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Культура Документы
2007)
Abstract
The stress corrosion cracking (SCC) behaviour of medium carbon steel (MCS) in
caustic soda, potash and a mixture of these reagents was studied by fracturing this
material on a tensometer after every seven days of immersion in these media. Percentage
elongation and reduction in cross-sectional area were used to investigate the SCC of the
steel. The results obtained showed that MCS is susceptible to SCC in both caustic soda
and potash media. Carbon cracking caused intergranular SCC in both media due to
retained internal stresses in the steel while hydrogen cracking also occurred in caustic
soda medium, hence MCS is more susceptible to SCC in caustic soda medium than potash
solution.
Keywords: SCC, MCS, caustic soda, potash, hydrogen cracking,, carbon cracking.
Introduction
Stress corrosion cracking, SCC, refers to
cracking caused by the simultaneous action of
tensile stress and a specific corrosive medium
[Uhlig and Revie (1991); Jones (1996) and
Saxena et al. 2006)]. Many investigations have
classified all cracking failures occurring in
corrosive media as SCC including failures due
to hydrogen embrittlement. However, these
two types of cracking failures respond
differently to environmental variables (Kedzier
and Rizzo 1992).
Medium Carbon Steel (MCS) is widely
used in the construction of machine parts that
are employed in manufacturing, processing and
production industries. The best approach to
militate corrosion of these structures is to study
the corrosive behaviour of this metallic
material in an environment concerned to
proffer appropriate method of protection.
The research works of Jacobs (1985); Oni
and Ashaolu (1991); Oni (1997), Singh-Raman
and Muddle (2004); Chen et al. (2006) and
Rogante et al. (2006) had discussed the various
*Correspondence to: Afolabi A. S., Tel: +27 11 717 7539, Fax: +27 11 403 1471, E-mail:
afolabisammy@yahoo.com
**Metallurgical and Materials Engineering Department. School of Engineering & Engineering
Technology, Federal University of Technology, Akure, Nigeria.
169
Discussion
Figs. 1 and 2 show the SCC of MCS in
100% NaOH and 100% K2CO3 expressed in
terms of percentage reduction in cross sectional
area and percentage elongation to fracture
respectively. These two parameters are known
to be useful indexes for evaluating the SCC
behaviour of steel in a given medium. These
parameters were derived as stated in 3.1
following the procedures and precautions of
McIntyre and Dillon (1985) and Beaver and
Koch (1994). From the Figures, it could be
observed that both the percentage elongation
and reduction in cross sectional area decrease
with exposure time in the two media. This
behaviour, according to Kim and Wilde (1979)
is a characteristic of hydrogen induced
cracking in steels. A close look at the Figures
reveals that lower percentage reduction in cross
sectional area and percentage elongation to
fracture are observed in 100% NaOH which
indicates higher susceptibility of SCC as
compared to 100% K2CO3 medium. This
Results
i. The percentage elongation (%Ef) of the
samples was calculated suing the formula
%Ef = L - Lo x 100....(i)
Lo
where L = Length after fracture and
Lo = Initial gauge length
ii. The percentage reduction in area (%RA) is
given by
%RA = Ao - A x 100..(ii)
Ao
where Ao = Cross sectional area before
deformation.
170
Conclusions
The SCC of MCS was investigated in
100% NaOH, 100% K2CO3, 50% NaOH +
50% K2CO3, 70% NaOH + 30% K2CO3 and
70% K2CO3 + 30% NaOH media. Based on
the comparison of the results obtained and the
observations made during the course of the
work, the following conclusions can be made.
(i) The ductility of MCS decreased with
exposure time in caustic soda and
potash media, an indication that MCS is
susceptibility to SCC in these media.
(ii) The susceptibility of MCS to SCC is
higher in caustic soda solution than in
potash medium. This is due to the
combined
carbon
cracking
and
hydrogen cracking in the former as
compared to carbon cracking only in
the latter.
(iii) While hydrogen atom is endangering
specie in the cracking mechanism of
MCS in caustic soda, reduction in
concentration of this medium by potash
solution reduced the susceptibility of
this material to SCC.
(iv) There is no indication that hydrogen
atom is an endangering specie when the
steel is exposed to 100% K2CO3 and
70% K2CO3 + 30% NaOH mixture due
to change in pH of the solution.
(v) Intergranular SCC of MCS occurred in
media due to retained and unrelieved
internal stresses caused by hardening
process of the steel.
171
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