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User Guide
2001 Landmark Graphics Corporation
September 2001
Trademarks
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Table of Contents
Preface
Introduction
1.1 Program Function . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-1
1.2 Hardware/Software Requirements . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-3
Chapter 2
Getting Started
2.1 Starting DESKTOP-PVT . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-5
2.2 Main Screen Layout . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-6
2.2.1 Menu Bar . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-6
2.3 Data Entry Methods . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-8
2.4 Pop-Up Windows . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-8
2.4.1 File Box Popup . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-8
2.4.2 Text Entry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-9
2.4.3 Single Item Selection Panel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-10
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2.4.4
2.4.5
2.4.6
2.4.7
2.4.8
2-11
2-12
2-13
2-14
2-15
2-16
2-16
2-17
2-17
2-18
2-18
Chapter 3
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Equation-of-State Properties
5.1 Component . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
5.1.1 System - Select Component From System Default Table . . . . . . .
5.1.2 User - Make User-Defined Component . . . . . . . . . . . . . . . . . . . . . .
5.1.3 Volatile - Define Volatile Component . . . . . . . . . . . . . . . . . . . . . . .
5.1.4 Composition - Global Reference Composition . . . . . . . . . . . . . . . .
5.1.5 Load EOS - Load Component From File . . . . . . . . . . . . . . . . . . . . .
5.1.6 Append EOS - Append Component From File . . . . . . . . . . . . . . .
5-31
5-31
5-32
5-33
5-33
5-34
5-34
5-35
5-36
5-36
5-36
5-38
5-38
5-39
5-41
5-42
5-44
5-44
Chapter 6
Heavy/Pseudo/Regres
6.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-49
6.2 Heavy - Heavy Fraction Characterization . . . . . . . . . . . . . . . . . . . . . . . . . . .
6.2.1 Parameter - Input For Heavy Fraction Characterization . . . . . . .
6.2.2 Calculate - Activate Calculation . . . . . . . . . . . . . . . . . . . . . . . . . . . .
6.2.3 Graphics - Graphic Results of Extended Analysis . . . . . . . . . . . . .
6.2.4 Review - Tabular Results of Pseudo-Components . . . . . . . . . . . . .
6.2.5 Save EOS - Save EOS Parameters . . . . . . . . . . . . . . . . . . . . . . . . . . .
6.2.6 Append EOS - Add Heavy Fraction Components to System . . . .
6.2.7 Replace EOS - Load Heavy Fraction Components to System . . .
6-50
6-50
6-56
6-57
6-57
6-57
6-57
6-57
6-58
6-58
6-59
6-60
6-60
6-60
6-61
6-61
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7-74
7-75
7-75
7-76
7-76
7-76
7-77
7-77
7-77
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7.3.20
7.3.21
7.3.22
7.3.23
7.3.24
7-136
7-137
7-141
7-145
7-152
Chapter 8
9-162
9-162
9-165
9-166
9-168
9-168
9-168
9-169
9-171
9-171
9-171
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Tutorial
10.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-177
10.2 Heavy Ends Characterization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-177
10.3 Default Fluid Predictions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-179
10.4 Regression . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-183
10.5 Component Pseudoization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-185
10.6 Regression After Pseudoization . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-188
10.7 Regression on Viscosity Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10-190
Appendix A
References
Subject Index
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List of Figures
Preface
Introduction
Chapter 2
Getting Started
Figure 2-1: An Example of Rectangular Push Buttons for
Multiple Item Selection Panel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-11
Figure 2-2: An Example of Square Toggle Buttons for Multiple
Item Selection Panel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2-11
Chapter 3
Equation-of-State Properties
Figure 5-1: System-Defined Component Panel . . . . . . . . . . . . . . . . . . . . . . . . . . 5-32
Figure 5-2: User Defined Fluid Component Table . . . . . . . . . . . . . . . . . . . . . . . 5-33
Figure 5-3: Volatile Component Selection Panel . . . . . . . . . . . . . . . . . . . . . . . . . 5-33
Figure 5-4: Global Reference Composition Panel . . . . . . . . . . . . . . . . . . . . . . . . 5-34
Figure 5-5: Equation-of-State Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5-36
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Heavy/Pseudo/Regres
Figure 6-1: Parameter Options Form . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-51
Figure 6-2: Pseudoization Parameter Options Form . . . . . . . . . . . . . . . . . . . . . 6-59
Figure 6-3: Regression Variable Panel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-63
Figure 6-4: EOS Regression Variable Definition Table . . . . . . . . . . . . . . . . . . . . 6-63
Figure 6-5: Binary Coeff Regression Variable Definition Table . . . . . . . . . . . . 6-64
Figure 6-6: Composition Regression Variable Definition Table . . . . . . . . . . . . 6-64
Figure 6-7: k-Coefficient of Lohrenz-Bray-Clark Viscosity Correlation . . . . . 6-65
Figure 6-8: k-Coefficient of Pedersen Viscosity Correlation . . . . . . . . . . . . . . . 6-65
Figure 6-9: Tc-Binary Interaction Coefficient of Pederson
Viscosity Correlation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-66
Figure 6-10: Component Coefficients of K-Value Correlation . . . . . . . . . . . . . 6-66
Figure 6-11: Correlation Coefficients of Carbon Dioxide Saturated
Water Properties . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-67
Figure 6-12: Correlation Coefficients of Solubility of Carbon Dioxide in
Pure Water . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-67
Figure 6-13: Assigning Regression Variables to s0 and s1 Coefficients . . . . . . 6-68
Figure 6-14: Assigning Regression Variable to Coefficient d1 . . . . . . . . . . . . . . 6-68
Figure 6-15: Regression Limits Panel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6-69
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Tutorial
Appendix A
References
Subject Index
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Preface
Audience
This manual is intended to assist new and experienced users of
DESKTOP-PVT in the generation of PVT properties where laboratory data
is limited, or the development of a mathematical model that agrees with
experimental data.
Organization
The information in this manual is arranged in a logical manner for
maximum ease-of-use. The following chapters are included:
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Conventions
This manual uses certain conventional methods to indicate the correct
mouse button and keyboard usage.
MB2
MB3
Three-Button Mouse
(Right-Handed)
Four-Button Mouse
(Right-Handed)
The buttons on the mouse are named MB1, MB2, MB3, etc. as shown in the
illustrations above. Button arrangement may be reversed for left-handed
mouses (e.g., MB1 on far right). Typical uses for each button are described
below.
Mouse Button
MB1
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Typical Uses
Used to select menu options, push buttons in the application interface, etc.
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Mouse Button
Typical Uses
MB2
MB3
Used to toggle on and off a help message for the highlighted item in the Graphics option. Also used to access
Option Flag windows.
MB4
Used to toggle on and off a help message for the highlighted item.
Mouse Operations
You can use the mouse by rolling it across the surface of the mouse pad or
desk (except on Sun). As you move the mouse, the pointer moves to a
corresponding location on the screen. The following terms are used to
describe various mouse operations:
Mouse Operation
Instructions
Click
Double-click
Triple-click
Control-click
Shift-click
Drag
Select
Shade
Drag the mouse pointer across a group of text, or double-click to shade a word, or triple-click to shade a line
or a paragraph.
Set cursor
Key Combinations
Some keys such as the Control key and Alt key are used in combination
with others. For example, you can press Control-D by holding down the
Control key and pressing the D key. The same applies to combinations like
Alt-F4, Meta-F4, etc. Always hold down the first key before pressing the
second.
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Combining keys may also be used with mouse clicks. For example,
Control-click means to hold down the Control key and click MB1. ControlShift-click means to hold down the Control key and the Shift key before
clicking once with MB1.
Keyboard Operation
Cursor Movement Control Keys
The keys used to control cursor movement include the up, down, left, and
right arrow keys. If the cursor reaches the boundary of a multiple-page
table, a further arrow key movement in the same direction will make the
table scroll in that direction. In addition, the left and right arrow keys
allow the user to move the cursor in the data field to edit previously
entered data.
F2 Key
Depending on the occasion, the F2 function key can serve one of two
functions:
1. In composition entry tables, the F2 key will copy fluid compositions
from other sources. (see Section 7.2.1)
2. In the fluid property table, the F2 key will load default component
properties, i.e., either from system default tables or using interpolation
calculations. (see Section 5.2.1)
F5 Key
In a list entry panel, the F5 function key will either display a cascade table
for additional data entry, or a selection menu for the user to specify an
option (see Section 2.4.6). The user must first place the mouse cursor over
the box cell for the F5 function key work.
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Chapter
1
Introduction
1.1 Program Function
DESKTOP-PVT is an interactive phase behavior program designed to
simulate the behavior of hydrocarbon fluid mixtures subjected to any
variety of laboratory procedures. The fluids may be either liquid or vapor,
and may undergo phase changes during the simulated experiments.
DESKTOP-PVT is designed to be user friendly through employing an
event-driven interface with pull-down menus and pop-up windows.
DESKTOP-PVT allows the user to enter data directly on screen or import
data from an existing batch-type input file. It is easy to assign fluid
properties and experimental conditions in DESKTOP-PVT. An extensive
data bank of fluid properties and default values for laboratory procedures
is built into DESKTOP-PVT. Only minimum data entry is required to
complete a simulation. In addition, DESKTOP-PVT provides tools to
create, save, and retrieve files containing input data and results
interactively. The graphical and tabular simulation results can be viewed
interactively on screen or sent to hardcopy devices. DESKTOP-PVT also
provides a batch mode option which can be employed when interactive
simulation is not feasible.
DESKTOP-PVT can be used, in a purely predictive mode, to generate PVT
properties where laboratory data is limited, or it can be used to develop a
mathematical model that agrees with experimental data. In the latter case,
the mathematical model of the fluid system can be used in a compositional
reservoir simulator such as VIP-COMP to analyze oil and gas production
characteristics. In addition, the tabular data necessary to define fluid
behavior in VIP-ENCORE may be generated by DESKTOP-PVT.
To aid in developing a fluid model that matches experimental data, a
nonlinear regression package is provided as an integral part of DESKTOPPVT. This facilitates the adjustment of unknown or uncertain parameters
that affect fluid behavior.
Any or all of the various laboratory procedures can be simulated in
arbitrary sequence. Fluid samples can vary in composition from one
procedure to another, and operating temperature and pressure may
change. Multiple fluid samples can be analyzed with a single laboratory
procedure by sequentially simulating the same procedure for each
different sample.
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1-2
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IBM RS/6000
1-3
1-4
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Chapter
2
Getting Started
2.1 Starting DESKTOP-PVT
The DESKTOP-PVT can be initialized in different ways by utilizing
various command line options.
1. At the command line prompt, type dtpvt and press the Enter key.
The program will display the main window known as the Display
Window, which contains the DESKTOP-PVT header. The user must
enter all input data through the menu process or import data from an
existing data file. Refer to Chapter 3 for details regarding the
procedure for importing an existing file through the File menu.
2. At the command line prompt, type dtpvt {file} and press the Enter key.
Here {file} is the name of a batch-type data file. Refer to Section 2.7 for
a detailed description of a batch-type data file. The data contained in
the file will be loaded into memory upon initialization and will be
ready for editing and calculation.
3. At the command line prompt, type dtpvt -b {file} and press the Enter
key.
Again, {file} is the name of a batch-type data file. The command line
option -b will direct the program to execute in the batch mode and no
further user interaction will be necessary. With this option, the user
loses the ability to review the results in the interactive graphic mode
and only the tabular report given as dtpvt.out will be generated.
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Getting Started
Menu Bar
Graphic
Display
Area
2-6
Description
See
Chapter
File
Config
Component
Heavy
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Getting Started
Description
See
Chapter
Pseudo
Regres
Fluid
Tests
Run
Report
To select any menu option, just click on the desired menu and select the
desired option (or drag the mouse pointer to it). For example, to open a
file, with MB1 click the word File on the Menu Bar, then click the word
Open on the pull-down menu. A pop-up window appears which displays
a list of file names to be opened.
Some menu items may not be available for users to access if the items in
the Config menu are not adequately defined. For example, the Heavy
menu will not be accessible if the Heavy option in the Config menu is not
turned on. This is because the Menu Bar has been set up so that irrelevant
menu items will not be displayed and cannot be accessed. There are four
optional menus: Heavy, Pseudo, Regres, and Tests. The appearance of the
first three menus are controlled by the corresponding items in the Config
menu using a yes/no flag, i.e., the flag will be used to turn on/off the
appropriate menu items. The Tests menu has a dynamic arrangement,
such that only the tests which have been selected in the Test Type selection
window in the Config menu will be highlighted. Refer to Chapter 4 for a
detailed description of the Config menu.
Although there is no strict rule for the order of data entry, a typical
simulation will follow a "left to right" sequence in DESKTOP-PVT. For
example, a user may first retrieve an input data file using Open in the File
menu. The user can then reconfigure the simulation environment by
invoking the items in the Config menu. Components may be added/
deleted through the Component menu, or component properties may be
modified through the Fluid menu. The conditions of laboratory
procedures may be changed through the Tests menu. Once all changes are
completed, the user selects Go from the Run menu to start the calculation
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Getting Started
process. Finally, the user may review the results by selecting Graphics
from the Report menu.
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Getting Started
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Rectangular
Push
Button
Square
Toggle
Button
Figure 2-2: An Example of Square Toggle Buttons for Multiple Item Selection
Panel
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Getting Started
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Getting Started
Numeric Data - The data displayed in the data entry field can be an
integer or a real number.
Cascade Table Entry - When the data entry box indicates more data is
available, the user can access it by pressing the F5 function key or
clicking the button with MB1 while the mouse cursor is on the desired
box cell.
Cascade
Table
Entry
Numeric
Date
Alphanumeric
Menu Item
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Getting Started
Slider Bar
For certain rectangular data entry windows, the size of the table may be
dynamically varied inside the window. An example of these dynamic
windows is the table for entering laboratory measurements in the
saturation pressure calculations. In this table, the number of columns (for
temperature stages) can be increased by pressing the AddColAfter or
AddColBefore button, and reduced by pressing the DeleteCol button.
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Getting Started
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Pseudoization Process
Regular Run
DESKTOP-PVT also provides mechanisms to read EOS data file so that the
EOS data generated in the previous runs can be used as the initial input
for the next run. See Sections 5.1.5 and 5.1.6 for details of reading EOS data
files.
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Getting Started
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Chapter
3
Input Data File
3.1 Introduction
The File menu in the Menu Bar provides a means for creating, saving and
retrieving files containing simulation input data and results. There are
seven selection items in this menu:
Last Run
Open
New
Save
Load Database
Save Database
Exit
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3-20
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3-22
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Chapter
4
Setup Simulation Environment
4.1 Introduction
The major function of the Config menu is to define the global simulation
environment. Through the Config menu selections, the user dictates the
required input and the calculations DESKTOP-PVT will perform later. The
simulation details, however, are not required to input at this stage. For
example, the Regression entry in the Config menu is used to activate (or
deactivate) the DESKTOP-PVT nonlinear regression function which
allows automatic adjustment of the equation-of-state properties of
individual components. When the Regression option is on (activated), the
corresponding menu for nonlinear regression will be displayed on the
Menu Bar entitled Regres. The Regres menu requires the specification of
regression parameters.
There are twelve items under the Config menu.
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System Info
EOS
Binary Coeff
Test Type
Regression
Pseudoization
Thermal
Water-In-Oil
Heavy
Run-Time Compos
Composition Sor
Run Sequence
4-23
Two of the items, Composition Sor and Run Sequence, will be displayed
only if the Pseudoization and Run-Time Compos options are activated,
respectively. Because of their calculation features, the functions of
Regression, Pseudoization and Heavy are mutually exclusive, i.e., only
one of the three functions can be activated at a time.
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1 6 djkcor
2v cj v ck
djk = 1 --------------------------13
13
v cj + v ck
where vcj and vck are the critical volumes for component j and k,
respectively, and djkcor is an input exponent.
The numerical key 1 can be used to specify one run for a selected test
procedure or the user can click the name of the desired item and an
asterisk will appear in the cell box. The asterisk indicates that one test run
has been defined. To specify multiple runs for a test procedure, the
numerical keys 2 to 9 are used to edit the number of runs in the data entry
field to the left of the test type name. Whenever any data exists in the data
entry field, click the test type name button to clear the field.
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Chapter
5
Equation-of-State Properties
5.1 Component
The Component menu allows the user to define the components of the
fluid system used for phase behavior simulation. The component
information is one of the bases of the fluid system. Many input data in
DESKTOP-PVT are dependent upon components specification. Thus,
components should be defined before accessing other data screens. There
are six items available in the Component menu for defining fluid
components:
System
User
Volatile
Composition
Load EOS
Append EOS
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Equation-of-State Properties
the desired option. When finished, click the OK button to return to the
display window.
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Equation-of-State Properties
with the composition of the first test. Figure 5-4 is an example menu for
entering global composition.
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Equation-of-State Properties
Property
Binary Coeff
Binary Exponent
Gas Enthalpy
LBC Visc
Pedersen Visc
K-Value Correl
CO2TAB Correl
These items can be accessed only if fluid components have been defined in
the Component menu, as described in Section 5.1. The following sections
discuss the options on this menu in more detail.
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Equation-of-State Properties
Property Table
The table entries are dependent upon the equation-of-state being selected
in the Config menu. When selected the Property Table will display a
rectangular table for entering critical properties. In general, there are eight
entries for each table:
5-36
Omega A. Omega A.
Omega B. Omega B.
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Equation-of-State Properties
14
cm
12
mole
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Equation-of-State Properties
s = 1 D MW
1 6 djkcor
2v cj v ck
-
djk = 1 -------------------------- v 1cj 3 + v 1ck 3
where vcj and vck are the critical volumes for component j and k,
respectively, and djkcor is an input exponent. Selecting the Binary
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Equation-of-State Properties
Exponent option will display a data window for entering djkcor (Figure 57). The default value of djkcor is 1.0.
H i = h io + h i1 T + h i2 T + h i3 T + h i4 T + h i5 T
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Equation-of-State Properties
and the user can edit the gas enthalpy coefficients, hin, for each
component.
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Equation-of-State Properties
00
00
00
00
4 4
= b + ( [ C 1 + C 2 r + C 3 r + C 4 r + C 5 r ] 10 )
where is the phase viscosity, b is a base viscosity, is a function of
pseudo critical pressures, pseudo critical temperatures, and mixture
molecular weight, and r is a pseudo reduced phase density.
By default, the coefficients are:
C1 = 0.1023
C2 = 0.023364
C3 = 0.058533
C4 = -0.040758
C5 = 0.0093324
The user may change these default coefficients by selecting the LBC Visc
menu item, and changing the value in the dialog box (Figure 5-9).
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Equation-of-State Properties
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Equation-of-State Properties
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Equation-of-State Properties
Ki =
Di
B
A i + -----i + C i P EXP ---------------
T E i
P
(5-1)
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Equation-of-State Properties
Figure 5-14 shows the data entry table for entering correlation coefficients
of solubility of carbon dioxide in pure water. The coefficients are a0 to a4,
b0 to b4, and c0 to c4 to be discussed next. Default values are available for
all coefficients.
cP
R sw = a P 1 b sin --- --------------------
2 c P + 1
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if P < P
5-45
Equation-of-State Properties
and
o
R sw = R sw + m ( P P )
if P P
where
4
a =
ai ( 10 3 T )
i=0
4
b =
bi ( 10 3 T )
and
0<b<1
i=0
4
c =
10 3
ci ( 10 3 T )
i=1
2
2
sin1 ( b )
p = --- -------------------------------------------
2
2
c 1 --- sin1 ( b )
R sw = a P ( 1 b )
c Po c Po
c Po
---------------------
-m = a 1 b sin --- --------------------+
cos
--- -------------------- 2 c P o + 1 2 c P o + 1
2 c P o + 1
with Rsw in scf of carbon dioxide per stb water, temperature (T) in degree
Fahrenheit, pressure (P) in psia and
a0 =1.16306, a1 =-16.6304, a2 = 111.07305, a3 =-376.85925, a4 =524.88916
b0 =0.96509, b1 = -0.27255, b2 = 0.09234, b3 = -0.10083, b4 = 0.09979
c0 =1.28030, c1 =-10.75660, c2 = 52.69622, c3 = -222.39488, c4 =462.67255
This correlation matches the solubility data of Wiebe (1941)1 for liquid and
supercritical carbon dioxide in water within 10 scf/stb for temperatures
between 54 and 212 degrees Fahrenheit and pressures up to 10,000 psia.
The calculated solubility in pure water is further adjusted for the effects of
salinity to obtain the solubility of carbon dioxide in brine
R sb
log -------- = s o S T s1
R sw
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Equation-of-State Properties
The formation volume factor of carbon dioxide saturated water (or brine)
is calculated using
1
B w = ------ [ w, sc + 0.02066 R sb ]
w
w = w, atm + 0.001 d 1 R sb
where d1 = 5.8, Bw is in rb/stb, w,sc is water density at standard
temperature in lb/cu ft and w,atm is water density at temperature and 14.7
psia in lb/cu ft. Both w,sc and w,atm are calculated using the correlation
from Rowe and Chou (1970)5. The correlation of carbon dioxide saturated
water density is developed using the data of Parkinson and De Nevers
(1969)6, and Sayegh and Najman (1987)7.
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Equation-of-State Properties
Figure 5-16 shows the data entry table for entering coefficient d1 for
calculating carbon dioxide saturated water density. The default value is
5.8.
For pressures less than 5000 psia the water compressibility is calculated
using the correlation from Rowe and Chou (1970)5. For pressures greater
than 5000 psia,
1
1
------- = ------------------ + 7.033 ( P 5000 )
Cw
C w, 5000
where Cw,5000 is water compressibility at temperature and 5000 psia from
Rowe and Chou correlation in 1/psia. The above correlation is derived
from the water compressibility correlation by Osif (1988)8.
Water viscosity is calculated from Kestin et al. correlation (1978)9. The
effects of carbon dioxide solubility are ignored in both compressibility and
viscosity calculations.
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Chapter
6
Heavy/Pseudo/Regres
6.1 Introduction
The mechanisms for assigning equation-of-state components and their
properties for a fluid mixture are discussed in Chapter 5. In this chapter,
we discuss three functions that can be used to obtain or modify some of
the component properties. These functions are represented by three items
in the main menu, i.e., Heavy, Pseudo, and Regres.
The Heavy function is used for calculating heavy fraction characterization
from laboratory measured properties for the heavy fraction. Pseudo is
used to reduce the original fluid system into a pseudo system by
specifying which of the original components will be lumped into which
pseudo component. Regres is a nonlinear regression package that
facilitates the adjustment of unknown or uncertain parameters that affect
fluid behavior. These menus are available only if their corresponding
option flags, Heavy, Pseudoization and Regression items in the Config
menu, are activated. Because of their distinctive calculation features, these
functions are mutually exclusive, i.e., only one of the three functions can
be activated at a time.
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Heavy/Pseudo/Regres
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Heavy/Pseudo/Regres
NOTE:
To edit data indicated as <F5> on this form, either click MB1 over the
button next to the desired item or position the mouse cursor over the
box cell for the desired item to edit to make the F5 key accessible.
Any items that give you choice to make, move the mouse pointer
over the desired box cell and click MB3 to access a separate options
window. Choose the desired item and then click Ok to return to the
previous window.
Mole Fraction. The mole fraction of the total fluid sample contained in
the heavy fraction. This is required input.
6-52
First Single Carbon No. The first single carbon number (FSCN) of the
heavy fraction to be considered in the extended analysis, i.e., for C7+
enter 7, for C10+ enter 10. This number must be greater than 6. This is
required input. (Default is 7)
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Heavy/Pseudo/Regres
Last Single Carbon No. The carbon number of the last component to
be considered in the extended analysis for the heavy fraction. This is
required input. (Default is 45)
Regression on ALPHA (Y/N). Text label that activates the option for
automatic ALPHA calculation. If this option is activated, the
distillation data must be entered before calculation begins.
6-53
Heavy/Pseudo/Regres
14 FSCN 6
where FSCN is the default first single carbon number, 7, discussed
above. This is required input.
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Heavy/Pseudo/Regres
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Heavy/Pseudo/Regres
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Heavy/Pseudo/Regres
To edit data indicated as <F5> on this form, either click MB1 over the
button next to the desired item or position the mouse cursor over the
box cell for the desired item to edit to make the F5 key accessible.
Any items that give you choice to make, move the mouse pointer
over the desired box cell and click MB3 to access a separate options
window. Choose the desired item and then click Ok to return to the
previous window.
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Heavy/Pseudo/Regres
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Heavy/Pseudo/Regres
The parameters available for regression are categorized into ten types as
shown in Figure 6-3.
These are:
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Heavy/Pseudo/Regres
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Heavy/Pseudo/Regres
H2O Binary. Binary interaction coefficients for water (H2O) and all
other components. This menu is available only if Thermal in the
Config menu has been activated, and the H2O component has not
been assigned as a fluid component.
VISP k-Coef. The k-coefficients (k1 to k7) for calculating the viscosity
of the reference component in the Pedersen et al. viscosity correlation
(Figure 6-8).
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Heavy/Pseudo/Regres
Ki =
Di
B
A i + -----i + C i P EXP ---------------
T E i
P
(6-1)
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Heavy/Pseudo/Regres
Figure 6-12 shows the data entry table for assigning regression
variables to correlation coefficients of solubility of carbon dioxide in
pure water. The coefficients are a0 to a4, b0 to b4, and c0 to c4 give in
Section 5.2.7.
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Heavy/Pseudo/Regres
Figure 6-13 shows the data entry table for assigning regression
variables to s0 and s1 coefficients for adjusting the salinity effects on
the carbon dioxide solubility in water.
Figure 6-14 shows the data entry table for assigning regression
variable to coefficient d1 for calculating carbon dioxide saturated
water density.
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Heavy/Pseudo/Regres
Regression variables are used to alter the initial values of various EOS
properties. Most of the EOS properties are adjusted by multiplying their
initial values with regression variables. The exceptions are binary
interaction coefficients, composition and volume shift parameters, where
subtraction is used instead of multiplication. For this treatment of
regression variables, using values equal to 1 for all regression variables is
equivalent to using the unaltered EOS properties.
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Heavy/Pseudo/Regres
6-70
Basic. Only the values of the objective function and the regression
variables at each regression iteration are printed.
Initial Search Vector Length. The initial value of the search vector
length in the regression calculation. This is required input. (Default is
0.2)
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Heavy/Pseudo/Regres
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Chapter
7
Input Data for Laboratory Procedures
7.1 Introduction
The Tests menu on the Menu Bar is used for entering data from laboratory
measurements. The Tests menu has a dynamic arrangement so only the
tests selected in the Test Type selection window in the Config menu will be
highlighted. The user must enter all required data for all selected tests, but
may enter data in any sequence.
The user can request the data entry menu for a test by clicking on the
desired item with MB1. If the test has multiple runs, an additional menu
containing run numbers will be displayed. The user must select a run
before the data entry menu can be accessed.
In Section 7.2, commonly used data for laboratory procedures are
described. The data set for each laboratory procedure is discussed in
Section 7.3.
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7.2.1 Composition
The fluid composition is required for most of the laboratory test
procedures. As discussed in Section 4.11, there are two ways to specify the
fluid composition in DESKTOP-PVT. The fluid composition for a test can
be entered directly, or the liquid, vapor, or overall composition of an
intermediate step in another test can be loaded. The latter method is
referred to as an indirect composition specification. For direct composition
specification, the user must enter the numerical values of the fluid
composition in mole fraction. For indirect composition specification, the
user must specify the referenced test and its particular step. Both
specifications are completed through the Composition item in the data
entry menus for laboratory procedures.
For all tests, there is a Composition entry field. To access the composition
entry menu, the user should position the cursor on the field, and press the
F5 function key or click the field with MB1.
For direct composition specification, the entry menu has a two-column
format for most of the tests. The first column, which is not used for data
entry, lists the component names under the Component header. The
second column, under the Mole Fraction header, is used for entering fluid
composition in mole fraction. There are a few tests, for example swelling
and multiple contact vaporization tests, which require specification of
both the fluid and the injected gas compositions. A three-column
composition menu is provided for these tests. The fluid composition is
entered in the second column with the Fluid Mixture header, and the third
column, with the Injected Gas header, is used for entering the injected gas
composition.
In a composition entry menu, the F2 function key can be used to copy a
previously entered fluid composition of other laboratory test procedures.
A menu of abbreviated test names will be displayed once the user presses
the F2 function key. By clicking the button next to the desired test and then
click the Ok button, the program is instructed to copy the fluid
composition from that test. This copy composition function can save data
entry efforts for simulating several tests with the same fluid composition.
For indirect composition specification, the composition assignment is a
two-step procedure. A menu of abbreviated test names will be displayed
when the user presses the F5 function key in the Composition entry field
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or clicking the Composition entry field with MB1. The user must select a
test which references one of its liquid, vapor, or overall compositions.
The user must provide the run sequence of all laboratory procedures if the
test compositions are to be indirectly specified. In the Run Sequence menu
the user also specifies which tests will use indirect composition
specification. DESKTOP-PVT will process the user specifications in the
Run Sequence menu, and list the tests that can be referenced. The tests
menu lists a subset of all the laboratory tests specified in the Test Type
selection window of the Config menu.
A second menu will be displayed once the user has selected a test in the
abbreviated test names menu. This menu lists the pressure stages for the
selected test. The user should position the cursor on the desired pressure
stage and press Enter to complete the indirect composition specification.
F. Degrees Fahrenheit
C. Degrees Centigrade
K. Degrees Kelvin
R. Degrees Rankin
To change the temperature units, the user can either enter one of the unit
identifiers (F, C, K or R) directly, or select the temperature units menu by
clicking MB3 in the temperature units specification field. A selection menu
will be displayed. Select the desired item by the diamond button next the
that item and then click Ok to return to the previous menu.
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KPA. Kilo-Pascals
To change the pressure units, the user can either enter one of the unit
identifiers (PSIA, PSIG, KPA or KGCM2) directly, or select the pressure
units menu by click MB3 in the pressure units specification field. A
selection menu will be displayed. Select the desired item by the diamond
button next the that item and then click OK to return to the previous
menu.
To change the density units, the user can either enter one of the unit
identifiers (LB/FT3 or GM/CC) directly, or select the density units menu
by clicking MB3 in the density units specification field. A selection menu
will be displayed. Select the desired item by the diamond button next the
that item and then click OK to return to the previous menu.
7-76
SCF/STB. Field units of standard cubic feet of gas per barrel of stock
tank oil
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To change the GOR units, the user can either enter one of the unit
identifiers (SCM/STCM or SCF/STB) directly, or select the GOR units
menu by clicking MB3 in the GOR units specification field. A selection
menu will be displayed. Select the desired item by the diamond button
next the that item and then click OK to return to the previous menu.
To change the enthalpy units, the user can either enter one of the unit
identifiers (KBTU/LBMOLE or J/KGMOLE) directly, or select the
enthalpy units menu by clicking MB3 in the enthalpy units specification
field. A selection menu will be displayed. Select the desired item by the
diamond button next the that item and then click OK to return to the
previous menu.
To change the saturation pressure type, the user can either enter one of the
unit identifiers (DEWPT or BUBPT) directly, or select the saturation
pressure type menu by clicking MB3 in the saturation pressure type
specification field. A selection menu will be displayed. Select the desired
item by the diamond button next the that item and then click Ok to return
to the previous menu.
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7-78
Gas Z-Factor
Liquid Density
Vapor Pressure
Saturation Pressure
Viscosity
Swelling
Differential Expansion
Multi-Contact Vaporization
Phase Envelope/Psat
Gas Enthalpy
Liquid Enthalpy
Water Property
Saturating Pressure/H2O
Distillation
Steam Distillation
Separator/No Reg
Separator/Reg
Phase Envelope/Full
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
7-79
Figure 7-2 shows an example of the table for entering laboratory measured
data. In this example the gas z-factors are measured at two pressure
stages.
7-80
Gas Visc. The gas viscosities (cp) measured at the pressure stages.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
7-81
Figure 7-4 shows an example of the table for entering laboratory measured
data. Liquid densities are measured at two pressure stages in this
example.
7-82
Liq Visc. The liquid viscosities (cp) measured at the pressure stages.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
7-83
Figure 7-6 shows an example of the table for entering vapor pressure data.
The vapor pressures are measured at two temperature stages in this
example.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
7-85
Figure 7-8 shows an example of the table for entering laboratory measured
data. The saturation pressures are measured at one temperature stage in
this example.
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Fluid Type. Alpha label specifying the fluid mixture type. This is
required input.
Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
7-87
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
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7-90
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Z-factor@ Psat (Z-Psat). The measured fluid compressibility factor (Zfactor) at the cell temperature and saturation pressure.
Weight Factor/Z-Psat. The regression weight factor of the measured Zfactor at the cell temperature and saturation pressure. (Default is 1)
Liq Volume Fraction Type. Two options are available to define the
reference volume used for normalizing measured liquid volumes. This
data is used to select the reference volume and define the volume
fraction of liquid. Volume fraction of liquid is defined as the liquid
volume measured at a pressure stage divided by the reference volume.
This is required input.
MEAS PRES. The reference volume is the total cell volume at the
pressure stage at which the liquid volume is measured.
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Relative Vol. The total volume of the fluid mixture measured at the
pressure stages divided by the volume measured at the saturation
pressure.
7-91
7-92
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Temperature Unit. The temperature units which are the same for all
measurements in this test. This is required input. (Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Z-factor @ Psat (Z-Psat). The measured fluid compressibility factor (Zfactor) at the cell temperature and saturation pressure.
Weight Factor/Z-Psat. The regression weight factor of the measured Zfactor at the cell temperature and saturation pressure. (Default is 1)
7-93
Black Oil Table Generation. The dialog window for generating black
oil table data.
7-94
Cum Gas Prod. The cumulative gas produced after returning the PVT
cell to its original volume at the pressure stages. This is expressed as a
mole fraction of the gas originally in the PVT cell.
Oil Vol Frac. The measured volume fractions of oil after returning the
PVT cell to its original volume at the pressure stages.
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Figure 7-15 shows the dialog window used to enter black oil table
generation parameters.
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7-95
Figure 7-18: Pressure levels above the saturation pressure at which black oil
data is generated.
7-96
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
7-97
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Inj Gas Frac. Moles of injected gas in the mixture divided by the total
number of moles in the mixture at the end of any stage. This is
required input.
Sat Vol Frac. The volume of the saturated mixture at the end of any
stage divided by the saturated volume of the original mixture.
Sat Pres Type. Alpha label specifying the type of measured saturation
pressures. This is required input.
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7-100
Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIA)
Gas-Oil Ratio (GOR) Unit. The units for all gas-oil ratio
measurements. This is required input. (Default is SCF/STB)
GOR Calculation Option. Alpha label specifying the definition of gasoil ratio. This is required input.
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Rel Oil Vol. The relative oil volumes (oil formation volume factor, Bo),
barrels of oil at a pressure level per barrel of residual oil at 60 F.
Gas Z-Fac. The z-factors of the produced gas measured at the pressure
stages.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
7-103
Moles Added. The number of moles of fluid (gas or oil) added at each
contact step. It is assumed the oil originally in the PVT cell is one mole.
This is required input.
Gas Z-Factor. The z-factors of the removed gas at each contact step.
Liq Vol Frac. The liquid volume fraction before gas removed at each
contact step.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Enthalpy Unit. The enthalpy units which are the same for all enthalpy
measurements in this test. This is required input. (Default is KBTU/
LBMOLE)
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Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Enthalpy Unit. The enthalpy units which are the same for all enthalpy
measurements in this test. This is required input. (Default is KBTU/
LBMOLE)
7-109
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
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7-112
Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
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Figure 7-32 also shows an example of the table for entering bubblepoint
pressures of oil in the presence of water. The bubblepoint pressures are
measured at one temperature stage in this example.
Figure 7-32: Data Entry Table for Bubblepoint Pressure of Mixture with H2O
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7-114
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
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Blend Fraction Option. Alpha label specifying the units for which
fractions of the original crude, residue and distillate are mixed in
preparing the blend. This is required input.
Blend API Gravity Table. The measured API gravities of blends. The
detailed table entries are discussed later.
Distillation Curve
Figure 7-34 shows the menu for entering laboratory measured distillation
data.
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Figure 7-35: Data Entry Table for Distillation Molecular Weight Measurements
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M.W., Crude Heavy Frac (MWc). The molecular weight of the heavy
fraction of the original crude.
Weight Factor/ MWc. The regression weight factor for the measured
molecular weight of the heavy fraction of the original crude. (Default
is 1)
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M.W., Residue Heavy Fraction. This table is used for entering the
measured molecular weight of the heavy fraction of the residues. The
entries are the same as the above four items, except the data entry
number on the distillation curve may also be input.
Wt Frac, Crude Heavy Frac (Wt). The measured weight fraction of the
crude heavy fraction in the original crude.
Figure 7-36: Data Entry Table for Distillation Residue API Gravity
7-118
Weight Factor. The regression weight factor for the measured API
gravity of residue. (Default is 1)
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Dstl Curve No. The data entry number on the distillation curve.
Figure 7-38: Data Entry Table for Distillation Distillate API Gravity
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Weight Factor. The regression weight factor for the measured API
gravity of the distillate. (Default is 1)
Start Curve No. The data entry number on the distillation curve which
defines the starting temperature of the distillate.
End Curve No. The data entry number on the distillation curve which
defines the ending temperature of the distillate.
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Figure 7-42: Data Entry Table for Distillation Blend API Gravity
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Crude Frac. The volume or weight fraction of the original crude in the
blend.
DstCurve No. The data entry number on the distillation curve for the
residue used in the blend.
Distillate No. The data entry number of the distillate in the Distillate
API Gravity Table for the distillate used in the blend.
Wt Factor. The regression weight factor for the measured API gravity
of the blend. (Default is 1)
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Viscosity Measurements
Figure 7-43 shows the menu for entering viscosity data.
ln ( ln ( + 1 v min ) ) = A + B ln ( T )
(7-1)
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Crude Viscosity (cp). The data table for the measured viscosities of the
original crude.
Residue Viscosity (cp). The data table for the measured viscosities of
the residues.
Distillate Viscosity (cp). The data table for the measured viscosities of
the distillates.
Blend Viscosity (cp). The data table for the measured viscosities of the
blends.
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Figure 7-44 shows the data table for the original crude viscosity.
Temp. Temperature of the measured viscosity. The units are the same
as those specified in the main menu of the distillation test.
Pres. Pressure of the measured viscosity. The units are the same as
those specified in the main menu of the distillation test.
If one of the Twu viscosity correlations is selected, a viscosity data file will
be generated. This file will contain component viscosity data at the
temperatures specified in the crude viscosity table. The file can be saved
later and used in VIP-THERM.
Figure 7-45 shows the menu for entering residue viscosity.
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Temp. Temperature of the measured viscosity. The units are the same
as those specified in the main menu of the distillation test.
Pres. Pressure of the measured viscosity. The units are the same as
those specified in the main menu of the distillation test.
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Temp. Temperature of the measured viscosity. The units are the same
as those specified in the main menu of the distillation test.
Pres. Pressure of the measured viscosity. The units are the same as
those specified in the main menu of the distillation test.
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Temp. Temperature of the measured viscosity. The units are the same
as those specified in the main menu of the distillation test.
Pres. Pressure of the measured viscosity. The units are the same as
those specified in the main menu of the distillation test.
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Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Initial Oil Volume In Cell. The volume of crude oil initially injected
into the PVT cell, in cubic centimeters (cc). This is required input.
API Gravity, Initial Oil (APIo). The API gravity of the original crude.
This is required input.
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Figure 7-49 shows the table for entering laboratory measured steam
distillation data.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
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Figure 7-51 also shows the table used for entering the separator conditions
data. For each stage, a maximum of two destinations can be assigned for
each of the two output streams (vapor and liquid). For example, the liquid
stream leaving a separator can be sent to the oil sales line, or a fraction of
the liquid stream can be sent to the oil sale line with the rest of the liquid
stream sent to a downstream separator. If the output streams are sent to
two destinations, then two data cards, one for each destination, are
required for a complete description of the stage conditions (type 1 and
type 2 data cards). Otherwise, only one data card is needed for each stage
(type 1 card). Type 2 data cards, if required, must immediately follow type
1 data cards for each stage.
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Stage No. The separator stage number. Every separator must have an
(positive) integer stage number. The nonzero stage number indicates a
type 1 data card. If a type 2 data card is required for a separator stage,
enter 0 for the Stage No. This is required input.
Vapor Frac. The fraction of the vapor stream leaving a separator stage
is sent to the destination indicated in Vapor Dest. Values must lie in the
range of 0 to 1. If the value for a type 1 data card is less than one, a type
2 data card must be provided for this stage. This is required input.
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Liquid Frac. The fraction of the liquid stream leaving a separator stage
is sent to the destination indicated in Liquid Dest. Values must lie in
the range of 0 to 1. If the value for a type 1 data card is less than one,
then a type 2 data card must be provided for this stage. This is
required input.
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Figure 7-52 shows the input menu for simulating the laboratory separators
test.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIA)
Gas-Oil Ratio (GOR) Unit. The units for all gas-oil ratio
measurements. This is required input. (Default is SCF/STB)
Density Unit. The density units which are the same for all density
measurements in this test. This is required input. (Default is LB/FT3)
Oil Density or Gas Z-Factor. Oil density (for bubblepoint fluid) or Gas
Z-factor (for dewpoint fluid) at reservoir temperature and saturation
pressure.
Weight Factor/Bo or Bg. The regression weight factor of the oil or gas
formation volume factor. (Default is 1)
Stock Tank Oil API Gravity. The API gravity of stock tank oil at
standard conditions.
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Total Gas-Oil Ratio (TGOR). The total gas-oil ratio, in standard cubic
feet of gas per stock tank barrel of oil, calculated by separation through
all stages to surface conditions.
Figure 7-53 shows the table for entering laboratory measured separator
data.
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Oil Vol Fact. Separator volume factor in barrels of oil at stage pressure
and temperature per barrel of stock tank oil at standard conditions.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIA)
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later. This file contains the composition information that can be exported
directly to VIP-COMP.
Figure 7-55 shows the input menu for calculating composition variations
with depth. The input data are reservoir temperature, pressure and
hydrocarbon composition at a reference depth.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input.
(Default is F)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIA)
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Depth Unit. The depth units which are the same for all depth
measurements. This is required input. (Default is FT)
Option For Entering Depth. Two options are available to enter the
depths where compositions are calculated.
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Optional Input. An item for activating the optional input menu for
this test. The detailed entries are discussed later.
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Figure 7-56 shows the Optional Input menu for calculating composition
variations with depth.
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Min Depth Interval for Calc. The minimum depth interval allowed in
the composition calculation. If the computed depth interval is less than
this minimum value, the calculation will be reported as a failure.
(Default is 1)
Max Depth Interval for Calc. The maximum depth interval allowed in
the composition calculation. If the user specified depth interval is
greater than this value, the compositions at additional intermediate
depths will be performed with this depth interval between the user
specified depths. (Default is 100)
Depth Interval Reduction Scale. The factor for reducing the size of
depth interval when a composition calculation fails. If the composition
calculation which failed was of size of D, the next intermediate
composition calculation will be of size D times this factor. (Default is
0.2)
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Figure 7-57 shows the input menu for calculating properties of carbon
dioxide saturated water.
Format of Data Table. Alpha label specifying the table format to enter
carbon dioxide saturated water properties. This is required input.
(Default is SATWAT) Only SATWAT option will generate enough data
in co2tab.log file to be used by VIP-COMP, and is explained in the
documentation.
Seven options are available:
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Salinity Units. The brine salinity units. There are two options
Temperature Units. The temperature units which are the same for all
temperature measurements in this test. This is required input. (Default
is F)
Pressure Units. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIA)
Figure 7-58 shows the input menu for entering laboratory measured data
for SATWAT option.
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Weight Factor. The regression weight factors for the measured data of
carbon dioxide saturated water. (Default is 1)
Figure 7-59 shows the input menu for entering measured data of carbon
dioxide saturated water.
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Figure 7-60 shows an example of the main input menu for simulating the
MCSVAP test.
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Temperature Unit. The temperature units which are the same for all
temperature measurements in this test. This is required input. (Default
is F, degree Fahrenheit.)
Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIA)
Stream Unit. The stream units which are the same for all stream
measurements in this test, including the amounts of initial oil and
water, the injected steam, and produced fluids. This is required input.
(Default is G, grams.)
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API Gravity of Initial Oil (APIo). The API gravity of the initial oil.
Use only if initial oil is undersaturated.
Initial Quantity of Oil in Cell. Initial amount of oil in PVT cell in the
units specified by Stream Unit. This is required input. (Default is 100)
Figure 7-61 shows an example of the data table for entering laboratory
measured MCSVAP data.
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H2O Injected. Amount of H2O injected into PVT cell for each contact
in the units specified by Stream Unit. This is required input.
Cell Vapor. Amount of equilibrium vapor formed for each contact and
then withdrawn in the units specified by Stream Unit.
Oil Satn. PVT cell oil saturation in fraction at equilibrium for each
contact before withdrawal of vapor.
H2O M.F./Oil. Mole fraction of H2O in the PVT cell oil phase for each
contact before withdrawal of vapor. This number is calculated only if
the water-in-oil option is activated.
H2O M.F./GAS. Mole fraction of H2O in the PVT cell vapor phase for
each contact before withdrawal of vapor. This number is calculated
only if the water-in-oil option is activated.
Prod Oil API. API gravity of produced oil for each contact.
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ln ( ln ( + 1 min ) ) = A + B ln ( T )
where T is absolute temperature. The default value is 0.2. This value
will be internally reset to 0 if any input or calculated viscosity value is
less than the input value.
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Initial Oil Viscosity(cp). The data table for the measured viscosity of
the initial oil.
Cell Oil Viscosity(c). The data table for the measured viscosity of the
PVT cell oil.
Produced Oil Viscosity(cp). The data table for the measured viscosity
of the produced oil.
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Figure 7-63 shows the data table for entering the measured initial oil
viscosity.
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Pres. Pressure of the measured viscosity. The temperature units are the
same as those defined in the MCSVAP main menu.
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Figure 7-64 shows the data table for entering the measured PVT cell oil
viscosity. The same data format is also used for produced oil viscosity.
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Pres. Pressure of the measured viscosity. The temperature units are the
same as those defined in the MCSVAP main menu.
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Successive substition
Newton-Raphson
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Temperature Unit. The temperature units which are the same for all
measurements in this test. This is required input. (Default is F)
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Pressure Unit. The pressure units which are the same for all pressure
measurements in this test. This is required input. (Default is PSIG)
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LMol Frc. Liquid (oil) phase mole fraction at the pressure stages.
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Chapter
8
Calculation of Laboratory Procedures
8.1 Introduction
The Run menu contains items for activating laboratory test calculations,
selecting phase behavior calculation methods, and specifying control
parameters for phase behavior calculations. There are six items in the Run
menu:
GO
Calc Method
Psat Tol
Flash Tol
Expansion Tol
Debug
Except for the GO item, a window for entering data will be displayed
when an item is selected. The GO entry is used to activate the phase
behavior calculation. The remaining menu items are used to select
calculation parameters.
The default values for the phase behavior calculation parameters in
DESKTOP-PVT are adequate for most fluid systems. However, for
difficult near-critical fluid systems, some parameters in the saturation
pressure and flash calculations may need to be changed. DESKTOP-PVT
allows the user to change any of these parameters for any of the simulated
tests. The changes in a test will effect only that particular test. Each test
may have its own set of parameters for phase behavior calculations.
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Dp Factor. The factor for reducing the size of a pressure interval when
an intermediate flash fails. If the flash which failed was of size P, the
next intermediate flash calculation will be of size P times this factor.
(Default is 0.1)
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Chapter
9
Report - Calculation Results
9.1 Introduction
Graphic and tabular reports for the calculated results are created from the
Report menu. At the termination of the phase behavior calculation, the
program is ready to proceed to the Graphics option in the Report menu,
and the results are ready to be examined. In addition, the user can
generate reports by retrieving a database file. See Sections 2.7, 3.6, and 3.7
for more information about database file manipulation. There are fourteen
options in the Report menu.
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Graphics
GraTitle
SavGraph
GetGraph
Table
PrtTable
SavTable
GetTable
SaveEOS
SaveKval
SaveVisc
SaveZgrd
SavCO2T
SaveBOE
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9.2 Graphics
The graphic module provides an environment for users to graphically
display calculated results and observation data. This is an interactive
environment that provides a wide range of control over the graphical
presentation of calculated results and observation data. The graphic
module is activated by selecting Graphics from the Report menu.
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If the cursor device has buttons in addition to MB1, the use of other
buttons will be context dependent. However, it is generally true that
MB3 and MB4 (if available) can be used to toggle on and off a help
message for the highlighted item. Pressing MB2 will clear away the
menu area so it will not appear on a screen dump. To redisplay the
graphics selection menu area again press MB2.
2. Graphic Device with Only a Keyboard: (Not applicable for X-Window
Terminals)
Point to the desired item by using the left and right arrow keys, and
press the Enter key to select the item. The user may type the first few
letters which are unique enough to distinguish one item from another
to make a selection. Toggle the help message with the ? key.
The exact items of the Graphic Menu Bar are dependent on laboratory
procedures. Figure 9-2 is an example plot with the Graphic Menu Bar.
Usually, the first several items in the menu are the fluid properties
available for review. A selection of these items will immediately display
the corresponding plot on the screen. The solid curve with dots represents
the calculated results. The dots indicate the calculated points. The
observation data points, if present on the same plot, will be shown as cross
marks. If there are too many menu items to fit in one row, >> MORE will
be displayed at both ends of the menu. The >> MORE item indicates
additional items are available for selection. The user can position the
cursor on >> MORE to display additional items for selection.
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The last two items on the graphics selection menu are CONTRL and EXIT.
The EXIT item allows the user to quit the current graphic session for the
selected laboratory procedure, and return to the previous menu for
selecting another laboratory procedure for graphic reports. The CONTRL
item provides a method for users to manipulate graphic attributes
interactively.
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Figure 9-3: Example Plot with the Control Item Selected on the Graphic Menu
Bar
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ZOOM
The ZOOM option allows the user to select and display sections of the plot
scene for close detail observations. Several options (Figure 9-4) are
provided to specify the area of interest.
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IXscale. The IXscale option allows the user to specify the horizontal
extent (x-axis) to be zoomed interactively. The graphic cursor will be
overlayed with a vertical line to indicate the area boundary. To define
the desired boundary, position the vertical line at the desired location
of the first boundary and press MB1. Move the vertical line to the
second boundary position and press MB1. The zoomed picture will be
displayed upon specification of both boundaries.
IYscale. The IYscale option allows the user to specify the vertical
extent (y-axis) to be zoomed interactively. The graphic cursor will be
overlayed with a horizontal line to indicate the area boundary. To
define the desired boundary, position the horizontal line at the desired
location of the first boundary position and press MB1. Move the
vertical line to the second boundary position and press MB1. The
zoomed picture will be displayed upon specification of both
boundaries.
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KXscale. The KXscale option allows the user to specify the horizontal
extent (x-axis) to be zoomed through keyboard entry. When KXscale is
selected, the following prompt appears above the graphic area:
Enter scale min & max for x-axis:
The user must enter two values indicating the new x-axis extent. Enter
the minimum value first followed by a space, then enter the maximum
value and press the Enter key.
This feature is most useful when the user wishes to zoom out the
plotting area. The zoomed picture will be displayed upon completing
keyboard entries.
KYscale. The KYscale option allows the user to specify the vertical
extent (y-axis) to be zoomed through keyboard entry. When KYscale is
selected, the following prompt appears above the graphic area:
Enter scale min & max for y-axis:
The user must enter two values indicating the new y-axis extent. Enter
the minimum value first followed by a space, then enter the maximum
value and press the Enter key.
This feature is most useful when the user wishes to zoom out the
plotting area. The zoomed picture will be displayed upon completing
keyboard entries.
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HIGHER. The HIGHER option returns the user to the previous menu.
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VALUE
The VALUE option provides a means of obtaining X, Y plot location data
from the plot scene. The following prompt will appear:
Select Point [1=Select, 2=Escape]
Position the cursor at the desired location within the scene and press MB1.
The value(s) for the selected point are presented below the menu bar. Two
y-axis values will be shown; however, the value of RY-axis, which shows
the value of the right-hand side y-axis, is immaterial. When the user is
finished, press MB2 to exit the value option.
L_TYPE
The L_TYPE option allows the user to change the line style. The line style
can vary from a solid line to different length line segments. The change
will be effective through the entire graphic report session until a different
line style is selected. To change the line style, select L_TYPE and continue
depressing MB1 until you find the desired line style.
COLOR
The COLOR option allows the user to change the line color. The change
will be effective through the entire graphic report session until a different
line color is selected. To change the color, select color and continue
depressing MB1 until you find the desired color.
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TEXT
The TEXT option allows the user to add text to the display screen at any
location. This feature provides a mechanism for the user to customize his
plots. When the Text option is selected, the following options (Figure 9-5)
will be displayed on the Graphic Menu Bar.
ADD. The ADD option allows the user to add text to the screen. The
following prompt will appear above the graphic area:
Enter Text:
Type in the desired text (up to 80 characters per line) and press the
Enter key. The following prompt will appear:
Enter Scale Factor [Default=1.0]:
This prompt allows you to set the size of the text before it is added to
the screen. A default size will be used if you press Enter; otherwise,
enter the desired size. Then the following prompt will appear:
Select Bottom-Center Point For Text
Position the cursor at the location around which the text should be
centered. Press MB1 and the text will be drawn on the screen.
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NOTE:
MOVE. The MOVE option allows the user to change the location of
text. When MOVE is selected, the following prompt appears below the
Menu Bar:
Point To Text With Cursor [1=Select 2-4=Escape]
The selected text will be highlighted and the following menu appears:
OK HIGHER
Select OK if the highlighted text is the appropriate text to be moved.
The following prompt will appear below the Menu Bar:
Select Bottom-Center Point For Text
Position the cursor at the desired new location and press MB1. The text
will be moved to the new location.
SCALE. The SCALE option provides a way to change the scale (size)
of text. When SCALE is selected, the following prompt appears below
the Menu Bar:
Point To Text With Cursor [1=Select 2-4=Escape]
Position the cursor over the desired text and press MB1. The selected
text will be highlighted (highlighting is yellow on multi-color screens).
Select OK from the next menu to confirm the selection. The following
prompt will appear:
Enter Scale Factor:
Enter the desired new scale factor. For example, with the current text
scale displayed considered 1, a scale factor entry of 2 will double the
text size. An entry of 0.5 will halve the size.
DELETE. The DELETE option allows the user to remove user defined
text from the plot. When DELETE is selected, the following prompt
appears below the Menu Bar:
Point To Text With Cursor [1=Select 2-4=Escape]
Position the cursor over the desired text and press MB1. The selected
text will be highlighted. Select OK from the menu to confirm the
deletion.
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REDRAW. To refresh the screen and remove the effects of text being
moved, etc., select the REDRAW option.
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PRINTER
Selection of the PRINTER option will produce output for the PRINTER
device. The output will be saved in a postscript file named psout.ps in the
directory in which the program was started. This file may be
automatically routed by the VIPPRINTER command to the print queue
specified by the environment variable VIPPOST.
REDRAW
To refresh the screen, and remove the effects of graphic attributes being
changed, select the REDRAW option.
HIGHER
This option will return the user to a higher level menu, i.e., to graphic item
selection menu.
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NOTE:
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Chapter
10
Tutorial
10.1 Introduction
This tutorial presents a complete step-by-step fluid characterization
example. The data required for entry into the program are presented in
Tables 10-1 to 10-5. The fluid characterization procedure is:
1. Heavy Ends Characterization
2. Default Fluid Predictions
3. Regression on Default Predictions
4. Component Pseudoization
5. Regression on Pseudoized Description
6. Regression on Viscosity data
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Tutorial
The values for HVY1, HVY2, and HVY3 should already be present.
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Before pressing F2, your mouse pointer must be on the entry box.
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Tutorial
density units are correct. Entries for quantities not measured, such
as Z-factor and Liquid Viscosity in this example, should be left as
zero. Click OK to return to the previous menu.
When finished click OK to return to display window.
b. Select Cnst Composition from the Tests menu.
Enter the composition, either re-type the overall composition, or
press F2 and load the global reference composition. Click OK to
return to the previous menu. Enter the temperature (276 F) and
Bubble Point Pressure (4375 psig). Set Liquid Volume Fraction
Type to saturation (while the mouse pointer is over the data cell
click MB3 to access the Liquid Volume Fraction Type window.
Click OK to return to the previous menu).
Under Laboratory Measurements enter the Relative Oil Volume
and the Volume of Liquid Phase between the bubble point and the
first depletion level. In continuously decreasing values of pressure,
enter all the data from Table 10-2 and enter the data from pressure
4375 to 3960 psig from Table 10-4. Data entry into the test should
exclude viscosity data. Otherwise property regression would
thereby include viscosity, thus reducing the match of the other
property data. Click OK to return to the previous menu.
When finished click OK to return to the display window.
c. Select Sat Pressure from the Tests menu.
Enter the composition, either re-type the overall composition, or
press F2 and load the global reference composition. Click OK to
return to the previous menu. Under Laboratory Measurements,
enter the temperature (276 F) and Bubble Pt Pressure (4375 psig).
Click OK to return to the previous menu.
When finished click OK to return to the display window.
d. Select Cnst Volume from the Tests menu.
Enter the composition, either re-type the overall composition, or
press F2 and load the global reference composition. Click OK to
return to the previous menu. Enter the temperature (276 F), and
Saturation Pressure (4375 psig).
Next, name the lightest and heaviest components which contain
heptanes plus. In this example, First Heavy Component Name is
HVY1 and the Last Heavy Component Name is HVY3.
Under Laboratory Measurements enter the measured data. Add as
many columns as needed and enter the data for this test from
Tables 10-3 to 10-4. Enter the pressure, the gas z-factor, gas phase
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Tutorial
Figure 10-2
Figure 10-3
Figure 10-4
NOTE:
9. Save the data for this run by selecting Save from the File menu. Name
the file DEFAULT. DAT.
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Tutorial
10.4 Regression
As shown in Figures 10-1 to 10-4, the default predictions, using the
combined heavy ends characterization and the pure component data,
often does a poor job reproducing the experimental data. Therefore,
regression on some of the equation of state parameters is necessary. Start
with the data in the file, DEFAULT.DAT. We will regress on Omega A and
Omega B for the 3 heavy components and C1, and the binary interaction
parameters for C1 with the 3 heavy components. The order in which the
regression variables are defined is not important. However, please note
that the regression variables are numbered as follows in this tutorial:
Regression Variable
Number
Omega A-HVY1
Omega A-HVY2
Omega A-HVY3
Omega A-C1
Omega B-HVY1
Omega B-HVY2
Omega B-HVY3
Omega B-C1
10
11
1. If the program has been exited, start DESKTOP-PVT, and retrieve the
file, DEFAULT.DAT, by selecting Open from the File menu. If you are
continuing from Section 10.3, skip this step as the data from
DEFAULT.DAT is still loaded in the program.
2. Turn on regression by selecting Regression from the Config menu and
choose Yes.
3. To set the regression variables select Variable from the Regres menu.
a. Select EOS Property and click OK. Enter the number for the
regression variable in the appropriate place in the EOS property
table for regression variables 1-8 (see above table). Click OK to
return to the previous menu.
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Tutorial
b. Select Binary Coeff and click OK. Enter the numbers for the binary
interaction parameter regression variables in the appropriate
places in the table for variables 9-11 (see above table). Click OK to
return to the previous menu.
c. Select Exit and click OK to return to the display window.
4. From the Regres menu select Limits. Leave the initial value for all the
variables as 1.0. Change the Minimum to 0.7 and the Maximum to 1.3
for all the regression variables. This allows 30% change in each
regression variable.Click OK to return to the display window.
5. Select Control from the Regres menu. Change the Max Number of
Iterations to 20. Click OK to return to the display window.
6. Run the program by selecting Go from the Run menu. It will take
substantially longer to run this regression calculation compared with
the previously calculated default prediction.
7. The results can be viewed graphically by choosing Graphics from the
Report menu. The resulting figures should look like:
Figure 10-5
Figure 10-6
Figure 10-7
Figure 10-8
NOTE:
8. From the Report menu select Save EOS to save these calculated
equation-of-state values in a separate file. Name this file
REGRESS.EOS.
9. Save the data for this run by selecting Save from the File menu. Name
this file REGRESS.DAT.
10-184
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Original Components
P1
CO2, C1
P2
P3
P4
HVY2
P5
HVY3
1. If the program has been exited, start DESKTOP-PVT, and retrieve the
file REGRESS.DAT by selecting Open from the File menu. If you are
continuing from Section 10.4, skip this step and goto step 3, as the data
from REGRESS.DAT is still loaded in the program.
2. Replace the equation of state characterization with the results from the
previous regression section by selecting Load EOS from the
Component menu and choosing REGRESS.EOS. There will be a delay
while the program processes the file.
3. Turn off regression by selecting Regression from the Config menu and
choosing No.
4. Check to insure that the properties have been loaded properly, by
running the program. Select Go from the Run menu. (This calculation
should be very fast.) View the results be selecting Graphics from the
Report menu. The picture for liquid saturation for the Constant
Composition Expansion should look like Figure 10-7. (You may wish
to save this file by selecting Save from the File menu and name the file
FILENAME.DAT.)
5. Turn pseudoization on by selecting Pseudoization from the Config
menu and choosing Yes.
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Tutorial
6. From the Pseudo menu select Pseudo Name. Click AddRowAfter five
times to add five new rows and fill in the rows with the names of the
new pseudo-components. Click OK to return to the display window.
7. From the Pseudo menu select Parameter.
a. Select Original Composition to enter the composition being
pseudoized. Press F2, select Global Ref Comp and then select OK.
Click OK to return to the previous menu.
b. Enter the temperature (276 F) and Bubble Pt Pressure (4375 psig).
c. Change Unit Pressure to psig by clicking the box cell with MB1.
Select PSIG and click OK to return to the previous menu.
d. Select Pseudo-Comp P1 Lump. Turn on CO2 and C1 by clicking
the button beside the desired option. Click OK to return to the
previous menu.
e. Repeat the previous step to define each pseudo-component, P2, P3,
etc. (Refer to the table on the previous page.)
f.
8. Select Calculate from the Pseudo menu to calculate the pseudocomponent properties.
9. Save the equation of state parameters in the file by selecting Save EOS
from the Pseudo menu. Name the file PSEUDO.EOS.
10. Save the file which created the pseudo components by selecting Save
from the File menu. Name the file CREATPSD.DAT.
11. Replace the existing 12 component equation of state characterization
with the newly created 5 component description by selecting Replace
EOS from the Pseudo menu.
12. By performing the previous step, the global reference composition has
been replaced with its corresponding pseudo-component values. This
can be checked by selecting Composition from the Component menu.
Click OK to return to the display window. All the compositions for the
simulated tests, however, must be reset.
13. Turn pseudoization off, by selecting Pseudoization from the Config,
menu and choosing No.
14. Re-enter the composition data for the individual tests to be simulated.
a. Select Density from the Tests menu. Select composition, press F2
and load the global reference composition. Click OK to return to
the previous menu. All the remaining data should be correct. Click
OK to return to the display window.
10-186
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Figure 10-10
Figure 10-11
Figure 10-12
NOTE:
17. Save the data for this run by selecting Save from the File menu. Name
the file PSEUDO.DAT.
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Tutorial
Number
Omega A-P3
Omega A-P4
Omega A-P5
Omega A-P1
Omega B-P3
Omega B-P4
Omega B-P5
Omega B-P1
10
11
1. If the program has been exited, start DESKTOP-PVT, and retrieve the
file PSEUDO.DAT by selecting Open from the File menu. If you are
continuing from Section 10.5, Component Pseudoization, skip this step
as the data from PSEUDO.DAT is still loaded in the program.
2. From the Config menu select Regression and choose Yes to turn
regression on.
3. Select Variable from the Regres menu to set the regression variables.
a. Select EOS Property and click OK. Enter the number for the
regression variable in the appropriate place in the EOS property
table for regression variables 1-8 (refer to the above table).
10-188
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NOTE:
There may already be numbers in this table. These are carried in the
program memory from the regression in Section 10.4. If numbers are
present, they are probably incorrect, and must be reset.
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Tutorial
11. Turn regression off by selecting Regression from the Config menu and
choose No.
12. Run this file by selecting Go from the Run menu.
13. The results can be display by selecting Graphics from the Report menu
and should look like:
Figure 10-13
Figure 10-14
Figure 10-15
Figure 10-16
NOTE:
14. Save this in a separate file by selecting Save from the File menu. Name
this file 5CMPTUNE.DAT
10-190
Number
Zc Component P1
Zc Component P2
Zc Component P3
Zc Component P4
Zc Component P5
Landmark - R2003.0
Tutorial
1. If the program has been exited, start DESKTOP-PVT, and retrieve the
file 5CMPTUNE.DAT by selecting Open from the File menu. If you are
continuing from Section 10.6, Regression After Pseudoization, skip
this step as the data from 5CMPTUNE.DAT is still loaded in the
program.
2. Viscosity data is measured in a Constant Composition Expansion
Experiment. Therefore, select Test Type from the Config menu.
Deselect all tests except Cnst Composition by deleting the number
beside the desired item. Click OK to return to the display window.
3. From the Config menu select Regression and choose Yes to turn
regression on.
4. From the Regres menu select Variable to set the regression variables.
a. Select EOS Property and click OK. Enter the number for the
regression variable in the appropriate Zc column in the EOS
property table. Note, there may already be numbers in this table in
the columns for Omega A and Omega B. These are carried in the
program memory from the previous regressions. If they are
present, they must be reset to zero. Click OK to return to the
previous menu.
b. Select Binary Coeff and click OK. Zero out any numbers which
may be present. Click OK to return to the previous menu.
c. Select Exit and click OK to return to the display window.
5. Select Limits from the Regres menu. Set the Minimum to 0.5 and the
Maximum to 2.0 for all five variables. Click OK to return to the display
window.
6. From the Regres menu select Control. Change the Max Number of
Iterations to 20. Click OK to return to the display window.
7. Enter the data for the simulated experiment. From the Tests menu
select Cnst Cmposition.
a. Check that the composition has been set by pressing F5 while your
mouse pointer is over the desired item. If the composition is not set
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Tutorial
b. Check that the temperature is set to 276 F and the bubble point
pressure is 4375 psig.
c. Select Laboratory Measurements. Erase all the present data by
pressing DeleteRow until all the Pending Row is the only row left.
Add 18 new rows by pressing AddRowAfter or AddRowBefore.
Enter the pressures and oil viscosities from Table 10-5. Click OK to
return to the previous menu. Click OK to return to the display
window.
8. From the Run menu select Go to run the program
9. The results can be viewed graphically by selecting Graphics from the
Report menu. Select Cnst Composition and click OK. From the
Graphics Menu Bar select VISCo to display the oil viscosity. The
picture for oil viscosity for the Constant Composition Expansion
should look like Figure 10-17.
10. Select Save EOS from the Report menu to save the calculated equationof-state values in a separate file. Name this file VISTUNE.EOS. This
will be the PVT file containing the equation of state parameters for
input to a reservoir simulator.
11. Save the data for this run by selecting Save from the File menu. Name
this file VISTUNE.DAT.
10-192
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5.84
50.43
Ethane
9.65
Propane
8.75
iso-Butane
2.36
n-Butane
3.53
iso-Pentane
1.58
n-Pentane
1.37
Hexanes
2.29
Heptanes Plus
Heptanes Plus - Molecular Weight
Heptanes Plus - Specific Gravity
R2003.0 - Landmark
14.2
183.
0.8345
10-193
Tutorial
10-194
Relative
Volume
(Used in)
6000
0.92
CCEXP
5000
0.9386
CCEXP
4500
0.9909
CCEXP
1.0000
CCEXP
4328
1.0052
CCEXP
4267
1.0117
CCEXP
4230
1.0158
CCEXP
4059
1.0368
CCEXP
3709
1.0883
CCEXP
3408
1.1472
CCEXP
2688
1.3595
CCEXP
1962
1.7834
CCEXP
1271
2.7310
CCEXP
951
3.6866
CCEXP
Density
gm/cc (Used in)
0.4924 CCEXP
0.4530 CCEXP
Landmark - R2003.0
Tutorial
R2003.0 - Landmark
M.W.
Heptanes
Plus
Gas Z-Factor
Gas Phase
Prod. (Cum %)
Used In
4375
183
Not Avail.
CVDEP
3700
138
0.893
8.753
CVDEP
3000
129
0.858
19.629
CVDEP
2200
120
0.860
35.179
CVDEP
1400
115
0.892
52.727
CVDEP
700
116
0.939
69.232
CVDEP
10-195
Tutorial
(Bubble Pt)
Used In
100.00
CCEXP
4300
65.1
CCEXP
4150
57.0
CCEXP
3960
53.0
CCEXP
50.1
CVDEP
3000
45.0
CVDEP
2200
41.4
CVDEP
1400
37.6
CVDEP
700
33.3
CVDEP
3700
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Tutorial
0.106
5780
0.102
5415
0.098
4980
0.095
4620
0.093
4375
R2003.0 - Landmark
Liquid Viscosity
(Centipoise)
(Bubble Pt)
0.091
4225
0.099
4100
0.101
3900
0.105
3700
0.109
3400
0.114
3000
0.125
2600
0.137
2200
0.153
1800
0.172
1400
0.199
1000
0.231
700
0.260
10-197
Tutorial
10-198
OMEGAB
X
X
X
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Tutorial
R2003.0 - Landmark
MWGRP
125.00
300.00
10-199
Tutorial
10-200
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R2003.0 - Landmark
Tutorial
10-201
Tutorial
10-202
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Tutorial
10-203
Tutorial
10-204
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Appendix
A
References
1. Wiebe, R.: The Binary System Carbon Dioxide-Water Under
Pressure, Chemical Reviews, 29 (1941) 475-481.
2. Malinin, S.D. and Savelyeva, N.I.: The Solubility of CO2 in NaCl and
CaCl2 Solutions at 25, 50, and 75 Under Elevated CO2 Pressures,
Geochemistry International, (1972) 410-418.
3. Malinin, S.D. and Kurovskaya, N.A.: Solubility of CO2 in Chloride
Solutions at Elevated Temperatures and CO2 Pressures, Geochemistry
International, (1975) 199-201.
4. McRee, B.C.: CO2: How It Works, Where It Works, Petroleum
Engineers, (Nov. 1977) 52-63.
5. Rowe, A.M. and Chou, J.C.: Pressure-Volume-TemperatureConcentration Relation of Aqueous NaCl Solutions, J. of Chemical and
Engineering Data, Vol. 15, No. 1 (1970) 61-66.
6. Parkinson, W.J. and De Nevers, N.: Partial Model Volume of Carbon
Dioxide in Water Solutions, I & EC Fundamentals, Vol. 8, No. 4 (Nov.
1969)709-713.
7. Sayegh, S.G. and Najman, J.: Phase Behavior Measurements of CO2SO2- Brine Mixtures, The Canadian Journal of Chemical Engineering, Vol.
65 (April 1987) 314-320.
8. Osif, T.L.: The Effects of Salt, Gas, Temperature, and Pressure on the
Compressibility of Water, SPE Reservoir Engineering, Vol. 3, No. 1 (Feb.
1988) 175-181.
9. Kestin, J., Khalifa, H.E., Abe, Y, Grimes, C.E., Sookiazian, H. and
Wakeham, W.A.: Effect of Pressure on the Viscosity of Aqueous NaCl
Solutions in the Temperature Range 20-150 C, J. of Chemical and
Engineering Data, Vol. 23, No. 4 (1978) 328-336.
10. Whitson, C. H. and Torp, S. B.: Evaluating Constant Volume
Depletion Data, JPT, (Mar., 1983), 610-620.
11. Coats, K. H.: Simulation of Gas Condensate Reservoir Performance,
JPT, (Oct., 1985), 1870-1886.
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A-206
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000000Subject Index
A
calculation
how activated 8-156
how to invoke 2-16
of phase envelope 4-26
calculation method
selecting 8-156
carbon dioxide
saturated water properties 5-44
carbon dioxide saturated water
entering property correlations 6-67
saving data in file 9-175
carbon dioxide solubility 5-44
how calculated 5-45
Cavett correlation 6-55
click and drag
definition of xvii
CO2 saturated water 4-27
component K-value
entering for distillation test 7-120
Component menu
Append EOS option 5-34
Load EOS option 5-34
overview of 5-31
System option 5-31
User option 5-32
Volatile option 5-33
components
setting default 5-31
user-defined 5-32
volatile 5-33
composition 4-30
loading from another test 5-33
saving data in file 9-175
composition expansion procedure 4-26
composition source
defining 4-27
composition specification 4-29
composition variation test 4-29
composition variations with depth 4-27
B
batch data file
definition of 2-16
batch mode 2-5
bibliography xviii, A-205
binary coefficients
specification of 5-38
binary exponents
defining 5-38
binary interaction coefficients
entering for nonlinear regression 6-64, 6-65
how to define 4-25
plotting 6-57
use in mixing rules 5-38
binary interaction coefficients of H2O
how to specify for thermal 4-28
blend API gravity data
entering for distillation test 7-122
boiling point temperature
entry in property table 5-37
plotting 6-57
bracket molecular weights 6-53
bubble point pressure 4-26, 7-85
of pseudo components 6-60
oil-water 7-112
R2003.0 - Landmark
Subject-207
Subject
compressibility
of water, how calculated 5-48
Config menu
Binary Coeff option 4-25, 5-38
Composition Sor option 4-27, 6-58
EOS option 4-24
Heavy option 4-29
overview of 4-23
Pseudoization option 4-27
Regression option 4-27
Run Sequence option 4-29
Run-Time Compos option 4-29
System Info option 4-24
Test Type option 4-25
Thermal option 4-28
Water-In-Oil option 4-29
confirmation dialog
how to use 2-12
constant composition expansion test 4-29
constant composition test 7-88
constant volume depletion procedure 4-26, 7-92
constant volume depletion test 4-29
Control key combinations xviii
correlation
Cavett 6-55
Edmister 6-56
Kesler-Lee 6-55
Riazi-Daubert 6-55
Riedel-Pitzer 6-55
use to calculate EOS 6-55
Whitson 6-56
critical pressure
entry in property table 5-36
plotting 6-57
use in heavy fraction 6-56
critical temperature
entry in property table 5-36
plotting 6-57
critical z-factor
entry in property table 5-36
plotting 6-57
crude viscosity data
entering for distillation test 7-124
cursor movement control xviii
D
dat file extension 2-16
Subject-208
data
generating table of 9-173
printing a table of 9-173
retrieving from database 9-173
retrieving tabular data 9-174
saving table of 9-173
saving to a database 9-172
data entry
general guidelines 2-7
data file
how to open new 3-20
data set
adding descriptive text 4-24
database file
definition of 2-17
how to open 3-20
saving 3-20
debugging information 8-160
defaults
component 5-31
density
laboratory procedures 4-26
liquid 7-81
density correlation 5-45
entering for nonlinear regression 6-67
density units
use as input in test procedures 7-76
derivative calculation
in regression 6-71
DESKTOP-PVT
batch mode 2-5
how to exit 3-21
Overview 1-1
starting the program 2-5
dew point pressure 7-85
of pseudo components 6-60
differential expansion procedure 4-26
differential expansion test 4-29, 7-99
differential liberation test 7-99
differential vaporization test 7-99
Display Window
description of 2-6
distillate API gravity
entering for distillation test 7-119
distillation curve
entering 7-116
distillation table
use in heavy fraction 6-56
distillation test 4-26, 7-114
dtpvt.ini file 3-19, 3-21
Landmark - R2003.0
E
Edmister correlation 6-56
enthalpy 4-26
gas, how to specify 5-39
of a gas mixture 7-107
of a liquid mixture 7-109
enthalpy units
use as input in test procedures 7-77
EOS data file
appending 5-34
definition of 2-17
opening and loading 5-34
EOS parameters
calculation for heavy fraction 6-55
equation-of-state
calculation in heavy fraction 6-54
how to specify 4-24
saving calculations 9-174
use in DESKTOP-PVT 1-2
use in pseudoization 6-58
equation-of-state data file
definition of 2-17
equation-of-state parameters
appending for pseudo components 6-61
appending to a file 6-57
entering for nonlinear regression 6-63
overwriting 6-57
overwriting for pseudo components 6-61
review in table format 6-60
review in tabular form 6-57
saving 6-57
saving for pseudo components 6-60
F
File Box Pop-up
how to use 2-8
File menu
Exit option 3-21
Last Run option 3-19
Load Database option 2-17, 3-20
New option 3-20
Open option 2-16, 3-20
overview of 3-19
Save Database option 2-17, 3-20
Save option 2-16, 3-20
file types
summary of 2-16
R2003.0 - Landmark
Subject
G
gamma distribution function 6-50
alpha parameter 6-53
for heavy fractions 6-50
gas compressibility factor 4-26, 7-79
gas enthalpy
how to specify 5-39
of a mixture 7-107
gas-oil ratio units
use as input in test procedures 7-76
Gibbs method 8-156
Subject-209
Subject
H
H2O Binary Coef menu
display of 5-38
H2O equation-of-state properties
how loaded 4-28
hardware/software requirements 1-3
heavy ends characterization
tutorial on 10-177
heavy fraction
review results 6-57
heavy fraction characterization 6-49
how to activate 4-29
use in generating EOS data 2-17
heavy fraction properties
entry of 6-50
Heavy function
overview 6-49
Heavy menu
Append EOS option 6-57
Calculate option 6-56
Graphics option 6-57
overview 6-50
Parameter option 6-50
Replace EOS option 6-57
Review option 6-57
Save EOS option 6-57
hydrocarbon composition
variation with depth 7-137
I
ideal gas state 5-39
input data
recalling from last simulation 3-19
input data file 2-16
opening and reading 3-20
item selection panel
how to use 2-10, 2-11
iteration
for nonlinear regression 6-70
Subject-210
K
Kesler-Lee correlation 6-55
K-value correlation
specifying for nonlinear regression 6-66
K-values
entering for distillation test 7-120
how computed 5-44
saving tables of 9-174
L
laboratory distillation test 7-114
laboratory procedures 4-29
bubble point pressure 4-26
CO2 saturated water 4-27
common input data for 7-74
composition expansion 4-26
composition variation 4-27
constant volume depletion 4-26
density 4-26
differential expansion 4-26
distillation test 4-26
enthalpy 4-26
gas compressibility factor 4-26
multiple contact vaporization 4-26
phase envelope calculation 4-26
saturation pressure 4-26
separators 4-26
specifying other conditions 7-75
steam distillation 4-26
steam vaporization 4-27
swelling test 4-26
use in simulation data 1-2
vapor pressure 4-26
vaporization test 4-26
viscosity 4-26
water properties 4-26
laboratory separator test
calculation of 7-132
laboratory tests 4-29
last single carbon number
entry of 6-53
line color
in plots 9-168
line style
in plots 9-168
liquid density 7-81
Landmark - R2003.0
liquid enthalpy
of a mixture 7-109
liquid water properties 7-111
list entry panel
how to use 2-13, 2-14
Lohrenz, Bray and Clark 8-156
Lohrenz-Bray-Clark correlation
alternatives to 5-42
M
manual
overview of xv
MB1, MB2, etc.
definition of xvi
Menu Bar
description of 2-6
menu options
how to select 2-7
mixing rules
parameters used in 5-38
mole fraction
calculation of 6-50
entering for nonlinear regression 6-64
entry of 6-52
how to specify 4-29
plotting 6-57
review in table format 6-60
review in tabular format 6-57
mole fraction distribution
entry of 6-52
molecular weight
calculation of 6-50
entering for distillation test 7-117
entry in property table 5-36
entry of 6-52
minimum expected in heavy fraction 6-54
plotting 6-57
molecular weight boundary
in heavy fraction 6-54
molecular weight interval
in heavy fraction 6-54
mouse buttons
how to use xvi
multiple contact steam vaporization test
thermal properties for 4-28
multiple contact vaporization test 4-26, 7-102
multistage separator
modeling of 7-130
R2003.0 - Landmark
Subject
N
new data file
how to open 3-20
Newton-Raphson method 8-156
nonlinear regression 6-49
entering control data 6-70
entering variables for 6-62
package included 1-1
tutorial on 10-183
nonlinear regression calculation
overview of 6-62
non-volumetric observed data 6-71
O
observed data
use in regression 6-71
oil composition
water-free 7-112
Omega A,B
entry in property table 5-36
opening a database file 3-20
output
quantity for regression 6-70
output file
definition of 2-18
P
Parachor
entry in property table 5-37
Parkinson and De Nevers 5-47
Passut-Danner ideal gas state 5-39
Pedersen method 8-156
Pedersen viscosity correlation
how to specify 5-42
phase envelope
calculation of 7-136
phase envelope calculation 4-26, 7-104
Subject-211
Subject
plotting
annotation of plots 9-169
changing the line color 9-168
changing the line style 9-168
customized title 9-172
obtaining X, Y plot location data 9-168
retrieving data 9-173
saving data 9-172
selecting lab procedures for 9-162
zooming the plot 9-166
pop-up windows
summary of 2-8
PostScript output file
definition of 2-18
predictive mode
use in DESKTOP-PVT 1-1
pressure
critical of fluids 5-36
pressure units
definition of 5-36
of pseudo components 6-60
use as input in test procedures 7-76, 7-77
pressure-volume relations test 7-88
printer
setting up output 2-18
PRINTER option 2-18
printing
table of data 9-173
properties
specifying for fluids 5-36
property table
entering for fluids 5-36
pseudo components 6-49
entering data for 6-59
entering number and name 6-58
specifying for heavy fractions 6-53
Pseudo function
overview 6-49
Pseudo menu
Append EOS option 6-61
Calculate option 6-58, 6-60
overview of 6-58
Parameter option 6-59
Pseudo Name option 6-58
Replace EOS option 6-61
Review option 6-60
Save EOS option 6-60
pseudo-critical temperature
entering for nonlinear regression 6-66
Subject-212
pseudoization
detail discussion/activating 4-27
overview of 6-58
regression after
tutorial on 10-188
tutorial on 10-185
use in DESKTOP-VIP 1-2
Q
quitting DESKTOP-PVT 3-21
R
reference temperature
entry in property table 5-37
Regres menu
Control option 6-70
Limits option 6-69
overview of 6-62
Variable option 6-62
regression
tutorial on 10-183
regression function
activating 4-27
regression variables
entering 6-67
how to specify for thermal 4-28
setting initial value of 6-69
regression weight factors
entering for distillation test 7-120
Reid, Prausnitz and Sherwood 8-156
Report menu
GetGraph option 2-17, 9-173
GetTable option 9-174
Graphics option 9-162
GraTitle option 9-172
overview of 9-161
PrtTable 9-173
PrtTable option 2-18
SaveCO2T option 9-175
SaveEOS option 9-174
SaveKval option 9-174
SaveVisc option 9-175
SaveZgrd option 9-175
SavGraph option 2-17, 9-172
SavTable option 9-173
Table option 2-18, 9-173
Landmark - R2003.0
S
salinity effects
adjusting 5-47
saturation pressure 4-26
of pseudo components 6-60
use in test procedures 7-85
saturation pressure calculation
controlling convergence 8-157
thermal properties for 4-28
saturation pressure type
of pseudo components 6-60
saving a database file 3-20
saving current data 3-20
Sayegh and Najman 5-47
SCN equation-of-state parameters 6-56
screen layout 2-6
search vector length
initializing for regression 6-70
separator, multistage
modeling of 7-130
separators 4-26
solubility
CO2, calculation of 5-45
R2003.0 - Landmark
Subject
specific gravity
entry in property table 5-37
entry of 6-52
plotting 6-57
starting the program 2-5
steam distillation 4-26
steam distillation test
overview of data requirements 7-127
thermal properties for 4-28
steam vaporization 4-27
steam vaporization test
overview of 7-145
sum-of-square
reduction in 6-71
swelling test 4-29, 7-97
swelling test procedure 4-26
system information
adding 4-24
T
table entry panel
how to use 2-15
table look-up
use to calculate EOS 6-55
temperature
boiling, entry of 5-37
critical, of fluids 5-36
reference, entry of 5-37
temperature units
definition of 5-36
of pseudo components 6-60
use as input in test procedures 7-75
Subject-213
Subject
Test menu
Cnst Composition option 7-88
Cnst Volume option 7-92
Density option 7-81
Differential option 7-99
Distillation option 7-114
Gas Enthalpy option 7-107
Liquid Enthalpy option 7-109
Multi-Contact option 7-102
overview of 7-73
Phas Envlop option 7-104
Phas Envlop/Full option 7-136
Sat Pressure option 7-85
Sat Pressure/H20 option 7-112
Separator/No Reg option 7-130
Separator/Reg option 7-132
Steam Distillation option 7-127
Steam Vaporizatn option 7-145
Swelling option 7-97
Vapor Pressure option 7-83
Viscosity option 7-87
Water Property option 7-111
Z-Factor option 7-79
ZGRAD option 7-137
test procedures
specifying the type of 4-25
text
adding to a plot 9-169
text-entry window
how to use 2-9
thermal option
how to activate 4-28
title
customizing for a plot 9-172
tutorials
fluid characterization 10-179
heavy ends characterization 10-177
nonlinear regression 10-183
overview of 10-177
pseudoization 10-185
regression after pseudoization 10-188
regression on viscosity data 10-190
Twu viscosity correlation 8-156
U
unpseudoized fluid compositions
how to specify 4-29
user-defined components 5-32
Subject-214
V
vapor pressure 4-26, 7-83
vaporization test 4-26
VIPPOST variable 2-18
VIPPSOUT variable 2-18
VIP-THERM
activating Thermal option in PVT 4-28
defining volatile components 5-33
water-in-oil option for 4-29
viscosity 4-26
entering for nonlinear regression 6-65
of fluid mixture 7-87
of water,calculation of 5-48
regression tutorial 10-190
saving data in file 9-175
viscosity correlation 8-156
specifying 5-42
use in pseudoization 6-58
viscosity data
entering for distillation test 7-123
volume shift parameter
entering for nonlinear regression 6-64
entry in property table 5-37
how computed 5-38
plotting 6-57
use in heavy fraction 6-56
W
water compressibility
how calculated 5-48
water formation volume factor 5-45
water properties 4-26, 7-111
water viscosity
how calculated 5-48
water-free oil composition 7-112
water-in-oil option
how to activate 4-29
Watson characterization factor
for heavy fraction 6-54
use of 6-51
weight factor
use as input in test procedures 7-77
weight fraction
entry of 6-52
plotting 6-57
Whitson correlation 6-56
Landmark - R2003.0
Subject
Z
z-factor 7-79
critical 5-36
plotting 6-57
zoom
plots 9-166
R2003.0 - Landmark
Subject-215
Subject
Subject-216
Landmark - R2003.0