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Villard et a1.
[45]
[54]
PROCESS OF PRODUCING
CONCENTRATED SOLUTIONS 0}?
AMMONIUM NITRATE
Date of Patent:
;/
[211
1426746
4/1966
496847 12/1938
Mar. 2, 1987
[ 1
.............................................. ..
56
tame '
France .
[58]
gran
[22] F11ed:
4,927,617
References Cited
OTHER PUBLICATIONS
193-198, (1978).
Primary ExaminerJohn D011
[57]
3,301,657
ep
ens
ABSTRACT
-
ma 1 a P1P: mac r
3,419,378 12/1968
3 464808 9/1969
t.
f
.
.
wh
h
l bal ?
.
mm o ammomum nitrate.
en t e g o
ow 1s
'
3,482,945
3,502,441
Keams .
Keams _
'
higher
than
I'CCYC1111 g
'
NH3
HNO3
R
NH4NO3
5%
US. Patent
NH3
NH4NO3
4,927,617
4,927,617
following unit.
This unit is essentially characterized by the fact that it
comprises at least a pipe reactor provided with feed
means for introducing reactives (HNO3-NH3), at least
a separator for separating steam from the reaction prod
uct (concentrated aqueous solution of ammonium ni
trate) and optionally recycling means of part of the
drawing.
Pipe reactor (R) is provided at one of its ends with
three feed means for NH3, HNO3 and NH3NO3 recy
cled solutions. The feed means are preferably built up in
order to cause a turbulent ?ow. At the other end of the
separate the desired product. The applicant has found 40 the solutions in a liquid state in case of unit stopping. In
the upper part of separator (S), steam is carried off
injected together with ammonia, into a flow of recycled
following arrow (F). Condensate is discharged at H.
solutions of ammonium nitrate, the pipe reactor product
Preheating of NH3 and HNO3 takes place in heat ex
is an easily separable mixture of droplets of ammonium
changers (ECH1, ECHZ) before introduction in reactor
nitrate solution and steam. Nitric acid is injected in the 45
(R). The amount of NH3 added in storage tank (G) a
presence of a volume of ammonium nitrate ranging
function
of the acidity of the product solutions, which is
between 1 and 5 times the volume of produced ammo
a function of the amount of HNO3 used. An excess of
nium nitrate solution. The lower the global ?ow of
HNO3 is necessary to maintain acidity in the product
reactives, the higher the recycling rate.
EXAMPLE 1 (comparative)
4,927,617
4
EXAMPLE 2
In an unit as illustrated in the annexed ?gure with the
same pipe reactor as in example 1 are fed per hour:
218.4 liters of 57.5% nitric acid at 20 C.,
5
46 kg of gaseous ammonia at 60 C.,
30
35
45
55
65
ll