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January 2013
International GCSE
Chemistry (4CH0) Paper 1C
Science Double Award (4SC0) Paper 1C
Edexcel Level 1/Level 2 Certificate
Chemistry (KCH0) Paper 1C
Science (Double Award) (KSC0) Paper 1C
January 2013
Publications Code UG034348
All the material in this publication is copyright
Pearson Education Ltd 2013
Question
number
1 a
M1
M2
M3
M4
M5
M6
M7
b
i
ii
2 a
i
ii
b
c
i
ii
iii
Answer
nucleus
protons
neutrons
electrons
shells
protons AND electrons
electrons
3
5
C
B
fluorine / F2
hydrogen chloride
hydrochloric (acid)
HCl
Notes
Marks
1
1
1
1
1
1
1
1
1
1
1
1
1
1
1
In either order
Accept F
Total
15
Question
number
3 a
i M1
M2
ii
b
c
i
ii
iii
Answer
bubbles / fizzing / effervescence
iron/solid disappears
OR
green/colourless solution (forms)
M1
M2
M1
M2
2
(1)
2
white
blue
D
boiling point
100 C
melting/freezing point
/
0 C
Notes
Accept gas formed /given off
Ignore any name or formula
Accept iron/solid gets smaller /
dissolves
Ignore references to heat change /
change in pH
Penalise oxidation states other than (II)
Accept ferrous sulfate
Reject ferric sulfate
Accept multiples and fractions
Ignore colourless
Ignore all qualifiers such as pale / dark
Marks
1
1
1
1
1
1
1
1
Question
number
3 d
i
ii
Answer
low density / less dense than air
non-flammable
OR
does not burn / explode (when ignited)
H2(g) H2(l)
Notes
Marks
Total
12
Question
number
4 a
i
ii
i
ii
iii
iv
Answer
oxygen / air
iron(III) oxide / ferric oxide
M1 grease / oil
M2 paint
Notes
Marks
1
1
1
Not just some of the nail/it falls off
Accept mass increased more
Ignore highest mass
Ignore just mass increased by 0.3 g
Accept weight in place of mass
1
Accept
should
Accept
Accept
1
1
Question
Answer
number
4
d
M1 galvanising / sacrificial (protection)
M2 zinc more reactive (than iron)
OR
iron less reactive (than zinc)
Notes
Marks
1
1
Total
11
Question
number
5 a
Answer
M1
(compound/molecule/substance containing)
carbon and hydrogen (atoms)
M2
only
Notes
Marks
Question
number
5 c
i
Answer
alkene(s)
ii
iii
Notes
CnH2n
M1
M2
M3
M4
Marks
1
Question
number
5 d
i
ii
iii
iv
i
ii
Answer
but-1-ene
C4H8
M1 (compounds/molecules with) same molecular
formula / same number of each type of atom
colourless / decolorised
C2H4Br2
Notes
Marks
Accept butene
Ignore mention of cis or trans
1
1
1
1
1
1
14
Question
number
6
a
M1
M2
M3
M4
M5
M1
M2
M3
Answer
(same) volume of solution/liquid
(same) concentration (of solution/liquid)
(same) amount of metal
(same) (total) surface area
/ state of subdivision of solid
(same) method/length of time/speed of
stirring
22.4
17.7
4.7
Notes
Marks
1
1
1
Question
number
6
c
i M1
M2
Answer
magnesium / Mg
largest difference in (recorded) temperatures
Notes
DEP on M1
Do not accept results in place of
temperatures
Explanation must be comparative:
Not just rises are 10.5 and 15.5 without
reference to values for other metals
Not just very different temperature
changes
Accept two temperatures furthest apart
Not just largest temperature rise
No penalty for quoting wrong difference,
eg 4 C
Marks
1
1
Question
number
6 c
ii M1
M2
iii
iv
Answer
magnesium / Mg
largest temperature rise/change
Notes
Marks
DEP on M1
Do not accept results in place of
temperatures
Accept answers stating most heat
produced / most exothermic
Must be implied comparison
Accept copper more reactive than silver
but not just silver is unreactive
Reject references to differences in
reactivities of silver and copper ions /
silver and copper sulfate
Accept two metals did not react
Accept two showed zero (temperature
rises)
Ignore state symbols
Accept correct ionic equation with or
without spectator ions
Total
1
1
13
Question
number
7 a
i M1 (A)
Answer
reduced AND (B) oxidised
Notes
Marks
M2 (A)
ii
iii
gain of electrons
M3 (B)
gain of oxygen
M1
2O2 O2 + 4e()
M2
1
1
1
1
Question
number
7 a iv M1 coke
Answer
Notes
Ignore coal / carbon
Reject other raw materials such as
limestone/haematite
M2 independent
Accept makes carbon dioxide which
then produces CO/reducing agent
M2 dependent on M1
Accept just solubility, ignoring
qualifying statements such as only
slightly soluble, or only dissolves
under pressure
Accept denser than oxygen
Ignore does not burn
M4 dependent on M3
Ignore references to covering /
sitting on fire
Accept M1+M2, and M3+M4 reversed
Marks
1
1
1
1
1
1
Question
Answer
number
7 b ii M1 SO2 + H2O H2SO3
M2 adverse effect on plants/trees/crops/vegetation
OR
Notes
Marks
eg damages / causes
rusting/corrosion
Question
number
7
c
M1
M2
M3
M1
M2
M3
M1
M2
M3
Answer
Mr(PbCO3) = 267 / Ar (Pb) = 207
n(PbCO3) / n(Pb) = 1.87 mol
m(Pb) = 387 388 g
OR
Mr(PbCO3) = 267 / Ar (Pb) = 207
m(Pb) = 207 500
267
m(Pb) = 387 - 388 g
OR
Mr(PbCO3) = 267 / Ar (Pb) = 207
% Pb = 207 100 = 77.5 %
267
m(Pb) = 500 0.775 = 387.5 g
Notes
Marks
1
1
1
1
1
1
1
1
1
17
Question
number
8 a
i M1
M2
ii
Answer
Notes
reversible (reaction)
/ goes forwards and/or backwards
/ can go in either direction
enthalpy/heat/energy change
exothermic / heat/energy given out/lost
M1
M2
M1
M2
M3
M4
(effect
(effect
(effect
(effect
of
of
of
of
temp on rate)
temp on yield)
catalyst on rate)
catalyst on yield)
increased
decreased
increased
unchanged
Marks
Ignore equilibrium
Ignore kJ/mol
Reject energy produced/released
Accept enthalpy in place of
heat/energy
Ignore references to temperature
Ignore all curves and connecting lines
Ignore line representing x-axis and
any label
Accept R for reactants and P for
products
No penalty for products to left of
reactants
Accept formulae in place of words for
reactants and products
Do not penalise minor errors in
formulae (e.g. NH instead of NH3) or
missing coefficients
1
1
1
1
1
1
Question
number
8 d
i M1
M2
M3
ii
M1
M2
Answer
Notes
Marks
decreased
1
1
1
1
1
15
Question
number
9 a
i M1
M2
ii
iii
iv
M1
M2
Answer
Notes
35 on lines 1 and 3
44 on line 2
isotopes
same number of electrons (in outer shell)
OR
same electron arrangement or configuration
79
Br
79 is closer to 79.9/more accurate value
Marks
1
1
1
1
1
1
Question
number
9 b
i M1
M2
ii
M1
M2
Answer
Notes
Marks
1
1
1
1
Question
Answer
number
9 b iii M1 (sodium bromide) ionic bonding / + and ions
M2 (hydrogen bromide) attraction between
molecules
/ intermolecular forces (of attraction)
M3 ionic bonding stronger
OR
IMF / attractions between HBr molecules weaker
Notes
Marks
1
1
Question
number
9 c
M1
Answer
Na
13.8
23
M2 0.6
M3 NaBrO4
Br
47.9
80
O
38.3
16
0.6
2.4
Notes
Marks
1
1
16
Question
number
10 a
10
Answer
organic compounds flammable
OR
decreases chance of fire
OR
less vapour/gas escapes
M1
M2
M3
ii
iii
iv
117 (C) 1
E
Notes
Marks
Total
2
1
1
1
7