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DATE : 11-01-2015
PAPER-1
PART- I MATHEMATICS
1.
lim
2e x sin x 3x x 2 2
x3
x0
4.
n =
(tan1 x) dx
x 0
x x 2 x3
x3
2 1
..... x
....... 3x x 2 2
1
2
6
6
x3
Sol. In =
Lim
.....................
x3 x3
3
6
x3
n 1 1 x2 dx.
0
1
In =
1
xn1
dx
4(n 1) n 1 1 x 2
0
1
1
6
(n + 1) In =
2.
1 n 1
1
xn1
tan1 x
0
n 1
xn1
dx
2
4
1
x
0
1
(n 1) n2 =
xn1
dx
2
4
0 1 x
Required Sum
vHkh"V ;ksx
1
(n + 1) In + (n 1) In 2 =
1
xn 1dx
2 n
2 0
n = 10 , Sum ;ks
xQ y
2 10
5.
Sol.
z 3 = 5
z
10
and
z2 =
(1)
1
4
1
4
f(x) y =
5 vkSj
y=
and y =
2
5
Hence
vr%
2
x
dx +
2
dx
x
2
5
=
2
5
+ 2 ln 1 2 ln
2
= 2 2 ln
= 2 + 2ln
5
2
(2)
10
12
2
1
= 1 or 1
= 1 or 1
if = 1 then z 3 + 1 = 0
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SOL JRCT3110115-1
and z 2 = 1
z = 1
if
= 1 then z 3 1 = 0 and
2
z = 1
z = 1
Hence z = 1 & = 1 or
z = 1
&
= 1 ]
f(x) = ex x
x3
3
Sol. f(x) = ex x
x3
3
6.
7.
Sol. dx
f '(x) = ex 1 x2
8.
x=0
dy
dx
x3 1
x 2x
2
x
1 dt
2 t
=t
(2x
x3 2
x
x2
1
2x1 1
=1
x1 = 0, y = 1
required point (x1,y1) (0, 1)
minimum distance between two curve = 2x length of
r from (0, 1) on the y = x
x 2
x
2 2 dx
x
x
2
= 2x
2.
) dx = dt
10.
+c
Sol.
x
x
; g(x) 2
.....................
x a
x b
x
x
f(x) 2
; g(x) 2
.....................
x a
x b
f(x)
= 2x + 1
dx is equal .....................
x 6 2x 3
Let x2 +
. Minimum .....................
f ' (x) = 0
ex = 1 + x2
At x = 0, minima occurs and f(x)min = 1 = a
So a + b = 1
x3 1
9.
ewy gSA
let ekuky = x3 ex + 3 = k
y = x3 ex + 3
Sol.
f(x) =
x a
h(x) =
; g(x)
dy
dx
and
x b
x2 x 1
x 2 ax (1 b2 )
= ex + 3 [3x2 + x3] = 0
x = 0, x = 3
at x = 3, y = 27 ij
so, for two distinct real roots K (0, 27)
so, number of prime value of will be 2, 3, 5, 7, 11, 13, 17,
19, 23 = 9
natural domains
So, discriminant of denominator part of each function less
than zero.
a > 0, b > 0 and a2 4(1 b2) < 0
a2
4
+ b2 < 1
2 1
=
4
2
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SOL JRCT3110115-2
11.
14.
(A), (C)
15. lim 1
n n 4
Sol.
2
(n
n2 r 2
1
n
=
2
n
n
r0
2n
1
Sol. n S =
n
2(x |x|)
g(x)
r0
2
2
n (1 x ) dx = x n (1 x )
= 2 n 5 2
S =
(A) incorrect
(B) g(x) is many one
(C) , [ 1, 1] + [ 2, 2]
(D) f(x) = f(x) Hence in correct vr% xy r
16.
gSA
; . = 6 ...(2)
x2 + ax + 3 =
; . = 3 ...(3)
a b 2c
AB
Now =
AC
2cos 2
cos cos 2x dx = 0
2
I1 = 0
1
cos( cos 2x) dx =
cos( cos t) dt
20
[Put 2x = t]
=
2
2
[2x = t
ba
ab
a
2
=2
Lim
esinx (e
tan x sin x
1) .
(tan x sin x)
x 0
...(1)
/2
I2 =
ba
ca
/2
/2
=0
On adding t ks
M usij
x) dx
2I1 =
; . = 2 ...(1)
x2 + bx + 6 =
cos( cos
x) dx
I1 =
2x 2
0 1 x2 dx
(A) x + ax + 2 = 0, .....................
(A) x2 + ax + 2 = 0, .....................
cos( sin
x) dx .....................
/2
Sol. I1 =
/2
cos( sin
r 2
n 1
n
= 2 n 5 4 + 2 tan12
25 2 tan1 2
e
e4
Suppose 1 =
e2 n 5 4 2 tan
.........
12.
13.
2
2
dx
1 dx
2
0 1 x
0
1/ n
zn = 12.
j[kusij]
/2
cos( cos t)
dt = 3
I2 + I3 = 0 ......(2)
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SOL JRCT3110115-3
17.
(A)
mV0 q
d1
=
mV
d
q
0
2
1 (x 1)
d1
d2
19.
(B)
f (x) is onto
obviously at x = 0 and x = 2, value of f (x) is
same
many one
range of f (x) is (1, )
(D)
range of f is R
Jf JN
mv x mv y
PART-II PHYSICS
18.
Sol.
(C)
20.
vy
vx
v y v x
21.
22.
23.
Sol.
R1 sin1 = d1
R2 sin1 = d2
R1 d1
=
R2 d2
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SOL JRCT3110115-4
24.
33.
25.
27.
focus
and rFkk
1
q
40 (2L) 2
converge at focus
28.
In a radioactive decay
,d jsfM;ks/kehZ{k; vfHkf ;k
Sol. NA 2 = NB 9
NA = 4.5 NB
34.
29.
30.
(D)
31.
Sol. d =
h
p
vp
p = mv
ve
gS
me
mp
p=
2mK mK = p
2
32.
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SOL JRCT3110115-5
PART-III CHEMISTRY
35.
(B)
(C)
36.
41.
m=4
3
2
1
3d orbital d {kd (1e)
3
1
0
3p orbital d {kd (2e)
2
1
1
2p orbital d {kd (2e)
Total number of electrons = 1 + 2 + 2 = 5.
by sDVkWuksad h d qy la[;k= 1 + 2 + 2 = 5.
Sol. Negligible liquid water present in 1st vessel will not be able
to maintain its equilibrium with water vapours in 2nd vessel
and whole of it will vapourise. As a result, gaseous moles
in double capacity 2nd vessel will slightly increase. So final
total pressure will be slightly greater than (P+P')/2.
42.
- +
PhO Na
Me2SO4
Ph
44.
PhO Mg
NaOH[1eq]
Sol. PhOH
OMe
37.
vf/kd gksrk gS] blfy , ,d by sDVkWu d kst ksM +usij Na+ (g)
vf/kd re ek=kk esa t kZeqDr d jrk gSA
3+
At low pressure, if RT =
vEy
Alc. KOH
Sol.
2 aP ..............
nkc ij
P 2 (V) = RT
V
i.e. vFkkZ
r,
PV2 RTV + a = 0
V=
39.
RT R 2 T 2 4Pa RT
=
2P
2P
No anti -H is present.
fuEu esalsd kSu izd k'kh; : i ----------------Sol. (A) Square Planar complex. So optically inactive.
(B) & (C) don't contain POS & COS. So, optically active.
Sol. (A) oxZlery h; la
d qy A blfy , izd kf'kd : i lsvf" ;A
40.
OH
CH3
CH3
Br
,s
Yd ks-KOH
Br
Sol.
CH3
CH3
xk l
H
Br
lei{k ,Yd hu
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SOL JRCT3110115-6
PAPER-2
MATHEMATICS
Sol. 1 amu =
1
1.992648 1023 g = 1.66054 1024g
12
4x = n + ( 1)n
1
1.992648 1023 g = 1.66054 1024g (12C
12
ekud d svuql kj)
1
H ekud d svuq
l kj 1 amu = 1.6736 1024 g.
D;ksafd amu d k eku c<+rk gSblfy , vkoksxzknksla[;k ?kVsxhA
Product of which of the reaction can ..........
= 75
24
Sol. 1 amu =
48.
1
2
2.
Hg(OCOCH ) /THF/H O
3 2
2
NaBH /OH
4
2
3
1
3
CH3CHCH3
OH
CH3
C1
(1) CH3MgBr
(B)
(2) H
O
CH3CHCH2CH3
C3
C
(1, 0)
C2
OH
Br
or
Mg
(C)
;k t = 3
z+
PhCCH3
and
Br
HBr(excess)
2
3
2
3
An+1 = 0
as A5 is null matrix n + 1 can be any number greater
than or equal to 5. n = 4
PhCCH3
H3O+
Br
PhCCH3
O
Na (excess)
3.
CH
(D)
1
3
(P)
CH3COCCH3
49.
PhMgBr
either
(3, 0)
4.
A( a ), B( b ), C( c ) are ......................
Sol. Given
.....................
Acetone
AC AB
=0
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SOL JRCT3110115-7
(3) vks
j (4) d kst ksM usij
3/4
2I =
3/4
1/ 4
...(i) &
...(ii)
a b
=
5 4
b c
=
=
4 3
a
(i) o (ii) ls
5
c
3
I=
1
4
8.
b2 + c2 = a2
ax3 + 4x =
1
x
...(1) &
f=kT;k esa = 1
6
6
x=
Hence vr%a = 5, b = 4, c = 3
5.
6.
f(f(x)) dx
10.
......................
11.
f(f(x)) dx d k ......................
&
+x+
f(1 x) = (1 x)3
1
4
3
2
1/ 4
3x 2
2
, 2 & Q
, 2
2
2
3/4
Sol. f(x) = x3
1/ 4
a=4
3/4
...(2)
Thus P
f(x) + f( 1 x) is .....................
f(x) + f( 1 x) d k ......................
7.
1
2
x2
=1 =1
3ax2 + 4 =
Since in radius pw
fd
dx
1/ 4
1
2
2I =
Now vc a + c = 2b
mid point of PQ is O
PQ d k e/; fcUnqO gS
A
x1 + x2 = 0,
(1 x)2 + 1 x +
1
4
x12 + x 22 x1 x2 4 = 0
x1 = 2 , x2 = 2
so, equation of PQ is x + y = 0
blfy , PQ d k lehd j.k x + y = 0
y
3/4
Now vc, I =
f(f(x)) dx
...(3)
1/ 4
3/4
also I =
(2)
2
(x1, x1 x12)
f(f(1 x)) dx
1/ 4
3/4
=
f(1 f(x)) dx
(1,0)
Q
3/4
1/ 4
3/4
1/ 4
dx
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(x2, x22 x2 2)
(2, 0)
1
, 9
2 4
...(4)
1/ 4
2I =
SOL JRCT3110115-8
2 x , x 1
2
2x x , x 1
Now vc
y = 2 x x = 2 y
as pw
fd
x1 y1
Sol. f(x) =
2x 2 x1
,
3
2(x 22 x 2 2) (x12 x1 2)
0=
3
So
blfy ,,
0=
y = 2x x2 y = 1 (x 1)2
1 y
2x2 + x1 = 0
...(i)
and (2x22 + x12) (2x2 + x1) 6 = 0 ...(ii)
From (i) and (ii)
x1 = 2 and x2 = 1
(i) o (ii) ls
x1 = 2 vkS
j x2 = 1
(x 1)2 = 1 y x = 1 +
f(x) = g(x) x = 0, 1, 2
f(2) = 0 & f(1) > 0
b=2, c=1
g(x)
P
(1,0)
Q
x = 0,
(2, 0)
(1,0)
(2x x
x 2) dx
(x
2) dx =
x3 x 2
2x
2
3
2
18.
, 3
d k lfn'k Hkkx
19.
= (y z) i + (z x) j + (x y)
1
{(a b)2 + (b c)2 + (c a)2}
2
( i +
5
2
Q1 2 i j k , ......................
Q1Q2
, 2
If a, b, c are integers......................
=
12.
3
2
9
2
, ,
n = 5, 6, 7
Hence number of 'n' = 3
Area {ks
=kQ y =
No of values = 7
(1, 2)
1
, 9
2 4
(2,0)
12 4 = 2
3
12
(x 1)
(50)
k + 2(x i + y j + z k )
j + k ) = 0
2x + y z = , x + 2y + z = , x y + 2z =
x=y=z=
It
is
straight
line
passing
through
origin
and
1
perpendicular to the plane r.(i j k)
Norm of
(Q1 Q2 ) ( 2)2 (1 x)2 (1 y)2 (1 z)2 10
15.
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SOL JRCT3110115-9
Sol. 9f(3)
x2 f(x)
f(x)
f '(x) +
dx k
0
3
2xf(x)dx + (f(x))2 dx + k
0
Sol.
(2xf(x) (f(x)
) dx k,
Now
2x f(x) f2(x) = x2 (f(x) x)2 x2
3
3
2x f(x) f2(x)dx
x2 dx
Let z1 =
3
2
(2xf(x) (f(x)
ei
& z2 =
ei2
) dx 9
Then,
0
kmin = 9
ei( 12 )
z1 . z2 =
i.e., 1 + 2 = /2
z1
z2
ei( 1 2 )
(ii) 2 2b b = 4 b =
/2
The value of
/2
n2
x cot xdx is
d k ......................
or b 2 + 2b = 4 b = 2
both are not possible
I=
5 3 15
Product of possible value of b =
=
2 2
4
Two complex numbers ......................
nkslfEeJ la[;k;saz1, z2 ......................
3 3 3 3 5
, , , , , , , ,
4 4 4 4 4 4 4 4
7 7 7 7 5 5 3 7
, , , , , , , .
4 4 4 4 4 4 4 4
23.
2
3
|4| = 15
3
5
7
or
or
2
2
2
5
2
C-III
0<b<1
Minimum value = 1 b2
Maximum value = Maximum (f(0), f(1))
= Maximum (1, 2 2b)
(i) 1 b = 4 b = 3 Not possible
22.
or
= purely imaginary
/2
/2
x logsin x 0
logsin x dx
0
/2
=0
as t S
l k fd
logsin x dx =
0
1
log 2
2
logsin x
lim x log sin x = lim
x 0
x 0
1/ x
x 2
cot x
lim
=
lim
2
x 0
1/ x x 0 tan x
lim x,
= 0.1 = 0
x 0
tan x
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SOL JRCT3110115-10
PHYSICS
kx a(B2l 2C m)
24.
a 2 2
x
B l Cm
Sol.
u sin 2
R
g
2sin cos
3 20
10
300
20
sin 1 sin 2
q max BlCVmax
q max BlCX 0
1
1 3
sin
2
4 16
2
sin
K
B 2l 2 C m
Vmax X 0
16sin4 16sin2 + 3 = 0
..(3)
X0
3 1
;
2 2
KC
m
1 2 2
Bl C
= 60.; 30
H max
u 2 sin 2
0.75 m ;
2g
0.25 m
31.
v max 20 m / s
T
2u sin
3
;
g
5
1
5
32.
25.
(D)
26.
(AB)
27.
mg
mRlft Zr d j ld rk gSA
29.
Kx IlB ma
q
Bvl
C
I BlCa
..(2)
From (1) and (2)
..(1)
3
to reach its equilibrium position. The upward
4
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SOL JRCT3110115-11
acc. =
axg
axg
4g
=
=
x
m
a( / 4)
4g
3
and A =
.
4
Therefore vmax =
F0
J2
1 F0
= K
2m2
2 K
2K
m2
K
J = F0
3
g
2
m2
T 1
2
4 4
K
le; =
35.
=
m2
2 k
<N> =
m2 m2 2F0
J
4J
=
= F0
/
=
T/4
T
K 2 k
Ans. 36
40. Maximum power transfer to external
Sol. For maximum power transfer in external circuit R = 0;
10
0.5 50 watt
0.5 0.5
36.
07
37.
constant.
decrease.
A crZ
u
In chamber A
38.
= (PA)i (PA)f =
eas
nA RT nA RT nA RT
V
2V
2V
......(1)
In chamber B B crZ
u
1.5 P
essa
(PB)i (PB)f =
......(2)
(1) o (2) ls
nA
1
2
=
=
nB
1.5 3
or ;k
39. Given system is in equilibrium
Sol. If J is the impulse imparted to the m2 by spring after
removal of F0 (up to the time spring attains its natural
length for the first time.)
mA
2
=
mB
3
V
2V
2V
or ;k
or ;k
mA / M
2
=
mB / M
3
3mA = 2mB
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SOL JRCT3110115-12
AI =
4
d
3
CHEMISTRY
47.
50.
4
3
OH
Sol. (I)
4
3
=
R
4
d
3
Con.H2SO4
1
1
4
or
=
v 3R 3R 4d
OH
(II)
4
1
1
4
3
3
3R 3R 4d = R
3
3
solving we get d =
R=
4 = 3 cm
4
4
OH
(III)
0 r 2
2R
Con.H2SO4
Ans.
Con.H2SO4
51.
fuEu vfHkf ;k d k eq[; mRikn -------------------Sol. It is Bimolecular elimination reaction and in this reaction
-Hydrogen and leaving group should be present on
opposites side.
03
52.
Ecell = Ecell
0.06
[ Zn 2 ]
log
2
[ Ni 2 ]
At equilibrium Ecell = 0
0
Ecell
=
0.06
[ Zn 2 ]
log
2
[ Ni 2 ]
0
0
ENi
EZn
=
2
2
, Ni
, Zn
F=
M 2
F=
3M2R
16
3R
8
0.24 (0.75) =
log
[ Zn 2 ]
[ Ni 2 ]
0.06
[ Zn 2 ]
log
2
[ Ni 2 ]
0.06
[ Zn 2 ]
log
2
[ Ni 2 ]
= 17
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SOL JRCT3110115-13
[ Zn 2 ]
Taking antilog,
[ Ni 2 ]
= 1017
= 1017
[ Ni ]
or
Sol.
lSy d sfy ,
[Ni2+] = 1017 M.
lSy vfHkf ;k] Zn, Zn2+ || Ni2+, Ni gSA
Zn + Ni2+
Zn2+ + Ni ft ld sfy ,
0
Ecell = Ecell
lkE; ij
60.
2
0.06
[ Zn ]
log
2
[ Ni 2 ]
R gksld rk -----------------61.
Ecell = 0
0
Ecell
=
0
ENi
2
, Ni
R can ..............
S can be ................
S gksld rk ------------------
0.06
[ Zn 2 ]
log
2
[ Ni 2 ]
Sol.(60 to 61)
Cl
NaOH
0.06
[ Zn ]
log
2
[ Ni 2 ]
0
EZn
=
2
, Zn
OH
0.06
[ Zn 2 ]
0.24 (0.75) =
log
2
[ Ni 2 ]
log
[ Zn 2 ]
[ Ni 2 ]
(Chiral)
(R)
Ag+
(S)
1,2-Me shift
OH
O
(T)
OH
= 17
[ Zn 2 ]
= 1017
[ Ni 2 ]
;g lkUnzrk vuqikr n'kkZrk gSfd y xHkx lEiw.kZNi2+ vk;uksad k
vip;u Ni esa gks t krk gS o blfy, Zn lsZn2+ d h lkUnzrk
izkIr gksrh gSt ksfd y xHkx 1 M [ Ni(NO3)2 = 1 M]. gksrh gSA
bl izd kj,
1
17
63.
L. atm
300 K
mol K
10 atm.
= 10
[ Ni ]
53.
64.
[Ni2+] = 1017 M.
or ;k
Sol. 1+1+1+2+1+0+1+2+0+0=9.
Sol. Since almost whole of the Ni2+ ions is reduced to Ni, total
charge delivered =
nNi 2 2 F
65.
2+
Sol.
AgA
Ag+ +
(x+y)
A
x
AgB
Ag+ +
(x+y)
B
y
= 1 0.5 2 F
= 96500 C.
58.
x
3
y
y = 5 108 ;
AgA AgB
x = 15108
m0 (AgA) S( AgA)
1000
m0 (AgB) S( AgB)
1000
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
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SOL JRCT3110115-14
H2CBr
67.
CH3
E=
Br
69.
68.
CH2Br
Sol.
p q = 5 11 = 55.
Cl
Br
Sol. A =
Br
Br
CH3
reaction.
B=
H2C
Br
CH3OCH2Br and
CH3
CH3
Br
Inactive
CH2Br
gy %
Cl
Br
C=
D=
CH3
Br
Inactive
CH3OCH2Br
rFkk
SN1
rFkkSN2 vfHkf ;k
nsrsgSA
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PTC024029
SOL JRCT3110115-15
DATE : 11-01-2015
CODE-0
PAPER-1
MATHEMATICS
1.
8.
(C)
(B)
2.
9.
(D)
(A)
3.
10.
(D)
(A)
15.
(BCD) 16.
17.
4.
11.
(D)
5.
(ABD) 12.
(A)
6.
(ACD) 13.
(D)
7. (B)
(ABC) 14. (AC)
(C)
(C)
(C)
(D)
A p,r ; B q, C q, D r
PHYSICS
18.
25.
32.
(A)
(D)
(C)
19.
26.
(B)
(A)
20.
27.
(B)
(C)
21.
28.
(D)
(AB)
22.
29.
33.
23.
30.
24.
31.
(A)
(ABCD)
CHEMISTRY
35.
(A)
36.
(C)
37.
(D)
38.
(B)
39.
(D)
40.
(A)
41.
(C)
42.
(B)
43.
(B)
44.
(A)
45.
(BD)
46.
(BC)
47.
(AB)
48.
(ABCD)
49.
(ABCD) 50.
51.
A pqr ; B q ; C ps ; D ps
PAPER-2
MATHEMATICS
1.
8.
(BD)
(D)
2.
9.
(AB)
(B)
3.
10.
(ACD) 4.
(B)
11.
(ABC) 5.
(B)
12.
(ABC) 6.
(C)
13.
(C)
(C)
7.
14.
(B)
(C)
15.
(A)
16.
51
17.
65
17
19.
50
20.
09
21.
15
22.
08
23.
20
18.
PHYSICS
24.
(ABC) 25.
(D)
26.
(AB)
27.
(BC)
28.
(BCD) 29.
(B)
30.
(A)
31.
38.
(B)
(C)
32.
39.
(B)
(36)
33.
40.
(C)
(50)
34.
41.
(B)
(07)
35.
42.
(B)
(21)
36.
43.
(C)
(27)
37.
44.
(A)
(36)
45.
(03)
46.
(12)
CHEMISTRY
47.
(A)
48.
(A)
49.
(B)
50.
(C)
51.
(B)
52.
(C)
53.
(A)
54.
61.
(A)
(A)
55.
62.
(C)
(09)
56.
63.
(C)
(10)
57.
64.
(C)
(09)
58.
65.
(A)
(27)
59.
66.
(C)
(05)
60.
67.
(C)
(55)
68.
(02)
69.
(04)
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
Toll Free : 1800 200 2244 | 1800 258 5555 | CIN: U80302RJ2007PTC024029
SOL JRCT3110115-16