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Support Materials
National Assessment Bank pack
Revised Chemistry (Higher)
Principles to Production FE4D 12/NAB001
SCQF level 6
History of changes
Version
number
Date
Description
Authorised by
December 2011
Introduction
Security and confidentiality of Support Materials
This material is intended solely for the purpose of assessment of candidates against
National Unit standards in SQA approved centres and must not be released prior to
examination/practical test or distributed more widely for any other purpose.
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paper-based libraries, stockpiling ahead of assessment events and saving to
portable storage devices and laptop computers.
The assessment and marking information in this publication can be used or adapted
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In addition to a centres own security procedures, any suspected breach of the above
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The information in this publication may be reproduced in support of SQA
qualifications. Where the publication includes materials from sources other than SQA
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Every effort has been made to contact copyright holders and SQA apologises if any
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General information
Before using this National Assessment Bank pack centres should read the relevant
Unit specification which details the standard of performance expected of candidates.
It is important to ensure that this pack is used in a context appropriate to the Unit
and, if applicable, the associated Group Award. A copy of the Unit specification can
be found on SQAs website www.sqa.org.uk.
1
December 2011
Assessment conditions
Arrangements documents and subject guides refer to assessment being carried out
under controlled conditions to ensure reliability and credibility. For the purposes of
internal assessment, this means that the assessment evidence should be compiled
under supervision to ensure that it is the candidates own work.
Instruments of Assessment
This Unit has two Outcomes. Outcome 1 and 2 are assessed by a holistic end of Unit
test. It is expected that the learning and teaching process will involve some
diagnostic assessment and review of learning before the candidate attempts the end
of Unit test.
Quality assurance
Centres should retain assessment evidence and internal verification records. Units
are subject to external verification by SQA.
Re-assessment
Time is allowed within Units for assessment and re-assessment of Outcomes. Where
candidates have not attained the standard necessary to pass a particular Outcome
or Outcomes, they should have the opportunity to be re-assessed. SQAs advice is
that there should normally be one Unit re-assessment opportunity, or in exceptional
circumstances two. In some cases candidates will be required to resubmit original
work which has been revised to take account of earlier weaknesses. In other cases,
candidates will be required to undertake a new instrument designed to assess the
particular Outcome(s) in which they were unsuccessful. In all cases, evidence from
the original assessment should be used for formative purposes prior to
re-assessment.
Outcomes 1 and 2
The recommended method of re-assessment is for candidates to re-sit another entire
test to allow them to demonstrate success. A number of different assessments are
available.
Cut-off scores
A cut-off score of 60% should be used for this Unit assessment, in this case 18 out of
30.
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December 2011
A prelim which covers all Units and replicates the standard, format, duration and
security of SQAs Question Paper.
or
A prelim which covers a minimum of two Units of the Course and replicates the
standard, format, duration and security of SQAs Question Paper plus an
additional test, which provides evidence of attainment against the Course Grade
Desciptions for a grade A award, covering the third Unit, preferably with some
integration of work from the other two Units.
or
A prelim which covers a minimum of two Units of the Course and replicates the
standard, format, duration and security of SQAs Question Paper plus a high
scoring NAB for the third Unit to support an appeal for a grade C, but not an
appeal for grades A or B.
Evidence produced from NABs alone will not be sufficiently compelling for appeals.
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December 2011
4
December 2011
PC (a)
Getting most from
costly reactants
(a) Factors affecting the Q1
design
(b) Calculations
involving 100 %
yield
Outcome 1
PC(b)
PC(c)
Outcome 2
PC(a)
PC(b)
(c) Calculations
involving solutions
Q5
Q6
Q16
Q7
Q14(a)
Q13(b)
Q8
Q13(c)(i)
Q17(a)
Q17(b)
(g) Excess
Q14(b)
Controlling the
rate
(a) Collision theory
(b) Reaction profiles
Q13(c)(ii)
Q17(c)
Q17(c)
Q14(c)
Q13(a)(i)
Q9
Q3
Q10
Q13(a)(ii)
3 Chemical energy
(a) Enthalpy
(b) Enthalpies of
combustion
(c) Hesss Law
Q11
Q7
Q4
Q12
Q18(a)
Q18(b)
Q15(a)
Q15(b)
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December 2011
Name of centre
Name of candidate
Date of Assessment
Mark
Pass 18/30
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December 2011
Part A
This part of the paper consists of 12 fixed-response questions and is worth 12
marks.
In questions 14, choose the most suitable word from the following list to complete
the sentence.
biodegradable
concentration
constant
equal
gram
mole
temperature
toxic
The number of particles with energy greater than the activation energy can be
used to explain the effect of
substances.
on reaction rate.
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December 2011
NaCl(aq)
AgNO3(aq)
NaNO3(aq)
AgCl(s)
The mass of silver chloride precipitated when 005 mol NaCl(aq) is added to
excess AgNO3(aq) is:
4250 g
7170 g
8495 g
1434 g
10
20
30
40
When 0025 mol of hydrochloric acid reacts with 0025 mol of sodium hydroxide
145 kJ of energy was given out.
HCl(aq) + NaOH(aq) NaCl(aq) + H2O()
The energy, in kJ mol-1, given out when one mole of hydrochloric acid reacts with
one mole of sodium hydroxide is:
A
29
58
87
116
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December 2011
-227
Reaction pathway
-66
-227
-361
-427
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December 2011
20
60
30
30
40
14
50
5
11 The combustion of a fuel is found to raise the temperature of 500 cm3 of water by
20 C.
The energy transferred to the water is
A
418 kJ
836 kJ
8360 kJ
41800 kJ
H = -3952 kJ mol-1
-6795 kJ mol-1
-1109 kJ mol-1
+1109 kJ mol-1
+6795 kJ mol-1
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December 2011
Part B
Marks
This part of the paper consists of six questions and is worth 18 marks.
13 Ammonia is made by the Harber Process.
N2(g) + 3H2(g)
2NH3(g)
Potential energy
Reaction pathway
(b) What effect does the use of a catalyst have on the position of
equilibrium?
NH3(aq)
(ii) Ammonia gas is less dense than air and cannot be collected
by displacement of water because it is too soluble.
Draw a diagram showing a suitable method of collecting the
gas.
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December 2011
Marks
14 Magnesium reacts with sulfuric acid according to the equation:
Mg(s) + H2SO4(aq)
MgSO4(aq) + H2(g)
(c) The volume of hydrogen produced over time in this reaction was
measured and is shown on the graph.
300
Powder
225
Volume of
hydrogen
produced 150
3
/cm
75
0
20
40
60
80
100
120
140
160
180
Time/s
(b) An indicator did not have to be added to identify the end-point of this
titration.
Give a reason for this.
Scottish Qualifications Authority
National Assessment Bank/FE4D 12/001 V1
Revised Chemistry (Higher): Principles to Production
1
12
December 2011
Marks
16 Calculate the volume, in litres, of 4 g of methane gas, CH4(g).
Take the molar volume to be 23 litres mol-1.
(GFM 28)
(b) (i) Calculate the theoretical yield of ethene from 328 kg ethanol.
(c) Give a reason why a reaction with a high percentage yield may
have a low atom economy.
(b) The XeF bond enthalpy is -160 kJ mol-1. Use this plus your
answer to part (a) to calculate the enthalpy for the reaction.
Total marks: 30
Pass mark: 18
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December 2011
Marks
Toxic
Constant
Temperature
Mole
B
C
B
A
C
D
A
B
1
1
1
1
1
1
1
1
1
1
1
1
Part B
13 (a) (i)
(ii)
Activation
energy
catalyst
(b) No effect
14 (a) 001
(b) Magnesium
(c) Slope less steep than powder and finishing at the same final
volume
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December 2011
Marks
15 (a) 13 x 10-4 mol
16 16 g occupies 23 l
4 g occupies 575 l (unit not needed)
17 (a) 128
(ii) 21(%)
Total marks: 30
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December 2011