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KEY SHEET
Physics :
1) 3
2)
3)
4)
5)
6)
7)
11) 1
12) 2
13) 2
14) 2
15) 3
16) 2
17) 2
21) 2
22) 2
23) 4
24) 2
25) 3
26) 3
8)
9)
10) 1
18) 2
19) 4
20) 2
27) 4
28) 1
29) 2
30) 1
Mathematics :
31) 2
32) 2
33) 1
34) 1
35) 4
36) 4
37) 1
38) 3
39) 2
40) 1
41) 2
42) 2
43) 3
44) 3
45) 4
46) 2
47) 1
48) 4
49) 1
50) 2
51) 1
52) 3
53) 3
54) 3
55) 3
56) 2
57) 1
58) 2
59) 4
60) 1
61)1
62) 1
63) 1
64) 4
65) 3
66) 2
67) 4
68) 2
69) 3
70) 1
71) 1
72) 3
73) 1
74) 4
75) 3
76) 1
.i
Chemistry :
78) 3
79) 2
80) 1
81) 4
82) 1
83) 3
84) 1
85) 3
86) 1
87) 2
88) 2
89) 1
90) 1
te
ps
77) 1
SOLUTIONS
Assuming that ionization occurs as a result of a completely inelastic collision, we can write
mv0 m mH u
ud
1.
ys
PHYSICS
ww
w
.s
t
Where m is the mass of incident particle mH the mass of hydrogen atom v0 the initial velocity of
incident particle and u the final common velocity of the particle after collision. Prior to collision the
KE of the incident particle was
mv 2
E0 0
2
The total kinetic energy after collision
m mH u 2
m 2 v02
E
2
2 m mH
The decrease in kinetic energy must be equal to ionization energy.
mH
E1 E0 E
E0
m mH
E1
mH
E0 m mH
i.e, greater the mass m, the smaller the fraction of initial kinetic energy that be used for ionizartion.
PD 2V
q 10 C
In the first case
i.e,
2.
3.
Point P is an antinode i,e the string is vibrating in its second harmonic. Let f 0 be the fundamental
frequency. Then
2 f 0 100 Hz
f 0 50 Hz
Now P is an antinode (at length l / 4 from one end) so centre should be a node. So, next higher
frequency will be sixth harmonic or 6 f 0 which is equal to 300 Hz as shown below:
4.
Given that v1 v2
angle 900 900 with horizontal. Now horizontal component of velocity remains unchanged.
Therefore
ps
.i
v1 cos v2 sin
v
3
Or tan 1
v2 4
1
1
4
2
K min m v1 cos 2 3 5.76 J
2
2
5
Weins displacement law is
ww
w
6.
.s
t
ud
ys
te
Or 37 0
mT b ( b Weins constant)
b 2.88 106 nm K
m
T
2880 K
1000 nm
Energy distribution with wavelength will be as follows:
From the graph it is clear that
U 2 U1 (in fact U 2 is maximum)
7.
1 1 1
F f1 f 2
1
1
1 1
1
1 1 2 1
F
R
R
mv
v
r 0 0
B0 q B0
Or
8.
1 2
R
.i
will be
3B0
ps
te
v
3 v0
3 v0
0
v0 t
0 t
cos 60
2 B0
2 B0 2 3B0
3B0
Free body diagram of the two bodies are as follows
.s
t
ud
ys
11.
R
1 2
x
3
sin
r
2
600
T
tOA
6 3B0
Or F
ww
w
Or 2 f 4 20 f
Or f 8 N
2
4
Maximum friction between the two blocks can be: m 2kg
f max mg 0.5 2 10 10 N
12.
13.
d M di
d 4
2A
M 2
Further d M di 2 1 2Wb
During fusion binding energy of daughter nucleus is always greater than the total binding energy of
the parent nuclei. The difference of binding energies is released. Hence
Or di
14.
15.
In perfectly inelastic collision between two particles linear momentum is conserved. Let be the
angle between the velocities of the two particles before collision. Then
p 2 p12 p22 2 p1 p2 cos
2
v
2
2
Or 2m mv mv 2 mv mv cos
2
1
Or 1 1 1 2 cos
Or cos
2
16.
1
Here, Z1 R
V
V
i 0 and i2 0
Z1
Z2 ;
As Z 2 Z1 i1 i2
tan
1
And Z 2 R
2C
2
y 2 2
2
x
2
1
2
tan
2
1
cot
2
2
2
900
ps
Or cot
.i
17.
Or 1200
cut of
19.
cut of
ys
Let nth minima of 400 nm coincides with mth minima of 560 nm, then
2n 1 7 14
400
560
.....
Or
2n 1 2m 1
2m 1 5 10
2
2
i.e, 4th minima of 400 nm coincides with 3rd minima of 560 nm.
Location of this minima is
2 4 11000 400 106
Y1
14 mm
2 0.4
Next 11th minima of 400 nm will coincide with 8th minima of 560 nm
Location of this minima is
2 11 11000 400 106
Y2
42 mm
2 0.1
Required distance Y2 Y1 28 mm
Let the initial amplitude decreases to a1 to the other side i.e, after the first sweep;
Decreases in elastic potential energy Work done against friction
1
1
Or ka 2 ka12 mg a a1
2
2
1
Or k a a1 a a1 mg a a1
2
20.
ud
VA VB
.s
t
ww
w
18.
te
tan
Or a a1
2 mg
k
2 mg
k
.
2 mg
an 1 an
k
Adding all the above equations
2 n mg
a an
k
The block stops when
mg
mg kan or an
k
Substituting in the above equation we get:
20 0.3 15 n 7
ka
mg
2n 1
a Or 2n 1
mg 0.04 110
k
;
Let l be the end correction. Given that, fundamental tone for a length 0.1m first overtone for the
length 0.35 m.
v
3v
4 0.1 l 4 0.35 l
Solving this equation, we get
l 0.025m 2.5cm
The average speed of molecules of an ideal gas is given by
8 RT
v
i.e, v T for same gas.
M
Since, temperature of A and C are same average speed of O2 , molecules will be equal in A and C i.e,
v1 .
Linear acceleration of cylinder is zero i,e ,
mg sin Frictional force f upwards m mass of cylinder
24.
.s
t
ud
ys
22.
te
ps
.i
21.
Similarly a1 a1
Or
25.
26.
27.
28.
fR
2f
mR
ww
w
R radius of
cylinder
Or
mR
R
1
mR 2
2
For no slipping between cylinder and plank
a R 2 g sin
In n-type semiconductors electrons are the majority charge carriers.
Current I can be independent of R6 only when R1 , R2 , R3 , R4 and R6 form a balanced Wheatstone
bridge.
R
R
Therefore, 1 3 or R1 R4 R2 R3
R2 R4
The average velocity in the first half of the distance v , while in the second half the average
velocity is v. Therefore t1 t2 . The work done against gravity in both halves is mgl / 2 .
The distribution of charge on the outer surface depends only on the charges outside and it
distribution itself such that the net, electric field inside the outer surface due to the charge on outer
surface and all the outer charges is zero. Similarly the distribution of charge on the inner surface
depends only on the charges inside the inner surface, and it distribution itself such that the net,
YAK
YA LK
m
K eq
m YA LK
YAK
ps
T 2
.i
29.
electric field outside the inner surface due to the charge on inner surface and all the inner charges is
zero.
Also the force on charge inside the cavity is due to the charge on the inner surface. Hence answer is
option.
YAK
K1 K 2
L
K eq
YA
K1 K 2
K
L
te
ys
YA
YA
F L and in case of spring F K .x . Comparing these two we find K of wire
L
L
1
2 mR 2 2 MR 2
2
4m 2m
8m
4m M
ww
w
.s
t
ud
30.
YA
. Because in case of a wire,
L
MATHEMATICS
31.
32.
z 2 , z 3 , z 4 2 10
Form an equilateral triangle
z 22 z32 z 24 z 2 z3 z3 z 4 z 4 z 2
z 22 z32 2z 2 2z 3 z 2 z 3 6 0
Numbers in the form 7k 14
7k 1 15
7k 2 15
7k 3 14
7k 4 14
7k 5 14
7k 6 14
to get maximum number of elements, one element from 7k, and all elements of the from , 7k+1,
7k+2, 7k+3
33.
34.
ps
Given that coefficients of 2nd, 3rd & 4th terms is (a b) n are in A.P.
2n c2 n c1 n c3 n 7, n 2 (not possible)
te
36.
.i
35.
Pr 1 n Pr n Pr 1
a
b
c
a c
b2
1
1
1
c
b
&
n
b
a
b b
a(b c)
a(n r)n r 1) b(n r 1) c
1 .1
2 6
required probability =
5
1 . 1 1 . C2
2 6
2 25
= 8
23
3r 3 (r 1)!
n 1
40.
(n 1)(n 1)!
(n 2)!
AP 2 PB2 (60) 2
2AP.PB
1 3h 2 3h 2 3600
h 20
2
3h 2 .2
line lies on the plane
cos120o
41.
(n 2)!
ww
w
n 1
.s
t
ud
ys
a 5 b 2 4 5log 2 a 2 log 2 b 2
5log 2 a 2 log 2 b
5log 2 a.2 log 2 b maximum value of 5 log 2 a.2 log 2 b 1
2
38. Conceptual.
(r 2)(r 2)! (r 1)(r 1)!
39.
(r 2 3r 3)(r 1)!
n 1 6
n5
7
n2
1 is x+y+z=0
2
3
1
b
c
p.d 18 1 cos 2 d 18
0
b)
/2
2I
6sin d
/2
sin d
sin cos
/2
1d I 4
ud
1
k ab sin C
2
1
k bc sin A
2
1
a 2 b2 c2
k acsin B Given expression becomes
2
2
In triangle APB
AP
sin B
2
AB
46.
47.
ww
w
.s
t
45.
.i
a)
P 36sin 2
x y
x2
y2
cos 1
1
1 0
2 3
4
9
ps
44.
3 3
1 ab sin 75o
2
2
R 2
b 6
te
43.
2R
o
o
sin 45
sin 60
sin 75o
ys
42.
a abc
xp xq y(pxq) yp yq z(pxq) p (pxq) 0
C AQ
In triangle AQC, Sin
2 AC
BI
AB
AI
In triangle ABI,
A B
A
C
sin Sin cos
2 2
2
2
CI
AC
& In triangle ACI,
A
B
Sin cos
2
2
AP AQ
A
cot
BI CI
2
1
1
1
w.k.t
2
2
PA CA
AD2
/2
cos d
sin cos
0
48.
Y lt
1 tan 2 ln 1 x
1
ln(1 x )
cos x(1 x)
x 0
log e y lim
2 tan 2 ln 1 x
x 0
2 ln(1 x)
49.
50.
ye
Centroid divides the line segment, joining the points circumcentre & orthocenter in 1:2 ratio
circumcentre is P(2,3) & Image of orthocenter, with respect to any side of the triangle, lies on its
circumcircle (i.e) Q (8,5)
diameter = 2PQ 4 10
ps
.i
t1 t 2 2t1t 2
& Centroid of triangle OAB
3
t1 t 2 & 3 t12 t 22
Is
2
(t1 t 2 ) 2 2t1t 2 3
52.
t tan x, dt sec 2 x dt
9t
ww
w
.s
t
ud
51.
ys
te
9 2 3
3
4
2
3x 2 2x 4y
cos x sin x
cos x x sin x x x
I
dx
dx
x(cos x x)
x(cos x x)
1
(sin x 1)
dx log x log(cos x x) log c
= dx
x
cos x x
log cx log(cos x x)
Cx
log
cos x x
7t 3 dt
(t 3 t)1/2
9t 8 7t 6
(t 9 t 7 )1/2 dt
y t9 t7
dy
2 y c
y
2
53.
1
e tan (sin x ) dx
I1
/2 e tan 1 (sin x) e tan 1 (cos x)
2
1
3
2I1 1 dx
/2
2
I1
3
4
1
I2
2I 2
54.
5
2
esin
tan 1 (sin x )
(sin x )
5
2
1dx I
I 1
sin 1
dx
tan 1 (cos x )
1
4
sin 1
2
1 (2sin ) 2n
lt
2
n (2sin ) 2n
f (sin
0
f (sin
0
1
Domain of y sin 1 (2x) sin 1
2
[2x]
Is 1 , 0 no solution
2
Let A (Ct1 , C / t 2 ) B (Ct 2 , C / t 2 )
C C
t1
t2
Slope of AB =
1 t 1 t 2 1
Ct1 Ct 2
x)dx
ww
w
.s
t
ud
57.
/2
2
ys
56.
.i
ps
te
55.
58.
59.
60.
CHEMISTRY
61. P4 N 2O P4O10 N 2
( A)
64.
67.
(B)
(C )
Ca 2 1s 2 2s 2 2 p 6 3s 2 3 p 6 Mn 2 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 5 Zn 2 1s 2 2s 2 2 p 6 3s 2 3 p 6 3d 10
Thus the size of Zn 2 ion is smallest and of Ca 2 is largest among the three due to increase in effective
nuclear charge with increase in atomic number.Smaller the size of ion ,lighter is the hydration
enthalpy.Thus ,the order of hydration enthalpy is Zn 2 1 Mn 2 1 Ca 2 1 .
2047 kJ mol 1841kJ mol 1577 kJ mol
K 2Cr2O7 4 NaCl 6 H 2 SO4 2 CrO2Cl2 2 KHSO4 4 NaHSO4 3H 2O
red vapor ' p '
.i
Conceptual
A 2B C
t=0
Pi
0 0
at t
Pi -x 2x x
if t
0
2Pi Pi
Pt Pi 2x
P P
x t i
2
P
and P 3pi Pi
3
P
2.303
K
log i
t
Pi x
The base in which lone pairs are more available for donation,forms most stable adduct with the lewis
acid, B(CH 3 )3 .
Presence of electron releasing groups like ,Me makes the electron more available for donation,where
as an electron withdrawing group decreases the electron releasing tendency of the base.
ww
w
73.
.s
t
ud
ys
te
ps
70.
72.
CH3
Thus
75.
and
Acids.
H 3 PO 4 PO34 H 2 PO 4 HPO 42
Initial milli moles : 20 0.1 20 0.1
After reaction: - 2
2
2
Buffer solution of H 2 PO 4 (acid) and HPO 4 (Conjugate base) is formed
P P
H
=P
Tf K f .m
0.93 1.86x
M 60
60
n
2
30
m.f CH 2 O 2
82.
36 1
x
M 1.2
81.
ka2
4p
4s
Cu 2 [ Ar ]3d 9
4p
4s
te
3d
NH3
[Cu ( NH 3 ) 4 ]2 [ Ar ]
.i
79.
HPO 24
log
H 2 PO 4
ps
76.
78.
Ka2
ys
4p
.s
t
4s
[Cu ( NH 3 ) 4 ] [ Ar ]3d 10
ud
ww
w
Completely filled orbitals are highly stable, so NH 3 ligand occupy 4s and 4p orbitals.
85. Conceptual
x
87.
log tan(45o ) log p log 2
m
x
2p
m
4, at P 2 atm
88. Due to emulsification surface tension decreases.