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crude oil
C1 Revision (higher)
114 minutes
114 marks
Page 1 of 43
Q1.
(a)
Use the Chemistry Data Sheet to help you to answer this question.
The chemical equation for charcoal burning is:
C + O2
CO2
carbon dioxide
(1)
(b)
Propane is a hydrocarbon.
(i)
(1)
(ii)
Page 2 of 43
(iii)
hydroxide.
water.
(1)
(c)
Boiling point in C
Ethane (C2H6)
gas
89
Ethene (C2H4)
gas
104
Butane (C4H10)
gas
Butene (C4H8)
gas
Hexane (C6H14)
liquid
+69
Hexene (C6H12)
liquid
+64
Hydrocarbon
Tick ( )
Q2.
Page 3 of 43
(ii)
(b)
In this question you will be assessed on using good English, organising information clearly
and using specialist terms where appropriate.
Describe and explain how petrol is separated from the mixture of hydrocarbons in crude
oil.
Page 4 of 43
Q3.
Page 5 of 43
(b)
(c)
In this question you will be assessed on using good English, organising information clearly
and using specialist terms where appropriate.
Petroleum products, such as petrol, are produced from crude oil.
The graph shows the possible future production of petroleum products from crude oil and
the expected demand for petroleum products.
Page 6 of 43
Canadas oil sands hold about 20% of the worlds known crude oil reserves.
The oil sands contain between 10 to 15% of crude oil. This crude oil is mainly bitumen.
In Canada the oil sands are found in the ground underneath a very large area of forest. The
trees are removed. Then large diggers and trucks remove 30 metres depth of soil and rock
to reach the oil sands. The oil sands are quarried. Boiling water is mixed with the quarried
oil sands to separate the bitumen from the sand. Methane (natural gas) is burned to heat
the water.
The mixture can be separated because bitumen floats on water and the sand sinks to the
bottom of the water. The bitumen is cracked and the products are separated by fractional
distillation.
Use the information given and your knowledge and understanding to suggest the
advantages and disadvantages of extracting petroleum products from oil sands.
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(6)
(Total 11 marks)
Q4.
Page 7 of 43
(i)
(ii)
The table gives the name and formula for each of the first three alkanes.
Complete the table to show the formula of butane.
Name of alkane
Formula
Methane
CH4
Ethane
C2H6
Propane
C3H8
Butane
(1)
(b)
HCH
H
Draw the structural formula of propane, C3H8
(1)
Page 8 of 43
(c)
The relative amounts of and the market demand for some hydrocarbons from the
fractional distillation of crude oil are shown in the graph.
(i)
Why is the market demand for the C5 C8 fraction higher than the market demand for
the C21 C24 fraction?
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(1)
(ii)
Page 9 of 43
(iii)
Q5.
(b)
Page 10 of 43
Q6.
(1)
(b)
The boiling points of alkanes are linked to the number of carbon atoms in their molecules.
(i)
Describe the link between the number of carbon atoms in an alkane molecule and its
boiling point.
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(1)
Page 11 of 43
(ii)
Suggest two reasons why all of the alkanes in the bar chart are better fuels than the
alkane with the formula C30H62
1 .............................................................................................................
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2 ............................................................................................................
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(2)
(c)
During the last 200 million years the carbon cycle has maintained the percentage of
carbon dioxide in the atmosphere at about 0.03 %.
Over the last 100 years the percentage of carbon dioxide in the atmosphere has increased
to about 0.04 %.
Most of this increase is caused by burning fossil fuels to heat buildings, to generate
electricity and to power our transport.
Fossil fuels contain carbon that has been locked up for millions of years.
(i)
Burning fossil fuels, such as petrol, releases this locked up carbon. Balance the
chemical equation for the combustion of one of the alkanes in petrol.
2 C8H18
25 O2
........ CO2
........ H2O
(1)
(ii)
Where did the carbon that is locked up in fossil fuels come from?
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(1)
(iii)
The burning of fossil fuels has caused the percentage of carbon dioxide in the
atmosphere to increase to above 0.03 %.
Explain why.
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(2)
(Total 8 marks)
Page 12 of 43
Q7.
There is no difference in carbon dioxide emissions for all mixtures of petroleum diesel and biodiesel.
Use the information and your knowledge and understanding to evaluate the use of plant oils to produce
biodiesel.
Remember to give a conclusion to your evaluation.
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Page 13 of 43
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(5)
(Total 5 marks)
Q8.
The table shows how much carbon dioxide is produced when you transfer the same amount
of energy by burning coal, gas and oil.
(a)
Page 14 of 43
(b)
The second bar-chart shows how much sulphur dioxide is produced by burning the same
three fuels.
Compare the amount of sulphur produced by burning gas with the amount produced by
burning coal.
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(1)
(c)
Burning fuels also produces nitrogen oxides, even though the fuels contain no nitrogen.
Explain why this happens.
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(2)
(d)
When you release the same amount of energy from coal, gas and oil, different amounts of
carbon dioxide are produced.
Use the information below to explain why.
(3)
(e)
Page 15 of 43
Q9.
(i)
Stage
The crude oil is heated to 350 C.
When a fraction in the vapours cools to its boiling point, the fraction
condenses.
Any liquids flow down to the bottom of the column and the hot
vapours rise up the column.
(ii)
Page 16 of 43
(b)
In this question you will be assessed on using good English, organising information clearly
and using specialist terms where appropriate.
Each year in the UK, billions of plastic bags are given free to shoppers. These bags are
made from poly(ethene) and are often used only once.
After being used many of these plastic bags are either thrown away as litter or buried in
landfill sites.
In 2006 over 10 billion of these plastic bags were given free to shoppers.
In 2009 the number of plastic bags given to shoppers had decreased to 6.1 billion.
One reason for the decrease was because some supermarkets made people pay for their
plastic bags.
From 2011 a new type of plastic shopping bag made mainly from poly(ethene) had a useby date of only one year printed on the bag.
Use the information above and your knowledge and understanding to describe advantages
and disadvantages of using plastic shopping bags made from poly(ethene).
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(6)
(Total 10 marks)
Page 17 of 43
Q10.
(a)
(b)
What type of chemical reaction takes place when compound X is converted into
compounds Y and Z?
.....................................................................................................................................
(1)
(c)
(ii)
Q11.
Known crude oil reserves are being used up rapidly. Crude oil is used to produce many
useful fuels, such as petrol. One way to conserve crude oil reserves would be to increase the
production of bio-fuels.
(a)
Ethanol can be produced for use as a bio-fuel. Cars can be powered by ethanol or
ethanolpetrol mixtures.
Sugar cane can be fermented to give a mixture of water (boiling point 100 C) and ethanol
(boiling point 78 C).
(i)
Page 18 of 43
(ii)
3O2
2.........
3.........
(2)
(b)
The cost of producing a bio-fuel, such as ethanol, by fermentation, is at least three times
higher than the production cost of petrol. It costs less to produce ethanol from alkanes. In
the production, the vapour of an alkane is passed over a hot catalyst.
(ii)
C
(1)
(iii)
Page 19 of 43
(c)
As explained in parts (a) and (b), ethanol can be made using either sugar or alkanes as the
starting material.
Evaluate the advantages and disadvantages of using these two starting materials to
produce ethanol.
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(4)
(Total 10 marks)
Q12.
(a)
(b)
Hydrocarbons, such as decane, in the naphtha fraction are cracked to produce ethene.
The balanced chemical equation shows the cracking of decane.
(i)
C10H22
C8H18
decane
octane
C2H4
ethene
Page 20 of 43
(ii)
H
(1)
(c)
The flow diagram below shows how ethanol, for use as a fuel, can also be produced from
food crops.
Use the information in the two flow diagrams and your own knowledge and understanding to
evaluate whether more of this ethanol should be produced from food crops or from crude oil.
Remember to give a conclusion to your evaluation.
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(5)
(Total 9 marks)
Page 21 of 43
Q13.
This question is about the use hydrocarbons and the production of compounds from
hydrocarbons.
(a)
C2H4
Hydrocarbon J
C6H14
Hydrocarbon K
Hydrocarbon L
Choose the correct processes from the box to complete the sentences.
combustion
(i)
hydration
thermal decomposition
polymerisation
(ii)
(iii)
Describe a test to distinguish between hydrocarbons K and L and give the result of
the test.
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(2)
(b)
Hydrocarbon J burns completely in oxygen to produce carbon dioxide and water vapour.
2 C8H18
(i)
25 O2
16 CO2
18 H2O
Page 22 of 43
(ii)
The mass of carbon dioxide produced is greater than the 114g of hydrocarbon J
that was burned.
Explain why.
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(2)
(c)
Process 2
(i)
(ii)
Page 23 of 43
Q14.
The equation below shows the cracking of a hydrocarbon compound into two different
compounds, A and B.
(a)
(b)
Q15.
Poly(ethene) is a long-chain saturated hydrocarbon. The formula for part of the polymer
chain is:
(a)
Write the structural formula of the small molecule from which poly(ethene) is made.
(2)
Page 24 of 43
(b)
Page 25 of 43
M1.
(a)
oxygen
must be name
do not accept oxide or dioxide
1
(b)
(i)
2 x CC
and
5 x CH
all single (line) bonds
1
(ii)
C3 H8
must be formula
do not accept lower case h
1
(iii)
water
1
(c)
[6]
M2.
(a)
(i)
exothermic
accept combustion
allow burning or oxidation or
redox
1
(ii)
(b)
Marks awarded for this answer will be determined by the Quality of Written
Communication (QWC) as well as the standard of the scientific response.
Examiners should also refer to the information in the Marking guidance.
0 marks
No relevant content.
Level 1 (1-2 marks)
There is a statement that crude oil is heated or that substances are cooled.
However there is little detail and any description may be confused or inaccurate.
Page 26 of 43
Hydrocarbons (or petrol) that have (relatively) low boiling points and are
collected near the top of the fractionating column or hydrocarbons with
(relatively) high boiling points are collected near the bottom of the fractionating
column
Heat the crude oil / mixture of hydrocarbons or crude oil / mixture is heated to
about 350C
The condensed fraction (or petrol) separates from the vapours / gases and
flows out through a pipe
Some vapours / gases rise out of the top of the fractionating column
[9]
M3.
(a)
vapours condense
1
Page 27 of 43
at different temperatures
allow they have different boiling points
1
(b)
(c)
Marks awarded for this answer will be determined by the Quality of Written
Communication (QWC) as well as the standard of the scientific response.
0 marks
No relevant content.
Level 1 (1-2 marks)
There is a basic description of at least one advantage or one disadvantage of
extracting petroleum products from oil sands.
Level 2 (3-4 marks)
There is a clear description of an advantage and a disadvantage of extracting
petroleum products from oil sands.
Level 3 (5-6 marks)
There is a detailed description of both advantages and disadvantages of extracting
petroleum products from oil sands.
Page 28 of 43
the oil sands are needed because crude oil is running out
Disadvantages:
[11]
M4.
(a)
(i)
(ii)
C4H10
1
Page 29 of 43
(b)
H
H
H
H C C C H
H
H
H
1
(c)
(i)
(ii)
C2H4
do not accept C4H8
1
(iii)
cracking
[10]
M5.
(a)
Page 30 of 43
(b)
[4]
M6.
(a) complete diagram with 2 carbon atoms and 5 hydrogen atoms each CC
and each CH linked by a single line (bond)
1
(b)
(i)
the greater the number of (carbon) atoms (in an alkane molecule) the
greater its boiling point or vice versa
allow as the (carbon) chain gets longer the boiling point increases
ignore melting points
do not accept reference to greater number of molecules
1
Page 31 of 43
(ii)
low viscosity
high flammability
accept easier to burn / ignite
small molecules
accept short chains
ignore number of carbon atoms
burn completely
ignore speed of burning
2
(c)
(i)
16 (CO2) + 18 (H2O)
1
(ii)
(iii)
[8]
Page 32 of 43
M7.
sustainable / renewable
can use waste vegetable oils / fats (from food industry) or can use waste plant material
can be used to conserve crude oil (instead of / mixed with petroleum diesel)
biodegrades (easily)
ignore engine effects
conclusion supported by the argument presented, which must give added value to the points for
and against given above
1
[5]
Page 33 of 43
M8.
(a)
(b)
a lot less / much less / 18 times less (converse must specify coal)
gains 1 mark
1
(c)
ideas that
(d)
ideas that
coal produces most carbon dioxide / more CO2 than gas / oil
oil and gas also contain hydrogen / contain more hydrogen atoms than carbon
atoms / also produce water
any three for 1 mark each
3
(e)
sulphur
for 1 mark
2
[9]
M9.
(a)
(i)
(1)
5
3
(6)
4
2
all numbers in the correct order gains both marks
any two numbers in the correct position gains 1 mark
2
Page 34 of 43
(ii)
Water
ignore formula if correct name given
accept hydrogen oxide
allow H2O
1
carbon dioxide
allow CO2
accept carbon monoxide / CO or carbon / C
1
(b)
Marks awarded for this answer will be determined by the Quality of Written
Communication (QWC) as well as the standard of the scientific response.
Examiners should also apply a best-fit approach to the marking.
0 marks
No relevant content.
Level 1 (1-2 marks)
There is a basic description of at least one advantage or one disadvantage
caused by using plastic shopping bags made from poly(ethene)
Level 2 (3-4 marks)
There is a clear description of both an advantage and a disadvantage,
caused by using plastic shopping bags made from poly(ethene).
Level 3 (5-6 marks)
There is a detailed description of both advantages and disadvantages
caused by using plastic shopping bags made from poly(ethene)
examples of the chemistry/social points made in the response:
ignore cost unqualified
Advantages:
Bags can be reused (for shopping) or another specified use eg bin liners
Disadvantages:
Bags are made from (crude) oil which is a non-renewable resource/running out
[10]
M10.
(a)
hydrocarbon
1
(b)
(c)
(i)
(ii)
fuel
1
[4]
M11.
(a)
(i)
by (fractional) distillation
accept a description of the distillation process (heat and how
separation works) eg heat and condense
accept boil / vapourise etc for heat
or
fractionation
1
(ii)
CO2
note the order of these products must be correct
1
H2O
wrong way round = 1 mark
1
Page 36 of 43
(b)
(i)
H
H
C
= C
H
H
accept CH2 = CH2
1
(iii)
Page 37 of 43
(c)
candidates must include both sugar cane and crude oil in their evaluation
and both an advantage and a disadvantage to gain full marks.
if they do not then the maximum mark is three
any four from:
advantages of using sugar
enough land to grow sugar cane / land cannot be used to grow food / deforestation
continuous process
faster process
4
[10]
M12.
Page 38 of 43
(b)
(i)
heat / vaporise
mention of hydrogen = max 1
accept thermal (decomposition) for heat
allow boil
do not allow temperatures below 100C
ignore steam
1
catalyst
allow alumina / porous pot
ignore other catalysts
1
(ii)
4 C H and C = C
ignore brackets with or without an n before them
do not allow poly(ethene)
1
Page 39 of 43
(c)
low / less energy / fuel needed for process or lower temperature [ignore heat or
quoted temperatures]
high / more energy needed for process or/ higher temperature
carbon neutral
not carbon neutral or releases locked up carbon
low technology
high technology
risk of major oil spillage
can be used to make other products
disadvantages eg:
advantages eg:
food shortages
conserves food
need very large areas of (arable) land to grow crops or can only grow
in certain areas / climates
labour intensive
can accept reverse arguments
Page 40 of 43
a conclusion
with a reasoned argument based on valid advantages and disadvantages
there must be at least one advantage and one disadvantage,
however, a matched pair, although only awarded one mark would
allow the conclusion mark to be awarded
1
[9]
M13.
(a)
(i)
thermal decomposition
1
(ii)
hydration
1
(iii)
(b)
(i)
352 (g)
for correct answer
if answer is incorrect 400 + 114 162 gains 1 mark
2
(ii)
(c)
(i)
(ii)
process is continuous
1
[11]
Page 41 of 43
##
(a)
(b)
Compound A is reactive
or can be used to make many substances
or can be used in polymerisation/making plastics/named plastic
or can be used as a fuel
any one for 1 mark
1
[3]
M15.
(a)
C=C
do not accept C2H4
1
(b)
[5]
Page 42 of 43
Page 43 of 43