Академический Документы
Профессиональный Документы
Культура Документы
Huang Junhua1
e-mail:chejuntie@bipt.edu.cn
Abstract
The problem of corrosion leakage of seawater desalting
pipe system causes great economic loss of freshwater
supply. By observing and concluding corrosion leakage
pipes in the scene, we find that the leakage places of
seawater corrosion are on the pipe welding joint and
nearby.
In this paper, we lucubrate on the seawater corrosion
failure in the field of steel pipe welding joint and nearby.
By means of the analysis of chemical elements, metallic
phase experiments, corrosion rate experiments, phase
analysis of X-Ray Diffraction,
phase discrimination
etc, we find a corrosion failure mechanism of seawater
desalting pipes.
Keywords: Seawater corrosion; Corrosion failure
analysis; Heated affected zone;
phase
1 Introduction
A seashore seawater desalination handling equipment
pipeline presents leakage accident. By observing in the
scene, we find that the low-pressured sections not present
leakage and the high-pressured sections leakage is
serious. All the leakage places of seawater corrosion are
on the pipe welding joint and nearby, and the effects are
not good after many times mending. In the paper, we
lucubrate on the seawater corrosion failure analysis in
the field of steel pipe welding joint and nearby. By
2 Experiment method
Experiment pipe is 00Cr18Ni14Mo2Cu2 austenitic
stainless steel. The ordinary manual electric arc welding
method is used to execute welding without heat
treatment after welding. We analyze the material of
welded joint and nearby. Finally, by means of the
analysis of chemical elements, metallic phase
experiments, corrosion rate experiments, phase analysis
of X-Ray Diffraction,
phase discrimination etc, we
confirm the corrosion factors and the corrosion
mechanism.
Elements
Si
Mn
Ni
Cr
Mo
Cu
Weld zone
0.35
paucity
14.13
17.74
1.32
paucity
Heat-affected zone
Base metal zone
GB/T14976-2002
00Cr18Ni14Mo2Cu2
0.35
0.21
0.81
1.03
13.29
12.65
15.90
16.38
1.60
1.69
1.48
1.87
Zones
1.00
2.00
12.00
16.00
17.00
19.00
1.2
2.75
1.00
2.50
WZ
BMZ
700
500
600
400
500
300
400
200
200
E/mv(vs.SCE)
E/mv(vs.SCE)
300
100
0
-100
-200
-300
100
0
-100
-200
-400
-300
-500
-400
-600
-500
-700
-600
-800
-7
-6
-5
-4
-3
-2
-1
-7
-6
-5
-4
-1
BMZ
WZ
HAZ
700
600
600
500
500
400
300
300
200
200
E/mv (vs.SCE)
400
100
0
-100
-200
100
0
-100
-200
-300
-300
-400
-400
-500
-500
-600
-600
-700
-800
-700
-6
-5
-4
-3
-2
-1
-7
-6
-5
-4
-3
-2
-1
lg|I/(mA/cm )|
lg|I/(mA/cm )|
-2
lg|I/(mA/cm )|
lg|I/(mA/cm )|
E/mv(vs.SCE)
-3
2
Fitting
Tafel slope
Tafel slope
accuracy
bA(mV)
bC(mV)
0.99
47.90
221.98
7.02
10-4
8.03
10-3
Weld zone
0.99
63.89
102.77
5.65
10-4
6.46
10-3
Heat-affected zone
0.95
32.99
202.70
4.61
10-3
5.27
10-2
zones
Corrosion current
density
mA/cm2
Corrosion rate
mm/a
No
33-0397
Cr0.19Fe0.7Ni0.11
Phase
No
34-0396
Fe-Cr
phase
Sample peak
d(A)
Peak value I
I%
Card number
43.556
2.0762
11012
999
33-0397
44.444
2.0367
176
15
34-0396
50.682
1.7997
2036
184
33-0397
64.794
1.4377
68
34-0396
74.561
1.2717
2102
190
33-0397
77.881
1.2255
31
81.811
1.1763
23
2.5
34-0396
d(A)
I%
2.035
999
44.521
-.077
1.438
199
64.836
-.042
1.174
499
82.064
-.253
phase discrimination
4. Conclusions
1.
2.
3.
4.
Reference
[1] Shanghai Institute of Machinery Manufacturing
Technology editor-in-chief, metallographic analysis
technique [M], Shanghai: Shanghai Science and
Technology Literature Publishing House, 1987,6.
[2] Ji Xiaomei, CAO Cunan, Material Corrosion
Principles [M], Beijing: Chemical Industry Press,
2002, 9.
[3] Zuo Yansheng, Chen Wenzhe, Liang Wei, Modern
materials analysis [M], Beijing: Beijing University
of Technology Press, 2000, 12.
Corresponding author
Che Juntie: PhD Candidate for China University of Petroleum (Beijing), Professor for Beijing Institute of Petrochemical
Technology.
Address: Beijing Institute of Petrochemical Technology, Beijing 102617, P R China 102617
Phone:010-81292105
Mobile telephone: 13718598875
E-mail address:chejuntie@bipt.edu.cn