Test 99

Name _________________________

Chemistry 11600-B

Section ____________

EXAM III

TA ___________________________

Monday, 8:00 PM

Total Points = 145

April 9, 2012

THIS EXAM IS FOR STUDENTS WITH MONDAY-WEDNESDAY 2:30 or 3:30

LECTURE. YOU SHOULD HAVE A GREEN COMPUTER ANSWER SHEET!
Directions:
1.

Each student is responsible for following directions. Read this page carefully.

2.

Write your name and other requested information on this page and on the separate answer
sheet.

3.

CODE your name on the answer sheet using an ordinary (#2) pencil.

4.

CODE your correct 10-digit identification number (PUID) on the answer sheet. THIS IS
VERY IMPORTANT!

5.

CODE your lab section number on the answer sheet. Please use all four digits, 0101,
0102, 0201, etc. This is also very important!

6.

CODE the test number shown in the upper right-hand corner on the answer sheet in the
block labeled ATest/Quiz Number@. This is Test Form #99.

7.

Put all calculations on the examination pages. DO NOT PUT ANY EXTRA MARKS
ON THE COMPUTER ANSWER SHEET!

8.

This exam consists of 20 multiple-choice questions worth 7.25 points each. Choose the
one best or correct answer for each question and write it both on your exam paper and on
the computer answer sheet. The computer answer sheet is the only one that will be
graded!

9.

This exam consists of 9 pages plus a page of useful information, a Periodic Table, and a
sheet of scratch paper. Please check to be sure that you have them all!

KEEP YOUR ANSWERS AND WORK COVERED TO PROTECT

THE INTEGRITY OF YOUR WORK!!

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______

1. If the same amount of heat is added to 5.00 g samples of each of the metals below, which
metal will experience the smallest temperature change?
Metal
Al
Au
Cu
Fe
a.
b.
c.
d.
e.

______

Al
Au
Cu
Fe
There is not enough information to tell

2. Calculate the heat capacity of a metal if 31 g of metal at 80C is dropped into 100g of water at
10C and the final temperature is 14C.
a.
b.
c.
d.
e.

______

Specific Heat Capacity

(J/g.K)
0.897
0.129
0.385
0.449

0.08 J/gK
0.82 J/gK
2.40 J/gK
4.18 J/gK
223 J/gK

3. To make a glass of tea, you pour 250 mL of tea, whose temperature is 20C, into a glass
containing 4 ice cubes (at equilibrium, the final temperature is 0o C). Each cube has a mass of
about 20 g. How much ice will remain to float at the surface? Ice tea has a density of 1.0g/mL
and a specific heat capacity of 4.2 J/gK. The heat of fusion for ice is 333 J/g.
a.
b.
c.
d.
e.

none
17 g
21 g
25 g
31 g

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______

4. Determine the standard reaction enthalpy for the formation of 2 moles of C from A and B:
4A + 3B 2C
if the following reactions are known:
2A + D C + F
2D 3B + 2F
a.
b.
c.
d.
e.

Ho = +200 kJ
Ho = +100 kJ

100 kJ
200 kJ
300 kJ
400 kJ
500 kJ

Questions 5 and 6 refer to the heating curve below, which is for 1 kg of a substance.

Temperature (oC)

400
300
200
100
0
0

50

100
Heat added (kJ)

______

5. Estimate the enthalpy of fusion per gram.

a.
b.
c.
d.
e.

25 J
50 J
100 J
125 J
150 J

150

200

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______

6. Estimate the specific heat capacity of the liquid.

a.
b.
c.
d.
e.

______

0.250 J/gK
0.375 J/gK
0.625 J/gK
2 J/gK
4 J/gK

7. A student in lab combined 50.0 mL of 0.25 M HNO3 with 50.0 mL of 0.25 M NH3 in a coffee
cup calorimeter. She determined that T was 7.35 C. Calculate Hrxn in kJ/mol. (Assume
that for both solutions the density is 1 g/mL and the specific heat capacity is 4.184 J/gK).
a.
b.
c.
d.
e.

0 kJ/mol
117 kJ/mol
246 kJ/mol
357 kJ/mol
458 kJ/mol

Questions 8-11 refer to the chemical reaction:

A(g) + B(g) C(g)

______

Ho = 100 kJ

8. A mixture of 2 moles of B and 2 moles of A releases:

a.
b.
c.
d.
e.

0 kJ
50 kJ
100 kJ
150 kJ
200 kJ

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______

9. Which line on the following graph shows the change in the free energy (G) for the reaction
A(g) + B(g) C(g) as the temperature increases from 0 K?

a.
b.
c.
d.
e.

a
b
c
d
e

______ 10. Ssystem

and Ssurroundings
for the reaction A(g) + B(g) C(g) are likely to be,
respectively:

a.
b.
c.
d.
e.

both positive.
positive and negative.
negative and positive.
both negative.
Not enough information to answer.

______ 11. If the standard molar entropies of A(g) and B(g) are 100 J/molK and 160 J/molK
respectively, and Go = 82 kJ/mol at 300K, the standard molar entropy of C(g) is:
a.
b.
c.
d.
e.

100 J/molK
120 J/molK
140 J/molK
160 J/molK
180 J/molK

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______ 12. Two gases are physically separated by a barrier in a glass container. When you pull out the
barrier, the two gases mix together because:
a. The entropy of the mixed state is higher than the entropy of the separated state.
b. The entropy of the mixed state is lower than the entropy of the separated state.
c. There are many more ways of reaching the mixed state (via random collisions between the
molecules) than there are ways of reaching the separated state.
d. Both a and c are true
e. Both b and c are true

______ 13. All of the following statements concerning entropy are true EXCEPT:
a.
b.
c.
d.
e.

Entropy values for substances are greater than or equal to zero.

Entropy is a state function.
A positive change in entropy denotes a change toward greater disorder.
The entropy of a substance in the gas phase is greater than in the solid phase.
Entropy is zero for elements under standard conditions.

______ 14. C onsider the combustion of octane:

C8H18(l) + 12O2(g) 8CO2(g) + 9H2O(g)
Useful information:

Hof (kJ/mol)

O2 (g)

CO2 (g)

H2O (g)

-393.5

-241.8

Octane
(C8H18)
-250.1

The standard enthalpy for the reaction of 1 mole of octane in excess oxygen is:
a.
b.
c.
d.
e.

241.8 kJ
393.5 kJ
635.3 kJ
5074 kJ
42.6 MJ

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CHM 11600-B Exam 3 (Test 99) 04/09/12

Questions 15 18 refer to the following plot of lnKeq vs. T1, measured for:
A+BC

ln Keq

Slope = 300,
intercept =4

1 / T ( K1)
______ 15. The reaction is:
a.
b.
c.
d.
e.

Exothermic
Endothermic
Endothermic only at low temperatures
Endothermic only at high temperatures
There is not enough information to say if its endothermic or exothermic

______ 16. When 1 mol of A reacts with 1 mole of B to produce 1 mol of C under standard conditions,
the entropy change of the system is given by:
a.
b.
c.
d.
e.

R
2R
3R
4R
5R

______ 17. When 1 mol of A reacts with 1 mole of B to produce 1 mol of C under standard conditions,
the entropy change of the surroundings is given by:
a.
b.
c.
d.
e.

R
2R
3R
4R
5R

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______ 18. The value of ln Keq at 300K is:

a.
b.
c.
d.
e.

1
2
3
4
5

______ 19. Given the graph below of G vs. Q for the reaction A+B C in aqueous solution at room
temperature, suppose the concentrations of A and B are held constant at 0.50 M. What would
the concentration be for C at equilibrium?

a.
b.
c.
d.
e.

0.20 M
0.75 M
1.00 M
1.50 M
3.00 M

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CHM 11600-B Exam 3 (Test 99) 04/09/12

______ 20. What is the boiling temperature of water in La Paz (Bolivia)? La Paz is high up in the
mountains (the Andes), where the atmospheric pressure is about 0.67 atm. Give your best
estimate by neglecting the temperature-dependence of Ho and So (given in the following
table at 298K):

H2O (l)
H2O (g)
a.
b.
c.
d.
e.

71oC
79oC
87oC
95oC
103oC

Hof (kJ/mol)
-285.83
-241.83

So (J/mol.K)
69.95
188.84

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CHM 11600-B Exam 3 (Test 99) 04/09/12

Potentially Useful Information

Formulas: X = Xfinal Xinitial
q = C m T
E = q + w
w = PV
Suniv = Ssystem + Ssurr
Ssurr = H/T
G = H TS
G = Go + RT ln Q
Go = RT ln K

Constants: 1 J = 1 Newton-meter
1 L = 1 x 103 m3
1 cal = 4.184 J
1 atm = 760 torr = 101,325 Pa = 101,325 Newton/m2
R = 8.3145 J/molK
0 K = 273.15oC
Cwater = 4.184 J/gK
1 bar = 100 kPa
1 bar 1 atm

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CHM 11600-B Exam 3 (Test 99) 04/09/12

Key
1.

a.

2.

b.

3.

b.

4.

c.

5.

a.

6.

b.

7.

c.

8.

e.

9.

d.

10. c.
11. b.
12. d.
13. e.
14. d.
15. a.
16. d.
17. a.
18. e.
19. b.
20. c.