Atomic masses : [H = 1, D = 2, Li = 7, C = 12,

N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al =

27, Si = 28, P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn =
65,
As = 75, Br = 80, Ag = 108, I = 127, Ba = 137,
Hg = 200, Pb = 207]

Straight Objective Type

This section contains 30 multiple choice questions. Each question has 4 choices (1),
(2), (3) and (4) for its answer, out of which ONLY ONE is correct.

31.

The increase in volume of air, when temperature of 600 ml of it, is increased from 27C to
47C under constant pressure, is

(1) 20 mL

32.

33.

(2) 80 mL

(4) 500 mL

Among the following plots, which does not represent Charle's law for a given amount of gas.

(1)

(2)

(3)

(4)

The hybridisation and shape of BrF3 molecule are :

(1) sp3d and T shaped
(2) sp2d2 and tetragonal
(3) sp3 and bent
(4) none of these

34.

(3) 40 mL

Which of the following is not linear ?

(1) 3

(2) Cl2+
(3) HgCl2
(4) XeF2

Which is the right structure of XeF4 ?

35.

Xe

(1)

F
F

F
Xe

(2)

F
Xe

(3)

F
F

Xe

(4)

36.

The rates of diffusion of two gases A and B are in the ratio 1 : 4. Then the ratio of molecular
masses :
(1) 1/12

37.

(2) 5/24

(3) 16

(4) 1/6

X mL of He gas effuses through a hole in a container in 5 sec. The time taken for the effusion
of the same volume of unknown gas specified below under identical conditions is :
(1) 10 sec. CH4

(2) 10 sec. SO2

(3) 30 sec. C5H12 gas

(4) 20 sec. O2

38.

The correct order of decreasing oxidation number of P in compounds is :

PO < H4P2O7 < H3PO2 < P4
(1) H3 3

(2) H4P2O7 < H3PO3 < H3PO2 < P4

(3) H3PO3 < H4P2O7 < P4 < H3PO2

(4) H4P2O7 < P4 < H3PO2 < H3PO3

39.

For the reaction 2P + Q

3R, 12 mole of P and 5 mole of Q will produce

(1) 18 mole of R
(2) 15 mole of R
(3) 16 mole of R
(4) 17 mole of R

40.

The most unlikely resonating structures of p-nitrophenoxide ion is :

(1)

(2)

(3)

(4)

M
9

41.

The mass of Glucose (C6H12O6) required to prepare 50 mL of its

aqueous solution is :

(1) 10 g
(2) 1 mg

(3) 1 g
(4) 100 mg

42.

Li3+ and a proton are accelerated by the same potential, their de-Broglie wavelengths have the
ratio (assume mass of proton = mass of neutron) :
(1) 1 : 2
(2) 1 : 4

1 : 21
(3)

1 :3 3
(4)

43.

Identify the INCORRECT statement

(1) Orbitals of a subshell have same value

) value may not belong to same

subshell.

(2) The orbital having value of = 2 will

(3)

44.

of ( n + ) but the orbitals having same (n +

have

2 orientations in space.

3p and 3d orbitals have directional

character.

(4) Orbits in Bohrs model are two

dimensional in nature.

Electron in a hydrogen atom makes a transition from an excited state to the ground state,
which of the following statement is true?
(1) Its kinetic energy increases, potential

energy decreases and total energy also

decreases.
(2) Its kinetic energy decreases, potential

energy decreases and total energy also

increases.
(3) Its kinetic energy decreases and total

energy increases.

(4) Its kinetic energy, potential energy and

total energy, all increases.

45.

A single isolated H-like species can produce maximum spectral lines upon backtransition

from

(n 1) th excited state upto ground state :

n(n 1)
2
(1)

(2) n
n(n 1)
2

(3)

46.

(4) n 1

In which of the following reaction size of product ion is less than initial atom/ion ?
(1) Ne(g) + e Ne (g)
(2) Na(g) Na+ (g) + e
(3) O(g) + e O (g)
(4) Mg++(g) + e Mg+ (g)

47.

The five successive ionisation energies for an atom X are 800, 2425, 3660, 25025 and 32800
KJ/mole respectively. The number of valence electrons are :
(1) 1
(2) 2
(3) 3
(4) 4

48.

Electron gain enthalpy of first element in the following pairs is higher ?

(1) F, Cl
(2) Se, O
(3) O, F
(4) S, Cl

49.

Elements having highest electron affinity and highest electronegativity are respectively ?
(1) Cs & F
(2) Li & I
(3) I & F
(4) Cl & F

50.

Which of the following statements is correct regarding Ist

and IInd ionisation energy of

nitrogen and oxygen:

(1) Ist ionisation energy of nitrogen is lower

than oxygen and opposite is true for

second ionisation energy.

(2) Ist ionisation energy of nitrogen is higher

than oxygen and same is true for second

ionisation energy.
(3) Ist ionisation energy of nitrogen is higher

than oxygen and opposite is true for

second ionisation energy.

(4) None of these.

51.

Correct name is written against which of the following chemical formulae ?

(1) CaSe2O7
Calcium pyroselenate
(2)

Ni(HSO3)2

Nickel (II) metasulphite

(3) Sr(PO3)2
Stronsium phosphate
(4) CsOBr
Cesium bromite

52.

With respect to oxygen maximum oxidation state is shown by

(1) Halogen family

(2) oxygen family
(3) nitrogen family
(4) Boron family

53.

Match the column-I with the correct name column-II and choose the correct option.
Column-I
(P) Na3

BO3

Column-II
(i) Sodium metaborate

(Q) NaBO2

(ii) Magnesiumpermanganate

(R) MgMnO4

(iii) Magnesiummanganate

(S) Mg(MnO4)2 (iv) Sodiumborate

Codes :

54.

(1)

(i)

(ii)

(iii)

(iv)

(2)

(iv)

(i)

(iii)

(ii)

(3)

(iv)

(i)

(ii)

(iii)

(4)

(i)

(iv)

(iii)

(ii)

Which of following anion has pyro-preffix :

(1) S2O72

(2) SO52

(3) S2O82
(4) SO

55.

2
3

Minimum oxidation state of A and B elements is 2 and 1 respectively, if maximum

oxidation state of B element is + 7 then formula of compound A and B in which numbers of 'A'
atom are maximum :

56.

(1) B2A3

(2) B2A7

(3) B2A5

(4) BA

Names of which of the following end in -ous acid ?

(A) HNO3

57.

(B) H2CO3

(C) H2SO3

Which of the following contains both electrovalent and covalent bonds ?

(1) CH4

(3) NH4Cl

(2) H2O2
(4) none

(D) HPO3

58.

Which of the following is an exception of Octet rule :

(1) CH4

59.

(3) XeF2

(4) CO2

(C) CH3

(D) CF3

Which of the following is nonplanar molecule :

(A) XeF4

60.

(2) PH3

(B) H2O

In the given figure, mercury columns of 10 cm each are trapped between gas columns of 10
cm each. If Patm = 75 cm of Hg, then the gas pressure in the topmost gas column will be :

(A) 55 cm of Hg

(B) 35 cm of Hg

(C) 65 cm of Hg

(D) 45 cm of Hg