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P V = nRT
where:
P is the pressure of the gas
V is the volume of the gas
n is the amount of substance of gas (also known as number
of moles)
R is the ideal, or universal, gas constant, equal to the product of the Boltzmann constant and the Avogadro constant.
Isotherms of an ideal gas. The curved lines represent the relationship between pressure (on the vertical, y-axis) and volume (on
the horizontal, x-axis) for an ideal gas at dierent temperatures:
lines which are further away from the origin (that is, lines that
are nearer to the top right-hand corner of the diagram) represent
higher temperatures.
Equation
The state of an amount of gas is determined by its pressure, volume, and temperature. The modern form of the
equation relates these simply in two main forms. The
1
PV =
m
RT
M
P =
R
T
M
P = Rspecific T
This form of the ideal gas law is very useful because it
links pressure, density, and temperature in a unique formula independent of the quantity of the considered gas.
Alternatively, the law may be written in terms of the
specic volume v, the reciprocal of density, as
P v = Rspecific T
It is common, especially in engineering applications, to
represent the specic gas constant by the symbol R. In
such cases, the universal gas constant is usually given a
dierent symbol such as R to distinguish it. In any case,
the context and/or units of the gas constant should make
it clear as to whether the universal or specic gas constant
is being referred to.[5]
1.3
Statistical mechanics
2 Applications to thermodynamic
processes
The table below essentially simplies the ideal gas equation for a particular processes, thus making this equation
easier to solve using numerical methods.
A thermodynamic process is dened as a system that
moves from state 1 to state 2, where the state number
is denoted by subscript. As shown in the rst column
of the table, basic thermodynamic processes are dened
such that one of the gas properties (P, V, T, or S) is constant throughout the process.
For a given thermodynamics process, in order to specify the extent of a particular process, one of the properties ratios (which are listed under the column labeled
known ratio) must be specied (either directly or indirectly). Also, the property for which the ratio is known
must be distinct from the property held constant in the
previous column (otherwise the ratio would be unity, and
not enough information would be available to simplify the
gas law equation).
P V = N kB T
where P is the absolute pressure of the gas measured in
pascals; N is the number of molecules in the given volume
V. The number density is given by the ratio N/V; kB is the
Boltzmann constant relating temperature and energy; and
T is the absolute temperature.
The number density contrasts to the other formulation,
which uses n, the number of moles and V, the volume. This relation implies that R=NAkB where NA is
Avogadros constant, and the consistency of this result
with experiment is a good check on the principles of statistical mechanics.
a. In an isentropic process, system entropy (S) is constant. Under these conditions, P 1 V 1 = P 2 V 2 , where
is dened as the heat capacity ratio, which is constant for
a calorically perfect gas. The value used for is typically 1.4 for diatomic gases like nitrogen (N2 ) and oxygen
(O2 ), (and air, which is 99% diatomic). Also is typically 1.6 for monatomic gases like the noble gases helium
(He), and argon (Ar). In internal combustion engines
varies between 1.35 and 1.15, depending on constitution
gases and temperature.
3
A residual property is dened as the dierence between a where the rst equality is Newtons second law, and
real gas property and an ideal gas property, both consid- the second line uses Hamiltons equations and the
ered at the same pressure, temperature, and composition. equipartition theorem. Summing over a system of N particles yields
Derivations
3N kB T =
4.1
Empirical
qk F k .
k=1
qk F k
I
q dS,
=P
surface
k=1
P V = nRT
q=
qx
qy
qz
+
+
= 3,
qx
qy
qz
4.2
4.2.1
Theoretical
Kinetic theory
q dS = P
P
surface
( q) dV = 3P V,
volume
The ideal gas law can also be derived from rst principles
using the kinetic theory of gases, in which several simplifying assumptions are made, chief among which are that
the molecules, or atoms, of the gas are point masses, possessing mass but no signicant volume, and undergo only
elastic collisions with each other and the sides of the container in which both linear momentum and kinetic energy
are conserved.
4.2.2
P V = N kB T = nRT,
Statistical mechanics
3N kB T =
qk F k
= 3P V,
k=1
5 See also
Van der Waals equation
Boltzmann constant
dp dp dp
Conguration integral
y
z
x
+ qy
+ qz
q F = qx
dt
dt
dt
Dynamic pressure
H H H
= qx
qy
qz
= 3kB T, Internal energy
qx
qy
qz
References
Further reading
Davis and Masten Principles of Environmental Engineering and Science, McGraw-Hill Companies, Inc.
New York (2002) ISBN 0-07-235053-9
Website giving credit to Benot Paul mile Clapeyron, (17991864) in 1834
External links
Conguration integral (statistical mechanics) where
an alternative statistical mechanics derivation of the
ideal-gas law, using the relationship between the
Helmholtz free energy and the partition function,
but without using the equipartition theorem, is provided. Vu-Quoc, L., Conguration integral (statistical mechanics), 2008. this wiki site is down; see
this article in the web archive on 2012 April 28.
Online Ideal Gas law Calculator
EXTERNAL LINKS
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