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minimum weight. From 1903 to about 1930 absolute minimum weight was necessary
for practical flight. Consequently, the strength/weight ratio (specific strength) was the
prime driver for materials selection and continues to be of major importance to this
day. For the first 25 years the airframe was a wooden structure braced by wire and
covered with fabric treated with varnishes. Sitka spruce was the most favored
structural material due to its fine, straight-grained wood with a minimum of knots.
The fabric was usually tightly woven wool or cotton covered with a varnish referred
to as 'dope'. With the exception of the engine, fasteners and wires, the early airplane
had very little metal in its structure. The Wright brothers did use an aluminum-copper
casting alloy for the crankcase of their self-designed internal combustion engine
because of the alloy's strength and the weight requirements of the aircraft. However,
aluminum was not used for airframes until some years later after precipitation
hardening was discovered by Alfred Wilm. In the 1920s some designers, e.g. Dr Hugo
Junkers, Claudius Dornier and Adolph Rohrbach, experimented with aluminum
aircraft. The low specific gravity of aluminum (2.7) leads to high specific properties
which, in turn, favor the selection of aluminum alloys in weight-critical applications.
Junkers selected 'duralumin', an age-hardenable aluminium alloy which contained
additions of copper, magnesium and manganese. Duralumin was the age-hardenable
alloy discovered in 1906 by Alfred Wilm, a German chemist who was seeking a
lightweight alloy to replace brass for cartridge casings. Although duralumin was used
in dirigibles, it suffered from exfoliation corrosion when exposed to air and, prior to
the Junkers design, was not used in load-bearing components of aircraft. However, in
1927, metallurgists at Alcoa developed a method to clad aluminum alloys with pure
aluminum, which was not susceptible to exfoliation corrosion, and thereby offered
protection in an aggressive environment. At about the same time anodizing, a method
for producing a very thick, protective oxide film on the surface of aluminum, was
developed in England. The anodized film usually contains chemical compounds such
as chromates which are collected from the anodizing bath and render the film more
corrosion resistant than films that form naturally in air. The protection given by
cladding and anodizing served to establish a dramatically new baseline for
aerostructures and after 1927 aluminum alloys became commonplace in airframes.
Although polymer matrix composites (PMCs) are being used in modern commercial
aircraft, e.g. for the horizontal stabilizer of the Airbus A340 and the Boeing 777,
aluminum alloys continue to be the primary material of choice for airframes, Table 1.
Predominant loads during flight are tension in the crown, shear in the sides
and compression in the bottom. These loads are caused by bending of the
fuselage due to loading of the wings during flight and by cabin pressure.
Taxiing causes compression in the top and tension in the bottom, however
these stresses are less than the in-flight stresses.
Strength, Young's modulus, fatigue initiation, fatigue crack growth, fracture toughness
and corrosion are all important, but fracture toughness is often the limiting design
consideration.
Materials for aerospace systems
Since the first days of powered flight, aircraft designers have focused on achieving
minimum weight, both in airframes and in propulsion systems. For example, the
original Wright Flyer employed an engine with an aluminium block, which was
virtually unheard of at the turn of the 20th century. From 1903 to about 1930 absolute
minimum weight was necessary for practical flight, due in large part to the limited
capability of the available propulsion systems. Consequently, the strength/weight ratio
was the prime driver for materials selection for both engines and aircraft. While this
consideration continues to be of first order importance, light weight is now necessary
but not sufficient. Current design criteria are much more complicated, as mentioned in
the Introduction, and winning products require new design methods as well as
improved materials and processing methods. The transition from internal combustion,
piston engines to turbines represented a major game changer in aircraft. Beginning
in the early 1940s with the German Messerschmitt Me-262 fighter aircraft, turbines
became the preferred type of propulsion system. The performance of the early turbine
engines was severely limited by materials capability, especially in terms of operating
temperature. Jet powered fighters were in operation in the late 40s but large jet
aircraft, e.g. bombers and transports did not become feasible until nearly a decade
later, largely because of the increased difficulty of producing large turbine engines
with adequate reliability. As will be described later, turbine technology has evolved
and, today, propulsion technology is not the limiting factor it once was.
The evolution of aircraft and the role of materials
The evolution of aircraft that fly farther and faster has been a consistent goal of
aircraft designers. Achieving this goal has required new materials with other attributes
in addition to strength and light weight. For example, aircraft that fly at higher speeds
require higher temperature capability materials due to frictional heating. As a
consequence, skin materials have progressed from wood and fabric used in the early
aircraft to advanced alloys of aluminum, titanium, and polymer matrix composites
containing high-strength carbon fibers. Perhaps the most sophisticated aircraft ever
built in the western world is the SR-71 Blackbird which had an all Ti alloy skin. This
military aircraft was used for high altitude reconnaissance missions and was capable
of speeds in excess of mach 3. The lessons learned from military operation of the SR71 showed what practical limitations existed for commercial supersonic flight,
especially above mach 2, where the skin temperatures exceed the capability of Al
alloys. As a consequence, there has not yet been a large supersonic vehicle produced
and entered into scheduled service that flies at these speeds. The Soviet Tupolev
design bureau did produce several all-Ti Tu-144 aircraft but even in their economic
system, it was not considered practical. The Concorde operates at mach 1.8 and is an
Al airplane. Even so, it has not been economical to operate and is being retired from
revenue service despite its technical success. Damage tolerance became recognized as
an important issue in 1954 when three Comet jet airplanes, manufactured with 7075type aluminum, crashed. The cause of the crashes was attributed to premature fatigue
failure of the pressurized fuselage associated with stress concentrations at windows
and hatches. Today, fracture toughness and fatigue crack growth have been
incorporated as a primary design criterion in many products in the same manner as
strength was used 35 years ago. In fact, newer, higher toughness Al alloys for fuselage
skins have enabled significant weight reductions through removal of some of the
circumferential frames that serve, among other things, to arrest a running crack. This
is discussed in detail later and is mentioned here as an example. Beginning in the
80s, jet powered flight had become a given and other considerations for aircraft
such as fuel costs, the revenue opportunities associated with increasing range and
payload, and reducing landing weight fees again returned the technical focus to
weight reduction but without sacrificing life. Then, in the 90s, the realization of the
benefits of extending the life of the aging aircraft fleet resulted in a technical focus on
improved damage tolerance and improved corrosion resistance. One response to this
requirement was the possibility of retrofitting existing aircraft with newer and
advanced alloys. This was done extensively in the case of the B-52 bomber and other
military aircraft. In the case of commercial products, derivative aircraft models and
the emergence of new, large twin engine aircraft was more representative of product
trends. The currently used airframe design methods have evolved over many years
and the practices employed today incorporate both the benefit of this past experience
and availability of better analytical methods. Static strength has been an important
first order consideration since the beginning of flight and aircraft are usually designed
to withstand a maximum operating load plus a safety factor, which is typically 1.5. In
modern aircraft, static strength is necessary but not nearly sufficient, largely because
of the protracted service lives expected of aircraft. The effect of fatigue on aircraft
integrity began to be considered as long as 70 years ago. Design methods that
consider fatigue as a constraint were introduced. Today, there are 2 conceptual
approaches to calculating fatigue limited structural life: safe life and fail safe. Safe life
design requires that no fatigue failure occurs in N lifetimes, where N always is greater
than one and typically on the order of four. Safe life design was introduced in the
1930s and 1940s and relies strongly on detailed knowledge of service experience and
requires rigorous product testing. Fail safe design was introduced in the 1950s and
assures that catastrophic failure is not probable as the result of a failure of a single
structural element. To achieve this result, fail-safe designs incorporate redundant
crack pathways in the design. Finally, damage tolerance was introduced in the late
1960s and early 1970s, and couples crack growth analysis with periodic inspections to
detect cracks and remove cracked load bearing members from service in situations
where these would have a high probability of failure prior to the next scheduled
inspection. The material property requirements for use in airframes vary depending on
the particular component under consideration [2]. The fuselage is a semi-monocoque
structure that is made up of skin to carry cabin pressure (tension) and shear loads,
longitudinal stringers or longerons to carry the longitudinal tension and compression
loads due to bending, circumferential frames to maintain the fuselage shape and
redistribute loads into the skin, and bulkheads to carry concentrated loads including
those associated with pressurization of the fuselage. Strength, Youngs modulus,
fatigue crack initiation resistance, fatigue crack growth rate, fracture toughness and
corrosion resistance all are important, but fracture toughness is often the limiting
design consideration. The wing is essentially a beam that is loaded in bending during
flight. The wing supports both the static weight of the aircraft and any additional
loads encountered in service due to maneuvering or turbulence. Additional wing loads
also come from the landing gear during taxi, take-off and landing and from the
leading and trailing edge the flaps and slats during that are deployed during take-off
and landing to create additional low speed lift. The upper surface of the wing is
primarily loaded in compression because of the upward bending moment during flight
but can be loaded in tension while taxiing. The stresses on lower part of the wing are
just the opposite. Compressive yield strength and modulus of elasticity in
compression are the static material properties that influence design and, due to
alternating loads caused during flight, fatigue resistance is also important. The tail of
the airplane, also called the empennage, consists of a horizontal stabilizer, a vertical
stabilizer or fin, and control surfaces e.g. elevators and rudders. Structural design of
both the horizontal and vertical stabilizers is essentially the same as for the wing.
Both the upper and lower surfaces of the horizontal stabilizer are often critical in
compression loading due to bending and, therefore, the modulus of elasticity in
compression is the most important property.
Evolutionary improvement of aluminium alloys for aircraft
Improved structural materials are usually classified as either a revolutionary product,
e.g. rapidly solidified and mechanically alloyed P/M alloys, discontinuous and
continuous fiber reinforced metals and polymers, and structural laminates, or
evolutionary, i.e. derivative alloys and tempers. Revolutionary products have had
limited success in incorporation into aircraft due to cost of manufacture, qualification
and certification and possibly modification of existing material production
infrastructure. Although polymer matrix composites are being used in modern
commercial aircraft, e.g. for the fin of the Airbus A310, the horizontal stabilizer of the
Airbus A340 and the Boeing 777, aluminium alloys have remained the materials of
choice for the airframe of most commercial aircraft. Evolutionary improved
aluminum alloys have had a much more rapid insertion due to their lower
manufacturing and/or life cycle costs, low substitution risk and the use of an existing
material production infrastructure. A summary of various microstructure/property
relationships for aluminum alloys is given in Table1. The basic metallurgical concepts for
maximizing properties of age-hardenable aluminum alloys are well known [2,5]; the
challenge is putting them into practice in alloy design. For example, the impurities Fe
and Si form coarse constituents in 2XXX 7XXX, and 8XXX aluminum alloys and
result in lower fracture toughness [2,6] and have an adverse effect on both fatigue
crack initiation and fatigue crack growth resistance [7]. Coarse primary phases formed
when solubility limits are exceeded at the solution heat treatment temperature (or
those formed during processing and not re-dissolved during subsequent heat
treatment) have a similar effect [8]. Consequently, low Fe and Si levels, a good
knowledge of complex phase diagrams and tight controls on composition can be used
to produce a good balance of strength, fracture toughness and fatigue crack growth
clad since they can be susceptible to intergranular corrosion. In addition, the 2XXX
alloys cannot be fusion welded, a process that is being considered for reducing weight
and costs of manufacturing. The 6XXX alloys are weldable and cheaper than 2XXX
alloys, however, Cu-rich 6XXX, e.g. 6013-T6 and 6056-T6 are also susceptible to
intergranular corrosion. This susceptibility is associated with the formation of
precipitate free zones at grain boundaries, which are developed during artificial aging,
are depleted in Si and Cu and are anodic with respect to the grains [10]. A new temper
has been developed, designated T78 that has a controlled degree of overaging that
desensitizes 6056 to intergranular corrosion, keeping the yield strength at an
acceptable level with respect to the T6 temper. Other experimental tempers have been
developed that prevent intergranular corrosion without any loss in strength [11]. An
alternative to changing alloys to facilitate joining, is the use of a relatively new
joining method known as friction stir welding
(FSW). In this method, the alloys are not melted, but instead are joined in the solid
state by mechanical working. In a sense, they simply are kneaded together with a
rotating tool. The use of FSW creates the opportunity to join a wide range of Al
alloys that cannot be fusion welded. Superplastic forming is also a way to reduce part
count and manufacturing cost since it lends itself to the manufacture of very
complicated parts. For example, a single sheet can be formed into a complex
arrangement of ribs and stiffeners and hence replace an assembly of parts and
fasteners at a reduced manufacturing cost and at a reduced rate. Superplastic 7XXX
alloys have been available for some time, however there have been difficulities with
developing superplastic 6XXX alloys. A thermo mechanical process has recently been
developed for 6013-6011 alloys that produces a microstructure amenable to
superplastic forming [12]. The process involves obtaining a fine, uniform distribution
of one micron-sized particles for subsequent particle stimulated nucleation of
recrystallization in order to obtain a fine (9.5 micron), equiaxed, recrystallized grain
structure and a random texture. The alloys are then superplastic above 500 C.
Uniaxial tests indicated a strain rate of 0.5 at 540 C and elongations of 375% using a
stress of 4.7MPa.
Lighter weight, higher stiffness materials for aircraft
Aluminum-lithium alloys are attractive for aerospace applications because they have
lower density and higher modulus than conventional aluminium aerospace alloys.
made from 2124. The Al-Li alloy 2098 has been successfully
demonstrated/flight tested for F16 skins and has showed a 6X life improvement over
2024 skins. There are a number of new aluminum materials that are being developed
for use in commercial transport aircraft. Laminated hybrids of aluminium sheet with
aramid-fiber-reinforced (ARALL) or glass-fiber-reinforced (GLARE) composites
have high fatigue resistance and the potential for significant weight savings in aircraft.
These materials also have resistance to burn through in the event of a fire and can
potentially substitute for titanium in firewalls. On the negative side are the very high
material costs, typically 710 times that of monolithic aluminum sheet. The cargo
door of the C-17 is fabricated from ARALL. Laminates also offer the potential for
adding extra functionality, e.g. load monitoring, damage detection, etc. Combining
such functionality would make them more cost effective in aerospace structures.
Other aluminium alloys under development include Al-Mg-Sc alloys. Although
potentially very expensive because of the presence of scandium, they appear to have
excellent corrosion resistance, and as a body skin they may not need to be clad or
painted which would reduce maintenance costs. Higher strength forgings, ageformable alloys, less quench-sensitive alloys, and rivet alloys with improved
ormability are all being examined and developed for future use in subsonic aircraft.
Since a significant portion of airframe design is stiffness driven, there are
opportunities for new metallic materials providing high specific stiffness relative to
currently available materials. For example, aluminum beryllium alloys may provide
an affordable sheet metal alternative to resin matrix composites in stiffness critical
airframe structure. A comparison of the specific modulus and specific strength of
AlBe (62%Be, 38%Al) with boron/epoxy, Ti, and Carbon/epoxy is shown in Fig. 8.
Aluminum beryllium alloys are currently used for secondary structures such as
equipment shelves and support structure due to low density, high stiffness, and good
vibration damping characteristics. Application of these materials in primary structure
requires the establishment of a database for design and manufacturing, safe
manufacturing practices that avoid exposure to beryllium dust and particulates, and
corrosion protection methods for components in the field. Also appropriate safety
protocols to control exposure to beryllium in field maintenance must be applied.
Metallic sandwich panels with periodic, open cell cores are being developed with
novel fabrication and design tools [13]. They can be fabricated using protocols based
both on sheet forming of trusses and textile assembly. Analysis, testing and
optimization have revealed that sandwich panels constructed with these cores sustain
loads at weights greatly superior to stochastic forms and competitive with the lightest
known honeycomb core systems. The benefits of the truss/textile cores over
honeycombs reside in their higher specific strength at low relative density, and lower
manufacturing costs.
The need for advanced materials
Determining the best material to use for a particular application is not straightforward.
It will depend on many factors including customer requirements (eg performance,
cost, safety), design requirements (eg strength, temperature capability, density) and
material technology prospects (eg materials/processes currently and potentially
available). For aerospace applications, the large number of safety requirements such
as the protection against bird, ballistic and lightening strike and containment of events
like fire and fan blade off, makes finding an appropriate material particularly
challenging. Materials with high specific strength (strength per unit of weight) have
long been popular with the aerospace industry, as components made from such
materials provide the required strength with less weight, thereby reducing fuel burn
and operating cost. With growing concern over climate change and the focus on
reducing fuel burn and emissions intensifying, the importance of this characteristic
has never been greater. However, high strength, light weight materials are not the only
way to reduce fuel burn and emissions. Developing materials with enhanced
temperature capability will allow the engine to runhotter, improving the engines
thermal efficiency, reducing fuel burn and emissions.1 This is particularly critical for
the blades of the high pressure turbine, situated directly after the combustor, as their
temperature capability currently limits maximum engine temperatures.
In addition to this, adaptive materials, materials which have properties that can be
altered by changing the conditions they are subject to, can help to optimise the
aircrafts performance throughout the flight cycle leading to reduced fuel burn and
emissions.
Developing materials with these desired characteristics (improved specific strength,
high temperature capability, adaptive properties, etc) whilst satisfying other customer
and design requirements, is extremely difficult. As a result, manufacturers are moving
well beyond traditional materials (see Figure 4 on p.5 for material usage in aircraft),
investigating more innovative and exotic alternatives like composites, advanced metal
alloys, ceramics, nanomaterials and smart materials. These materials and the efforts
underway to develop them are discussed here.
Composites
Composites are materials made from two or more components that have significantly
different physical or chemical properties which remain distinct (on a macroscopic
level) within the finished structure. The advantage of composite materials is that the
properties they exhibit are different to simply the sum of the properties of the
constituent materials. Composites consist of reinforcement and matrix material. The
reinforcement, which generally takes the form of fibres, has high tensile strength but
is susceptible to breakage. In contrast, the matrix which surrounds and supports the
reinforcement has a relatively low tensile strength but is extremely tough. When
combined, the matrix and the reinforcement, counteract each others weaknesses to
produce a material that is stronger, stiffer and more damage resistant than either
material alone.
Fibre reinforcements can take many forms, they can be woven fabrics, multiaxial
fabrics (constructed by overlaying unidirectional fibres in different orientations),
braided fabrics or preforms (produced by stacking and shaping layers of woven,
multiaxial and/or braided fabric into pre-determined three-dimensional forms). The
type of fibre used will depend on the required properties (strength, cost, complexity,
etc) of the part being produced. In many cases, the fibres are received preimpregnated
with a controlled amount of resin (matrix material). As explained previously, there is
no single method of composite production. One way to make composite parts is
through the hand layup of pre-impregnated fibres (prepregs) in an open mould,
followed by cure in an autoclave. An autoclave is a sealable vessel, in which a high
temperature and pressure gas, usually nitrogen, is pumped into, thereby applying the
heat and pressure necessary for the material to form the shape of the mould. This
process, although well-established, is not ideal. The initial expenditure required to
purchase an autoclave is high which means that this method is only cost effective if
several components are being produced. However, unlike moulding methods, in
which considerable time and energy is spent heating up and cooling down the tools,
autoclaves are relatively energy efficient. Another drawback is that hand layup is very
laborintensive. Automated layup systems such as automated tape laying, tow
placement and filament winding can be used to reduce labour and also increase layup
accuracy and repeatability, however these processes may only lend themselves to
components of certain shapes and sizes.
An alternative to autoclave curing is closed moulding. One popular type of closed
moulding is resin transfer moulding (RTM). RTM involves placing the fibre layup in a
two-part closed mould into which resin and catalyst are pumped under low to medium
pressure. A variation of RTM is vacuum-assisted RTM (VARTM). In VARTM, the
resin is drawn into the mould by vacuum alone. The advantage of this process is that,
in some cases, it does not require high heat or pressure and can be undertaken with
low cost tooling hence allowing for the inexpensive production of large, complex
composite parts.
There are many other production methods in which, like RTM and VARTM, the fibres
are infused with resin during the compression process. Some of these require
autoclaves to make the process more robust and safer and/or special tooling. The main
advantages of all these methods are that there are no prepreg costs and that they can
use a wider range of fabrics (3D weaving, 2D and 3D braiding, stitching, knitting,
etc). Another method of composite manufacture used frequently is compression
moulding. With this process, a compound consisting of resin and fibres is arranged in
a preheated mould cavity (shaped according to desired part shape) before the mould is
closed, clamped and pressure applied. As the material viscosity drops, the compound
flows to fill the cavity, thereby creating the required shape. Compression molding
requires an expensive press and tools and is therefore a suitable method of production
when the quantity of components is significant. There are several benefits associated
with using composites in aircraft. One clear advantage is their high specific strength.
For example, carbon fibre is stronger and stiffer than aluminium, titanium or steel at a
fraction of the weight. A further benefit is that this strength can be tailored in any
direction. By varying the orientation of the fibres, the strength of a composite material
in any direction can be varied in accordance with the applied loads.7 This is clearly a
very useful property for aerospace applications where components are subject to
many different forces but need to avoid being thicker or heavier than required.
However, the real benefit of composites comes not from their high specific strength
but their ability to resist fatigue (damage which occurs when a material is subject to
cyclic loading) and corrosion, and to withstand temperature extremes. Such attributes
can enable reduced maintenance costs as airframe inspections /maintenance activities
do not need to be as frequent or extensive as for metallic aircraft. Boeings
understand composite material properties and failure modes, means that the weight
savings they offer do not always offset the costs incurred with this material choice.
However, with the use of certain processes and technologies (eg infusion
technologies, the introduction of high tow count fabrics and component integration)
composites can be cost competitive or even lower cost than their metallic equivalents.
Furthermore, as manufacturers improve production efficiency, this technology
matures and the industry acquires more experience with it, there will inevitably be
further opportunities for cost reduction.
Nevertheless, composites have been enthusiastically embraced by the aerospace
ndustry, with aircraft manufacturers progressively increasing the amount of composite
material used in the airframe and in aircraft systems.
Selecting the optimum material for a specific application meant analyzing every area
of the airframe to determine the best material, given the operating environment and
loads that a component experiences over the life of the airframe. For example,
aluminum is sensitive to tension loads but handles compression very well. On the
other hand, composites are not as efficient in dealing with compression loads but are
excellent at handling tension. The expanded use of composites, especially in the
highly tension-loaded environment of the fuselage, greatly reduces maintenance due
to fatigue when compared with an aluminum structure. This type of analysis has
resulted in an increased use of titanium as well. Where loading indicates metal is a
preferred material system but environmental considerations indicate aluminum is a
poor choice, titanium is an excellent low-maintenance design solution. Titanium can
withstand comparable loads better than aluminum, has minimal fatigue concerns, and
is highly resistant to corrosion. Titanium use has been expanded on the 787 to roughly
14 percent of the total airframe. Every structural element of the 787 has undergone
this type of life-cycle analysis and material types are based on a thorough and
disciplined selection process.
The right material for the right application. Without preconceived ideas, Boeing
engineers were able to specify the optimum material for specific applications
throughout the airframe.
In addition to lowering the overall airplane weight, moving to a composite primary
structure promises to reduce both the scheduled and nonroutine maintenance burden
on the airlines.
In addition to using a robust structural design in damage-prone areas, the 787 has
been designed with the capability to be repaired in exactly the same manner that
airlines would repair an airplane today with bolted repairs. These can be just as
permanent and damage tolerant as they are on a metalstructure.Reduced scheduled
maintenance. Experience with the Boeing 777 proves that composite structures
require less scheduled maintenance than noncomposite structures. For example, the
777 composite tail is 25 percent larger than the 767s aluminum tail, yet requires 35
percent fewer scheduled maintenance labor hours. This labor hour reduction is due to
the result of a reduced risk of corrosion and fatigue of composites compared with
metal.
capability to get an airplane flying again quickly, despite minor damage that might
ground an aluminum airplane.
In total, the reduced risk of corrosion and fatigue associated with composites
combined with the composite repair techniques described will lower overall
maintenance costs and maximize airline revenue by keeping airplanes flying as much
as possible.