9)
ecf from [H+]
(correct answer = [2])
[1]
[1]
(iii)
start at pH = 1.94 (ecf from (ii) and goes up > 2 pH units before steep portion)
steep portion (over at least 3 pH units) at V = 10 cm3
flattens off at pH 1213
(c)
[1]
[1]
[1]
[8]
[1]
[1]
[1]
[1]
[4]
[Total: 14]
UCLES 2009
Page 3
2
(a)
Syllabus
9701
[1]
[1]
[1]
[1]
(b) relevant Eo quoted: Cl2/Cl , 1.36; Br2/Br , 1.07; (H2SO4/SO2, 0.17 not required)
Br is more easily oxidised because its Eo is more negative
or Cl2 is more oxidising because its Eo is more positive
(c)
Paper
04
[4]
[1]
[1]
[2]
Allow almost any reducing agent from the Data Booklet (see below) with Eo less than 1.07 V.
But do not allow reducing agents that require conditions that would react with Br2 in the
absence of the reducing agent (e.g. NH3 or OH), and also do not allow reducing agents
that could produce, or act as, oxidising agents (e.g. MnO42 and H2O2)
balanced equ. showing reduction of Br2 by the chosen reducing agent
(either ionic or molecular)
Eo = 1.07 (Eo of reductant) = x.xx (V) (see below)
[1]
[1]
[2]
[Total: 8]
List of acceptable reductants with resulting Eocell values
reductant
Ag
Al
Ba
Ca
Co
Cr Cr2+
Cr Cr3+
Cr2+
CuCu+
CuCu2+
Cu+
Eocell/V
0.27
2.73
3.97
3.94
1.35
1.98
1.81
1.48
0.55
0.73
0.92
reductant
FeFe2+
FeFe3+
Fe2+
H2
I
K
Li
Mg
Mn
NO2
HNO2
NH4+
Eocell/V
1.51
1.11
0.30
1.07
0.53
3.99
4.11
3.45
2.25
0.26
0.13
0.20
UCLES 2009
reductant
Na
Ni
Pb
SO2
S2O32
Sn
Sn2+
V
V2+
V3+
VO2+
Zn
Eocell/V
3.78
1.32
1.20
0.90
0.98
1.21
0.92
2.27
1.33
0.73
0.07
1.83
[1]
[1]
Page 4
3
Syllabus
9701
Paper
04
(c)
[1]
[1]
[2]
[1]
[1]
(e)
[1]
[1]
[1]
[1]
[1]
[1]
[5]
[1]
[1]
[2]
[Total: 11]
(a)
(i) homogeneous
[1]
(ii) ions in 2 and 3 are oppositely charged ions (thus attract each other) or
ions in 1 are similarly charged ions (thus repel each other)
[1]
(iii)
[1]
[1]
[1]
[5]
Page 5
Syllabus
9701
Paper
04
(b) (i) SO3 produces acid rain or SO3 + H2O H2SO4 or a consequence of acid rain,
e.g. lower pH of lakes; leaches aluminium from soils; kills fish/plants/rainforests;
dissolves/corrodes/damages buildings (NOT global warming)
[1]
(NOT asthma etc since this is not environmental)
(ii) the burning of fossil fuels/coal/oil/petrol/gas/diesel/fuel or car exhausts or roasting of
sulphide ores or cement manufacture or volcanoes
[1]
(iii) SO2 + NO2 SO3 + NO
[1]
NO + O2 NO2
[1]
[4]
[Total: 9]
(a) CH3CH2CH2CH2CH2OH
A
all three (any order)
(2 only = [1])
CH3CH2CH2CH(OH)CH3
B
CH3CH2CH(OH)CH2CH3
C
[2]
[2]
[1]
[1]
[1]
[1]
(iii) CHI3 + CH3CH2CH2CO2Na or anion (no credit for the acid, RCO2H)
[1] + [1]
[4]
(d) A CH3CH2CH2CH2CO2H
[1]
B CH3CH2CH2COCH3
C CH3CH2COCH2CH3
[1]
(letters may differ)
UCLES 2009
[1]
[3]
Page 6
(e)
Syllabus
9701
Paper
04
[1]
[1]
[1]
(a)
(i) I:
II:
[1]
NH3
[1]
[1]
(iii) delocalisation of lone pair on Cl over benzene ring produces a stronger C-Cl bond [1]
[4]
(b) (i) III: HNO3 + H2SO4
[1]
[1]
[1]
[1]
[1]
[5]
(c) e.g. add bromine water or Br2(aq) (a solvent is needed for the mark)
or add UI solution
phenylamine decolorises the bromine or gives a white ppt., hexylamine does not
or hexylamine turns UI blue, with phenylamine it stays green
UCLES 2009
[1]
[1]
[2]
Page 7
Syllabus
9701
Paper
04
(d)
CH3
N
N N
Cl
OH
CH3
(phenylazo group must be at 4-position to -OH)
(N=N must be double bond, not triple)
[1]
[1]
[2]
[Total: 13]
Section B
7
(a) For each element, award [1] mark for each column in one particular line in the table below.
The [2] marks awardable for each element are not conditional on each other, but dont take
the location from one line and the role from another.
element
location
red blood cells/haemoglobin
muscle (cells)/myoglobin
in mitochondria/cytochromes
in iron-sulphide proteins
in ferrodoxin
in nerve cells/nerves/nervous
system/neurones or in cell
membranes/phospholipid
bilayers
in kidneys
in the gut/carboxypeptidase
iron
sodium
zinc
role
in the liver/alcohol
dehydrogenase
[1]
UCLES 2009
[6]
Page 8
(b)
Syllabus
9701
Paper
04
[1]
(a)
0.4
20
= 0.02 g cm3
0.1
100
= 0.001 g cm3
Kpc = 0.02/0.001 = 20
[1]
[1]
[1]
[1]
[5]
Page 9
Syllabus
9701
Paper
04
[1]
[1]
[1]
[3]
(c)
(i) 4 (four)
[1]
(ii)
[1]
[1]
[3]
[Total: 11]
(a)
(i) correct diagram showing at least one monomer unit, and at least one N-H and C=O.
i.e. NH-C6H2-NH-CO or CO-C6H4-CO-NH
(no mark for this, but apply a penalty of [1] if candidates diagram does NOT show
these points correctly)
one H-bond between N-H of original chain and C=O group of new chain
[1]
one H-bond between C=O of original chain and N-H group of new chain
[1]
(ii) hydrogen bonds or H-bonds (in words; can be written on diagram)
(ignore ref to v d W)
[1]
(iii)
HO2C
or
CO2H
ClOC
allow HO2CHOOCHOCO-
COCl
[1]
allow ClCO-
H2N
NH2
[1]
allow NH2-
[5]
UCLES 2009
Page 10
Syllabus
9701
Paper
04
[1]
[4]
[Total: 9]
UCLES 2009
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2010 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
om
.c
s
er
Page 2
1
Syllabus
9701
(a) P: burns with white / yellow flame or copious white smoke / fumes produced
4P (or P4) + 5O2 P4O10
(1)
(1)
(1)
S + O2 SO2
(b)
Paper
41
(1)
[4]
(2)
(ii)
allotrope
type of structure
type of bonding
white
simple / molecular
covalent
red
giant / polymeric
covalent
(4)
(iii)
P
P
white P4 (1)
red Pn (1)
(in each case P has to be trivalent. Many alternatives allowable for the polymeric red P) (2)
(8 max 7)
[7]
[Total: 11]
UCLES 2010
Page 3
2
Syllabus
9701
Paper
41
(1)
(1)
(1)
(4 max 3)
[3]
(1)
(1)
(1)
(1)
(1)
(5 max 4)
[4]
(1)
(1)
(1)
[3]
[Total: 10]
(c)
(i)
..
Cl:C:Cl
+
or
..
Cl=CCl
[1]
(1)
(1)
(1)
(5 max 4)
[4]
(1)
(1)
(1)
[3]
[Total: 8]
UCLES 2010
Page 4
4
Syllabus
9701
Paper
41
(1)
(1)
[2]
[2]
[1]
(d)
(i) X is CH3CH2CN
(1)
(1)
(1)
(e) ethanolamine:
Na
or Cr2O72 / H+
or MnO4 / H+
or PCl3 / PCl5 / SOCl2
[3]
phenylamine:
Br2(aq)
decolourises / white ppt formed
+
o
or HNO2 / H at T<10 C, then phenol in NaOH (1) coloured dye formed
(1)
[4]
[Total: 12]
UCLES 2010
Page 5
5
(a)
(b)
Syllabus
9701
Paper
41
(1)
(1)
(1)
(1)
(iv) no change
(1)
(1)
(1)
(1)
(1)
(1)
[6]
[5]
[Total: 11]
6
(a)
(1)
(1)
[2]
(b)
(c)
(i) A is C6H5CO2C2H5
B is C6H5CONH2
(1)
(1)
(ii) ester
amide
(1)
(1)
(1)
(i) C is ClCOCOCl
D is ClCOCOCOCl
(1)
(1)
(1)
[5]
(iii) because its an amide or not an amine or its lone pair is delocalised (over C=O)
or less
available due to electronegative oxygen [NOT: E is neutral, but the diamine is
basic]
(1)
(iv) condensation (polymer) or polyester
(1)
[5]
[Total: 12]
UCLES 2010
Page 6
Syllabus
9701
Paper
41
7
CH 2 Cl
CH 2OH
Cl
Cl
NO 2
(ignore orientation)
CO 2H
COOCH 3
HO 2C
H3COCO
[6]
[Total: 6]
8
(a)
Block letter
Identity of compound
Guanine
Phosphate
Thymine
[3]
[2]
(1)
(1)
(1)
(1)
(4 max 3)
[3]
(1)
(1)
[2]
[Total: 10]
UCLES 2010
Page 7
9
Syllabus
9701
Paper
41
(1)
(1)
[2]
(b) field experienced by protons is influenced by adjacent atoms / protons are in two
different chemical environments
(1)
peaks are in the area ratio 3 : 1 (methyl to OH protons)
or are at 0.5 6.0 and 3.3 4.0
(1)
[2]
(c)
(i)
CH3CH2CO2H
propanoic acid
CH3CO2CH3
methyl ethanoate
HCO2CH2CH3
ethyl methanoate
all for (2) two for (1)
B is CH3CO
(1)
(1)
(1)
or ethyl methanoate
or the HCO proton
(1)
[6]
(1)
(1) [2]
[Total: 12 max 10]
[Total: 10]
UCLES 2010
Page 8
Syllabus
9701
Paper
41
[1]
(b)
(d)
[2]
both needed
(1)
(1)
(1)
(1)
[3]
(ii) volume of sphere can be large or one PEG molecule can only carry 1 or 2 drug
molecules
(1)
or can carry different types of drug
[2]
[2]
[Total: 10]
UCLES 2010
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2010 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
om
.c
s
er
Page 2
1
Syllabus
9701
Paper
42
(1) + (1)
(b) (i) the exponent / power to which a concentration is raised in the rate equation
(or in an equation, e.g. a in the equ: rate = k[A]a)
[2]
(1)
(ii) from 1 and 2: rate increases by 50% as does [RCl ], so rate [RCl ]1
from 1 and 3: rate [NaOH]1
(1)
(1)
(1)
(iv)
(can be a solid line)
(-)
R
HO
(+)
Cl
HO
(H) (H)
C
(H) (H)
HO
Cl
R
C
+ Cl
(H)(H)
marking points:
(+) or + on C and () or on Cl
lone pair and charge on: OH
curly arrow from OH (lone pair) to (+)C, and either a curly arrow breaking
C-Cl bond or 5-valent transition state (ignore charge)
SN1 alternative for last mark (only award mark if candidates rate
equation shows first order reaction): curly arrow breaking C-Cl bond and
carbocation intermediate.
(1)
(1)
(1)
[7]
(c) (i) (add RCl / RCOCl to) (aq) Ag+ / AgNO3 or named indicator (e.g. MeOr) or
use pH probe
(1)
White ppt appears (faster with RCOCl) or turns acidic colour (e.g. red) or
shows pH decrease
(1)
if water is the only reagent, and no pH meter used: award only the second
mark, for steamy / white fumes
(ii) (C=O is polarised /) carbon is more + than in R-Cl or carbon is positive or
RCOCl can react via addition-elimination
(mention of electronegativity on its own is not enough for the mark)
(1)
[Total: 12]
UCLES 2010
[3]
Page 3
2
Syllabus
9701
Paper
42
(1)
lattice energy and hydration energies both decrease (i.e. become less negative)
(1)
but H.E. decreases more (than L.E.) or change in H.E. outweighs L.E.
(1)
(1)
(b) (i) for Mg: H = 2993 1890 (2 550) = (+)3 (kJ mol1)
(1)
(1)
(1)
(1)
[4]
(1)
[5]
(1) + (1)
(1)
(1)
(1)
(iii) less soluble in NaOH due to the common ion effect or equilibrium is shifted
to the l.h.s. by high [OH ] (NOT just a mention of Le Chatr on its own)
(1)
[6]
[Total: 15]
UCLES 2010
Page 4
3
Syllabus
9701
(a) SiF4 is symmetrical or tetrahedral or bonds are at 109 or has no lone pair or
4 electron pairs shared equally or all Si-F dipoles cancel out, or SF4 has a lone
pair (on S).
Paper
42
(1)
[1]
(2)
[2]
(b)
compound
molecule has
an overall dipole
BCl 3
PCl 3
CCl 4
SF6
mark row-by-row,
(c) (i) Si and B have empty / available / low-lying orbitals or C does not have
available orbitals (allow B is electron deficient but not mention or implication
of d-orbital on B)
(ii) BCl 3 + 3H2O H3BO3 + 3HCl or 2BCl 3 + 3H2O B2O3 + 6HCl
(1)
(1)
(1)
(d) (i) Si3Cl 8O2 (this has Mr = 84 + 280 + 32 = 396) or Si4Cl 4O9 or Si8Cl 4O2
(1)
[3]
(ii)
mass number
133
247
263
structure
Cl 3Si
Cl 3Si-O-SiCl 2
Cl 3Si-O-SiCl 2-O
(3)
(if correct structures are not given for last 2 rows, you can award (1) mark for
two correct molecular formulae:
either Si2Cl 5O + Si2Cl 5O2 or Si3ClO8 + Si3ClO9 or Si7ClO + Si7ClO2)
(iii)
Cl
Si
Cl
Cl
Si
Cl
Cl
Si
Cl
Cl
Cl
allow ecf on the structure drawn in the third row of the table in (ii)
but any credited structure must show correct valencies for Si, Cl and O.
(1)
[5]
[Total: 11]
UCLES 2010
Page 5
4
Syllabus
9701
(a) Cr3+:
1s22s22p6... 3s23p63d3
2+
Mn : 1s22s22p6... 3s23p63d5
(allow (1) out of (2) for 3s23p64s23d1 and 3s23p64s23d3)
(1)
(1)
[2]
(3)
Paper
42
(1)
Fe3+/Fe2+ = +0.77 V
Fe(OH)3/Fe(OH)2 = 0.56V
[4]
(2)
Eocell = +0.46V (allow 0.37) in acid, but +0.96V in alkali or Eo (OH) > Eo (H+)
(1)
(1)
[4]
(d)
O
[1]
(1)
CH3CO2H
and
HO2C
CO2H
[1]
(1)
[1]
(1)
(or CO2H)
O
O
CO2H
H3C
or
CHO
H3C
[1]
(1)
[1]
(1)
[5]
(e) (i) (CH3)2C(OH)CH2OH
(1)
(ii) reaction I: (cold dilute) KMnO4 (cold not needed, but hot or warm negates)
reaction II: Cr2O72 + H+ + distil
(1)
(1)
[3]
UCLES 2010
Page 6
5
Syllabus
9701
Paper
42
(a) (i) because the carbons are sp2 / trigonal planar / bonded at 120 or are joined
by bonds / orbitals
(1)
(1)
[2]
(1)
(1)
NO2
NO2
(1)
(1)
[4]
(1)
[1]
(2)
(1)
Br
Br
NHCOCH3
N2 (Cl
Cl
Cl
(1)
OH
or
B
Cl
no reaction
Cl
(4)
[8]
[Total: 15]
UCLES 2010
Page 7
6
Syllabus
9701
Paper
42
(1)
(1)
[2]
(1)
(1)
(2)
[4]
(1)
needed
R
N
O
N
R
New strand must contain a minimum of two amino acid residues in a single
chain. Deduct a penalty of (1) for any wrong H-bond only if (2) marks have
already been scored.
(2)
[3]
(d) There are bonds or S-S bridges / linkages between the layers / sheets
(in -keratin) (but only van der Waals interactions between the layers in silk)
(1)
[1]
[Total: 10]
UCLES 2010
Page 8
7
Syllabus
9701
Paper
42
(a) The amino acid is uncharged / neutral / a zwitterion or charges balance / are
equal (NOT is non-polar)
It is equally attracted by the anode / + and the cathode / or attracted by neither
The pH of the buffer is at the isoelectric point/IEP of the amino acid any two
(b) (at pH 10), H2NCH2CO2 or NH2CH2COO
(2)
[2]
(1)
[1]
(3)
[3]
(c)
amino acid
relative size
A
small(est) (1)
B
large(st) (3)
C
middle
(2)
(numbers are OK to show relative sizes)
Mark each row
(d) (i) lys val ser ala gly ala gly asp
charge
ve
ve
+ve
(2)
(1)
(1)
[4]
[Total: 10]
UCLES 2010
Page 9
8
Syllabus
9701
(a) Reaction II since electrons are used up / required / gained / received (from
external circuit)
(b) (Pb2+ + 2e Pb)
(PbO2 + 4H+ + 2e Pb2+ + 2H2O)
Eo = 0.13V
Eo = +1.47V
two correct Eo values
[1]
(1)
[2]
(1)
(ii) They are less heavy / poisonous / toxic / polluting or are safer due to no
(conc) H2SO4 within them
(d) (i) Platinum or graphite / carbon
(1)
[2]
(1)
(ii) They need large quantities of compressed gases which take up space or the
hydrogen would need to be liquefied or the reactant is (highly) flammable /
explosive / combustible
Steel:
(1)
(1)
(e) Glass:
Paper
42
(1)
[2]
(1)
(1)
[3]
[Total: 10]
UCLES 2010
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the May/June 2010 question papers for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level syllabuses.
om
.c
s
er
Page 2
1
Syllabus
9701
Paper
43
(1) + (1)
(b) (i) the exponent / power to which a concentration is raised in the rate equation
(or in an equation, e.g. a in the equ: rate = k[A]a)
[2]
(1)
(ii) from 1 and 2: rate increases by 50% as does [RCl ], so rate [RCl ]1
from 1 and 3: rate [NaOH]1
(1)
(1)
(1)
(iv)
(can be a solid line)
(-)
R
HO
(+)
Cl
HO
(H) (H)
C
(H) (H)
HO
Cl
R
C
+ Cl
(H)(H)
marking points:
(+) or + on C and () or on Cl
lone pair and charge on: OH
curly arrow from OH (lone pair) to (+)C, and either a curly arrow breaking
C-Cl bond or 5-valent transition state (ignore charge)
SN1 alternative for last mark (only award mark if candidates rate
equation shows first order reaction): curly arrow breaking C-Cl bond and
carbocation intermediate.
(1)
(1)
(1)
[7]
(c) (i) (add RCl / RCOCl to) (aq) Ag+ / AgNO3 or named indicator (e.g. MeOr) or
use pH probe
(1)
White ppt appears (faster with RCOCl) or turns acidic colour (e.g. red) or
shows pH decrease
(1)
if water is the only reagent, and no pH meter used: award only the second
mark, for steamy / white fumes
(ii) (C=O is polarised /) carbon is more + than in R-Cl or carbon is positive or
RCOCl can react via addition-elimination
(mention of electronegativity on its own is not enough for the mark)
(1)
[Total: 12]
UCLES 2010
[3]
Page 3
2
Syllabus
9701
Paper
43
(1)
lattice energy and hydration energies both decrease (i.e. become less negative)
(1)
but H.E. decreases more (than L.E.) or change in H.E. outweighs L.E.
(1)
(1)
(b) (i) for Mg: H = 2993 1890 (2 550) = (+)3 (kJ mol1)
(1)
(1)
(1)
(1)
[4]
(1)
[5]
(1) + (1)
(1)
(1)
(1)
(iii) less soluble in NaOH due to the common ion effect or equilibrium is shifted
to the l.h.s. by high [OH ] (NOT just a mention of Le Chatr on its own)
(1)
[6]
[Total: 15]
UCLES 2010
Page 4
3
Syllabus
9701
(a) SiF4 is symmetrical or tetrahedral or bonds are at 109 or has no lone pair or
4 electron pairs shared equally or all Si-F dipoles cancel out, or SF4 has a lone
pair (on S).
Paper
43
(1)
[1]
(2)
[2]
(b)
compound
molecule has
an overall dipole
BCl 3
PCl 3
CCl 4
SF6
mark row-by-row,
(c) (i) Si and B have empty / available / low-lying orbitals or C does not have
available orbitals (allow B is electron deficient but not mention or implication
of d-orbital on B)
(ii) BCl 3 + 3H2O H3BO3 + 3HCl or 2BCl 3 + 3H2O B2O3 + 6HCl
(1)
(1)
(1)
(d) (i) Si3Cl 8O2 (this has Mr = 84 + 280 + 32 = 396) or Si4Cl 4O9 or Si8Cl 4O2
(1)
[3]
(ii)
mass number
133
247
263
structure
Cl 3Si
Cl 3Si-O-SiCl 2
Cl 3Si-O-SiCl 2-O
(3)
(if correct structures are not given for last 2 rows, you can award (1) mark for
two correct molecular formulae:
either Si2Cl 5O + Si2Cl 5O2 or Si3ClO8 + Si3ClO9 or Si7ClO + Si7ClO2)
(iii)
Cl
Si
Cl
Cl
Si
Cl
Cl
Si
Cl
Cl
Cl
allow ecf on the structure drawn in the third row of the table in (ii)
but any credited structure must show correct valencies for Si, Cl and O.
(1)
[5]
[Total: 11]
UCLES 2010
Page 5
4
Syllabus
9701
(a) Cr3+:
1s22s22p6... 3s23p63d3
2+
Mn : 1s22s22p6... 3s23p63d5
(allow (1) out of (2) for 3s23p64s23d1 and 3s23p64s23d3)
(1)
(1)
[2]
(3)
Paper
43
(1)
Fe3+/Fe2+ = +0.77 V
Fe(OH)3/Fe(OH)2 = 0.56V
[4]
(2)
Eocell = +0.46V (allow 0.37) in acid, but +0.96V in alkali or Eo (OH) > Eo (H+)
(1)
(1)
[4]
(d)
O
[1]
(1)
CH3CO2H
and
HO2C
CO2H
[1]
(1)
[1]
(1)
(or CO2H)
O
O
CO2H
H3C
or
CHO
H3C
[1]
(1)
[1]
(1)
[5]
(e) (i) (CH3)2C(OH)CH2OH
(1)
(ii) reaction I: (cold dilute) KMnO4 (cold not needed, but hot or warm negates)
reaction II: Cr2O72 + H+ + distil
(1)
(1)
[3]
UCLES 2010
Page 6
5
Syllabus
9701
Paper
43
(a) (i) because the carbons are sp2 / trigonal planar / bonded at 120 or are joined
by bonds / orbitals
(1)
(1)
[2]
(1)
(1)
NO2
NO2
(1)
(1)
[4]
(1)
[1]
(2)
(1)
Br
Br
NHCOCH3
N2 (Cl
Cl
Cl
(1)
OH
or
B
Cl
no reaction
Cl
(4)
[8]
[Total: 15]
UCLES 2010
Page 7
6
Syllabus
9701
Paper
43
(1)
(1)
[2]
(1)
(1)
(2)
[4]
(1)
needed
R
N
O
N
R
New strand must contain a minimum of two amino acid residues in a single
chain. Deduct a penalty of (1) for any wrong H-bond only if (2) marks have
already been scored.
(2)
[3]
(d) There are bonds or S-S bridges / linkages between the layers / sheets
(in -keratin) (but only van der Waals interactions between the layers in silk)
(1)
[1]
[Total: 10]
UCLES 2010
Page 8
7
Syllabus
9701
Paper
43
(a) The amino acid is uncharged / neutral / a zwitterion or charges balance / are
equal (NOT is non-polar)
It is equally attracted by the anode / + and the cathode / or attracted by neither
The pH of the buffer is at the isoelectric point/IEP of the amino acid any two
(b) (at pH 10), H2NCH2CO2 or NH2CH2COO
(2)
[2]
(1)
[1]
(3)
[3]
(c)
amino acid
relative size
A
small(est) (1)
B
large(st) (3)
C
middle
(2)
(numbers are OK to show relative sizes)
Mark each row
(d) (i) lys val ser ala gly ala gly asp
charge
ve
ve
+ve
(2)
(1)
(1)
[4]
[Total: 10]
UCLES 2010
Page 9
8
Syllabus
9701
(a) Reaction II since electrons are used up / required / gained / received (from
external circuit)
(b) (Pb2+ + 2e Pb)
(PbO2 + 4H+ + 2e Pb2+ + 2H2O)
Eo = 0.13V
Eo = +1.47V
two correct Eo values
[1]
(1)
[2]
(1)
(ii) They are less heavy / poisonous / toxic / polluting or are safer due to no
(conc) H2SO4 within them
(d) (i) Platinum or graphite / carbon
(1)
[2]
(1)
(ii) They need large quantities of compressed gases which take up space or the
hydrogen would need to be liquefied or the reactant is (highly) flammable /
explosive / combustible
Steel:
(1)
(1)
(e) Glass:
Paper
43
(1)
[2]
(1)
(1)
[3]
[Total: 10]
UCLES 2010
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Syllabus
9701
Paper
41
[1]
[1]
(ii) advantage:
[1]
[1]
(ii) amide
[1]
[1]
[1]
[Total: 12]
Page 3
2
Syllabus
9701
Paper
41
[1]
(ii) both forward & reverse reactions are going on at the same time, but the concentrations
of all species do not change (owtte)
or rate of forward = rate of backward reaction
[1]
(b) (i) Kc = [H+][OH]/[H2O]
[1]
(ii) Kw = [H+][OH]
rearrangement of equation in (i) gives Kc[H2O] = [H+][OH] & Kw = Kc[H2O] (owtte)
or the [H2O] is contained within Kw
[1]
[1]
[1]
[1]
(correct ans = [2]) ecf [1]
[1]
(correct ans = [2]) [1]
ecf [1]
(iv) pH = 11.0
ecf [1]
[Total: 12 max 11]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
(ii)
Cl
Cl
P
Cl
[1]
P
Cl
[1]
ecf from structure in (ii) [1]
[Total: 10]
University of Cambridge International Examinations 2011
Page 4
Syllabus
9701
Paper
41
[1]
(b) (i) catalytic converter and passing the exhaust gases over a catalyst/Pt/Rh
[1]
[1]
(c) No, it wouldnt be reduced. Because the reaction in (a) does not presuppose a particular fuel
(owtte)
[1]
Allow formed from N2 and O2 in air during combustion
(d) (i) SO3 produces acid rain
[1]
(ii) NO + O2 NO2
[1]
[1]
[1]
[1]
[1]
[1]
[Total: 11]
(a)
transformation
reagent + conditions
C2H4 C2H5Cl
C2H5OH C2H5Cl
C2H6 C2H5Cl
Cl2 + light
C2H4 C2H4Cl2
CH3CO2H CH3COCl
H 3C
H 3C
CH3
Cl
CH2Cl
Cl2 + AlCl3
Cl2 + light or heat
[6]
Page 5
Syllabus
9701
NO2
Paper
41
[1]
NO2
curly arrow from ring to NO2+ and from C-H bond to ring
correct intermediate, including charge in the right place
Note charge area must be more than half ring
[1]
[1]
(ii) C is C6H5CO2H
[1]
[1]
[1]
(If C is given as 3-bromotoluene, then allow the last [2] marks if steps 1 and 2 are
reversed.)
[Total: 12]
6
[1]
[1]
[1]
(iv)
compound
result
CH3OH
CH3CH2OH
CH3CHO
CH3CO2H
CHO
COCH3
[3]
Page 6
Syllabus
9701
Paper
41
CHO
CO2H
O
CO2H )
for D allow
CHO
(D + E + F): 3 [1]
(c) (allow displayed, skeletal and structural formulae)
Must be consistent with F
OH
G
allow for G
CO2H
CO2H
CO2H
CO2H
H
(only allow mark for H
if G is the 3-OH acid)
CO2H
OH
(G + H + J + K): 4 [1]
[1]
[Total: 14]
Page 7
7
Syllabus
9701
Paper
41
Enzyme + substrate
Enzyme-substrate complex
Enzyme + products
3 [1]
(c) a competitive inhibitor combines with the enzymes active site (so preventing the substrate
from binding)
[1]
non-competitive inhibitor bonds with the enzyme away from the active site/at an allosteric site
[1]
this changes the shape of the active site
[1]
Line must be of similar shape to original but level out below original line
[1]
(ii) Inhibitor reduces the number of enzymes with working active sites (owtte)
[1]
[Total: 10]
Page 8
8
Syllabus
9701
Paper
41
(a) partition separation due to the different solubilities of compounds in two solvents/phases
[1]
adsorption separation due to the different attractions between the compounds and the
stationary phase, relative to their solubility in the solvent
[1]
Note, if candidates do not refer to different solubilities and different attractions
max 1
(b)
X - sample
Ring:
A + B:
[1]
[1]
M
100 9 100
=
=
M + 1 1.1 n 0.3
Hence n =
[1]
1.1 n
100 0.3
= 3.03
1.1 9
p = 3
(answer + working) [1]
(If the mass peak is at 122 and the compound contains Br and 3 C atoms then
Q = (122 79 36)) thus Q = 7
ecf from (ii) [1]
(The compound is C3H7Br)
(iii) (R is at m/e 43), hence C3H7+
(d) Any two from H2, H2O, CO, C2H4, C2H2, CH4
[1]
2 [1]
[Total: 10]
Page 9
9
Syllabus
9701
Paper
41
[1]
[1]
2 [1]
[1]
(ii)
O
O
CH2
CH2 O
[1]
[1]
[1]
(d) Monomers in Terylene have to alternate in order to condense out water (owtte)
[1]
Alkenes can link in any order (and still form a polyalkene) (or diagram showing this)
[1]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Syllabus
9701
Paper
42
[1]
[1]
[2]
acid-base/proton transfer/neutralisation/exothermic/reversible/
[1]
(ii)
H
H
[1]
[1]
[1]
3 x [1]
[1]
[1]
[1]
[1]
[1]
(iii) deep blue colour would change to light blue [NOT intensity of colour decreases]
hexaquocopper(II) ion or [Cu(H2O)6]2+ or [Cu(H2O)n(NH3)an]2+, where a = 4 or 6
or ligand exchange (of NH3) by H2O
[1]
[1]
[4]
[1]
[1]
[1]
(Allow n=1 up to n=6. Also allow [CuCln]2n as product. Examples from many possible are:
[Cu(H2O)6]2+ + 2Cl [Cu(H2O)4Cl2] + 2H2O
[Cu(H2O)6]2+ + 4Cl [CuCl4]2 + 6H2O
equation could include HCl on the LHS, for example:
[3]
[Cu(H2O)6]2+ + 4HCl H2CuCl4 + 2H+ + 6H2O or CuCl42 + 4H+ + 6H2O
[Total: 18 max 17]
Page 3
Syllabus
9701
Paper
42
(a) (i)
high
electrical conductivity
high
medium
melting point
low
Si
Ge
Sn
Pb
medium
or
low
Si
Ge
Sn
Pb
[2] + [2]
(ii) m. pt. trend: (from) giant/macro molecular/covalent to metallic bonding
(or implied from at least two specific examples, e.g. diamond and tin)
(mention of simple covalent anywhere negates this mark)
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
or SnCl2(aq) will turn Cu2+(aq) from blue to colourless or give a pink/brown/coppercoloured ppt.
[1]
Sn2+ + Cu2+ Sn4+ + Cu
[1]
Other possible oxidants (Eo must be > +0.2V) include: S2O82, H2O2, Cl2, Br2, I2 and Ag+.
No observations with the first three of these, but this should be stated explicitly, e.g. no
colour change.
[5]
[Total: 11 max 10]
Page 4
3
Syllabus
9701
(a) L = F/e or F = Le
Paper
42
[1]
[1]
(b) (i)
+
P .S .
a no d e
c a tho d e
C uS O 4 (a q )
to represent
[1]
[1]
[1]
[1]
[1]
ecf [1]
[1]
ecf [1]
product at anode
product at cathode
AgF
O2
Ag
FeSO4
O2
H2
MgBr2
Br2
H2
6 correct [5]
5 correct [4] etc.
Names can be used instead of symbols. If the atomic symbol (e.g. Br or H or O) is used
instead of the molecular formula (e.g. Br2 etc.) then deduct [1] mark only for the whole table.
[5]
[Total: 15]
University of Cambridge International Examinations 2011
Page 5
4
Syllabus
9701
Paper
42
OCOCH3
chain
repeat unit
[1]
[1]
[1]
[1]
ecf [1]
ecf [1]
[6]
O
O
[1]
(ii) ester
[1]
[1]
[1]
(v) they have the same molecular formula or C4H6O2 (do NOT allow empirical formula) or
same no. and type of atoms or same functional group or both are esters or they are
isomers
[1]
[5]
Page 6
Syllabus
9701
Paper
42
[1]
(ii)
CO2H
CO2H
(letters may be reversed)(allow ecf from E, also allow ecf for G from F)
cis-trans or geometrical isomerism
[1] + [1]
[1]
[4]
[Total: 15]
Page 7
5
Syllabus
9701
Paper
42
OH
ONa
+ Na
OH
ONa
nothing special
+ NaOH
OH
[1]
H2
H2O
[1]
nothing special
NO REACTION
+ CH3CO2H
must be (aq)
OH
[1]
OH
[1]
Br
Br
[1]
+ Br2
Br
[5]
(c) H is
OH
NO2
[1]
[1]
[1]
[1]
[4]
[Total: 13]
Page 8
6
Syllabus
9701
Paper
42
[1]
[1]
[1]
trypsin
amylase
activity
10
pH
[1]
[1]
[1]
[3]
[Total: 10]
Page 9
7
Syllabus
9701
Paper
42
(a)
Number
Process
Correct sequence
(numbers)
Extract DNA
mark as follows:
[1] mark
[1] mark
[1] mark
[3]
[1]
(ii) Phosphate groups are present in DNA or it makes the DNA fragments/bands etc. visible
or locates their position or identifies them on a photographic plate etc.
[1]
(NOT because its radioactive or makes the bands coloured)
[2]
(c) (i) Yes, all 4 children share one/some band (or match/gene/fragment/part/DNA/
amino acid) with the mothers (DNA) (NOT the general statement matches the
mothers DNA)
[1]
(ii) Child 2, since he/she shares none of the bands of fathers DNA/fingerprint or their
fingerprint/DNA does not match the fathers DNA (the general match is OK here)
[1]
[2]
(d) (i) Compare DNA fingerprint for each fragment (can be read into use of the word
same below)
Match the DNA patterns to determine which came from which skin
[1]
[1]
(ii) A named example of biological origin (N.B. a material, not a whole organism)
[1]
e.g. leather (= bull skin), pollen, fish scales, leaves, seeds, feathers, hair, blood, textiles
(or a named one like wool or silk or cotton or linen/flax), wood.
(N.B. NOT human or goat skin, also not metal, pottery or stone. If more than one
material is given, mark the first one)
[3]
[Total: 10]
Page 10
8
Syllabus
9701
Paper
42
[1]
[1]
[2]
(b) Forms of the same element (or of carbon, since carbon is the context of the question)
[1]
with different structures/arrangements of atoms
[1]
allow different molecular structure, but not structural formula. Any mention of compound
negates the mark.
[2]
(c) Nanoparticles are smaller than (animal) cells or they can pass through the cell membrane
or pass into/between cells
[1]
Drugs can be bound to/enclosed by the nanoparticle
[1]
[2]
(d) (i) Reduction/redox
[1]
63.5 100
= 34.6%
183.5
(if Ar(Cu) = 64 is used, ans = 34.8%. allow 3435%)
Hence percentage of copper present =
[1]
(iii) If the ore contains 2% of chalcopyrite by mass, calculate how much copper is produced
from each tonne of ore.
1 tonne = 1000 kg
1 tonne of chalcopyrite would produce 346 kg of copper
1 tonne of 2 % ore would produce 346 0.02 or 6.9 kg of copper ecf from (d)(ii)
[1]
(accept 7.0 or 7 kg)
answer may be given as 7000 g or 7 103 tonnes. If no units are given, assume they
are tonnes, and mark accordingly)
(iv) By displacement with a metal (the following specified metals higher than Cu in the ECS
may be used: Fe, Zn, Sn, Pb, Al, Mg. (NOT Ca, Li, Na. K etc.) or with a suitable nonmetallic reducing agent, e.g. SO2 or Sn2+, but not something that wouldnt react, like H2
or By electrolysis (with carefully controlled voltage)
[1]
[4]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2011 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Syllabus
9701
Paper
43
[1]
[1]
[2]
acid-base/proton transfer/neutralisation/exothermic/reversible/
[1]
(ii)
H
H
[1]
[1]
[1]
3 x [1]
[1]
[1]
[1]
[1]
[1]
(iii) deep blue colour would change to light blue [NOT intensity of colour decreases]
hexaquocopper(II) ion or [Cu(H2O)6]2+ or [Cu(H2O)n(NH3)an]2+, where a = 4 or 6
or ligand exchange (of NH3) by H2O
[1]
[1]
[4]
[1]
[1]
[1]
(Allow n=1 up to n=6. Also allow [CuCln]2n as product. Examples from many possible are:
[Cu(H2O)6]2+ + 2Cl [Cu(H2O)4Cl2] + 2H2O
[Cu(H2O)6]2+ + 4Cl [CuCl4]2 + 6H2O
equation could include HCl on the LHS, for example:
[3]
[Cu(H2O)6]2+ + 4HCl H2CuCl4 + 2H+ + 6H2O or CuCl42 + 4H+ + 6H2O
[Total: 18 max 17]
Page 3
Syllabus
9701
Paper
43
(a) (i)
high
electrical conductivity
high
medium
melting point
low
Si
Ge
Sn
Pb
medium
or
low
Si
Ge
Sn
Pb
[2] + [2]
(ii) m. pt. trend: (from) giant/macro molecular/covalent to metallic bonding
(or implied from at least two specific examples, e.g. diamond and tin)
(mention of simple covalent anywhere negates this mark)
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
or SnCl2(aq) will turn Cu2+(aq) from blue to colourless or give a pink/brown/coppercoloured ppt.
[1]
Sn2+ + Cu2+ Sn4+ + Cu
[1]
Other possible oxidants (Eo must be > +0.2V) include: S2O82, H2O2, Cl2, Br2, I2 and Ag+.
No observations with the first three of these, but this should be stated explicitly, e.g. no
colour change.
[5]
[Total: 11 max 10]
Page 4
3
Syllabus
9701
(a) L = F/e or F = Le
Paper
43
[1]
[1]
(b) (i)
+
P .S .
a no d e
c a tho d e
C uS O 4 (a q )
to represent
[1]
[1]
[1]
[1]
[1]
ecf [1]
[1]
ecf [1]
product at anode
product at cathode
AgF
O2
Ag
FeSO4
O2
H2
MgBr2
Br2
H2
6 correct [5]
5 correct [4] etc.
Names can be used instead of symbols. If the atomic symbol (e.g. Br or H or O) is used
instead of the molecular formula (e.g. Br2 etc.) then deduct [1] mark only for the whole table.
[5]
[Total: 15]
University of Cambridge International Examinations 2011
Page 5
4
Syllabus
9701
Paper
43
OCOCH3
chain
repeat unit
[1]
[1]
[1]
[1]
ecf [1]
ecf [1]
[6]
O
O
[1]
(ii) ester
[1]
[1]
[1]
(v) they have the same molecular formula or C4H6O2 (do NOT allow empirical formula) or
same no. and type of atoms or same functional group or both are esters or they are
isomers
[1]
[5]
Page 6
Syllabus
9701
Paper
43
[1]
(ii)
CO2H
CO2H
(letters may be reversed)(allow ecf from E, also allow ecf for G from F)
cis-trans or geometrical isomerism
[1] + [1]
[1]
[4]
[Total: 15]
Page 7
5
Syllabus
9701
Paper
43
OH
ONa
+ Na
OH
ONa
nothing special
+ NaOH
OH
[1]
H2
H2O
[1]
nothing special
NO REACTION
+ CH3CO2H
must be (aq)
OH
[1]
OH
[1]
Br
Br
[1]
+ Br2
Br
[5]
(c) H is
OH
NO2
[1]
[1]
[1]
[1]
[4]
[Total: 13]
Page 8
6
Syllabus
9701
Paper
43
[1]
[1]
[1]
trypsin
amylase
activity
10
pH
[1]
[1]
[1]
[3]
[Total: 10]
Page 9
7
Syllabus
9701
Paper
43
(a)
Number
Process
Correct sequence
(numbers)
Extract DNA
mark as follows:
[1] mark
[1] mark
[1] mark
[3]
[1]
(ii) Phosphate groups are present in DNA or it makes the DNA fragments/bands etc. visible
or locates their position or identifies them on a photographic plate etc.
[1]
(NOT because its radioactive or makes the bands coloured)
[2]
(c) (i) Yes, all 4 children share one/some band (or match/gene/fragment/part/DNA/
amino acid) with the mothers (DNA) (NOT the general statement matches the
mothers DNA)
[1]
(ii) Child 2, since he/she shares none of the bands of fathers DNA/fingerprint or their
fingerprint/DNA does not match the fathers DNA (the general match is OK here)
[1]
[2]
(d) (i) Compare DNA fingerprint for each fragment (can be read into use of the word
same below)
Match the DNA patterns to determine which came from which skin
[1]
[1]
(ii) A named example of biological origin (N.B. a material, not a whole organism)
[1]
e.g. leather (= bull skin), pollen, fish scales, leaves, seeds, feathers, hair, blood, textiles
(or a named one like wool or silk or cotton or linen/flax), wood.
(N.B. NOT human or goat skin, also not metal, pottery or stone. If more than one
material is given, mark the first one)
[3]
[Total: 10]
Page 10
8
Syllabus
9701
Paper
43
[1]
[1]
[2]
(b) Forms of the same element (or of carbon, since carbon is the context of the question)
[1]
with different structures/arrangements of atoms
[1]
allow different molecular structure, but not structural formula. Any mention of compound
negates the mark.
[2]
(c) Nanoparticles are smaller than (animal) cells or they can pass through the cell membrane
or pass into/between cells
[1]
Drugs can be bound to/enclosed by the nanoparticle
[1]
[2]
(d) (i) Reduction/redox
[1]
63.5 100
= 34.6%
183.5
(if Ar(Cu) = 64 is used, ans = 34.8%. allow 3435%)
Hence percentage of copper present =
[1]
(iii) If the ore contains 2% of chalcopyrite by mass, calculate how much copper is produced
from each tonne of ore.
1 tonne = 1000 kg
1 tonne of chalcopyrite would produce 346 kg of copper
1 tonne of 2 % ore would produce 346 0.02 or 6.9 kg of copper ecf from (d)(ii)
[1]
(accept 7.0 or 7 kg)
answer may be given as 7000 g or 7 103 tonnes. If no units are given, assume they
are tonnes, and mark accordingly)
(iv) By displacement with a metal (the following specified metals higher than Cu in the ECS
may be used: Fe, Zn, Sn, Pb, Al, Mg. (NOT Ca, Li, Na. K etc.) or with a suitable nonmetallic reducing agent, e.g. SO2 or Sn2+, but not something that wouldnt react, like H2
or By electrolysis (with carefully controlled voltage)
[1]
[4]
[Total: 10]
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2012 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
1
Syllabus
9701
Paper
41
[1]
[1]
[1]
[3]
[1]
[1]
[1]
[3]
[3]
[3]
[1]
[1]
[1]
[3]
[Total: 12]
2.
(a) (i)
O
[1]
(ii) 180 kJ mol1
[1]
[1]
[1]
[1]
[5]
[1]
[1]
[1]
[1]
Page 3
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[1]
[1]
[8]
(c) (i) NO
(ii)
[1]
[1]
[1]
(iv) [Fe(H2O)6-n(NO)n]2+
[1]
[4]
(n = 1-6)
[Total:17]
3.
[1]
(any 3)
[1]
(c) 1.
[2]
[3]
[1]
[2]
2,4-DNPH [1]
Na metal
[1]
no reaction
[1]
or PCl5/SOCl2 [1]
or PCl3 + warm
no reaction
steamy fumes/fizzing
misty/white fumes
[1]
[1]
[5]
2.
2 x no reaction
no reaction
Page 4
(d) (i)
OH
N
H
Syllabus
9701
Paper
41
H
N
HO
[1]
(ii) Mr = 262, so 2.5 g = 2.5/262 = 9.54 103 mol
(1 mol indigo absorbs 9 mol of H2)
so volume of H2 = 9 24 9.54 103 = 2.06 dm3 (2060 cm3)
[1]
[1]
[3]
(e)
Br
Br
Br
N
H
Br
H
N
Br
Br
2 x Br on C=C
a Br on each ring
TWO non-adjacent Br on each ring
[1]
[1]
[1]
[3]
[Total: 16]
4
[1]
due to greater van der Waals (VDW) forces (intermolecular is not sufficient)
[1]
[1]
[1]
[1]
[1]
[1]
[7]
Page 5
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[1]
[5 max 4]
[Total: 11]
(a) (i)
OCH3
Br
Br
Br
[1]
(ii) Na metal
or
Fizzes/gas given off with phenol
or
C6H5OH + Na C6H5ONa + H2 or
OH
ONa
+ Na
1
+ /2 H2
NaOH
phenol dissolves (anisole doesnt)
C6H5OH + OH C6H5O + H2O
ONa
OH
+ NaOH
or
[1]
[1]
[1]
+ H2O
[1]
[1]
[1]
[4]
(b) (i)
(ii) step 2:
Sn + HCl
conc. + reflux
NO2
Cl
[1] + [1]
NOT LiAlH4, NaBH4
(warm is insufficient)
[1]
[1]
[1]
[5 max 4]
Page 6
(c) (i)
H
N
OH
NH2
O
Syllabus
9701
O
HO2C
CN
OH
Paper
41
F must be an amide
[4]
(ii) reaction 1: H2 + Ni or LiAlH4
reaction 2: heat + aqueous HCl
[1]
[1]
[6]
[Total: 14]
[1]
[2]
[3]
[1]
[1]
[1]
(c) (i) Some amino acids have more than one (triplet) code
[1]
[4]
[1]
[1]
[1]
[3]
[Total: 10]
Page 7
7
Syllabus
9701
Paper
41
(a)
Start point
Glutamic acid
Glycine
Lysine
[1]
[1]
[1]
[3]
[1]
[1]
[3]
[1]
[1]
[1]
[1]
[1]
[5 max 4]
[Total: 10]
Page 8
8
Syllabus
9701
Paper
41
(a)
LDPE
HDPE
minimum of 2 chains suitable sketches
[1]
(The close packing of unbranched side chains means)
LDPE more space between the chains/polymers or HDPE less empty space between the
chains
[1]
[2]
(b) van der Waals (VDW) forces
are weaker
[1]
[1]
[2]
(c)
Addition OR
condensation
different formula
(d) (i) (through its long chain of) delocalised electrons/mobile electrons
free electrons is not sufficient
(ii) planar
[1]
[2]
[1]
[1]
[1]
[2]
[5 max 4]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2012 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
Syllabus
9701
Paper
42
[1]
[1]
[1]
(iii) Mg2+ has a smaller radius/size or greater charge density than Ca2+ (ions required)
[1]
[1]
[5]
measure (known volume/mass of) water or stated volume of water (into calorimeter)
[1]
[2]
[3]
(d)
Page 3
2
Syllabus
9701
Paper
42
(a) (i)
or
[1]
(ii) incomplete combustion (of hydrocarbon fuels) or insufficient O2/air
(iii) NO + CO N2 + CO2
or CO + O2 CO2
equation needs to be balanced
[1]
[1]
[3]
[2]
[2]
[1]
(ii)
d-orbitals are split (by the ligand field) or orbitals near ligands are at higher energy
the splitting/energy gap depends on the ligands (surrounding the ion) or the metal
(ion)
when an electron moves from lower to higher orbital/energy level or is promoted/
excited
light/a photon is absorbed or colour seen/reflected/transmitted is complement of
colour absorbed (emitted contradicts this mark)
different energy gap means different frequency absorbed means different colour
5 [1]
(iii) from rows 1 and 3: rate3/rate1 = 2.0 which also equals [[complex]3]/[[complex]1]
[1]
(or this working mark can be awarded for any valid calculation that shows that order
w.r.t. complex is 1)
Thus order w.r.t. [complex] = 1 and order w.r.t. [CO] is zero
[1]
rate equation: rate = k[complex]
[1]
(iv) mechanism 2
[1]
its the only one that does not involve CO in the rate determining step or rate depends
on [complex] only.
[1]
[11 max 10]
[Total: 15]
Page 4
3
Syllabus
9701
Paper
42
any three
[2]
or Br2(aq)
or white ppt with A,
[1]
or and decolourises
with Lawsone
[1]
(iii) NaBH4 or LiAl H4 or SnCl 2 or Na + ethanol or any suitable reducing agents with
[1]
Eo < 0.2 V, e.g. SO2. NOT H2 + Ni etc.
(iv)
O
Br
H
O
OH
or
Br
O
H
Br
[1]
[6]
[1]
[1]
[1]
[5]
Page 5
Syllabus
9701
Paper
42
[1]
CH3
O
O
or -OCOCH3
or -OOCCH3
(ii) compound D is
O
[1]
CH 3
O
O
O
O
intermediate anion
Cl
CH3
[4 max 3]
[Total: 14]
Page 6
Syllabus
9701
Paper
42
(a) volatility: Cl 2 > Br2 > I2 or boiling points: Cl 2 < Br2 < I2 or Cl 2 is (g); Br2 is (l); I2 is (s)
[1]
more electrons in X2 down the group or more shells/bigger cloud of electrons
[1]
so theres greater van der Waals/dispersion/id-id/induced/temporary dipole force/attraction [1]
[3]
(b) (i) H2O > H2S (see * below for mark)
due to H-bonding in H2O (none in H2S)
diagram minimum is: H2O+H-OH or H2O:H-OH [allow (+) for +]
[1]
[1]
[1]
[1]
[1]
[3]
Page 7
(b)
first
compound
second
compound
NH2
NH2
Syllabus
9701
test
observation
with first
compound
none
none
CH3CH2COCl
CH3CH2CHO
CH3COCH2Cl
(2,4-)DNPH
I2/OH
none
I2/OH
none
CH3COCH3
add H2O/ROH
Fehlings/Benedicts solution
+ warm
Tollens reagent + warm
observation
with second
compound
decolourises/
white ppt.
yellow/orange/red
ppt.
(immediate)
white ppt.
steamy/misty/
white fumes
none
AgNO3(aq)
Paper
42
none
none
orange ppt.
yellow ppt./
antiseptic smell
yellow ppt./
antiseptic smell
red ppt.
none
silver/black ppt.
none
Cr2O7 + H + warm
turns green
no change
MnO4 + H+ + warm
decolourises
no change
[3]
[3]
[1]
[7]
[1]
(ii) (in parts (ii) and (iii), allow structural formulae instead of skeletal formulae)
or NaO
HO
and
or Cl
or Cl
OH
HO
OH
or ONa
[1] + [1]
[1]
[1]
Page 8
Syllabus
9701
Paper
42
(iv) F (or E, i.e. the alphatic di-acid) should be changed to something less flexible, e.g.
HO2C
HO2C
or
or
HO2C
CO2H
CO2H
HO2C-CO2H
HO2C
CO2H
CO2H
HO2C
CO2H
or allow a tri-carboxylic acid (or triphenol), i.e. one that will allow cross linking
[1]
[6]
[Total: 16]
(a)
amino acid
structure
type of interaction
alanine
H2NCH(CH3)CO2H
cysteine
H2NCH(CH2SH)CO2H
disulfide bonds
or S-S
lysine
H2NCH((CH2)4NH2)CO2H
ionic/electrovalent
hydrogen/H bonds
serine
H2NCH(CH2OH)CO2H
hydrogen/H bonds
[3]
[3]
[1]
Potassium in cell membranes/enzymes; controlling the flow of ions/water into or out of cells
or in nerves; controlling nerve impulses
or Na+ K+ pump; nerve impulses/control of cell volume/active transport
[1]
Zinc acting as a cofactor in enzymes (or a named one, e.g. carbonic anhydrase);
or in making of insulin
[1]
[3]
[1]
[1]
[2]
(d) (i) Sodium or chloride (sweat is salty) and Potassium (water retention in cells)
[1]
[1]
[2]
[Total: 10]
Page 9
7
Syllabus
9701
Paper
42
(b) (i) Peak at 1.26 = (3 ) CH3 or methyl and Peak at 2.0 = OH or alcohol
[1]
Structure:
[1]
CH3
CH3
OH
CH3
(ii)
Isomer
Isomer
Isomer
CH3CH2CH2CH2OH
(CH3)2CHCH2OH
CH3CH2CH(CH3)OH
5 groups of peaks
4 groups of peaks
5 groups of peaks
[1] + [1]
[1] + [1]
[6]
(c) (i) Phosphorus it has more electrons or high electron density (NOT phosphate)
[1]
(ii) H atoms dont have enough electron density to show up or they only contain one e
[1]
[2]
[Total: 10]
Page 10
8
Syllabus
9701
Paper
42
[1]
[1]
[1]
(ii) hydrolysis
[1]
(iii)
[1] + [1]
[4]
(c) (i) measured in nm, i.e. between 1 and 1000 nm (or 109 106 m). Any quoted value
or range between these limits is acceptable
(ii) One or both of the OH groups (NOT just oxygen or O)
[1]
[1]
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2012 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
1
Syllabus
9701
Paper
43
[1]
[1]
[1]
[3]
[1]
[1]
[1]
[3]
[3]
[3]
[1]
[1]
[1]
[3]
[Total: 12]
2.
(a) (i)
O
[1]
(ii) 180 kJ mol1
[1]
[1]
[1]
[1]
[5]
[1]
[1]
[1]
[1]
Page 3
Syllabus
9701
Paper
43
[1]
[1]
[1]
[1]
[1]
[1]
[8]
(c) (i) NO
(ii)
[1]
[1]
[1]
(iv) [Fe(H2O)6-n(NO)n]2+
[1]
[4]
(n = 1-6)
[Total:17]
3.
[1]
(any 3)
[1]
(c) 1.
[2]
[3]
[1]
[2]
2,4-DNPH [1]
Na metal
[1]
no reaction
[1]
or PCl5/SOCl2 [1]
or PCl3 + warm
no reaction
steamy fumes/fizzing
misty/white fumes
[1]
[1]
[5]
2.
2 x no reaction
no reaction
Page 4
(d) (i)
OH
N
H
Syllabus
9701
Paper
43
H
N
HO
[1]
(ii) Mr = 262, so 2.5 g = 2.5/262 = 9.54 103 mol
(1 mol indigo absorbs 9 mol of H2)
so volume of H2 = 9 24 9.54 103 = 2.06 dm3 (2060 cm3)
[1]
[1]
[3]
(e)
Br
Br
Br
N
H
Br
H
N
Br
Br
2 x Br on C=C
a Br on each ring
TWO non-adjacent Br on each ring
[1]
[1]
[1]
[3]
[Total: 16]
4
[1]
due to greater van der Waals (VDW) forces (intermolecular is not sufficient)
[1]
[1]
[1]
[1]
[1]
[1]
[7]
Page 5
Syllabus
9701
Paper
43
[1]
[1]
[1]
[1]
[1]
[5 max 4]
[Total: 11]
(a) (i)
OCH3
Br
Br
Br
[1]
(ii) Na metal
or
Fizzes/gas given off with phenol
or
C6H5OH + Na C6H5ONa + H2 or
OH
ONa
+ Na
1
+ /2 H2
NaOH
phenol dissolves (anisole doesnt)
C6H5OH + OH C6H5O + H2O
ONa
OH
+ NaOH
or
[1]
[1]
[1]
+ H2O
[1]
[1]
[1]
[4]
(b) (i)
(ii) step 2:
Sn + HCl
conc. + reflux
NO2
Cl
[1] + [1]
NOT LiAlH4, NaBH4
(warm is insufficient)
[1]
[1]
[1]
[5 max 4]
Page 6
(c) (i)
H
N
OH
NH2
O
Syllabus
9701
O
HO2C
CN
OH
Paper
43
F must be an amide
[4]
(ii) reaction 1: H2 + Ni or LiAlH4
reaction 2: heat + aqueous HCl
[1]
[1]
[6]
[Total: 14]
[1]
[2]
[3]
[1]
[1]
[1]
(c) (i) Some amino acids have more than one (triplet) code
[1]
[4]
[1]
[1]
[1]
[3]
[Total: 10]
Page 7
7
Syllabus
9701
Paper
43
(a)
Start point
Glutamic acid
Glycine
Lysine
[1]
[1]
[1]
[3]
[1]
[1]
[3]
[1]
[1]
[1]
[1]
[1]
[5 max 4]
[Total: 10]
Page 8
8
Syllabus
9701
Paper
43
(a)
LDPE
HDPE
minimum of 2 chains suitable sketches
[1]
(The close packing of unbranched side chains means)
LDPE more space between the chains/polymers or HDPE less empty space between the
chains
[1]
[2]
(b) van der Waals (VDW) forces
are weaker
[1]
[1]
[2]
(c)
Addition OR
condensation
different formula
(d) (i) (through its long chain of) delocalised electrons/mobile electrons
free electrons is not sufficient
(ii) planar
[1]
[2]
[1]
[1]
[1]
[2]
[5 max 4]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2013 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2
1
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
(a) The potential of an electrode compared to that of a standard hydrogen electrode (SHE)
or
the EMF of a cell composed of the test electrode and the SHE
all measurement concentrations of 1 mol dm3 and 298 K / 1 atm pressure
[1]
[1]
[2]
(b)
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[8]
[Total: 15]
Page 3
Syllabus
9701
Paper
41
100
120
(a) (i)
0.2
0.18
0.16
0.14
[CH3CO2CH2CH3]/mol dm-3
Mark Scheme
GCE A LEVEL May/June 2013
0.12
0.1
0.08
0.06
0.04
0.02
0
20
40
60
80
time/min
(b) (i) because H2O is the solvent or its concentration cannot change
(ii) because HCl is a catalyst
[1]
[1]
[1]
[1]
[1]
[8 max 7]
[1]
[1]
[2]
[Total: 9]
Page 4
3
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
[1]
[1]
[1]
[3]
(b)
reaction
acidbase
ligand
exchange
precipitation
redox
Cr(H2O)3(OH)3 + OH [Cr(H2O)2(OH)4] +
H2O
(Where more than one tick appears on a line in the table above these are alternatives but allow the
mark if both are given).
[8]
(c) n(H2) = 8/24 = 0.33 mol
from equation, this is produced from 0.22 mol of Al ecf ( 2/3)
Ar(Al) = 27 thus mass of Al = 27 0.22 = 5.9 6 g hence 5.96.0% ecf ( 27)
[1]
[1]
[1]
[3]
[Total: 14]
Page 5
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[1]
phenylamine (less basic) due to lone pair being delocalised into the ring
[1]
[4]
[1]
[1]
[1]
[1]
NH2
[1]
W is
Cl
O
[1]
[6]
[Total: 15]
Page 6
5
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
(a)
OH
CO2H
OH
H2O
Na
H2
H2
H2
H2
KOH(aq)
Na2CO3(aq)
CO2
X
[5]
[1]
[1]
[1]
(iv) reflux
[1]
dilute HCl
[1]
[5]
Page 7
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
(c) (i)
reagent and conditions
product with A
Br
OH
product with B
Br
Br2(aq)
no reaction
C(CH3)3
Br
no reaction
C(CH3)3
no reaction
C(CH3)3
O
no reaction
C(CH3)3
[6]
(ii) either: Cr2O72/H+: no observation with A and goes from orange to green with B.
or:
Br2(aq): white ppt. with A and no observation/ppt with B
[1]
[7]
[Total: 17]
Page 8
6
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
(a)
substance
protein synthesis
adenine
formation of DNA
alanine
aspartate
phosphate
[3]
[3]
[1]
[1]
hydrogen bonds
[1]
[1]
[4]
[1]
DNA :
tertiary :
hydrogen bonds
ionic bonds
disulfide bonds
[2]
[3]
[Total: 10]
Page 9
7
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
41
extract DNA
(b)
item for testing
human hair
[3]
[3]
drugs:
gas-liquid
or
thin-layer chromatography
[1]
[1]
[1]
[3]
[Total: 10]
Page 10
8
(a) (i)
Mark Scheme
GCE A LEVEL May/June 2013
CO2H
CH
Syllabus
9701
Paper
41
CO2H
CH2
CH
CH2
[1]
(ii) Addition
[1]
[1]
[3]
(b) (i) more / increase water absorbing properties (allow attracts water more)
[1]
more polar(ity)/more hydrophilic / has ionic side-chains (as well as hydrophilic ones)
(ii) It should be biodegradable/decompose
[1]
[1]
[3]
[1]
[1]
[2]
[1]
[1]
[2]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2013 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
[1]
[1]
[2]
(b) (i)
[1]
[1]
[1]
[1]
[1]
[1]
[8 max 7]
Page 3
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
energy/kJ moli1
(c)
+5.4
(2NO + Br2)
-23
2NOBr
extent of reaction
Page 4
2
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
(a) (i)
hydrogen
gas at 1 atm
Pt
H+/HCl at 1 mol dm-3 and 298K
H2(g) going in (i.e. not being produced) [1]
platinum electrode in contact with solution, with H2 bubbling over it [1]
H+ or HCl or H2SO4 [1]
3
solution at 1 mol dm (or 0.5 M if H2SO4) and T=298 K, p=1 atm [1]
(ii) Eo = 1.33 (-0.41) = 1.74 V
[1]
[1]
[1]
to green
[1]
[8]
[1]
[1]
[1]
(correct ratio = [3] marks)
vol of acid = 15 cm3
vol of salt = 85 cm3
[1]
[4]
Page 5
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
[1]
[1]
[2]
(d) e.g. hydrolysis of esters RCO2R' (+ H2O) RCO2H + R'OH or its reverse
or
[1]
[1]
[1]
[3]
NO2
[1]
[1]
(c) Sn/tin (or SnCl2, Fe) + HCl (NOT H2SO4 or H+, Zn, or LiAlH4.)
[1]
[1]
Page 6
Mark Scheme
GCE A LEVEL May/June 2013
(d) (i)
Br
or NH3+
NH2
Syllabus
9701
Paper
42
Br
N
N
NOT -NaO
Br
A
OH
or -ONa or -O-
[1] + [1]
[1]
[1]
[4 max 3]
[1]
[1]
NHCOC2H5
[1]
[3]
[Total: 11]
4.
[3 1]
[4]
Page 7
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
(b)
(colour due to) absorption of light/photons/frequencies/wavelengths
or
colour seen is complement of colour absorbed.
d-orbitals/d-subshell split (by ligand field)
(when photon is absorbed), electron is promoted or moves (from lower) to higher
(d)orbital
energy difference/gap or E or splitting corresponds to photon/frequency/wavelength in
visible region
in s-block elements the energy gap is too large (to be able to absorb visible light)
[any four 4 1]
[4]
(c) (i) 2MnO4 + 2H2O + 5SO2 2Mn2+ + 5SO42 + 4H+
(ii) solution will go from purple
to colourless
[1]
[1]
[1]
[3]
[1]
[1]
[1]
[3]
[Total: 14]
Page 8
5
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
(a) (i)
OH
OH
O
*
OH
*
*
HO
HO
OH
two or three centres correctly identified [1]
four centres correctly identified [2]
(ii) C16H18O9
[1]
(iii)
[1]
3 moles of H2
[1]
[1]
[6]
[1]
alkene or C=C
[1]
[1]
[1]
(iv)
Br(OH) Br
OH
OH
Br
(OH)
CO2H
HO2C
F
(OH can be at the 3, 4, or 5
positions, but not the 2 or 6
positions)
[1]
OH
Br
[1]
[1]
[1]
Page 9
Mark Scheme
GCE A LEVEL May/June 2013
(vi)
HO2C
Syllabus
9701
Paper
42
OH
OH
[1]
3 mol NaOH react with 1 mol of E, so n(NaOH) = 3/1800 = 1/600 mol = 1.67 10-3 mol
[1]
[1]
[3]
[Total: 17]
Page 10
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
(a)
substance
protein synthesis
formation of DNA
cysteine
cytosine
glutamine
guanine
[3]
[3]
(b) (i) Hydrogen bonding
Between bases or between A,T, C and G (all four needed)
(ii) Bonds are (relatively) weak or easily broken
This enables strands to separate or DNA to unzip/unwind/unravel.
[1]
[1]
[1]
[1]
[4]
Page 11
7.
(a) (i)
Mark Scheme
GCE A LEVEL May/June 2013
43.3
3.35
n=
Syllabus
9701
Paper
42
= 100
1.1 x n
100 x 3.35
43.3 x 1.1
[1]
(ii) The M and M+2 peaks are in the ratio 3 : 1 hence the halogen is chlorine/Cl
[1]
[1]
(iv) The multiplet with 4 hydrogens or peaks at 7.3 suggests a benzene ring
The singlet with 2 hydrogens or peak at 4.7 suggests a CH2 group
The singlet with 1 hydrogen or peak at 2.3 suggests an OH group
or reaction with Na suggests an OH group
OH must be an alcohol, not a phenol (due to its value)
Since L also contains 7 carbon atoms and chlorine, this accounts for 126 of the 142
mass, the remaining atom must be oxygen
Thus L is
CH2OH
Cl
(allow the 2-, 3- or 4- isomer)
[6]
[9 max 7]
(b) (i) we expect propene to have a CH3 peak or a peak at m/e 15
or cyclopropane would have fewer peaks
[1]
(ii) cyclopropane would have 1 peak (ignore splitting)
propene would have 2 (or 3, or 4) peaks
(ignore splitting)
or propene would have peaks in the 4.5-6.0 (alkene) region
no splitting of cyclopropane peak
(any two points)
[2]
[3]
[Total: 10]
Page 12
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
42
[2]
[1]
(iii) C(CH2OH)4
[1]
(iv) water
[1]
[5]
[1]
[1]
[2]
[1]
(ii) property e.g. becomes harder / more rigid / less flexible / stronger / higher melting
point.
because the chains are more strongly / tightly held
[1]
[1]
[3]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2013 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2
1
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
(a) The potential of an electrode compared to that of a standard hydrogen electrode (SHE)
or
the EMF of a cell composed of the test electrode and the SHE
all measurement concentrations of 1 mol dm3 and 298 K / 1 atm pressure
[1]
[1]
[2]
(b)
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[8]
[Total: 15]
Page 3
Syllabus
9701
Paper
43
100
120
(a) (i)
0.2
0.18
0.16
0.14
[CH3CO2CH2CH3]/mol dm-3
Mark Scheme
GCE A LEVEL May/June 2013
0.12
0.1
0.08
0.06
0.04
0.02
0
20
40
60
80
time/min
(b) (i) because H2O is the solvent or its concentration cannot change
(ii) because HCl is a catalyst
[1]
[1]
[1]
[1]
[1]
[8 max 7]
[1]
[1]
[2]
[Total: 9]
Page 4
3
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
[1]
[1]
[1]
[3]
(b)
reaction
acidbase
ligand
exchange
precipitation
redox
Cr(H2O)3(OH)3 + OH [Cr(H2O)2(OH)4] +
H2O
(Where more than one tick appears on a line in the table above these are alternatives but allow the
mark if both are given).
[8]
(c) n(H2) = 8/24 = 0.33 mol
from equation, this is produced from 0.22 mol of Al ecf ( 2/3)
Ar(Al) = 27 thus mass of Al = 27 0.22 = 5.9 6 g hence 5.96.0% ecf ( 27)
[1]
[1]
[1]
[3]
[Total: 14]
Page 5
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
[1]
[1]
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[1]
phenylamine (less basic) due to lone pair being delocalised into the ring
[1]
[4]
[1]
[1]
[1]
[1]
NH2
[1]
W is
Cl
O
[1]
[6]
[Total: 15]
Page 6
5
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
(a)
OH
CO2H
OH
H2O
Na
H2
H2
H2
H2
KOH(aq)
Na2CO3(aq)
CO2
X
[5]
[1]
[1]
[1]
(iv) reflux
[1]
dilute HCl
[1]
[5]
Page 7
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
(c) (i)
reagent and conditions
product with A
Br
OH
product with B
Br
Br2(aq)
no reaction
C(CH3)3
Br
no reaction
C(CH3)3
no reaction
C(CH3)3
O
no reaction
C(CH3)3
[6]
(ii) either: Cr2O72/H+: no observation with A and goes from orange to green with B.
or:
Br2(aq): white ppt. with A and no observation/ppt with B
[1]
[7]
[Total: 17]
Page 8
6
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
(a)
substance
protein synthesis
adenine
formation of DNA
alanine
aspartate
phosphate
[3]
[3]
[1]
[1]
hydrogen bonds
[1]
[1]
[4]
[1]
DNA :
tertiary :
hydrogen bonds
ionic bonds
disulfide bonds
[2]
[3]
[Total: 10]
Page 9
7
Mark Scheme
GCE A LEVEL May/June 2013
Syllabus
9701
Paper
43
extract DNA
(b)
item for testing
human hair
[3]
[3]
drugs:
gas-liquid
or
thin-layer chromatography
[1]
[1]
[1]
[3]
[Total: 10]
Page 10
8
(a) (i)
Mark Scheme
GCE A LEVEL May/June 2013
CO2H
CH
Syllabus
9701
Paper
43
CO2H
CH2
CH
CH2
[1]
(ii) Addition
[1]
[1]
[3]
(b) (i) more / increase water absorbing properties (allow attracts water more)
[1]
more polar(ity)/more hydrophilic / has ionic side-chains (as well as hydrophilic ones)
(ii) It should be biodegradable/decompose
[1]
[1]
[3]
[1]
[1]
[2]
[1]
[1]
[2]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2014 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
41
Section A
1
A and B
either C or D
C and D
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
(iv) if C is Fe2+; (as [C] increases), the E of the Fe2+ / Fe increases / becomes more positive /
less negative
[1]
so the overall cell potential / Ecell would decrease / become less positive / more
negative
[1]
or
if C is Cu2+; (as [C] increases), the E of the Cu2+/Cu increases / becomes more
positive / less negative
[1]
so the overall cell potential / Ecell would increase / become more positive / less negative
[1]
(c) (i) (colour change is) colourless to pink/pale purple
or (end point is the first) permanent (pale) pink/pale purple colour
(ii) {n(MnO4) = 0.02 18.1/1000 = 3.62 10-4 mol}
n(Fe2+) = 5 n(MnO4) = 1.81 103 mol
[1]
[1]
[1]
[1]
[Total: 16]
(a) (i) A complex is a compound / molecule / species / ion formed by a central metal atom / ion
surrounded by / bonded to one or more ligands / groups/ molecules / anions
[1]
A ligand is a species that contains a lone pair of electrons that forms a dative bond to a
metal atom / ion / or a lone pair donor to metal atom / ion
[1]
Cambridge International Examinations 2014
Page 3
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
41
(ii)
2+
2-
H2O
H2O
Cl
OH2
and
Cu
H2O
Cl
OH2
Cu
Cl
Cl
H2O
correct 3D structures:
octahedral and tetrahedral
[1] + [1]
[1]
(iii)
Cl
Pt
H3N
Cl
Cl
or
NH3
H3N
Pt
NH3
Cl
Cl
Pt
H3N
NH3
Cl
both structures
geometric or cis-trans
(b) (i) Cu(II) is [Ar] 3d9
Cu(I) is [Ar] 3d10
(ii) Cu(II):
NH3
or
Cl
Pt
Cl
NH3
[1]
[1]
[1]
[1]
Cu(I):
[2]
[1]
[2]
[1]
[1]
[Total: 16]
[1]
[1]
Page 4
Mark Scheme
GCE A LEVEL May/June 2014
OH
O
O
Paper
41
OH
trans-cis
Syllabus
9701
cis-trans
O
O
OH
cis-cis
[1]
(iii)
CO2H
+ CO2 or HO2C-CO2H
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
(ii) this is in 30 cm3 of solution, so [HCl] at finish = 0.5 103/0.030 = 1.67 102 mol dm3
pH = log10(1.67 102) = 1.78 ecf from (d)(i)
[1]
(iii) pH / vol curve: start at pH 11.9
vertical portion at V = 15 cm3
levels off at pH 1.8
[1]
[1]
[1]
(iv) indicator is B
[1]
[Total: 16]
(a)
3 [1]
Page 5
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
41
(b) (i)
OH
HO
CH
CN
Compound Z is
HO
[1]
step 1: HCN + NaCN or HCN + base
step 2: H2 + Ni or LiAlH4 or Na + ethanol
[1]
[1]
(ii) bromine decolourises or goes from orange to colourless or white ppt. formed
Br
HO
CHO
e.g.
[1]
(2
or 3
3 xbromines
Br in ring)in ring
2 or
HO
Br
[1]
(c)
O
NaO
OH
NH2
(i)(i)
(or ionic)
NaO
[1]
[1]
[1]
[1]
OH
NH3Cl
HO
NH3
(ii)
(ii)
(or ionic)
HO
OCOCH3
NHCOCH3
CH3COO
(iii)
(iii)
CH3CO2
M1: amide
M2: alcoholic ester
M3: both phenolic esters
(d) amide
ester
[1]
[1]
[1]
[5] max [4]
[1]
[1]
[Total: 14]
Page 6
5
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
41
[1]
[1]
[1]
(b) V is CH3CH(OH)CH=CH2
[1]
W is CH3CH=CHCH2OH
[1]
CH
[1]
CH3
HO
OH
C
H
CH
CH2
[1]
(d)
OH
OH
OH
or
CH3CH(OH)CH(OH)CH2OH
[1]
[Total: 8]
Page 7
6
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
41
(a)
feature
level of bonding
formation of -helix
secondary
tertiary
tertiary
primary
[3]
(b)
block letter
name
Deoxyribose
Cytosine
Phosphate
Thymine
4 [1]
[1]
[1]
(d)
(sugar, J)
(base, M)
DNA
deoxyribose
thymine / T
RNA
ribose
uracil / U
[1]
[Total: 10]
100 2.5
or equivalent
1.1 74
n = 3.1 hence G has three carbon atoms
(a) Expression: n =
[1]
[1]
3 [1]
Page 8
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
41
[1]
[1]
(iii) CH3CH2CO2H
(c) (i)
[1]
O
H3C
HO
O
N
H3C
or
or
H3C
or
CH3 or
OH
C
H
[1]
[1]
[1]
Or if 1, 3-dioxolane: 3.34.0
3.35.0
[1]
[1]
Or if 1, 2-dioxolane: 0.91.4
3.34.0
[1]
[1]
Or if dihydroxycyclopropane: 0.91.4
0.56.0
[1]
[1]
[Total: 11]
[1]
(ii) Hydrolysis
[1]
(iii) Drug B
[1]
[2]
(b) (i) At point Q because the hydrocarbon tails region is hydrophobic/non-polar/ form van der
Waals only
[1]
or can dissolve in the fat-soluble area
(ii) They all contain polar or hydrogen-bonding (groups)
(c) (i) range 1 109 to 1 107 m
(ii) (higher frequency radiation could) cause tissue/cell damage or mutation
or harmful to cells
[1]
[1]
[1]
[Total: 9]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2014 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2
1
(a) (i)
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
4s
3d
4s
4s
or
3d
4s
3d
Fe
Zn2+
Fe2+
[2]
(ii) (colour due to absorbance of visible light)
due to electron promoted (from lower) to upper orbital / energy level
in Zn2+ there's no space in higher orbital for the electron to go or completely
filled d-orbitals / shell
[1]
[1]
4
due to [Cu(H2O)6]2+
[1]
[1]
[1]
[1]
[1]
[1]
[1]
7
[1]
[1]
[1]
3
[Total: 14]
Page 3
2
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
[1]
B: platinum or Pt
[1]
[1]
D: lead (metal) or Pb
[1]
4
[1]
[1]
[1]
[1] +[1]
5
(c) (i) the (M2+ / M) Eo for the two elements are very similar or are 0.13 and 0.14 V
[1]
[1]
[1]
[1]
[1]
5
[1]
[3]
[1]
[1]
6
[Total: 20]
Page 4
3
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
[1] + [1]
(ii) D
[1]
3
[1]
1
[1]
[1]
(ii) [H+] = ([CH3CO2H] Ka) = (0.1 1.75 105) = 1.32(3) 103 (mol dm3)
pH = log10[H+] = 2.88 (2.9)
[1]
[1]
4
[1]
[1]
(iii) [H+] = Kw / [OH] = 1 1014 / 3.33 102 = 3.0 1013 mol dm3
pH = log10[H+] = 12.5(2)
[1]
[1]
[1]
[1]
[1]
[1]
7
[Total: 15]
Page 5
4.
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
[1]
1
(b) Br2 + Al Br3 Br+ + Al Br4 (or can use Al Cl3 or FeCl3 or FeBr3 etc.)
[1]
1
H
CH2
or
CH2
Br
Br
or
[1]
Br
or
Br
Br
etc
[1]
[1]
3
(d)
E is benzoic acid
[1]
[1]
[1]
3
(e)
G is
COCl
[1]
Cl
reaction 4: LiAlH4
[1]
[1]
3
[Total: 11]
Page 6
5.
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
[1]
[1]
2
[1]
1
(c)
CH3CH2CH(OH)CHO
CH3CH(OH)CH2CHO
HOCH2CH2CH2CHO
OH
CHO
CHO
HO
CHO
OH
[1]
[1]
2
OH
CHO
[1]
HO
CHO
[1]
2
[Total: 10]
Page 7
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
Section B
6.
(a) (i)
OH
O
NH2
OH
NH
O
[1]
[1]
[1]
4
(b)
DNA
RNA
Contains deoxyribose
Contains ribose
Contains thymine / T
Contains uracil / U
[1]
[1]
[1]
3
[Total: 10]
Page 8
7
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
(a) (i) (Electrophoresis): the size / shape / Mr of the amino acid or its charge
(ii) (Paper chromatography): the partition of the amino acid between, or the
relative solubility of the compound in, the 2 phases or solvent / water and
stationary phase / filter paper.
Paper
42
[1]
[1]
2
(b)
[1]
1
(c)
[1]
1
(d)
3 [1]
3
(e)
U
3 [1]
3
[Total: 10]
Page 9
8.
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
42
(a) (i) Any addition polymer (e.g. polyethene, polypropene, polystyrene, PVC,
PTFE, PVA, Teflon)
[1]
(ii) Any condensation polymer (e.g. polyamide, polyester, nylon, Terylene, PET,
PLA, Kevlar, Nomex)
[1]
2
(b)
[1]
[1]
2
(c)
O
O
or
O
CH3
CH3
O
O
[1]
[1]
2
(d)
[1]
1
[1]
[1]
[1]
3
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2014 series for most IGCSE, GCE
Advanced Level and Advanced Subsidiary Level components and some Ordinary Level components.
Page 2
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
43
Section A
1
A and B
either C or D
C and D
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
(iv) if C is Fe2+; (as [C] increases), the E of the Fe2+ / Fe increases / becomes more positive /
less negative
[1]
so the overall cell potential / Ecell would decrease / become less positive / more
negative
[1]
or
if C is Cu2+; (as [C] increases), the E of the Cu2+/Cu increases / becomes more
positive / less negative
[1]
so the overall cell potential / Ecell would increase / become more positive / less negative
[1]
(c) (i) (colour change is) colourless to pink/pale purple
or (end point is the first) permanent (pale) pink/pale purple colour
(ii) {n(MnO4) = 0.02 18.1/1000 = 3.62 10-4 mol}
n(Fe2+) = 5 n(MnO4) = 1.81 103 mol
[1]
[1]
[1]
[1]
[Total: 16]
(a) (i) A complex is a compound / molecule / species / ion formed by a central metal atom / ion
surrounded by / bonded to one or more ligands / groups/ molecules / anions
[1]
A ligand is a species that contains a lone pair of electrons that forms a dative bond to a
metal atom / ion / or a lone pair donor to metal atom / ion
[1]
Cambridge International Examinations 2014
Page 3
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
43
(ii)
2+
2-
H2O
H2O
Cl
OH2
and
Cu
H2O
Cl
OH2
Cu
Cl
Cl
H2O
correct 3D structures:
octahedral and tetrahedral
[1] + [1]
[1]
(iii)
Cl
Pt
H3N
Cl
Cl
or
NH3
H3N
Pt
NH3
Cl
Cl
Pt
H3N
NH3
Cl
both structures
geometric or cis-trans
(b) (i) Cu(II) is [Ar] 3d9
Cu(I) is [Ar] 3d10
(ii) Cu(II):
NH3
or
Cl
Pt
Cl
NH3
[1]
[1]
[1]
[1]
Cu(I):
[2]
[1]
[2]
[1]
[1]
[Total: 16]
[1]
[1]
Page 4
Mark Scheme
GCE A LEVEL May/June 2014
OH
O
O
Paper
43
OH
trans-cis
Syllabus
9701
cis-trans
O
O
OH
cis-cis
[1]
(iii)
CO2H
+ CO2 or HO2C-CO2H
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
(ii) this is in 30 cm3 of solution, so [HCl] at finish = 0.5 103/0.030 = 1.67 102 mol dm3
pH = log10(1.67 102) = 1.78 ecf from (d)(i)
[1]
(iii) pH / vol curve: start at pH 11.9
vertical portion at V = 15 cm3
levels off at pH 1.8
[1]
[1]
[1]
(iv) indicator is B
[1]
[Total: 16]
(a)
3 [1]
Page 5
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
43
(b) (i)
OH
HO
CH
CN
Compound Z is
HO
[1]
step 1: HCN + NaCN or HCN + base
step 2: H2 + Ni or LiAlH4 or Na + ethanol
[1]
[1]
(ii) bromine decolourises or goes from orange to colourless or white ppt. formed
Br
HO
CHO
e.g.
[1]
(2
or 3
3 xbromines
Br in ring)in ring
2 or
HO
Br
[1]
(c)
O
NaO
OH
NH2
(i)(i)
(or ionic)
NaO
[1]
[1]
[1]
[1]
OH
NH3Cl
HO
NH3
(ii)
(ii)
(or ionic)
HO
OCOCH3
NHCOCH3
CH3COO
(iii)
(iii)
CH3CO2
M1: amide
M2: alcoholic ester
M3: both phenolic esters
(d) amide
ester
[1]
[1]
[1]
[5] max [4]
[1]
[1]
[Total: 14]
Page 6
5
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
43
[1]
[1]
[1]
(b) V is CH3CH(OH)CH=CH2
[1]
W is CH3CH=CHCH2OH
[1]
CH
[1]
CH3
HO
OH
C
H
CH
CH2
[1]
(d)
OH
OH
OH
or
CH3CH(OH)CH(OH)CH2OH
[1]
[Total: 8]
Page 7
6
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
43
(a)
feature
level of bonding
formation of -helix
secondary
tertiary
tertiary
primary
[3]
(b)
block letter
name
Deoxyribose
Cytosine
Phosphate
Thymine
4 [1]
[1]
[1]
(d)
(sugar, J)
(base, M)
DNA
deoxyribose
thymine / T
RNA
ribose
uracil / U
[1]
[Total: 10]
100 2.5
or equivalent
1.1 74
n = 3.1 hence G has three carbon atoms
(a) Expression: n =
[1]
[1]
3 [1]
Page 8
Mark Scheme
GCE A LEVEL May/June 2014
Syllabus
9701
Paper
43
[1]
[1]
(iii) CH3CH2CO2H
(c) (i)
[1]
O
H3C
HO
O
N
H3C
or
or
H3C
or
CH3 or
OH
C
H
[1]
[1]
[1]
Or if 1, 3-dioxolane: 3.34.0
3.35.0
[1]
[1]
Or if 1, 2-dioxolane: 0.91.4
3.34.0
[1]
[1]
Or if dihydroxycyclopropane: 0.91.4
0.56.0
[1]
[1]
[Total: 11]
[1]
(ii) Hydrolysis
[1]
(iii) Drug B
[1]
[2]
(b) (i) At point Q because the hydrocarbon tails region is hydrophobic/non-polar/ form van der
Waals only
[1]
or can dissolve in the fat-soluble area
(ii) They all contain polar or hydrogen-bonding (groups)
(c) (i) range 1 109 to 1 107 m
(ii) (higher frequency radiation could) cause tissue/cell damage or mutation
or harmful to cells
[1]
[1]
[1]
[Total: 9]
w
ap
eP
e
tr
.X
om
.c
s
er
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2015 series for most
Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page 2
Mark Scheme
Cambridge International A Level May/June 2015
Question
1
(a)
(b) (i)
Syllabus
9701
Marking point
Paper
41
Marks
F2O / OF2
(ii)
bent or non-linear
(ii)
redox
(iii)
(iii)
(c) (i)
[Total: 8]
2
(a) (i)
(ii)
(b) (i)
CH3
NCH2CH3
CH3
P
(ii)
1
[Total: 7]
Page 3
Mark Scheme
Cambridge International A Level May/June 2015
(a) (i)
Syllabus
9701
relative
abundance
isotope
24
7879
25
10
26
1211
Mg
Mg
Mg
Paper
41
(ii)
(iii)
the charge density of the other cations are too small (to polarise the anion
sufficiently so the anion is more stable)
(b) (i)
[Total: 7]
4
(a) (i)
(ii)
(b)
2-
latt
Ag2SO4(s)
hyd
o
sol
2
+
(c) (i)
(ii)
or
2-
1
1
1
1
because the [Ag+(aq)] (in the Ag electrode) is less than 1.0 mol dm3
(iii)
no change
Cambridge International Examinations 2015
Page 4
Mark Scheme
Cambridge International A Level May/June 2015
(iv)
(d)
Syllabus
9701
Paper
41
1
1
[Total: 13]
(a)
14
C2
protons
electrons
neutrons
1
1
(b)
no reaction
CCl4:
GeCl4 and SnCl4: for each steamy fumes evolved or white solid produced
GeCl4 + 2H2O GeO2 + 4HCl
SnCl4 + 2H2O SnO2 + 4HCl
1
1
1
1
(c)
Ge / Sn use dorbitals
or Ge / Sn have low lying d orbitals
or carbon cannot expand its octet
or carbon cannot accommodate more than 4 bonded pairs
(d)
Sn4+ / Sn2+ = +0.15V and Pb4+ / Pb2+ = +1.69 V and Cl2 / Cl = + 1.36 V
F = Le
(e) (i)
(ii)
no. of electrons per mole = 1.35 x 1022 / 2.17 x 102 = 6.2 x 1023 (mol1)
1
[Total: 15]
Page 5
(a) (i)
Mark Scheme
Cambridge International A Level May/June 2015
CH3COCl
Syllabus
9701
or ethanoyl chloride
Paper
41
1
(ii)
electrophilic substitution
(iii)
(iv)
CHI3
(b) (i)
(ii)
polyamide or condensation
(iii)
H2O / water
(iv)
(v)
1
[Total: 10]
Page 6
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
41
1
(ii) B is CH3CH2CH3
(iii) C is CH2=CHCH2CH2CH3
F is CH3CH2CH2CO2H
G is CH3CO2H
H is CH3CH2CO2H
(iv) geometrical or cis-trans or EZ
1
CH3
CH
CH2
CH3
CH
CH2
CH
Br
+ Br
CH2
Br
Br
- Br
Br
1
1
[Total: 10]
(ii)
hydrogen(H) bonding
SS or disulfide bonds or
disulfur bond / bridge
Page 7
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
41
or
in words
the enzyme has a specific shape or substrate shape is complementary to
active site
the substrate bonds / binds / fits to the active site or other substrates do not fit
into active site
1
1
or in words
inhibitor binds to enzyme away from the active site or inhibitor binds to
allosteric site
this changes the shape (or structure) of the active site
substrate no longer fits the active site
1
1
1
[Total: 10]
(iii)
Page 8
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
(iv)
Paper
41
1
(c) (i) equilibrium constant (for the solution) of a solute between two (immiscible)
solvents
1
1
[Total: 10]
(ii) K
since it has the greatest % of hydrocarbons / carbon-containing compounds
or 99.6 % of it is burnt for energy
(iii) any two from
reacted with lime / CaO / soda lime / Ca(OH)2 / KOH / NaOH /
liquefied under pressure / 5 atm
dissolved in water under pressure / 5 atm
(b) (i) have a shorter carbon / hydrocarbon chain or shorter hydrocarbon
or fewer carbon atoms in its chain
or have high H / C ratio
(ii) Coal
1
Cambridge International Examinations 2015
Page 9
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
41
1
[Total: 10]
w
ap
eP
e
tr
.X
om
.c
s
er
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2015 series for most
Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page 2
1
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
42
[1]
sulfur: 1s22s22p63s23p4
(b) (i) 2HCl H2 + Cl2
[1]
[1]
(c) electronegativity:
The attraction by an atom / nucleus / element of the electrons in a bond or a shared
pair or a molecule
bond polarity:
..is due to atoms / elements of different electronegativities at each end of a bond
[2]
(d) (i)
F
[1]
(f) (i) Burning of fossil fuels or coal / oil / petrol / natural gas (NOT methane or hydrocarbons)
or volcanoes or roasting / burning sulfide ores
(ii) Acid rain
[2]
[Total: 11]
Page 3
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
42
[1]
[2]
[3]
1
O2
2
or
3PbO2 Pb3O4 + O2
[Total: 8]
Page 4
(a)
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
33
Paper
42
[2]
[4]
Both lattice energy / Hlatt and enthalpy change of hydration / Hhyd are involved
enthalpy change of hydration decreases more than lattice energy
So enthalpy change of solution / Hsol becomes more endothermic or more
positive or less exothermic or less negative (NOT Hsol decreases, or increases)
(c) precipitate / solid CaSO4 would form
due to the common ion effect or Ksp is exceeded or the following equilibrium
shifted over to the right
Ca2+(aq) + SO42(aq) CaSO4(s)
= 1.8 40 x 60
(= 4320 C)
n(e)
= 4320 / 96500
n(Cr)
= 0.776 / 52
[2]
[4]
[Total: 12]
Page 5
4
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
42
(a) (i) a solution that resists / minimises a change in its pH or helps maintain its pH.....
(NOT any of: "maintains pH"; "keeps pH constant"; "no change in pH")
.....when small amounts of acid / H+ or base / OH are added (both acid and
base are needed)
(ii) HCO3 reacts with H+ ions as follows:
HCO3 + H+ H2CO3 (or H2O + CO2)
[2]
[2]
(the equation arrows can be equilibrium arrows, as long as HCO3 is on the left)
(iii) (pKa = log(Ka) = 7.21)
[2]
and
(c)
[1]
[3]
[2]
Page 6
5
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
42
[1]
(ii)
OH
[1]
(iii) 22 = 4
[1]
(iv)
CH(CH3)2
H
CH(CH3)2
or
OH
OH
2 Hs have to be on the same side of the ring. Allow C3H7 or R for CH(CH3)2
(b) (i)
[1]
[1]
or
N
N
N2
or
N
N
(ii) step 1: conc HNO3 + H2SO4 (@ 25 oC < T < 60 oC see below) ("aq" negates)
step 2: Sn / Fe + HCl
step 3: HNO2 or NaNO2 + HCl (@ T< 10 C see below)
both temperatures correct for steps 1 + 3 (temperature not required for step 2)
(inclusion of the word "heat" or "reflux" in step 3 negates the temperature mark)
(c)
[4]
[5]
HBr
no reaction
Br
Na
ONa
NaOH(aq)
ONa
no reaction
ONa
[Total: 14]
Page 7
6
Mark Scheme
Cambridge International A Level May/June 2015
(a)
Syllabus
9701
Paper
42
There are three acceptable alternatives follow each column down vertically:
(i) D is
RCOCl
RCOOCH2CH3
RCO2 NH4+
(ii) step 1
NH3
(ii) step 2
NH3
(ii) step 3
heat
[1]
[1]
(iii)
[4]
compound
amide
alcohol
amine
carboxylic acid
amine
ester
amide
phenol
(iv) Mark this in the following way. For each structure of E, F, G and H:
[4]
check whether the structure fits the molecular formula C8H9NO2, i.e. that it has: one
nitrogen, two oxygens and eight carbons.
check that it contains the two groups that the candidate's answers to part (ii) says it
contains.
[Total: 13]
Page 8
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
(a) L it is the only compound that is an amino acid or can form (NOT contain)
NHCO / amide / peptide linkages / bonds
or
it contains an N atom / NH2 group / CO2H group
Paper
42
[1]
(b) mark both parts of this together max [4] from the following six points
[4]
M1
mRNA is complementary to or a copy of (a portion of) DNA
M2
mRNA encodes the sequence of amino acids in proteins or each of its
codons (base triplets) codes for one amino acid
M3
mRNA binds to / associates with the ribosome
M4
tRNAs are specific to their amino acids
M5
tRNA contains an anticodon or bonds to the codon / mRNA through base pairing or
translates the RNA code into the amino acid sequence
M6
tRNA carries the amino acid to the ribosome/mRNA
(c) max [3] from the following six points.
M1
the pH of that area of the protein would change
M2
protein becomes less hydrophilic / soluble or more hydrophobic
M3
fewer hydrogen bonds or more van der Waals (idid) forces
M4
fewer ionic bonds form
M5
the tertiary structure / folding / (3D) shape (of the protein) would change
M6
the active site would be different / less efficient
[3]
[Total: 8]
Page 9
8
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
42
[1]
[1]
(iii) S / sulfur it has the greatest number of electrons or highest electron density
[1]
[1]
[2]
[1]
[1]
(v) P is (CH3)3CCH2OH
[1]
(c) (i)
n=
[1]
[1]
[1]
[Total: 12]
Page 10
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
42
(a)
[3]
monomer
addition
condensation
both
[2]
(c) (i)
[1]
O
OH
OH
or
O
Cl
NOT
OH
OH
Cl
(d) Polythene has (weak) van der Waals (or idid) forces
PVC has stronger van der Waals forces or additional dipole forces
Nylon has (strong) hydrogen bonding
[1]
[3]
[Total: 10]
w
ap
eP
e
tr
.X
om
.c
s
er
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the May/June 2015 series for most
Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page 2
Mark Scheme
Cambridge International A Level May/June 2015
Question
1
(a)
(b) (i)
Syllabus
9701
Marking point
Paper
43
Marks
F2O / OF2
(ii)
bent or non-linear
(ii)
redox
(iii)
(iii)
(c) (i)
[Total: 8]
2
(a) (i)
(ii)
(b) (i)
CH3
NCH2CH3
CH3
P
(ii)
1
[Total: 7]
Page 3
Mark Scheme
Cambridge International A Level May/June 2015
(a) (i)
Syllabus
9701
relative
abundance
isotope
24
7879
25
10
26
1211
Mg
Mg
Mg
Paper
43
(ii)
(iii)
the charge density of the other cations are too small (to polarise the anion
sufficiently so the anion is more stable)
(b) (i)
[Total: 7]
4
(a) (i)
(ii)
(b)
2-
latt
Ag2SO4(s)
hyd
o
sol
2
+
(c) (i)
(ii)
or
2-
1
1
1
1
because the [Ag+(aq)] (in the Ag electrode) is less than 1.0 mol dm3
(iii)
no change
Cambridge International Examinations 2015
Page 4
Mark Scheme
Cambridge International A Level May/June 2015
(iv)
(d)
Syllabus
9701
Paper
43
1
1
[Total: 13]
(a)
14
C2
protons
electrons
neutrons
1
1
(b)
no reaction
CCl4:
GeCl4 and SnCl4: for each steamy fumes evolved or white solid produced
GeCl4 + 2H2O GeO2 + 4HCl
SnCl4 + 2H2O SnO2 + 4HCl
1
1
1
1
(c)
Ge / Sn use dorbitals
or Ge / Sn have low lying d orbitals
or carbon cannot expand its octet
or carbon cannot accommodate more than 4 bonded pairs
(d)
Sn4+ / Sn2+ = +0.15V and Pb4+ / Pb2+ = +1.69 V and Cl2 / Cl = + 1.36 V
F = Le
(e) (i)
(ii)
no. of electrons per mole = 1.35 x 1022 / 2.17 x 102 = 6.2 x 1023 (mol1)
1
[Total: 15]
Page 5
(a) (i)
Mark Scheme
Cambridge International A Level May/June 2015
CH3COCl
Syllabus
9701
or ethanoyl chloride
Paper
43
1
(ii)
electrophilic substitution
(iii)
(iv)
CHI3
(b) (i)
(ii)
polyamide or condensation
(iii)
H2O / water
(iv)
(v)
1
[Total: 10]
Page 6
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
43
1
(ii) B is CH3CH2CH3
(iii) C is CH2=CHCH2CH2CH3
F is CH3CH2CH2CO2H
G is CH3CO2H
H is CH3CH2CO2H
(iv) geometrical or cis-trans or EZ
1
CH3
CH
CH2
CH3
CH
CH2
CH
Br
+ Br
CH2
Br
Br
- Br
Br
1
1
[Total: 10]
(ii)
hydrogen(H) bonding
SS or disulfide bonds or
disulfur bond / bridge
Page 7
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
43
or
in words
the enzyme has a specific shape or substrate shape is complementary to
active site
the substrate bonds / binds / fits to the active site or other substrates do not fit
into active site
1
1
or in words
inhibitor binds to enzyme away from the active site or inhibitor binds to
allosteric site
this changes the shape (or structure) of the active site
substrate no longer fits the active site
1
1
1
[Total: 10]
(iii)
Page 8
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
(iv)
Paper
43
1
(c) (i) equilibrium constant (for the solution) of a solute between two (immiscible)
solvents
1
1
[Total: 10]
(ii) K
since it has the greatest % of hydrocarbons / carbon-containing compounds
or 99.6 % of it is burnt for energy
(iii) any two from
reacted with lime / CaO / soda lime / Ca(OH)2 / KOH / NaOH /
liquefied under pressure / 5 atm
dissolved in water under pressure / 5 atm
(b) (i) have a shorter carbon / hydrocarbon chain or shorter hydrocarbon
or fewer carbon atoms in its chain
or have high H / C ratio
(ii) Coal
1
Cambridge International Examinations 2015
Page 9
Mark Scheme
Cambridge International A Level May/June 2015
Syllabus
9701
Paper
43
1
[Total: 10]
ap
eP
e
tr
.X
om
.c
s
er
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and students, to indicate the requirements of the
examination. It shows the basis on which Examiners were initially instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began. Any
substantial changes to the mark scheme that arose from these discussions will be recorded in the published
Report on the Examination.
All Examiners are instructed that alternative correct answers and unexpected approaches in candidates
scripts must be given marks that fairly reflect the relevant knowledge and skills demonstrated.
Mark schemes must be read in conjunction with the question papers and the Report on the Examination.
CIE will not enter into discussion or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the November 2004 question papers for most IGCSE and GCE
Advanced Level syllabuses.
Grade thresholds taken for Syllabus 9701 (Chemistry) in the November 2004 examination.
maximum
mark
available
Component 4
60
44
39
22
The thresholds (minimum marks) for Grades C and D are normally set by dividing the mark
range between the B and the E thresholds into three. For example, if the difference between
the B and the E threshold is 24 marks, the C threshold is set 8 marks below the B threshold
and the D threshold is set another 8 marks down. If dividing the interval by three results in a
fraction of a mark, then the threshold is normally rounded down.
November 2004
GCE A LEVEL
MARK SCHEME
MAXIMUM MARK: 60
SYLLABUS/COMPONENT: 9701/04
CHEMISTRY
Paper 4 (Structured Questions A2 Core)
Page 1
Mark Scheme
A LEVEL NOVEMBER 2004
Syllabus
9701
[1]
Paper
4
[1]
ecf [1]
(iv)
amount of H+ used
= 0.2 x 25/1000
= 0.0050 mol
moles of guanidine
= moles of H+
= 0.0050 mol
[guanidine]
Mr = 8.68/0.147
(b) (i)
7 CaSO4 + 3 Ca(H2PO4)2 + 2 HF
(ii) Mr values:
[1]
[1]
Ca(H2PO4)2
= 234.1,
H2SO4 =
98.0
[1]
234.1 x 3
= 702.3
98 x 7 =
686
both [1]
[1]
4
[1]
[1]
[1]
= 6.9
3
Total 13
[1]
(b)
[1]
[1]
[1]
Page 2
Mark Scheme
A LEVEL NOVEMBER 2004
Syllabus
9701
[1]
ecf [1]
mass of H = 3.6 g
ecf [1]
disadvantages:
Paper
4
2
Total 9
[1]
[1]
[1]
[1]
Total 4
4
(a) an element forming one or more ions with a partially filled/incomplete d-shell
[1]
[1]
[1]
[1]
[1]
(c) ..3d9
(d) (i) an ion formed when a ligand (datively) bonds to a (central metal) cation
[1]
(ii)
[1]
Page 3
Mark Scheme
A LEVEL NOVEMBER 2004
Syllabus
9701
Paper
4
(e) (i) dark/deep/navy/royal/Oxford blue or purple [NOT Prussian blue or lilac or mauve]
[1]
(ii) 4NH3 + [Cu(H2O)6]2+
[Cu(NH3)4(H2O)2]2+ + 4H2O
[Cu(NH3)4]2+ + 6H2O
or
(f) CuCl42- is produced
[1]
[1]
[1]
[1]
3
Total 12
(a) (i) AlCl3/FeCl3/Al/Fe/I2 (+ heat) [aq negates] (N.B. NOT AlBr3 etc.)
[1]
(or names)
(ii) (sun)light/hf/UV (aq negates)
(b) SOCl2/PCl3/PCl5 [aq negates]
[1]
[1]
(or names)
[1]
(ii) (acyl chloride fastest) highly + carbon atom joined to 2 electronegative atoms
or
[1]
(aryl chloride slowest) delocalisation of lone pair over ring stronger C-Cl bond
or
[1]
Page 4
Mark Scheme
A LEVEL NOVEMBER 2004
(d)
C6H5-CO2C6H5
Syllabus
9701
C6H5-CONHCH3
[1]
Paper
4
C6H5-CO2H
[1]
[1]
OR
3
Total 9
6
(a) (i) E
[1]
(ii) CH3CH2CH2CO2-(Na+)
[1]
[1]
[1]
[1]
formulae:
[1]
the alcohol from D has 2 identical groups on its central carbon atom
[1]
4 max 3
Total 6
[1]
Page 5
(b)
Mark Scheme
A LEVEL NOVEMBER 2004
Syllabus
9701
Paper
4
or
or
or
or
or
(c) IV
KMnO4 + heat
[1]
HNO3 + H2SO4
VI
[1]
[1]
[1]
Total 7
w
ap
eP
e
tr
.X
w
om
.c
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and students, to indicate the requirements of the
examination. It shows the basis on which Examiners were initially instructed to award marks. It does
not indicate the details of the discussions that took place at an Examiners meeting before marking
began. Any substantial changes to the mark scheme that arose from these discussions will be
recorded in the published Report on the Examination.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the Report on the
Examination.
s
er
CIE will not enter into discussion or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the November 2005 question papers for most IGCSE and
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
Mark Scheme
GCE A LEVEL November 2005
Syllabus
9701
Paper
4
[1]
[1]
2
(b) (i)
A: platinum
B: H+(aq) or HCl(aq) or H2SO4(aq)
(ignore concentration)
C: voltmeter
D: silver (wire)
4 x [1]
(ii) (As [Ag+] decreases), the potential will decrease/become more negative
[1]
[1]
units [1]
7
(c) (i)
(ii) LE
[1]
(=
-903 kJ mol-1
[2]
[1]
4
(d) more energy needed, since rCl - < rBr- or ionised electron nearer to nucleus
or less shielding etc. or in terms of I.E.(Cl) > I.E.(Br)
1
total: 14
Page 3
Mark Scheme
GCE A LEVEL November 2005
Syllabus
9701
Paper
4
(a) The EMF of a cell made up of the test electrode and a standard hydrogen electrode.
(or the EMF of the electrode compared to the S.H.E.)
[1]
[1]
2
(b) The stronger the halogen is as an oxidising agent, the more positive is its Eo value.
[1]
[1]
[1]
Eo = 1.77 - 0.54 = 1.23 V
(ii)
or
[1]
[1]
[1]
4
Sn + 2I2 SnI4
[1]
[1]
2
total: 10
Page 4
Mark Scheme
GCE A LEVEL November 2005
(a) (i)
Syllabus
9701
Paper
4
[1]
[1]
[1]
[1]
[1]
1
(d) (i)
amphoteric
(ii) e.g.
e.g.
[1]
[1]
[1]
3
total: 13
m.pt./oC
3652
3550
1410
937
232
328
conductivity
2 x 103
1 x 10-15
2 x 10-2
2 x 10-2
9 x 104
5 x 104
Page 5
Mark Scheme
GCE A LEVEL November 2005
Syllabus
9701
(a) HO-C6H4-NH2 + 2AgBr + 2OH- O=C6H4=O + H2O + NH3 + 2Ag + 2Br(or C6H4O2)
(or C6H7NO)
Paper
4
[1]
1
[1]
because the lone pair on N is delocalised over/overlaps with the aryl ring
[1]
2
or
H2N-C6H4-ONa
[1]
F is HO-C6H4NH3+ Cl-
or
HO-C6H4NH3Cl
[1]
G is HO-C6H2Br2-NH2
up to
[1]
3
(d) (i)
[1]
(ii) reduction
[1]
(iii) Sn + HCl(aq)
[1]
3
(e) (i)
phenol, amide
[1] + [1]
[1]
3
total: 12
Page 6
Mark Scheme
GCE A LEVEL November 2005
(a) (i)
Syllabus
9701
Paper
4
addition (polymerisation)
[1]
[1]
2
[1]
1
(c) (i)
HO2CCH2CH2CO2H
(ii) ester
[1]
(accept covalent)
[1]
2
(d) (i)
(ii) H2N-CH2-CH(OH)-CH2-NH2
[1]
or H3N+-CH2-CH(OH)-CH2-NH3+
[1]
HO2C-CH(OH)-CH(OH)-CO2H or -O2C-CH(OH)-CH(OH)-CO2-
[1]
(allow bonus mark if the acid/base forms are consistent with the reagent used for the
hydrolysis)
[1]
4 max 3
(e) (i)
NC-CH2-CO2- K+
(ii) II:
[1]
[1]
[1]
3
total: 11
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and students, to indicate the requirements of the
examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
The grade thresholds for various grades are published in the report on the examination for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2006 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
Mark Scheme
GCE A/AS LEVEL - OCT/NOV 2006
1 (a)
Syllabus
9701
Paper
4
(b)
(c)
(d)
[3]
[2]
(i)
(ii)
square planar (can be read into very clear diagram in (i)) (1)
angles = 90 (1)
[4]
CCl4 does not react or SiCl4 does (or read into an equation) (1)
due to presence of available/low-lying/d-orbitals on Si (1)
SiCl4 + 2H2O SiO2 + 4HCl
(or SiCl4 + 4H2O Si(OH)4 + 4HCl etc: also allow partial hydrolysis) (1)
(e)
[3]
(alternative method:
1.0kg of Pb(C2H5)4 is 3.096 moles (1)
we need 8 x 3.096 = 24.77 moles of Na, which is 569 or 570g) (1)
[3]
[Total: 15]
UCLES 2006
Page 3
Mark Scheme
GCE A/AS LEVEL - OCT/NOV 2006
2 (a)
(i)
(ii)
C13H18O2 (1)
(iii)
Mr = 206
Paper
4
ecf (1)
Syllabus
9701
ecf (1)
(correct ans = (2) marks)
(b)
(i)
(ii)
[7]
pH = 3.0 (1)
(correct ans = (2) marks)
(c)
(i)
[3]
(ii)
(iii)
[6]
[Total: 16 max 15]
UCLES 2006
Page 4
Mark Scheme
GCE A/AS LEVEL - OCT/NOV 2006
3 (a)
(i)
(ii)
Syllabus
9701
Paper
4
[4]
[3]
(CO is poisonous...)
due to complexing/ligand exchange with (Fe of) haemoglobin (1)
(NOT redox involving Fe2+/Fe3+)
stopping O2 being transported around body/in blood/to tissues/from lungs (1)
[2]
[Total: 9 max 8]
UCLES 2006
Page 5
Mark Scheme
GCE A/AS LEVEL - OCT/NOV 2006
4 (a)
(b)
(c)
(i)
light or heat
(ii)
NaOH/KOH/alkali/OH- (1)
in alcohol/ethanol + heat
Syllabus
9701
Paper
4
(iii)
[-CH2CH(C6H5)-]
(iv)
CH2=CHCN
(i)
(ii)
(iii)
C/D is C6H5CO2Na
[5]
[aq or solution or dil etc. needed] (1)
[4]
(i)
Cl
Cl
CH2CH3
(1)
(ii)
(iii)
[3]
[Total: 12]
UCLES 2006
Page 6
Mark Scheme
GCE A/AS LEVEL - OCT/NOV 2006
5 (a)
(i)
(ii)
G is
CH3
Syllabus
9701
Paper
4
NHCOCH3
(1)
H is
Cl
(b)
(iii)
amide
IV:
H+/HCl + NaNO2
[4]
0CT10C
V:
OH
CH3
CH3
(1)
in NaOH(aq) (1)
(c)
[4]
[2]
[Total: 10]
UCLES 2006
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2007 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
1
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
Paper
04
[1]
[1]
[2]
(b) (i) acid strength increases from no. 1 to no. 3 or down the table or as Cls increase
due to the electron-withdrawing effect/electronegativity of chlorine (atoms)
stabilising the anion or weakening the O-H bond NOT H+ more available
(ii) chlorine atom is further away (from O-H) in no. 4, so has less influence
(iii) either: pH = (pKa log10[acid]) or Ka = 10pKa = 1.259 x 103
= (4.9 + 2)
[H+] = (Ka. c) = 3.55 x 104
= 3.4 (allow 3.5)
pH = 3.4
([1] for correct expression & values; [1] for correct working)
[1]
[1]
[1]
[1]
[1]
ecf [1]
[6]
(d)
[1]
[1]
[1]
[1]
NH3-CH(CH3)-CO2
Allow charges on H of H3N, and COO but not C-O-O
ecf [1]
([2] for correct answer)
[5]
correct atoms [1]
correct charges [1]
[2]
[Total: 15]
UCLES 2007
Page 3
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
Paper
04
[1]
[1]
[1]
[1]
[1]
[max 4]
2 x [1]
[1]
[1]
[max 3]
[1]
ecf from Ksp [1]
UCLES 2007
[1]
ecf [1]
[1]
[5]
[Total: 12]
Page 4
3
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
1
1
1
3 or KCrClO3 (scores 2)
[1]
Paper
04
[2]
[1]
[1]
[1]
Eo = 1.36 V
Cl2 + 2e 2 Cl
overall ionic equation:
Cr2O72 + 6Cl + 14H+ 2Cr3+ + 3Cl2 + 7H2O
[1]
[1]
[1]
+
or lower [Cl ] or [H ] will shift equilibrium in eqn to the left hand side
UCLES 2007
[1]
[1]
[6]
[Total: 9]
Page 5
4
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
[1]
[1]
[1]
[3]
Paper
04
[1]
[1]
[3]
[Total: 6]
[1]
[1]
[1]
[1]
(c) (i) (as KMnO4 is added), colour changed (from purple) to colourless NOT pink
or effervescence/bubbles (of O2) are produced
at end-point, change is to (first) pink
(ii) n(MnO4) = 0.02 x 15/1000 = 3 x 104
since H2O2 : MnO4 = 5:2,
n(H2O2) = (5/2) x 3 x 104 = 7.5 x 104 in 25 cm3
[H2O2] = 7.5 x 104 x 1000/25 = 3.0 x 102 mol dm3
UCLES 2007
[1]
[1]
[1]
[1]
[4]
[Total: 6]
Page 6
6
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
Paper
04
(a) (i)
O Na
C is
[1]
2 x [1]
[1]
[1]
OH
[1]
(iv) H3O+ and heat >80 or OH(aq) and heat >80
[1]
[7]
[1]
[1]
[2]
(c) (i)
OH
NO2
D is
[1]
(ii) tin/Fe + HCl NOT LiAlH4
[1]
(iii)
OCOCH 3
NHCOCH 3
2 x [1]
[4]
Cu
H2
N
O
OH2
[1]
[1]
[1]
[3]
[Total: max 15]
UCLES 2007
Page 7
7
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
[1]
[1]
[2]
(c)
Paper
04
[1]
[1]
CO2H
CH3
Cl
G is
reaction I:
reaction II:
reaction III:
reaction IV:
H is
Cl2 + AlCl3/accept other halogen carriers NOT aq, nor u.v.
KMnO4 + H+ NOT HCl nor HNO3
KMnO4 + H+ NOT HCl nor HNO3
Cl2 + AlCl3/accept other halogen carriers NOT aq, nor u.v.
[1] + [1]
both I + IV [1]
both II + III [1]
[4]
[Total: 7]
UCLES 2007
Page 8
8
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
Paper
04
(a) (i) Two interlinked spirals or chains or strands woven round each other
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[1]
[1]
[max 4]
[1]
[2]
[1]
[1]
[1]
[3]
[Total: 11]
UCLES 2007
Page 9
9
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
Paper
04
[1]
[1]
[1]
[3]
[1]
[1]
[1]
[max 2]
0.66 200
66
=
= 4.14 = 4 carbon atoms
14.5 1.1 15.95
Check for 1.1 in divisor, if missing, penalise
n=
[1]
[1]
[1]
[1]
[1]
[5]
[Total: 10]
UCLES 2007
Page 10
Mark Scheme
GCE A/AS LEVEL October/November 2007
Syllabus
9701
10 (a) Iron is higher in the reactivity series than copper (owtte)/allow use of Eo
Cu2+(aq) + Fe(s) Cu(s) + Fe2+(aq)
If conversion to Fe3+ given, Ecell is 0.38
Paper
04
[1]
[1]
[2]
[1]
[1]
[1]
[max 2]
[1]
[1]
7.5 150000
tonnes
1000
or 1,125 tonnes Cu
1125 x 0.6 = 675 tonnes (accept 680)
(ii) 450 x 0.17 = 76.5 tonnes (accept 77)
or 1125 x 0.17 = 191.25 tonnes (accept 191) this is an ecf if 675 not in (i)
(e) Aluminium is too high in the reactivity series/very reactive/aluminium forms
bonds with oxygen which are too strong/aluminium ore doesnt exist as sulphide
/Fe unable to displace Al
UCLES 2007
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[2]
[Total: 9]
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/04
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began.
All Examiners are instructed that alternative correct answers and unexpected approaches in
candidates scripts must be given marks that fairly reflect the relevant knowledge and skills
demonstrated.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2008 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
1
Mark Scheme
GCE A/AS LEVEL October/November 2008
(81Br 81Br+)
(81Br 79Br+)
(79Br 79Br+) ignore missing charges
(81Br+)
(79Br+)
Syllabus
9701
Paper
04
[1]
[1]
[1]
(ii) reaction I:
reaction II:
is
is
is
is
is
is
[1]
[1]
(any one)
[1]
CH2OH+/CH3O+
C2H379Br+
C2H381Br+
C2H379Br2+
ignore missing charges
81
+
79
C2H3 Br Br
6 correct [4]
C2H381Br2+
5 correct [3] etc
[4]
[Total: 13 max 12]
[1]
(b) table:
case
a
b
c
1
1
1
0
2
1
1
1
3
1
2
2
each horizontal row scores [1]
if no marks scored, a correct vertical row can score [1]
[3 max]
[1]
[1]
[1]
[1]
UCLES 2008
Page 3
Mark Scheme
GCE A/AS LEVEL October/November 2008
Syllabus
9701
Paper
04
[1]
[1]
[1]
[Total: 11]
(a) (i) carbonates become more stable down the Group/higher decomposition temperature
cation/M2+ radius/size increases down the group/M2+ charge density decreases
anion/carbonate ion/CO32 suffers less polarisation/distortion
(ii) ionic radii quoted:
Ca2+: 0.099 nm
Zn2+: 0.074 nm
Pb2+: 0.120 nm
[1]
[1]
[1]
[1]
=
=
=
=
[1]
[1]
[1]
[1]
Cu2O5CH2
221
10
[1]
(Mrs) [1]
[1]
[1]
[1]
(v) redox/displacement
[1]
[1]
[1]
[1]
[1]
[Total: 19]
UCLES 2008
Page 4
4
Mark Scheme
GCE A/AS LEVEL October/November 2008
Syllabus
9701
Paper
04
[1]
(ii) 8
[1]
[1]
[1]
=
1400 kJ mol1
=
1220 kJ mol1
H = +180 kJ mol1
1
from eqn in (i) : +90 kJ mol for each C=C formed (could be multiples of 90)
4 350
2 610
[1]
[1]
[Total: 6]
(a) G is 4-nitromethylbenzene
H is 4-nitrophenylethanoic acid
(b) step II:
[1]
[1]
[1]
step III:
(HCN negates)
[1]
step V:
Sn or Fe + HCl (+ heat)
[1]
[Total: 5]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[Total: 8]
UCLES 2008
Page 5
7
Mark Scheme
GCE A/AS LEVEL October/November 2008
Syllabus
9701
Paper
04
[1]
(b) diagram of at least two amino acids joining by the loss of water
at least one peptide bond drawn out in full
correct formula of the tripeptide
[1]
[1]
[1]
[1]
[1]
[1]
(ii) Mr
[1]
[1]
= 3 75 + 2 89 + 2 165 6 18
= 625
(allow [1] for Mr = 733)
(also ecf from (i))
[Total: 9]
8
(a) (i)
dotted line
must start and end
at same points
[1]
[1]
[1]
(b) (i) competitive inhibitor resembles the substrate OR competes for the active site of the
enzyme
[1]
non-competitive inhibitor can bind to a different site on the enzyme OR forms a covalent
bond/bonds permanently with the enzyme
[1]
UCLES 2008
Page 6
Mark Scheme
GCE A/AS LEVEL October/November 2008
Syllabus
9701
Paper
04
(ii)
mark for each line NB lines must cross to score mark for II
[2 1]
[1]
[1]
[1]
[Total: 10]
[1]
[1]
[1]
(b) (i) NMR can be done in solution / in vivo / shows labile protons / shows positions of protons
and/or carbon atoms
[1]
X-ray crystallography shows the positions of most atoms in structure / allows
measurement of bond length
[1]
(ii) different types of tissue have protons in different chemical environments / tumour and
healthy tissue absorb differently / allow at different frequencies
[1]
(c) (i) M : M+1 = 48 : 1.7
x = 100 1.7 = 3.2 hence there are 3 carbon atoms in the compound
1.1 48
NB if calculation shown 1.1 divisor MUST be present
[1]
since the compound has an m/e of 73 and contains 3 carbon atoms, 1 nitrogen atom and
1 oxygen atom, y = 73(36 +14+16) = 7
[1]
(ii) the NMR spectrum shows a quartet, triplet pattern characteristic of an ethyl group
the other broad peak must be due to NH protons
thus the structure of the compound is likely to be
CH3CH2CONH2
[1]
[1]
[1]
Page 7
Mark Scheme
GCE A/AS LEVEL October/November 2008
Syllabus
9701
Paper
04
[1]
[1]
(ii) spider silk is more elastic/flexible/less rigid than silkworm silk/has a lower density
silkworm silk absorbs water more easily
[1]
[1]
[1]
[1]
[1]
(iii) 3 from:
addition polymers have a limited range of bonds/monomers
[1]
addition polymers are non-polar/have fewer/no H-bonds
[1]
condensation polymers/proteins have a range of combinations of amino acids which give
a wide range of properties
[1]
condensation polymers/proteins have more functional groups/sidechains
[1]
different sequences of amino acids result in different 2/3 structure
[1]
[Total: 12 max 10]
UCLES 2008
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2009 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
Syllabus
9701
Paper
41
(a) CO2 is a gas (at room temperature); SiO2 is a high melting solid
CO2: simple / discrete molecular / covalent
SiO2: giant covalent or macromolecular / giant molecular
[1]
[1]
[1]
[3]
any two
[1]
[1]
[2]
[1]
[1]
[2]
[1]
[1]
[1]
use of the 5/2 ratio
correct rest of working
[1]
[1]
[1]
[1]
[1]
[8]
[1]
ecf
ecf
[1]
[1]
ecf
[1]
[4]
[Total: 19]
UCLES 2009
Page 3
Syllabus
9701
Paper
41
[1]
[1]
(b) CaF2 and CaS both have larger lattice energies (than CaCl2)
[1]
[1]
[1]
[3]
(d) (i) Ca
C
H
O
=
=
=
=
28.2/40.1
25.2/12
1.4/1
45.1/16
=
=
=
=
0.703
2.10
1.4
2.82
1
3
2
4
signs
[3]
[3]
formula is CaC3H2O4
(ii) malonic acid must be C2H4O4, i.e. CH3(CO2H)2
(1)
[2]
(must be structural)
[1]
[3]
[Total: 10]
any 3 points
[3]
[3]
[1]
[1]
[1]
[1]
[1]
[1]
[6]
[1] + [1]
[1]
[3]
[Total: 12]
UCLES 2009
Page 4
4
Syllabus
9701
Paper
41
[1]
[1]
[2]
[1]
[1]
[2]
(c)
reagent
Na(s)
RONa or RONa+
ArONa or ArONa+
NaOH(aq)
no reaction
ArONa or ArONa+
Br2(aq)
no reaction
tribromophenol
I2(aq) + OH(aq)
no reaction
no reaction
cyclohexanone
no reaction
Cr2O72 + H+:
[1]
[1]
[2]
[Total: 13]
UCLES 2009
Page 5
5
Syllabus
9701
(a) (i) I:
KMnO4
heat with H+ or OH
II: SOCl2 or PCl5 or PCl3
(NOT aq)
(ii) -[-CO-C6H4-CO-NH-C6H4-NH-]-
(ii) HOCH2CH2O-CO-C6H4-CO-OCH2CH2OH
or the polymer -[- OCH2CH2O-CO-C6H4-CO-]-
(d) I:
Paper
41
[1]
[1]
[1]
[1]
[4]
[1] + [1]
for [1]
for [2]
[4 max 3]
[1] + [1]
[1]
[3]
[1]
[1]
[1]
[1]
[4]
(e) (i) A species having positive and negative ionic centres / charges, with no overall charge [1]
(ii) -O2C-C6H4-NH3+
[1]
[2]
[Total: 16]
UCLES 2009
Page 6
6
Syllabus
9701
Paper
41
(2)
(1)
(1)
[3]
(1)
(1)
(1)
(1)
(1)
[5]
(1)
(1)
(1)
(1) [Max 3]
[Total: 12 max 11]
UCLES 2009
Page 7
7
Syllabus
9701
Paper
41
(1)
(1)
(b) X-ray crystallography can show the geometry of the arrangement of atoms /
bonding between atoms / shape of atoms
(1)
This can help explain how e.g. enzymes work (any reasonable example)
(1)
[2]
[2]
(1)
100 2
= 7
1.1 25
(1)
(1)
(1)
(1)
(1)
(x = 7,) y = 8, z = 2
(1)
Compound is 4-methoxylphenol
(1)
Max 5
Then x =
[6]
[Total: 10]
UCLES 2009
Page 8
8
Syllabus
9701
Paper
41
(1)
(1)
(c) The lengths of nanotubes are much shorter than the curvature of the paper /
they are so small that they are not effected by rolling
(1)
(d) Any molten ionic salt (or plausible organic ionic compounds)
(1)
[Total: 4]
(1)
(1)
(1)
(1)
(1)
[Total: 5]
UCLES 2009
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2009 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
1
Syllabus
9701
Paper
42
[1]
[1]
[1]
[3]
(b) (i) n(CO) = pV/RT = 1.01 105 140 103/(8.31 450) = 3.78
or
[1]
[1]
(iii) Mr = 233,
so 0.945 mol = 0.945 233 = 220g 100 220/250 = 88(.07)%
(or 0.9475 mol 220.8g 88(.3)%)
If RTP used answer is 90(.0)%
[1]
[1]
[4]
(c) (i) from data booklet, 1st IE = 502; 2nd IE = 966; sum = 1468 kJ mol1
so 460 = 1468 + 180 + 279 200 + 640 + LE
460 = 2367 + LE
LE = 2827 kJ mol1
( 1 for each error)
(ii) LE of BaS should be smaller than that of BaO, since S2 is bigger than O2.
[3]
[1]
[4]
[Total: 11]
UCLES 2009
Page 3
2
Syllabus
9701
Paper
42
[1]
in ethylamine, the alkyl group donates electrons to the N, making lone pair more available [1]
in phenylamine, the lone pair is delocalised over the ring, so is less available
[1]
[3]
(b)
halide
observation when
AgNO3(aq) is
added
observation when
dilute NH3(aq) is
added
observation when
concentrated
NH3(aq) is added
chloride
white ppt
dissolves
dissolves
[1]
bromide
cream ppt
no reaction /
slightly dissolves
dissolves
[1]
iodide
no reaction
no reaction
[1]
[3]
(c) (i) [Ag+(aq)] = Ksp = (5 1013) = 7.1 (7.07) 107 mol dm3
[1]
(ii) AgBr will be less soluble in KBr, due to common ion effect or equilibrium is shifted to
the left / or by Le Chateliers principle
[1]
[2]
(d) (i) Kc = [Ag(RNH2)2+]/[Ag+][RNH2]2
units are mol2 dm6
[1]
[1]
(ii) assume that most of the Ag+(aq) has gone to the complex, then
[Ag+(aq)] = 7.1 107
[Ag(NH3)2+] = 0.1
and [NH3] = {[Ag(NH3)2+]/(Kc[Ag+])} = {0.1/(1.7 107 7.1 107)}
= 0.091 mol dm3
[1]
[1]
(iii) When R = C2H5, Kc is likely to be greater, since the ethyl group will cause the lone pair
on N to be more available / nucleophilic / increases basicity
[1]
[5]
[Total: 13]
UCLES 2009
Page 4
3
Syllabus
9701
Paper
42
[1] + [1]
[2]
[1]
method: Take a known volume of Fe2+(aq)/in a pipette and place in (conical) flask
Add an excess of (dil) H2SO4
Titrate until end point is reached and note volume used
End point is first permanent pink colour
Repeat titration & take average of consistent readings
any 3 points
+7
+4
+2
[2]
+6
[1]
+6
+4
+3
[3]
[4]
[2]
+5
[1]
([2] marks for each equation: [1] for balancing of redox species,
[1] for total balancing: i.e. H2O and H+)
[6]
(d) Fe3+ is a homogeneous (catalyst)
Fe3+ oxidised I (and is reduced to Fe2+)
Fe2+ reduces S2O82 (and is oxidised to Fe3+)
or equations showing this
[2]
[2]
[Total: 14]
UCLES 2009
Page 5
4
Syllabus
9701
Paper
42
[1]
[1]
[2]
(b) HCl: nothing happens AND HI: purple fumes (at a low temperature)
purple is iodine formed (or in an equation: 2HI H2 + I2)
H-X bond energy becomes smaller/weaker down the group
[1]
[1]
[1]
[3]
[2]
[2]
[Total: 7]
(a)
compound
B
C
all 5 correct
[3]
(4 correct: [2], 3 correct: [1]. <3 correct: [0])
[3]
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[1]
[1]
[6]
[Total: 11]
UCLES 2009
Page 6
6
(a) L
M
N
Q
P
J
K
is
is
is
is
is
is
is
Syllabus
9701
CH3CH2Br
CH3CO2H
CH3CH2NH2
CH3CH2CO2H
CH3CH2CH2NH2
CH3CH2CONHCH2CH3
CH3CONHCH2CH2CH3
Paper
42
[7]
[7]
[1]
[1]
[1]
[3]
[1]
[1]
[2]
[1]
(ii) amine
[1]
[2]
[Total: 14]
(a) Primary:
[1]
[1]
Secondary:
[1]
[1]
Tertiary:
[1]
[max 6]
[1]
[1]
[2]
[1]
[1]
[2]
[Total: 10]
UCLES 2009
Page 7
8
Syllabus
9701
Paper
42
(a) Ratio of the concentrations of a solute / distribution of solute [1] in two immiscible liquids
(b) Kc =
[pesticide in hexane]
[pesticide in hexane]
hence 8.0 =
[pesticide in water]
0.0050 - [pesticide in hexane]
[1]
[2]
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[1]
[1]
(iii) Allow : pollution control / environmental legislation / removal of dioxins and furans /
mill closed down (owtte)
[1]
(iv) Five
[1]
[4]
[Total: 11]
UCLES 2009
Page 8
9
nanosphere diameter
1
Syllabus
9701
Paper
42
cell diameter
2
Both marks for correct sequence, [1] for cell smaller than DNA
[2]
(b) (i) Gaps in structure of shaft much smaller, hence less prone to fracture / more flexible
[1]
(ii) Composites and carbon nanotubes less dense than metal (of comparable strength)
[1]
[2]
[1]
[1]
(iii) Very much larger surface area means they dissolve more readily
[1]
[3]
[Total: 9]
UCLES 2009
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2010 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
Syllabus
9701
Paper
41
[2]
= 264 kJ mol1
= 244 kJ mol1
= 250 kJ mol1
[2]
[7]
[Total: 11]
(a) (i) A ligand is a species that contains a lone pair of electrons, or that can form a
dative bond (to a transition element) (1)
(ii)
species
OH
NH4+
CH3OH
CH3NH2
can be a ligand
cannot be a ligand
(4 )
[3]
[5]
[3]
[Total: 11 max 10]
UCLES 2010
Page 3
Syllabus
9701
Paper
41
[2]
[Total: 13]
4
[2]
Page 4
5
Syllabus
9701
Paper
41
[7]
(b) (i) compounds that have the same molecular formula, but different structures (1)
(ii) phenol (NOT hydroxy) (1)
(methyl) ketone or carbonyl (1)
(iii) K is 4-ethanoylphenol, HO-C6H4-COCH3 (must be 1,4- disubstituted isomer) (1)
(iv)
I2 + NaOH(aq)
NaOH(aq)
Br2(aq)
CO2
Br
OH
Br
COCH3
(2 Br needed)
COCH3
(anion needed)
[4]
[8 max 7]
[Total: 14]
UCLES 2010
Page 5
6
(a)
Syllabus
9701
Paper
41
(1) for each centre more than 2 centres shown deduct 1 mark
[2]
M (1)
L (1)
(+)
H
(-)
Cl
H
+
[3]
H
Cl
Cl
[3]
[Total: 12]
UCLES 2010
Page 6
7
Syllabus
9701
Paper
41
[3]
[3]
[Total: 10]
[4]
0.6 100
= 3 (1)
17.6 1.1
Y is CH3 C CH3
OH
(1)
(iv) All of the protons in Z are in the same chemical environment (1)
UCLES 2010
Page 7
9
Syllabus
9701
Paper
41
[4]
(b) More hydrogen can be packed into the same space/volume (1)
[1]
(c) If a system at equilibrium is disturbed, the equilibrium moves in the direction which tends to
reduce the disturbance (owtte) (1)
When H2 is removed the pressure drops and more H2 is released from that adsorbed (1)
The equilibrium H2adsorbed
H2gaseous (1)
[4]
[Total: 9]
UCLES 2010
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2010 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
Syllabus
9701
Paper
42
[2]
= 264 kJ mol1
= 244 kJ mol1
= 250 kJ mol1
[2]
[7]
[Total: 11]
(a) (i) A ligand is a species that contains a lone pair of electrons, or that can form a
dative bond (to a transition element) (1)
(ii)
species
OH
NH4+
CH3OH
CH3NH2
can be a ligand
cannot be a ligand
(4 )
[3]
[5]
[3]
[Total: 11 max 10]
UCLES 2010
Page 3
Syllabus
9701
Paper
42
[2]
[Total: 13]
4
[2]
Page 4
5
Syllabus
9701
Paper
42
[7]
(b) (i) compounds that have the same molecular formula, but different structures (1)
(ii) phenol (NOT hydroxy) (1)
(methyl) ketone or carbonyl (1)
(iii) K is 4-ethanoylphenol, HO-C6H4-COCH3 (must be 1,4- disubstituted isomer) (1)
(iv)
I2 + NaOH(aq)
NaOH(aq)
Br2(aq)
CO2
Br
OH
Br
COCH3
(2 Br needed)
COCH3
(anion needed)
[4]
[8 max 7]
[Total: 14]
UCLES 2010
Page 5
6
(a)
Syllabus
9701
Paper
42
(1) for each centre more than 2 centres shown deduct 1 mark
[2]
M (1)
L (1)
(+)
H
(-)
Cl
H
+
[3]
H
Cl
Cl
[3]
[Total: 12]
UCLES 2010
Page 6
7
Syllabus
9701
Paper
42
[3]
[3]
[Total: 10]
[4]
0.6 100
= 3 (1)
17.6 1.1
Y is CH3 C CH3
OH
(1)
(iv) All of the protons in Z are in the same chemical environment (1)
UCLES 2010
Page 7
9
Syllabus
9701
Paper
42
[4]
(b) More hydrogen can be packed into the same space/volume (1)
[1]
(c) If a system at equilibrium is disturbed, the equilibrium moves in the direction which tends to
reduce the disturbance (owtte) (1)
When H2 is removed the pressure drops and more H2 is released from that adsorbed (1)
The equilibrium H2adsorbed
H2gaseous (1)
[4]
[Total: 9]
UCLES 2010
w
ap
eP
e
tr
.X
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
CIE will not enter into discussions or correspondence in connection with these mark schemes.
CIE is publishing the mark schemes for the October/November 2010 question papers for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
om
.c
s
er
Page 2
Syllabus
9701
Paper
43
(a) (i) P2O5 + 3H2O 2H3PO4 (or similar) or P4O10 + 6H2O 4H3PO4 (1)
SO2 + H2O H2SO3 (1)
(ii) 2NO2 + H2O HNO2 + HNO3 (1)
(iii) 2ClO2 + 2NaOH NaClO2 + NaClO3 + H2O or ionic eqn (1)
[4]
[8]
[Total: 12]
2
[3]
[max 3]
[3]
[Total: 9]
UCLES 2010
Page 3
3
Syllabus
9701
Br2(aq) (1)
NaOH(aq) (1)
FeCl3(aq) (1)
Cr2O72/H+ (1)
Lucas test or ZnCl2/HCl (1)
2,4-DNPH/Bradys reagent (1)
Paper
43
[2]
[6]
[Total: 8]
reaction I:
reaction II:
reaction III:
reaction IV:
reaction V:
reaction VI:
reaction VII:
XXisis
N
OH
UCLES 2010
Page 4
Syllabus
9701
Paper
43
[2]
UCLES 2010
Page 5
6
Syllabus
9701
Paper
43
(a) (i) Br2 (ignore solvent, but do not credit AlCl3 or HCl or light) (1)
(ii) curly arrow from C=C to Br (1)
another one breaking Br-Br bond. (1)
correct intermediate cation and Br produced (not Br) (1)
[max 3]
[2]
[1]
[2]
[2]
[Total: 13]
[2]
[2]
[Total: 4]
UCLES 2010
Page 6
8
Syllabus
9701
Paper
43
(a) (i) diagram to show tetrahedral arrangement (3D or bond angle marked) (1)
(ii) 4 covalent bonds/bond pairs (with Cl) only or no lone pairs. (1)
[2]
[3]
[Total: 5]
[1]
[4]
all three correct (2)
(mRNA first allow 1 mark)
[2]
[4]
[Total: 11]
UCLES 2010
Page 7
Syllabus
9701
Paper
43
10 (a) (i) Partition substance is distributed between the stationary and mobile phase
or has different solubility in each phase (1)
Adsorption substances form bonds of varying strength with or are attracted to
or are held on to stationary phase. (1)
(ii)
Technique
Separation method
Paper chromatography
Partition
Thin-layer chromatography
Adsorption
Gas/liquid chromatography
Partition
3 correct (2)
2 correct (1)
(iii) %X = 44% (2) %; %Y = 56% (2%) (1)
[5]
(b) (i) They are largely composed of (carbon and) hydrogen which are active in the NMR
(owtte) or protons/H+/H exist in different chemical environments (with characteristic
absorptions) (1)
(ii) 2 correct displayed formulae (1)
In propanone all the protons are in a similar chemical environment (and hence there will
be one proton peak.) (1)
In propanal there are (three) different chemical environments and hence there will be
(three) proton peaks or three different chemical environments or three proton peaks (1)
[4]
[Total: 9]
UCLES 2010
Page 8
Syllabus
9701
Paper
43
[2]
(b)
[2]
(c) (i) Must not react with the drug or must not breakdown too easily/quickly (1)
(ii) The swelling/hydrolysis would begin in the stomach (and the drug would be released too
soon) or stomach is acidic or has low pH (1)
[2]
(d) Addition, condensation (1)
Suitable equation for addition (1)
Suitable equation for condensation (1)
(Addition equation must show polymeristion and balance allow nX X2n or Xn or Xn/2)
(Condensation can be simple reaction e.g. to single ester or amide but must balance
2 products)
(If polymerisation RHS must show a repeat unit but can leave out other product HCl etc.)
[3]
(e) Hydrolysis (1)
[1]
[Total: 11]
UCLES 2010
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
Syllabus
9701
Paper
41
(a) (i) either burn or shine light/uv on mixture of H2 + Cl2 but NOT heat
[1]
[2]
Cl-Cl = 244
= 182 kJ mol1
H-Cl = 431
Br-Br = 193
[2]
H-Br = 366
= 103 kJ mol1
[2]
(iv) H-Br bond is weaker than the H-Cl bond allow converse.
[1]
[8]
[1]
[2]
(iii) The overall reaction is endothermic or no strong bonds/only weak bonds are
formed or high Eact
(c) (i) homolytic fission is the breaking of a bond to form (two) radicals/neutral species/
odd-electron species
(ii) CH2Cl
the C-Br bond is the weakest or needs least energy to break/breaks most easily
(d)
Cl
Cl
Cl
Cl
Cl
Cl
Cl
[1]
[4]
[1]
[1]
[1]
[3]
Cl
4 structures: [2]
2 or 3 structures: [1]
Correct chiral atom identified
[1]
[3]
[Total: 18]
Page 3
2
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[1]
[1]
[6]
(b)
[CH3CHO]
/mol dm3
[CH3OH]
/mol dm3
[H+]
/mol dm3
[acetal A]
/mol dm3
[H2O]
/mol dm3
at start
0.20
0.10
0.05
0.00
0.00
at equilibrium
(0.20 x)
(0.10 2x)
0.05
at equilibrium
0.175
0.05
0.05
0.025
0.025
3 x [1]
4 x [1]
[1]
[1]
[1]
[max 9]
[Total: 15]
Page 4
Syllabus
9701
Paper
41
dxy
energy
[1]
3-
O
O
[1]
[1]
[7]
[1]
(iii)
[1]
[1]
[1]
O
Fe
O
O
O
O
[2]
[2]
[max 5]
[Total: 14]
Page 5
Syllabus
9701
Paper
41
[1]
(ii)
most basic
ethylamine
least basic
ammonia
phenylamine
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[1]
[1]
[5]
[1]
(ii)
reaction
reagent(s)
Step 1
NaNO2 + HCl
or HNO2 [1]
Step 2
H2O / aq
Step 3
HNO3
NB HNO3(aq) OK for both
conditions
T < 10C
heat/boil/T > 10
dilute
[1]
(both) [1]
(both) [1]
[4]
[5]
[Total: 14]
Page 6
5
Syllabus
9701
Paper
41
(b)
4 [1]
[4]
O
CO2H
O
D
D
E
E
2 [1]
[2]
(c) isomers of C
OH
OH
cis
cis
trans
trans
[1]
[1]
[1]
[3]
[Total: 9]
Page 7
Syllabus
9701
Paper
41
[1]
[1]
[2]
[1]
[1]
type of bonding
HNCH(CH2CH2CH2CH2NH2)CO
HNCH(CH2CH2CO2H)CO
HNCH(CH3)CO
HNCH(CH3)CO
HNCH(CH2SH)CO
HNCH(CH2SH)CO
Disulfide bonds
HNCH(CH2OH)CO
HNCH(CH2CO2H)CO
Hydrogen bonds
[4]
[Total: 10]
Page 8
7
Syllabus
9701
Paper
41
(a) Sketch and label the apparatus used to carry out electrophoresis e.g
Marks: power supply / electrolyte + filter paper / buffer / acid mixture central
(c) (i) They have insufficient electron density / only one electron
(ii) Sulfur
because it has the greatest atomic number / number of electrons
4 [1]
[4]
[1]
[1]
[1]
[1]
[1]
[1]
(max 3)
[max 3]
[1]
[1]
[1]
[3]
[Total: 10]
Page 9
8
Syllabus
9701
Paper
41
(a)
traditional material
Paper/cardboard/wood/leaves
hessian/hemp/jute
steel/aluminium
PVC in packaging
Cotton/wool/linen
Terylene in fabrics
Glass/china/porcelain/earthenware
metal/leather
Polycarbonate bottle
3 2 marks, 2 1 mark
[2]
(b) Reasons: Plastics/polymers pollute the environment for a long time do not decompose/
biodegrade quickly
[1]
They are mainly produced from oil
[1]
Produce toxic gases on burning
[1]
max two
Strategy 1: Recycle polymer waste / use renewable resources
Strategy 2: Develop biodegradable polymers
(c) PVC
Combustion would produce HCl / dioxins as a pollutant
or
nylon/acrylic
Combustion would produce HCN
[1]
[1]
[max 3]
[1]
[1]
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
Syllabus
9701
Paper
42
(a) (i) either burn or shine light/uv on mixture of H2 + Cl2 but NOT heat
[1]
[2]
Cl-Cl = 244
= 182 kJ mol1
H-Cl = 431
Br-Br = 193
[2]
H-Br = 366
= 103 kJ mol1
[2]
(iv) H-Br bond is weaker than the H-Cl bond allow converse.
[1]
[8]
[1]
[2]
(iii) The overall reaction is endothermic or no strong bonds/only weak bonds are
formed or high Eact
(c) (i) homolytic fission is the breaking of a bond to form (two) radicals/neutral species/
odd-electron species
(ii) CH2Cl
the C-Br bond is the weakest or needs least energy to break/breaks most easily
(d)
Cl
Cl
Cl
Cl
Cl
Cl
Cl
[1]
[4]
[1]
[1]
[1]
[3]
Cl
4 structures: [2]
2 or 3 structures: [1]
Correct chiral atom identified
[1]
[3]
[Total: 18]
Page 3
2
Syllabus
9701
Paper
42
[1]
[1]
[1]
[1]
[1]
[1]
[6]
(b)
[CH3CHO]
/mol dm3
[CH3OH]
/mol dm3
[H+]
/mol dm3
[acetal A]
/mol dm3
[H2O]
/mol dm3
at start
0.20
0.10
0.05
0.00
0.00
at equilibrium
(0.20 x)
(0.10 2x)
0.05
at equilibrium
0.175
0.05
0.05
0.025
0.025
3 x [1]
4 x [1]
[1]
[1]
[1]
[max 9]
[Total: 15]
Page 4
Syllabus
9701
Paper
42
dxy
energy
[1]
3-
O
O
[1]
[1]
[7]
[1]
(iii)
[1]
[1]
[1]
O
Fe
O
O
O
O
[2]
[2]
[max 5]
[Total: 14]
Page 5
Syllabus
9701
Paper
42
[1]
(ii)
most basic
ethylamine
least basic
ammonia
phenylamine
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[1]
[1]
[5]
[1]
(ii)
reaction
reagent(s)
Step 1
NaNO2 + HCl
or HNO2 [1]
Step 2
H2O / aq
Step 3
HNO3
NB HNO3(aq) OK for both
conditions
T < 10C
heat/boil/T > 10
dilute
[1]
(both) [1]
(both) [1]
[4]
[5]
[Total: 14]
Page 6
5
Syllabus
9701
Paper
42
(b)
4 [1]
[4]
O
CO2H
O
D
D
E
E
2 [1]
[2]
(c) isomers of C
OH
OH
cis
cis
trans
trans
[1]
[1]
[1]
[3]
[Total: 9]
Page 7
Syllabus
9701
Paper
42
[1]
[1]
[2]
[1]
[1]
type of bonding
HNCH(CH2CH2CH2CH2NH2)CO
HNCH(CH2CH2CO2H)CO
HNCH(CH3)CO
HNCH(CH3)CO
HNCH(CH2SH)CO
HNCH(CH2SH)CO
Disulfide bonds
HNCH(CH2OH)CO
HNCH(CH2CO2H)CO
Hydrogen bonds
[4]
[Total: 10]
Page 8
7
Syllabus
9701
Paper
42
(a) Sketch and label the apparatus used to carry out electrophoresis e.g
Marks: power supply / electrolyte + filter paper / buffer / acid mixture central
(c) (i) They have insufficient electron density / only one electron
(ii) Sulfur
because it has the greatest atomic number / number of electrons
4 [1]
[4]
[1]
[1]
[1]
[1]
[1]
[1]
(max 3)
[max 3]
[1]
[1]
[1]
[3]
[Total: 10]
Page 9
8
Syllabus
9701
Paper
42
(a)
traditional material
Paper/cardboard/wood/leaves
hessian/hemp/jute
steel/aluminium
PVC in packaging
Cotton/wool/linen
Terylene in fabrics
Glass/china/porcelain/earthenware
metal/leather
Polycarbonate bottle
3 2 marks, 2 1 mark
[2]
(b) Reasons: Plastics/polymers pollute the environment for a long time do not decompose/
biodegrade quickly
[1]
They are mainly produced from oil
[1]
Produce toxic gases on burning
[1]
max two
Strategy 1: Recycle polymer waste / use renewable resources
Strategy 2: Develop biodegradable polymers
(c) PVC
Combustion would produce HCl / dioxins as a pollutant
or
nylon/acrylic
Combustion would produce HCN
[1]
[1]
[max 3]
[1]
[1]
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes must be read in conjunction with the question papers and the report on the
examination.
Cambridge will not enter into discussions or correspondence in connection with these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2011 question papers for most
IGCSE, GCE Advanced Level and Advanced Subsidiary Level syllabuses and some Ordinary Level
syllabuses.
Page 2
1
(a) Cr3+:
Mn2+:
Syllabus
9701
Paper
43
[1]
[1]
[2]
[1]
[1]
[4]
[1]
[1]
[1]
(ii) No effect, because H+ does not appear in the overall equation or its effect on the
MnO2/Mn2+ change is cancelled out by its effect on the SO2/SO42 change
[1]
[4]
(d) (i) MnO2 + 4H+ + Sn2+ Mn2+ + 2H2O + Sn4+
(ii) n(MnO4) = 0.02 18.1/1000 = 3.62 104 mol
n(Sn2+) = 3.62 104 5/2 = 9.05 104 mol
n(Sn2+) that reacted with MnO2 = (20 9.05) 104 = 1.095 103 mol
reaction is 1:1, so this is also n(MnO2)
mass of MnO2 = 1.095 103 (54.9+16+16) = 0.0952 g
95% 96%; 2 or more s.f.
[1]
[1]
[1]
[1]
[1]
[1]
[6]
[Total: 16]
Page 3
2
Syllabus
9701
Paper
43
(a) (i) A molecule/ion/species with a lone pair (of electrons) or electron pair donor...
.... that bonds to a metal ion/transition element....
[1]
[1]
[2]
(b) (i) straight line from (0, 0.01) to point at (350, 0.0028) with all points on the line
[1]
[1]
[1]
either rate0 = 0.01/1020 = 9.8 106 mol sec1 when [Cr(CO)6] = 0.01 mol dm3
so k = 9.8 106/0.01 = 9.8 104
or t1/2 700 sec
k = 0.693/700 = 9.9 104
(iv) (units of k are) sec1
[1]
(v) N.B. the chosen mechanism must be consistent with the rate equation in (iii). Thus:
either if rate = k[Cr(CO)6]
mechanism B is consistent
[1]
because its the only mechanism that does NOT involve PR3 in its slow/rate-determining
step or only Cr(CO)6 is involved in slow step or [PR3] does not affect the rate
[1]
or
if rate = k[Cr(CO)6][PR3], then
mechanism A or C or D is consistent
because both reactants are involved in slow step
[1]
[1]
[9]
[Total: 11]
Page 4
3
Syllabus
9701
Paper
43
[1]
(ii) C6H5CH2CHO
[1]
[2]
O
N
H
[1]
[1]
Allow peptide bond shown in full (C=O) in a dipeptide ala-ala for 1 mark
H2N
O
N
H
OH
O
[3]
(c) (i) HCl or H2SO4 or NaOH or H+ or OH reagents
+ heat and H2O/aq (allow H3O+).
If T is quoted, 80 oC < T < 120 oC. NOT warm. conditions
(ii)
H2N
CO2H
[1]
[1]
CO2H
and
NH2
HO2C
(if a structural formula, it must have all H atoms) allow protonated or deprotonated
versions
[1] + [1]
[max 3]
Page 5
Syllabus
9701
Paper
43
[1]
(ii)
compound
H 2N
zwitterion
CO2H
H3N
CO2
OH
NH2CH3
NHCH3
HO
SO2
NH2
NH3
SO2
[3]
[4]
(e) (i) A buffer is a solution whose pH stays fairly constant or which maintains roughly the
same pH or which resists/minimises changes in pH
[1]
when small/moderate amounts of acid/H+ or alkali/OH are added
[1]
(ii) NH2CH(CH3)CO2H + H(Cl) +NH3CH(CH3)CO2H (+ Cl )
[1]
[1]
[1]
[1]
[1]
[7]
[Total: 19]
Page 6
Syllabus
9701
Paper
43
[1]
[1]
(b) (down the group) nitrates become more stable or require a higher temperature to
decompose
[1]
as size/radius of (cat)ion increases or charge density of ion decreases
[1]
so polarisation/distortion of anion/nitrate decreases
[1]
[3]
(c) (i) Li2CO3 Li2O + CO2
[1]
(ii) radius of Li ion/Li+ is less than that of Na ion/Na+ (or polarising power of M+ is greater) [1]
(iii) Brown/orange fumes/gas would be evolved or glowing splint relights
[1]
Since the nitrate is likely to be thermally unstable or decomposes (just like the
carbonate) or the balanced equation: 2LiNO3 Li2O + 2NO2 + O2
[1]
[4]
[Total: 8]
Page 7
5
Syllabus
9701
Paper
43
[1]
[1]
Cl2 2Cl
Cl + C2H6 C2H5 + HCl
C2H5 + Cl2 C2H5Cl + Cl
C2H5 + Cl C2H5Cl
or Cl + Cl Cl2 etc
[1]
[1]
[1]
[1]
all 3 names [1]
(iii)
structural formula of by-product
formed by
further substitution
CH3CH2CH2CH3
(termination of 2 ) C2H5
[3]
accept in the formed by column the formulae of radicals that will produce the
compound in the by-product column, or the reagents, e.g. C4H9 + Cl2 or C4H9 + Cl or
C4H10 + Cl2 (giving CH3CH2CH2CH2Cl).
do not allow anything more Clsubstituted than dichlorobutane.
N.B. C2H5Cl is the major product, not a by-product, so do not allow C2H5Cl.
(iv) J/K = 2.3 : 1 or 7:3 or 21:9
[2]
(reason: straightforward relative rate suggests 21:1, but there are 9 primary to 1 tertiary,
so divide this ratio by 9. 21/9 = 2.33)
allow [1] mark if J/K ratio is given as 21:1;
[10]
(c)
Cl
Cl
Cl
Cl
4 isomers 4 [1]
[1] + [1]
[max 5]
[Total: 16]
Page 8
6
Syllabus
9701
Paper
43
(a) (i) K, because it is the (only) one to contain nitrogen or its an amino acid
or because it contains CO2H or NH groups
(ii)
or
molecule: J,
molecule: L,
[1]
[1]
[2]
[1]
[1]
[1]
[3]
[1]
(ii) change in pH
increase in T (NOT decrease; T > 40 oC or too high are OK)
addition of heavy metal ions or specific, e.g. Hg2+, Ag+. Pb2+ etc.
any two bullet points [1] + [1]
change in pH disrupts ionic bonds
or metal ions disrupt ionic bonds
or metal ions disrupt SS bonds
or heating disrupts hydrogen bonds
any one [1]
This changes: the 3D structure or shape of the enzyme or the active site
[1]
[max 4]
[Total: 9]
Page 9
7
Syllabus
9701
Paper
43
(a)
structural information
analytical technique
three-dimensional
arrangement of atoms and
bonds in a molecule
X-ray crystallography/diffraction
chemical environment of
protons in a molecule
Electrophoresis / chromatography /
mass spectrometry
[1] + [1] + [1]
[3]
0.2 100
= 3.08 hence 3 carbons
5.9 1.1
(ii) Bromine
[1]
[1]
(iii) One bromine is present as there is only an M+2 peak / no M+4 peak or the M and M+2
peaks are of similar height
[1]
(iv) NMR spectrum shows a single hydrogen split by many adjacent protons and 6 protons in
an identical chemical environment. This suggests...
two CH3 groups and a lone proton attached to the central carbon atom
[1]
Empirical formula of N is C3H7Br
[1]
Hence N is (CH3)2CHBr or
H
CH3
CH3
Br
[1]
[6]
[Total: 11]
Page 10
8
Syllabus
9701
Paper
43
[1]
[1]
(iii) The gel coat stops it being broken down while passing through the upper part of the
digestive system/stomach
or the gel coat is stable to stomach acid.
[1]
[3]
(b) The drug is taken quickly/directly to the target
or more accurate dosing can be achieved
[1]
When the drug is taken by mouth it has to pass through the stomach/intestine wall to get into
the bloodstream. or some is digested/lost to the system
[1]
[2]
(c) (i) condensation (polymerisation)
(ii) hydrogen bonds or van der Waals
(iii) It would change the overall shape of the (drug) molecule
The fit into the active site would be less effective
(iv) Hydrolysis
[1]
[1]
[1] + [1]
[1]
[5]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2012 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[4]
[1]
(ii) 5 : 1
(iii) n(MnO4) = 0.02 15/1000 = 3 104 (mol)
[1]
(iv) n(Fe2+) = 5 3 104 = 1.5 103 (mol) ecf from (i) or (ii)
[1]
(v) [Fe2+] = 1.5 103 1000/2.5 = 0.6 (mol dm3) ecf from (iv)
[1]
(vi) In the original solution, there was 0.15 mol of Fe3+ in 100 cm3.
In the partially-used solution, there is 0.06 mol of Fe2+ in 100 cm3.
So remaining Fe3+ = 0.15 0.06 = 0.09 mol. ecf from (v)
[1]
This can react with 0.045 mol of Cu, which = 0.045 63.5 = 2.86 g of copper. ecf
[1]
[6]
(c) bonds broken are Si-Si and Cl-Cl = 222 + 244 = 466 kJ mol1
bonds formed are 2 Si-Cl = 2 359 = 718 kJ mol1
H = 252 kJ mol1
[2]
[2]
[1]
[1]
[2]
[Total: 14]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[4]
[1]
(ii) If Ecell = 0.17, this is 0.29 V less than the standard Eo,
so EAg electrode must = 0.80 0.29 = 0.51 V
[1]
(iii) 0.51 = 0.80 + 0.06log [Ag+], so [Ag+] = 10(0.29/0.06) = 1.47 x 105 mol dm3 ecf from (ii)
[1]
[3]
[1]
[1]
[1]
[3]
(d) AgCl
AgBr
AgI
white
cream
yellow
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[1]
[4]
[Total: 18]
Page 4
3
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
[1]
(ii) the correct allocation of the terms heterogeneous and homogeneous to common
catalysts
[1]
example of heterogeneous, e.g. Fe (in the Haber process) linked to correct system
equation, e.g. N2 + 3H2 2NH3
[1]
[1]
[1]
example of homogeneous, e.g. Fe3+ or Fe2+ (in S2O82 + I) linked to correct system
[1]
[1]
[1]
[8]
(b)
[2]
[Total: 10]
Page 5
4
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
[1]
[1]
[1]
(d) alkene
[1]
[1]
[5]
(f)
OH
CONH
H3C
CH3
OCH 3
capsaicin
CO 2H
H3C
CH3
C (cis/trans)
CH3
HO 2C
CO 2H
CO 2H
H3C
D
NC
F
alternative structure for capsaicin
COO
H3C
CH3
H3CO
NH2
ecf 5 [1]
[5]
[Total: 10]
Page 6
5
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
(a) phenol
ketone
[1]
[1]
[2]
(b)
reagent
observation
structure of product
type of reaction
sodium
metal
effervescence
/bubbles/fizzing
redox
O
aqueous
bromine
Br
decolourises
or white ppt.
electrophilic
substitution
HO
Br
CO 2Na
aqueous
alkaline
iodine
yellow ppt.
oxidation
HO
[2]
[8]
(c) (i)
SO 3H
H2N
N2
SO 3H
K
[1] + [1]
Page 7
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
[1]
at T < 10C
[1]
[1]
[5]
(d)
SOCl2/PCl5
/PCl3 + heat
add to G (in NaOH(aq))
(CH3CH2CO2H) CH3CH2COCl L
[1]
[1]
[1]
ecf from CH3COOH
[3]
[Total: 18]
Page 8
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
Section B
6
(a)
bonding
structure involved
tertiary
secondary
tertiary
primary
zero/one correct only [0], two correct only [1], three correct only [2] all four correct [3]
[3]
(b) labelled diagrams such as:
2 [1]
2 [1]
[4]
Page 9
Mark Scheme
GCE A LEVEL October/November 2012
(c)
phosphate
phosphate
II
III
C
sugar
phosphate
Paper
41
sugar
sugar
phosphate
Syllabus
9701
phosphate
sugar
phosphate
[1]
[1]
[1]
[3]
[Total: 10]
[1]
[1]
[1]
[3]
[1]
[1]
[2]
Page 10
Mark Scheme
GCE A LEVEL October/November 2012
(c) P is CH3CO2CH2CH3
Syllabus
9701
Paper
41
[1]
[1]
[1]
[2]
(b)
[1]
[1]
(c) (i) (Acid present would) hydrolyse the ester (linkage)
(ii) (Hot water would) soften (the container)
[1]
[1]
[2]
Page 11
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
41
(d) (i)
[1]
[1]
[1]
[1]
(iii) Accept any sensible physical property suggestion e.g. different melting point or different
density or different solubility.
[1]
[5]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2012 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
[1]
[1]
[1]
[1]
[4]
[1]
(ii) 5 : 1
(iii) n(MnO4) = 0.02 15/1000 = 3 104 (mol)
[1]
(iv) n(Fe2+) = 5 3 104 = 1.5 103 (mol) ecf from (i) or (ii)
[1]
(v) [Fe2+] = 1.5 103 1000/2.5 = 0.6 (mol dm3) ecf from (iv)
[1]
(vi) In the original solution, there was 0.15 mol of Fe3+ in 100 cm3.
In the partially-used solution, there is 0.06 mol of Fe2+ in 100 cm3.
So remaining Fe3+ = 0.15 0.06 = 0.09 mol. ecf from (v)
[1]
This can react with 0.045 mol of Cu, which = 0.045 63.5 = 2.86 g of copper. ecf
[1]
[6]
(c) bonds broken are Si-Si and Cl-Cl = 222 + 244 = 466 kJ mol1
bonds formed are 2 Si-Cl = 2 359 = 718 kJ mol1
H = 252 kJ mol1
[2]
[2]
[1]
[1]
[2]
[Total: 14]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
[1]
[1]
[1]
[1]
[4]
[1]
(ii) If Ecell = 0.17, this is 0.29 V less than the standard Eo,
so EAg electrode must = 0.80 0.29 = 0.51 V
[1]
(iii) 0.51 = 0.80 + 0.06log [Ag+], so [Ag+] = 10(0.29/0.06) = 1.47 x 105 mol dm3 ecf from (ii)
[1]
[3]
[1]
[1]
[1]
[3]
(d) AgCl
AgBr
AgI
white
cream
yellow
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[1]
[1]
[4]
[Total: 18]
Page 4
3
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
[1]
(ii) the correct allocation of the terms heterogeneous and homogeneous to common
catalysts
[1]
example of heterogeneous, e.g. Fe (in the Haber process) linked to correct system
equation, e.g. N2 + 3H2 2NH3
[1]
[1]
[1]
example of homogeneous, e.g. Fe3+ or Fe2+ (in S2O82 + I) linked to correct system
[1]
[1]
[1]
[8]
(b)
[2]
[Total: 10]
Page 5
4
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
[1]
[1]
[1]
(d) alkene
[1]
[1]
[5]
(f)
OH
CONH
H3C
CH3
OCH 3
capsaicin
CO 2H
H3C
CH3
C (cis/trans)
CH3
HO 2C
CO 2H
CO 2H
H3C
D
NC
F
alternative structure for capsaicin
COO
H3C
CH3
H3CO
NH2
ecf 5 [1]
[5]
[Total: 10]
Page 6
5
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
(a) phenol
ketone
[1]
[1]
[2]
(b)
reagent
observation
structure of product
type of reaction
sodium
metal
effervescence
/bubbles/fizzing
redox
O
aqueous
bromine
Br
decolourises
or white ppt.
electrophilic
substitution
HO
Br
CO 2Na
aqueous
alkaline
iodine
yellow ppt.
oxidation
HO
[2]
[8]
(c) (i)
SO 3H
H2N
N2
SO 3H
K
[1] + [1]
Page 7
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
[1]
at T < 10C
[1]
[1]
[5]
(d)
SOCl2/PCl5
/PCl3 + heat
add to G (in NaOH(aq))
(CH3CH2CO2H) CH3CH2COCl L
[1]
[1]
[1]
ecf from CH3COOH
[3]
[Total: 18]
Page 8
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
Section B
6
(a)
bonding
structure involved
tertiary
secondary
tertiary
primary
zero/one correct only [0], two correct only [1], three correct only [2] all four correct [3]
[3]
(b) labelled diagrams such as:
2 [1]
2 [1]
[4]
Page 9
Mark Scheme
GCE A LEVEL October/November 2012
(c)
phosphate
phosphate
II
III
C
sugar
phosphate
Paper
42
sugar
sugar
phosphate
Syllabus
9701
phosphate
sugar
phosphate
[1]
[1]
[1]
[3]
[Total: 10]
[1]
[1]
[1]
[3]
[1]
[1]
[2]
Page 10
Mark Scheme
GCE A LEVEL October/November 2012
(c) P is CH3CO2CH2CH3
Syllabus
9701
Paper
42
[1]
[1]
[1]
[2]
(b)
[1]
[1]
(c) (i) (Acid present would) hydrolyse the ester (linkage)
(ii) (Hot water would) soften (the container)
[1]
[1]
[2]
Page 11
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
42
(d) (i)
[1]
[1]
[1]
[1]
(iii) Accept any sensible physical property suggestion e.g. different melting point or different
density or different solubility.
[1]
[5]
[Total: 10]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2012 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
or
[1]
[1]
[1]
[1]
[1]
[1]
[1]
[Total: 5]
[1]
[1]
total n(Cl) = 3.08 or 3.09 or 3.1 102 mol [2 or more sig. figs.] allow ecf
(ii) Ag+(aq) + Cl(aq) AgCl(s)
[1]
(iii) moles sampled for the titration = 3.09 102 10/1000 = 3.09 104 mol ecf
[1]
this equals n(Ag+), so vol of AgNO3 = 3.09 104 1000/0.02 = 15.5 cm3 ecf
[1]
[Total: 5]
[1]
[1]
[Total: 4]
[TOTAL: 14]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
(a) catalyst: any two from the following three bullets for [1] mark:
speeds up/increases (NOT alters or changes) the rate of a reaction
lowers energy barrier/Eact or offers a lower energy pathway
is not used up or remains unchanged or does not alter its mass/concentration
or does not appear in stoichiometric equation or is regenerated
homogeneous: (catalyst and reactants) in the same phase/state
[1]
[1]
[Total: 2]
(b) (i) e.g. car exhausts/engines or aeroplanes or lightning or burning fuels or power stations
[1]
nitrogen reacts with oxygen or N2 + O2
[1]
H shown as negative
both Ea labelled and correct i.e. for the forward reaction
Ea(cat) < Ea(uncat)
[1]
[1]
[1]
[Total: 3]
[TOTAL: 10]
Page 4
3
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
(a) (1s22s22p6)3s23p63d9
[1]
[Total: 1]
[1]
[1]
[1]
[1]
[1]
[Total: 5]
(c)
V
salt
bridge
Pt
Cu
Fe3+ + Fe2+
Cu2+
[1]
[1]
[1]
[1]
[1]
[Total: 5]
or
(i)
ligand
exchange/substitution/displacement/replacement
precipitation/acid-base/deprotonation
(ii)
(iii)
Page 5
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
[1]
[Total: 4]
[1]
[1]
[1]
[Total: 3]
[2]
[Total: 2]
[TOTAL: 20]
[1]
[1]
[Total: 2]
(b) (i) (allow structural, displayed or skeletal formulae in (b), (c) and (e))
OH
OH
HO2C
CO2H
OH
OH
NC
H3CO
CN
HO
[1]
[Total: 4]
Page 6
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
(c) (i) reduction/redox (allow nucleophilic addition or hydrogenation, as appropriate from (ii)) [1]
(ii) NaBH4 or LiAlH4 or H2 + Ni/Pt or Na + ethanol
(iii)
HO2C
[1]
CO2H
[1]
[Total: 3]
[1]
[1]
[Total: 2]
(e)
O
H3CO
OCH3
HO
curcumin
OH
allow
complete formula
[2]
[Total: 2]
[TOTAL: 13]
(a) (i) contains a lone pair on N (that can react with H+)
(ii) e.g. C2H5NH2 + H(Cl) C2H5NH3+ (Cl)
or C2H5NH2 + H3O+ C2H5NH3+ + H2O
or C2H5NH2 + H2O C2H5NH3+ + OH etc
e.g. C2H5NH2 + CH3Br C2H5NHCH3 + HBr
or C2H5NH2 + CH3COCl CH3CONHC2H5 + HCl
[1]
[1]
[1]
Page 7
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
(iii) the lone pair (on N) in phenylamine overlaps with ring or is delocalised
electron density of N is reduced or N becomes more positive or lone pair is less
available
[1]
[1]
(iv)
N
H
N
ClCH3
Cl-
[1] + [1]
[7 max 6]
(b) (i) NaNO2 + HCl/H+ or HNO2 (HNO3 or NO3 negates this mark)
10 oC < T Y 10 oC or 'less than 10 oC'
[1]
[1]
NH2
or
but NOT
and
OH
N N
N N
N2
[1] + [1]
methyl orange:
(CH3)2N
and
H2 N
SO3Na
[1] + [1]
(iii) makes the molecule (more) hydrophilic/soluble in water (due to H-bonding or ionic
solvation)
or increases its melting point
[1]
[Total: 7]
[TOTAL: 13]
Page 8
6
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
[1]
[Total: 1]
[1]
[1]
ionic
disulfide bond
cysteine
hydrogen bond
asn, asp, arg, gln, glu, his, lys, ser, thr, try, tyr
[1] + [1]
[1 ] + [1]
(candidates can identify amino acids by name, three-letter abbreviation, formula of sidechain
or formula of whole amino acid)
[Total: 6]
(c) (globular proteins/enzymes need) polar/H-bonding/ionic (side chains) so as to....
....enhance their solubility or as part of their active site or to help their catalytic activity
[1]
[Total: 1]
(d) (i) A T
CG
[1]
[1]
[2]
[1]
[Total: 5]
[TOTAL: 13]
Page 9
7
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
(a) (i) No. of carbon atoms present in J is 100 1.3 = 5 carbons (must show working)
1.1 x 23.5
(NMR spectrum shows) 10 H (atoms present) (no reasoning need be shown)
[1]
[1]
(ii) Oxygen or O2 or O
[1]
(iii) J is (CH3CH2)2C=O
[1]
physical method
paper chromatography
partition
thin-layer chromatography
adsorption
gas-liquid chromatography
partition
[2]
(ii) 4
[1]
(iii)
[1]
[1]
[Total: 5]
[TOTAL: 10]
Page 10
8
(a) A
Mark Scheme
GCE A LEVEL October/November 2012
Syllabus
9701
Paper
43
[1]
[1]
monomer: H2C=CHCH3
[1]
[1]
[1]
Condensation
[1]
[max 5]
(b) (i) Need a statement from both columns for [1] mark.
(a)
(b)
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2013 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
(a)
8 e- around chlorine
1 Helectron (+) on the Cl - ion
3 covalent (ox) and one dative (oo) around N
[1]
[1]
[1]
[3]
[1]
[1]
(iii) CaO absorbs more water or CaO has greater affinity for water
[1]
[3]
[1]
[1]
[1]
[1]
[4]
[Total: 10]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[4]
[Total: 6]
Page 4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[1]
[5 max 4]
(d) (i) [H+] = (0.5 1.34 10-5) = 2.59 10-3 (mol dm-3)
pH = 2.59/2.6 (min 1 d.p)
[1]
ecf
[1]
[1]
[1]
[1]
ecf
[1]
[6]
(e) G is CH3CH2COCl
H is SOCl2 or PCl5
J is NaCl
(or corresponding Br compounds for G, H and J; CH3CH2COBr, SOBr2, NaBr)
[2]
[Total: 18]
Page 5
4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
[1]
[1]
[2]
[1]
[1]
(ii) (as the bond energy of C-X decreases) the halogenalkanes become more reactive
(answer must imply that it is from F to I)
[1]
[3]
(c) The C-Cl bond is weaker than the C-F and C-H bonds
or C-Cl bond (E = 340) and C-H (E = 410)
[1]
[1]
[1]
[3]
(d) Cl-CH2CH2-CO2H
HO-CH2CH2CH2-Cl
[1]
[1]
OH
Br
[1]
[3]
(e) (i) light/UV/h or 300C
[1]
[1]
[1]
ecf
[1]
[1]
[1]
[1]
[1]
[8]
[Total: 19]
Page 6
5
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
[1]
(ii) addition
[1]
(iii) C=C/double/ bond is broken and new C-C single bonds are formed
or double bond breaks and forms single bonds with other monomers
[1]
[3]
[1]
[1]
(c) (i)
[1]
[1]
[1]
[1]
[4]
(d) (i)
Any four:
hydrogen bond labelled
water H-bonded to O through H atom
+/- shown on each end of a H-bond
lone pair shown on O- or C=O or H2O on a correct H-bond
Na+ shown as coordinated to a water molecule
(ii) Solution became paler and Cu(2+) swapped with Na(+)
or darker in colour and polymer absorbs water
[3]
[1]
[4]
Page 7
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
[2]
(ii) NH3
[1]
(iii) H2O
[1]
[1]
[5]
[Total: 17]
Page 8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
Section B
6
[1]
(ii)
[1]
[1]
[1]
2 [1]
[6]
[1]
[1]
[1]
(iii)
[1]
[4]
[Total: 10]
Cambridge International Examinations 2013
Pa
age
e9
7
Ma
ark
k Sch
S hem
me
e
GCE
E A LEV
VEL
L Octo
O ob
ber//No
ove
em
mbe
er 2
201
13
Syllab
bus
s
97
701
1
Pa
ape
er
4
41
(
(a)
pow
p
werr su
upp
ply
y (id
dea
a of
o com
c mpllete
e circ
c uit)
e ctro
elec
oly
yte//bu
uffe
er solu
s utio
on
g /filtter pa
gel/
ape
er/a
abs
sorrbent pa
ape
er
(am
mino
o acid
a d) sam
s mp
ple//miixtu
ure
e [c
cen
ntre
e off plate
e]
4 [1]
4]
[4
( ) a
(b)
anyy tw
wo fro
om::
s e/M
size
Mr (of
( the
ea
amiino
o ac
cid sp
pec
cies
s)
c arge
cha
e (on the a
am
mino
o acid
a d specie
es)
te
em
mpe
eraturre
2 [1]
2]
[2
(
(c)
Rattio of the
R
e con
c nce
entrratiion
n off a so
olutte in e
eac
ch of two
o (immis
sciible
e) ssolvents
s
o e
or
equ
uilib
briu
um
m co
ons
sta
ant rep
pre
ese
enting
g th
he dis
strib
buttion
no
of a so
olu
ute be
etw
wee
en two
t o solv
ven
nts
o P
or
PC = [X]]a/[X
X]b (a
at a consta
ant temp
perratu
ure
e)
[1]
[1]
( ) (i)
(d)
(
Kpc = [Z
Z in e
ether]]/[Z
Z in
n H2O]
O allow
w reve
ers
se rattio
40
0 = (x
x/0.05
5)/(((4
x))/0.5))
= 3.2 g
(ii) Firstt ex
xtrracttion
n
40
0 = (x
x/0.02
25))/((4
4x
x)//0.5
5)
x = 2.6
2 67 g
[1]
e f
ecf
[1]
e f
ecf
[1]
e f
ecf
[1]
(iii) Sec
cond ext
e trac
ctio
on: 1.33
3g rem
r maiin in
i ssolutio
on
Sec
cond ext
e trac
ctio
on
40
0 = (y
y/0.02
25))/((1.3
33
y)/0.5)
y = 0.8
0 887
7g
mas
m ss ext
e traccte
ed = 2.67
2 7 + 0.89
9 = 3..56
6/3..6 g
[4
4]
[To
ota
al: 11]
Ca
amb
brid
dge
e In
nterrnattion
nal Ex
xam
mina
atio
ons
s 20
013
3
Page 10
8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
41
[1]
[1]
SO4(2-)
[1]
[1]
[4]
[1]
[1]
[1]
[3]
[1]
[1]
[2]
[Total: 9]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2013 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
(a)
8 e- around chlorine
1 Helectron (+) on the Cl - ion
3 covalent (ox) and one dative (oo) around N
[1]
[1]
[1]
[3]
[1]
[1]
(iii) CaO absorbs more water or CaO has greater affinity for water
[1]
[3]
[1]
[1]
[1]
[1]
[4]
[Total: 10]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[4]
[Total: 6]
Page 4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
[1]
[1]
[4]
[1]
[1]
[2]
[1]
[1]
[1]
[1]
[1]
[5 max 4]
(d) (i) [H+] = (0.5 1.34 10-5) = 2.59 10-3 (mol dm-3)
pH = 2.59/2.6 (min 1 d.p)
[1]
ecf
[1]
[1]
[1]
[1]
ecf
[1]
[6]
(e) G is CH3CH2COCl
H is SOCl2 or PCl5
J is NaCl
(or corresponding Br compounds for G, H and J; CH3CH2COBr, SOBr2, NaBr)
[2]
[Total: 18]
Page 5
4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
[2]
[1]
[1]
(ii) (as the bond energy of C-X decreases) the halogenalkanes become more reactive
(answer must imply that it is from F to I)
[1]
[3]
(c) The C-Cl bond is weaker than the C-F and C-H bonds
or C-Cl bond (E = 340) and C-H (E = 410)
[1]
[1]
[1]
[3]
(d) Cl-CH2CH2-CO2H
HO-CH2CH2CH2-Cl
[1]
[1]
OH
Br
[1]
[3]
(e) (i) light/UV/h or 300C
[1]
[1]
[1]
ecf
[1]
[1]
[1]
[1]
[1]
[8]
[Total: 19]
Page 6
5
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
(ii) addition
[1]
(iii) C=C/double/ bond is broken and new C-C single bonds are formed
or double bond breaks and forms single bonds with other monomers
[1]
[3]
[1]
[1]
(c) (i)
[1]
[1]
[1]
[1]
[4]
(d) (i)
Any four:
hydrogen bond labelled
water H-bonded to O through H atom
+/- shown on each end of a H-bond
lone pair shown on O- or C=O or H2O on a correct H-bond
Na+ shown as coordinated to a water molecule
(ii) Solution became paler and Cu(2+) swapped with Na(+)
or darker in colour and polymer absorbs water
[3]
[1]
[4]
Page 7
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[2]
(ii) NH3
[1]
(iii) H2O
[1]
[1]
[5]
[Total: 17]
Page 8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
Section B
6
[1]
(ii)
[1]
[1]
[1]
2 [1]
[6]
[1]
[1]
[1]
(iii)
[1]
[4]
[Total: 10]
Pa
age
e9
7
Ma
ark
k Sch
S hem
me
e
GCE
E A LEV
VEL
L Octo
O ob
ber//No
ove
em
mbe
er 2
201
13
Syllab
bus
s
97
701
1
Pa
ape
er
4
42
(
(a)
pow
p
werr su
upp
ply
y (id
dea
a of
o com
c mpllete
e circ
c uit)
e ctro
elec
oly
yte//bu
uffe
er solu
s utio
on
g /filtter pa
gel/
ape
er/a
abs
sorrbent pa
ape
er
(am
mino
o acid
a d) sam
s mp
ple//miixtu
ure
e [c
cen
ntre
e off plate
e]
4 [1]
4]
[4
( ) a
(b)
anyy tw
wo fro
om::
s e/M
size
Mr (of
( the
ea
amiino
o ac
cid sp
pec
cies
s)
c arge
cha
e (on the a
am
mino
o acid
a d specie
es)
te
em
mpe
eraturre
2 [1]
[2
2]
(
(c)
Rattio of the
R
e con
c nce
entrratiion
n off a so
olutte in e
eac
ch of two
o (immis
sciible
e) ssolvents
s
o e
or
equ
uilib
briu
um
m co
ons
sta
ant rep
pre
ese
enting
g th
he dis
strib
buttion
no
of a so
olu
ute be
etw
wee
en two
t o solv
ven
nts
o P
or
PC = [X]]a/[X
X]b (a
at a consta
ant temp
perratu
ure
e)
[1]
[1]
( ) (i)
(d)
(
Kpc = [Z
Z in e
ether]]/[Z
Z in
n H2O]
O allow
w reve
ers
se rattio
40
0 = (x
x/0.05
5)/(((4
x))/0.5))
= 3.2 g
(ii) Firstt ex
xtrracttion
n
40
0 = (x
x/0.02
25))/((4
4x
x)//0.5
5)
x = 2.6
2 67 g
[1]
e f
ecf
[1]
e f
ecf
[1]
e f
ecf
[1]
(iii) Sec
cond ext
e trac
ctio
on: 1.33
3g rem
r maiin in
i ssolutio
on
Sec
cond ext
e trac
ctio
on
40
0 = (y
y/0.02
25))/((1.3
33
y)/0.5)
y = 0.8
0 887
7g
mas
m ss ext
e traccte
ed = 2.67
2 7 + 0.89
9 = 3..56
6/3..6 g
4]
[4
[To
ota
al: 11]
Ca
amb
brid
dge
e In
nterrnattion
nal Ex
xam
mina
atio
ons
s 20
013
3
Page 10
8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
42
[1]
[1]
SO4(2-)
[1]
[1]
[4]
[1]
[1]
[1]
[3]
[1]
[1]
[2]
[Total: 9]
w
ap
eP
e
tr
.X
s
er
om
.c
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2013 series for most IGCSE,
GCE Advanced Level and Advanced Subsidiary Level components and some Ordinary Level
components.
Page 2
1
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
(a)
O
N
[1]
[1]
[1]
[3]
[1]
[1]
[1]
as radius of M2+ / metal ion increases or charge density of the cation decreases
[1]
[4]
species [1]
balancing [1]
[2]
[Total: 9]
Page 3
2
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
(c) (i) endothermic; because the equilibrium moves to the right on heating or with
increasing temperature or because bonds are broken during the reaction
[1]
(ii) e.g. halogenation or Friedel-Crafts alkylation / acylation
reactants [1]
products [1]
[3]
[Total: 7]
Page 4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
[1]
[2]
[3]
(b) (i) bond energies decrease from Cl2 to I2
due to increasing bond length or increase in number of electron shells
which causes less effective orbital overlap or less attraction for the shared pair
[1]
[1]
[1]
(ii) either because fluorine is electronegative, (hence each F wants to keep its electrons
to itself)
or because the bond length is so short there is repulsion between the lone pairs (on
F)
or repulsion between the nuclei (of F)
[1]
[4 max 3]
(c) (i) for chlorine:
H = E(H H) + E(Cl Cl) 2E(H Cl) =
=
for iodine:
H = E(H H) + E(I I) 2E(H I)
=
=
[2]
[1]
(ii) Hydrides become less thermally stable down the group from Cl to I
as the HX bond energy decreases (more than does the XX bond energy)
[1]
[1]
[5]
(d) (i)
Na
15.2 / 23
0.661
0.661 1.0
O
31.8 / 16
1.99
3.0
Br
53.0 / 79.9
0.663
1.0
[1]
thus NaBrO3
(ii) 3Br2 + 6NaOH NaBrO3 + 5NaBr + 3H2O
or 3Br2 + 6OH BrO3 + 5Br + 3H2O
[1]
species [1]
balancing [1]
[4]
[Total: 15]
Page 5
4
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
(a) (i) Carbon (graphite) has delocalised electrons whereas silicons electrons are
localised.
[1]
(ii) Tin has metallic structure or delocalised / mobile electrons whereas germanium has
localised electrons or giant covalent structure
[1]
[2]
(b) (i) 2 PbO2 2PbO + O2
[1]
[1]
[1]
[1]
[4]
[Total: 6]
Page 6
5
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
[1]
[1]
[1]
(ii) no special conditions
electrophilic addition
[1]
[1]
product [1]
(iii) light / UV or heat
(free) radical substitution
[1]
[1]
product [1]
[1]
[1]
OH
O
O
D
CH3CO2H
E
[1]
[1]
[1]
[6]
[TotaI: 16]
Page 7
6
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
(b) (i)
[1]
[1]
H
O
O
H +
H
H
carboxylic acid
amino group
attached to CO2H
[1]
attached to NH2
[1]
lone pair (on oxygen in H2O or CO2H or on nitrogen) shown at least once on
a H-bond
[1]
+ and shown at least once (at each end of the same H-bond)
[1]
(ii)
CO2
H3N
CH2
[1]
[5]
(+)
H3N
H3C
H
Cl
CO2H
CO2H
CO2H
H3C
+ Cl -
(-)
Cl
CH3
NH3
-H+
CO2H
H2N
any three of
CH3
H
(d) lysine @ pH 1:
aspartic acid @ pH 12:
NH3(CH2)4CH(NH3+)CO2H
O2C CH2 CH(NH2)CO2
[1]
[1]
[2]
Page 8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
[1]
(f)
Paper
43
[2]
[3]
[1]
(ii) J
[1]
(iii)
H
H2N
HO2C
CH3
OH
[1]
[3]
[Total: 17]
Page 9
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
Section B
7
(a) (i) Metals such as Hg, Ag, Cd, Pb, Cu (identified NOT just "heavy metals")
(allow names, atomic symbols or ions, names or formulae of salts e.g. Pb(NO3)2)
or penicillin or organophosphorus insecticide etc.
[1]
(ii) The ion / inhibitor binds to a part of the enzyme molecule away from the active site
or to an allosteric site
[1]
This changes the shape of the active site or denatures the enzyme
[1]
OR
the inhibitor forms a covalent / permanent bond with the active site
[1]
blocking entry of the substrate
[1]
(iii)
rate of
reaction
[1]
[4]
(b) (i) (DNA) mRNA ribosome tRNA (Protein)
[2]
[1]
[3]
[1]
2 [1]
[3]
[Total: 10]
Page 10
8
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
[1]
[1]
[1]
there is insufficient electron density / cloud around H atoms for X-ray crystallography
(d) (i)
4.5 100
=
n
1.5 1.1
100 0.15
n=
= 3.03 = 3
4.5 1.1
[1]
[2]
[1]
[1]
[1]
(iii) 3 (three)
[1]
[1]
[1]
[1]
[1]
[1]
[6]
[Total: 10]
Page 11
9
Mark Scheme
GCE A LEVEL October/November 2013
Syllabus
9701
Paper
43
[1]
graphite
black
good conductor
soft / slippery
less dense than
diamond
lower
diamond
transparent / colourless
non-conductor
hard / non slippery
more dense than graphite
higher
3 [1]
[4]
(b) Because each carbon is only bonded to 3 others or is unsaturated / doubly-bonded / sp2
or has 3 bonding locations
(NOT forms only 3 bonds)
C60H60
[1]
[1]
[2]
(c) (i) Number of atoms carbon present = 0.001 6.02 1023 / 12 = 5.02 1019
[1]
[1]
[1]
[1]
[4]
[Total: 10]
w
ap
eP
e
tr
.X
om
.c
s
er
9701 CHEMISTRY
9701/41
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2014 series for
most Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page 2
Question
1
(a) (i)
Syllabus
9701
Paper
41
Marking point
Marks
[NO]
[O2]
1st order and evidence of using expt 1 & 2 when the concentration is 2, rate doubles
(ii)
(0.00408 27)
rate = 0.11 (mol dm3 s1) to 2sf
(iii)
(Rate =) k [O2][NO]2
(iv)
k = 332(.03125)
mol2 dm6 s1
1
1
1
1
1
(b) (i)
(ii)
(c)
Mark Scheme
Cambridge International A Level October/November 2014
e.g. F2 + NO NOF + F
NO + F NOF
OR
F2 + NO NOF2
NO + NOF2 2NOF
Total
Marks
total
[6]
[5]
[2]
[13]
Page 3
Mark Scheme
Cambridge International A Level October/November 2014
3d
(a)
(b) (i)
(c)
4s
(Ni)
(Ni2+)
Syllabus
9701
Paper
41
1
degenerate
(ii)
(iii)
[2]
[4]
[3]
Page 4
(d)
Mark Scheme
Cambridge International A Level October/November 2014
A Ni(OH)2
OR
Ni(OH)2(H2O)4
B [Ni(NH3)6]2+ OR [Ni(NH3)n(H2O)6-n]2+
Ni2+ + 2OH
OR [Ni(H2O)6]2+
OR [Ni(H2O)6]2+
OR [Ni(H2O)6]2+
OR
[Ni(NH3)n(H2O)4-n]2+
Ni(OH)2
+ 2OH Ni(OH)2 + 6H2O
+ 2NH3 Ni(OH)2 + 4H2O + 2NH4+
+ 2OH Ni(OH)2(H2O)4 + 2H2O
Syllabus
9701
Paper
41
1
1
1
[4]
[13]
Page 5
(a) (i)
(ii)
(b) (i)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
101 = P35Cl35Cl
103 = P35Cl37Cl
105 = P37Cl37Cl
1
1
1
9:6:1
Cl
(ii)
Cl
Cl
1
1
Cl
Cl
(c) (i)
Cl
Cl
Cl
[3]
Cl
O O
P
Cl
[4]
P
O
O
P4O6 structure where each P has three P-O bonds and each O has two P-O bonds e.g.
O
(ii)
(d) (i)
(molecule/ion/species) that donates a lone pair of electrons (to a central transition metal atom or
ion)
Ksp =[Ca2+]3[PO43]2
[2]
Page 6
(ii)
(e) (i)
(ii)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
1
1
1
1
Total
(a) (i)
[4]
[3]
[16]
Page 7
(ii)
(b) (i)
(ii)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
any three of
curly arrow from inside the benzene ring to NO2+ group
intermediate penalise NO2 connectivity or missing methyl group (once)
curly arrow from C-H bond into ring
product + H+ (or as diagram H+)
allow 2- and 3-substituted nitromethylbenzene)
[4]
1
1
[3]
Page 8
(c)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
Na
redox/reduction
O
O
ONa
(or ionic)
Br2
O
Br
(electrophilic)
substitution
O
OH
Br
NaOH
hydrolysis/
acid-base/
OH
and
OH [1]
OH
or ionic
O
ONa
ONa
ONa
4
2
[6]
Page 9
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
Total
5
13
(a)
CH3CH2COCl carbon in C-Cl bond is more electron deficient since it is also attached to an
oxygen atom ora
[3]
1+1
(b)
(c) (i)
dipole on C-Br
curly arrow breaking C-Br bond
curly arrow from lone pair on N to carbon in C-Br bond
1
1
1
H2N
[2]
OH
O
H3C
CH2
Br
(ii)
nucleophilic substitution
(iii)
[5]
Page 10
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
(d)
Y=
W = H N+
3
(Cl)
X=
[3]
1
1
[2]
OH
O
OH
3
OH
H2N
Paper
41
O
OH
NH
H3C
(e)
CH2
CH2
O
CH2
O
CH2
CH2
CH2
N
H
15
(a)
(b) (i)
(ii)
1
1
1
1
1
by adsorption
1
Cambridge International Examinations 2014
[3]
[3]
Page 11
(c)
(d)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
(base pairing) A to T OR C to G
H-bonds between bases
two/double stranded/chains
anti-parallel strands
(general structure) sugar-phosphate backbone OR BASE-SUGAR-PHOSPHATE bonded
in a diagram
[3]
1
1
[2]
Total
(a)
11
H3C
H3C
[2]
[1]
CH3
HN
H3C
(b)
1
1
CH3
Page 12
(c)
(d)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
binds with the enzymes active site OR has a complementary shape to active site OR similar
shape to substrate
[3]
[1]
Total
(a)
(ii)
(b) (i)
M:M+1 = 100/(1.1 x n)
20.4/0.9 = 100/(1.1 x n)
x =4
C4H10O
H3C
(ii)
0.9-1.0
multiplet/1.8
singlet/2.5
3.4
is
is
is
is
(iii)
doublet
1H/one proton on adjacent carbon
CH3
OH
(2 x)CH3R/CH3/RCH
CHR/R3CH
OH
CH2O/CH3O
1
1
1
1
1
1
[3]
Page 13
(iv)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
41
Total
[9]
12
100
w
ap
eP
e
tr
.X
om
.c
s
er
9701 CHEMISTRY
9701/42
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2014 series for
most Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page 2
Question
1
(a) (i)
Syllabus
9701
Paper
42
Marking point
Marks
[NO]
[O2]
1st order and evidence of using expt 1 & 2 when the concentration is 2, rate doubles
(ii)
(0.00408 27)
rate = 0.11 (mol dm3 s1) to 2sf
(iii)
(Rate =) k [O2][NO]2
(iv)
k = 332(.03125)
mol2 dm6 s1
1
1
1
1
1
(b) (i)
(ii)
(c)
Mark Scheme
Cambridge International A Level October/November 2014
e.g. F2 + NO NOF + F
NO + F NOF
OR
F2 + NO NOF2
NO + NOF2 2NOF
Total
Marks
total
[6]
[5]
[2]
[13]
Page 3
Mark Scheme
Cambridge International A Level October/November 2014
3d
(a)
(b) (i)
(c)
4s
(Ni)
(Ni2+)
Syllabus
9701
Paper
42
1
degenerate
(ii)
(iii)
[2]
[4]
[3]
Page 4
(d)
Mark Scheme
Cambridge International A Level October/November 2014
A Ni(OH)2
OR
Ni(OH)2(H2O)4
B [Ni(NH3)6]2+ OR [Ni(NH3)n(H2O)6-n]2+
Ni2+ + 2OH
OR [Ni(H2O)6]2+
OR [Ni(H2O)6]2+
OR [Ni(H2O)6]2+
OR
[Ni(NH3)n(H2O)4-n]2+
Ni(OH)2
+ 2OH Ni(OH)2 + 6H2O
+ 2NH3 Ni(OH)2 + 4H2O + 2NH4+
+ 2OH Ni(OH)2(H2O)4 + 2H2O
Syllabus
9701
Paper
42
1
1
1
[4]
[13]
Page 5
(a) (i)
(ii)
(b) (i)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
101 = P35Cl35Cl
103 = P35Cl37Cl
105 = P37Cl37Cl
1
1
1
9:6:1
Cl
(ii)
Cl
Cl
1
1
Cl
Cl
(c) (i)
Cl
Cl
Cl
[3]
Cl
O O
P
Cl
[4]
P
O
O
P4O6 structure where each P has three P-O bonds and each O has two P-O bonds e.g.
O
(ii)
(d) (i)
(molecule/ion/species) that donates a lone pair of electrons (to a central transition metal atom or
ion)
Ksp =[Ca2+]3[PO43]2
[2]
Page 6
(ii)
(e) (i)
(ii)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
1
1
1
1
Total
(a) (i)
[4]
[3]
[16]
Page 7
(ii)
(b) (i)
(ii)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
any three of
curly arrow from inside the benzene ring to NO2+ group
intermediate penalise NO2 connectivity or missing methyl group (once)
curly arrow from C-H bond into ring
product + H+ (or as diagram H+)
allow 2- and 3-substituted nitromethylbenzene)
[4]
1
1
[3]
Page 8
(c)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
Na
redox/reduction
O
O
ONa
(or ionic)
Br2
O
Br
(electrophilic)
substitution
O
OH
Br
NaOH
hydrolysis/
acid-base/
OH
and
OH [1]
OH
or ionic
O
ONa
ONa
ONa
4
2
[6]
Page 9
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
Total
5
13
(a)
CH3CH2COCl carbon in C-Cl bond is more electron deficient since it is also attached to an
oxygen atom ora
[3]
1+1
(b)
(c) (i)
dipole on C-Br
curly arrow breaking C-Br bond
curly arrow from lone pair on N to carbon in C-Br bond
1
1
1
H2N
[2]
OH
O
H3C
CH2
Br
(ii)
nucleophilic substitution
(iii)
[5]
Page 10
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
(d)
Y=
W = H N+
3
(Cl)
X=
[3]
1
1
[2]
OH
O
OH
3
OH
H2N
Paper
42
O
OH
NH
H3C
(e)
CH2
CH2
O
CH2
O
CH2
CH2
CH2
N
H
15
(a)
(b) (i)
(ii)
1
1
1
1
1
by adsorption
1
Cambridge International Examinations 2014
[3]
[3]
Page 11
(c)
(d)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
(base pairing) A to T OR C to G
H-bonds between bases
two/double stranded/chains
anti-parallel strands
(general structure) sugar-phosphate backbone OR BASE-SUGAR-PHOSPHATE bonded
in a diagram
[3]
1
1
[2]
Total
(a)
11
H3C
H3C
[2]
[1]
CH3
HN
H3C
(b)
1
1
CH3
Page 12
(c)
(d)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
binds with the enzymes active site OR has a complementary shape to active site OR similar
shape to substrate
[3]
[1]
Total
(a)
(ii)
(b) (i)
M:M+1 = 100/(1.1 x n)
20.4/0.9 = 100/(1.1 x n)
x =4
C4H10O
H3C
(ii)
0.9-1.0
multiplet/1.8
singlet/2.5
3.4
is
is
is
is
(iii)
doublet
1H/one proton on adjacent carbon
CH3
OH
(2 x)CH3R/CH3/RCH
CHR/R3CH
OH
CH2O/CH3O
1
1
1
1
1
1
[3]
Page 13
(iv)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
42
Total
[9]
12
100
w
ap
eP
e
tr
.X
om
.c
s
er
9701 CHEMISTRY
9701/43
This mark scheme is published as an aid to teachers and candidates, to indicate the requirements of
the examination. It shows the basis on which Examiners were instructed to award marks. It does not
indicate the details of the discussions that took place at an Examiners meeting before marking began,
which would have considered the acceptability of alternative answers.
Mark schemes should be read in conjunction with the question paper and the Principal Examiner
Report for Teachers.
Cambridge will not enter into discussions about these mark schemes.
Cambridge is publishing the mark schemes for the October/November 2014 series for
most Cambridge IGCSE, Cambridge International A and AS Level components and some
Cambridge O Level components.
Page
e2
Que
estio
on
1
Marrk Sche
S eme
e
Cam
mbrridge In
nternatiiona
al A Le
evel O
Octo
oberr/No
ovem
mbe
er 2014
2 4
Sy
yllab
bus
970
9 1
Ma
arking poin
p nt
(a)) (i)
Ma
arks
m/e
m
35
3
Cll
37
3
37
3
Cll
35
C
Cl 35Cl
C o
or 35Cl
C2
37
Cl
C 35Cl
72
7
74
7
Markks
tota
al
ide
entiity
35
3
70
7
37
C
Cl 37Cl
C o
or 37Cl
C2
Pap
per
43
3
1
1
1
9:6
6:1
co
orrecct ch
harg
ges
co
orrecct ellectrronss
1
1
La
attice en
nerg
gy = H
Hf(SrrCl2) ((Hatom
(Sr)
(
+ Hi1(Sr) + H
Hi2(S
Sr) + H
Hatom
Hea(C
Cl))
a
m(Cll) + 2H
= +(8
830) ((+ 164 + 54
48 + 10
060 + 24
42 + (2 349
9))
=
2146 (kJ moll1)
1
1
1
SrrCO
O3 + 2H
HNO
O3 Srr(NO
O3)2 + CO
C 2 + H2O
[4]
(b)) (i)
(ii)
(c)) (i)
Ca
ambrridge
e Intterna
ation
nal Exam
E mina
ation
ns 20
014
[5]
Page 3
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
43
[2]
(down the group) nitrates become more stable / require a higher temperature to decompose
1
1
1
[3]
1
1
[2]
[BrO3] 1st order and the concentration is x2, rate doubles OR evidence using expt 1 & 4 eg ratios
[H+] 2nd order and the concentration is x2, rate x4 OR evidence using expt 1 & 2
[Br-] 1st order and the concentration is x4, rate x4 OR evidence using expt 1 & 3 eg ratios
1
1
1
(ii)
(Rate =) k [BrO3][Br][H+]2
(iii)
k = 1.32
mol3 dm9 s1
1
1
(ii)
(iii)
correct id of
one higher energy d orbital
the other higher energy d orbital
1
1
(ii)
(d)
(a)
(b) (i)
(a) (i)
[6]
[4]
Page 4
Paper
43
Cu(OH)2 OR [Cu(OH)2(H2O)4]
[Cu(NH3)4(H2O)2]2+
OR
[Cu(NH3)4]2+
2
[CuCl4]
1
1
1
(ii)
solution B
solution C
1
1
(iii)
1
1
[2]
green / yellow
orange / red AND blue / violet light is absorbed
1
1
[2]
1
1
[2]
1
1
1
1
[4]
CH3CH(NH2)COOH + H+ CH3CH(NH3+)COOH
CH3CH(NH2)COOH + OH CH3CH(NH2)COO + H2O
1
1
[2]
(c)
(d)
(a)
(b) (i)
(ii)
(c)
Syllabus
9701
(b) (i)
Mark Scheme
Cambridge International A Level October/November 2014
[6]
Page 5
Mark Scheme
Cambridge International A Level October/November 2014
pKa 2.99
OH
OH
pKa 4.40
HO
OH
HO
OH
OH
HO
1
O
+ H+
+ H+
HO
COOH
HOOC
H
[4]
[5]
COOH
HOOC
OH
OH
Paper
43
OH
-O
OH
HO
O
(ii)
OH
(d) (i)
Syllabus
9701
OH
(R,S)
(S,R)
H
HO
COOH
HOOC
(R,R)
OH
(a)
Page 6
(b)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
43
Reagent X e.g. Br2, HNO3, Na, NaOH, benzenediazonium salt / ion; RCOCl ; Fe3+ ; H2+Ni
substituted product for L-DOPA & vanillin (examples given are for X = Br2 and NaOH)
Br
Br
HO
HO
NH2
H 3 CO
COOH
HO
or
NH2
O
HO
H 3 CO
H
O
Reagent Y e.g. HCl; Na2CO3, Mg, SOCl2, PCl5, ROH + c.H2SO4; HCl+NaNO2 / HNO2; CH3Cl
Correct substituted product for L-DOPA
HO
1
1
NH3
COOH
HO
Reagent Z e.g. acidified Cr2O72 ; 2,4-DNPH, hydrazine ; Fehlings, Tollens; HCN; HCN + NaCN;
NaBH4 ;
correct substituted product for vanillin
1
1
HO
OH
HO
O
(a) (i)
C15H21NO2
[7]
Page 7
Mark Scheme
Cambridge International A Level October/November 2014
O
(ii)
OCH 3
Syllabus
9701
Paper
43
1
NHCH2CH3
(iii)
[4]
Page 8
(b)
Mark Scheme
Cambridge International A Level October/November 2014
OH
(i) LiAlH4
OCH3
Syllabus
9701
Paper
43
reduction / nucleophilic
addition
NHCH2CH3
OCH3
acid-base / neutralisation
OCH3
acylation / condensation
NH2CH2CH3
(Cl-)
O
(iii) CH3COCl
allow addition +
elimination
allow nucleophilic
substitution
N
H3CH2C
COCH3
[6]
Page 9
(a)
(b)
Mark Scheme
Cambridge International A Level October/November 2014
1
1
Kpc
= [J in ether]/[J in H2O]
= (2.14/20)/(52.14/75)
=2.81 OR 2.82
2nd extraction:
(d) (i)
Paper
43
(ratio of) the concentrations / distribution / amount / mass of solute in two (immiscible) solvents
at equilibrium OR equilibrium constant OR includes expression with K
1st extraction:
(c)
Syllabus
9701
2.81
=(x/10)/(5.0x)/75
2.81(5x) = 7.5x
x= 1.36 g
2.81
=(y/10)/(3.64y)/75
2.81(3.64-y) = 7.5y
y= 0.99 g
(ii)
non-volatile liquid, for example mineral oil or at least a C15 hydrocarbon oil
(iii)
1
1
[2]
[2]
[2]
[4]
Page 10
Mark Scheme
Cambridge International A Level October/November 2014
(e)
CO2H
CH2OH
Syllabus
9701
Paper
43
1
[1]
C = 33 %
A = T = 17 %
1
1
[2]
CO2H
CO2H
(a)
(b) (i)
(ii)
[2]
Page 11
(c) (i)
Mark Scheme
Cambridge International A Level October/November 2014
Paper
43
CHO
CHO
CHO
Syllabus
9701
1
1
(ii)
3-methylbutanal
(iii)
pentanal
2-methylbutanal
dimethylpropanal
5 absorptions
5 absorptions
2 absorptions
1
1
1
[6]
(a)
[1]
(b)
1
1
[2]
C
O
N
H
O
N
C
O
H
N
(c)
[1]
(d)
hydrogen bond
C=O and N-H in two different amino acids in the backbone diagram
1
1
[2]
Page 12
(e) (i)
(ii)
(iii)
Mark Scheme
Cambridge International A Level October/November 2014
Syllabus
9701
Paper
43
Hg2+ interferes with/breaks the disulfide bond / bridge not sulfite, sulfate, sulfur, sulfide
OR -S-S- shown with Hg2+ in an equation
OR disrupting ionic interactions linked to carboxyl / COO groups
[3]