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Introduction
Carbon Monoxide is a colourless, odourless and non irritant gas, which
cannot be perceived by the senses. Whenever carbon is burnt either at a
high temperature or in a limited supply of oxygen some carbon monoxide
is formed. Carbon Monoxide poisoning may be due to inhalation of the
fumes given off by slow combustion of stoves, by burning charcoal in an
open fireplace or by breathing air, which is contaminated by coal gas in a
badly ventilated room. (Coal gas contains 5- 10% of CO). Deaths in a
house which is on fire, are mainly due to this gas. It is more powerful than
Carbon dioxide. As this gas has an affinity for Hb. of the blood, the
combination of two makes latter an useless oxygen carrier and renders
Hb. Functions less and carbon oxide haemoglobin is produced. Poisonings
are mostly accidental. Haemoglobin has 240 times greater affinity for CO
than for Oxygen. Therefore even minute quantities are readily absorbed
into the blood stream.
Carbon Monoxide was first prepared by the reduction of a metallic oxide
by French Chemist Lassone. Cruikshank found that it was a compound of
carbon and oxygen only. Dalton established its formula to be CO. It occurs
in traces in volcanic gases, tobacco smoke and chimney gases.
In Northern India and in the hills in the cold weather fatal poisonings have
resulted from the use of the charcoal sigry in a closed room for the sake
of warmth. Since the introduction of motor car, many deaths have
followed the inhalation of the exhaust gases given off by the engine when
running. These cases have, almost invariably, been due to the closed
garage. A few cases have been reported in which the passengers in the
closed car have been affected by the exhaust gases finding their way into
the car between badly fitting floor- boards. In latest vehicles that are fitted
with the catalytic converter, CO should not be released into the
atmosphere, where the devices are working properly.
Petrol, on burning , gives carbon a dioxide together with carbon monoxide.
These exhaust gases may contain as much as 8% to 10% carbon
monoxide. Octane (C8 H18), a hydrocarbon found, in petrol on incomplete
combustion releases carbon monoxide.
Coal or coke burnt in domestic ovens, stoves, also produces some carbon
monoxide. It is not advisable to sleep in a room where coke or wood is
History
Aristotle (384322 BC) first recorded that burning coals produced toxic
fumes. An ancient method of execution was to shut the criminal in a
bathing room with smouldering coals. What was not known was the
mechanism of death. Greek physician Galen (129199 AD) speculated that
there was a change in the composition of the air that caused harm when
inhaled. In 1776, the French chemist de Lassone produced CO by heating
zinc oxide with coke, but mistakenly concluded that the gaseous product
was hydrogen, as it burned with a blue flame. The gas was identified as a
compound containing carbon and oxygen by the Scottish chemist William
Cumberland Cruikshank in the year 1800. Its toxic properties on dogs
were thoroughly investigated by Claude Bernard around 1846.
During World War II, a gas mixture including carbon monoxide was used to
keep motor vehicles running in parts of the world where gasoline and
diesel fuel were scarce. External (with a few exceptions) charcoal or wood
gas generators were fitted, and the mixture of atmospheric nitrogen,
carbon monoxide, and small amounts of other gases produced by
gasification was piped to a gas mixer. The gas mixture produced by this
process is known as wood gas. Carbon monoxide was also used on a large
scale during the Holocaust at some Nazi extermination camps, the most
notable by gas vans in Chelmno, and in the Action T4 "euthanasia"
program.1 In addition to the Holocaust during the world war, German
Nazis used gas vans to kill an estimated 700,000 prisoners by Carbon
monoxide poisoning. This method was also used in the gas chambers of
several death camps.
Atmospheric presence
1 Kitchen, Martin (2006). A history of modern Germany, 18002000. WileyBlackwell. p. 323. ISBN 1-4051-0041-9.
Physical Properties
Chemical
formula
CO
Molar mass
28.010 g/mol
Appearance
colourless gas
Odour
odourless
Density
(337.04 F;
C(312.7 F;
Poisonous Nature
Carbon monoxide if inhaled combines with the haemoglobin of the blood
to form a stable compound, carboxyl haemoglobin. It is more stable than
oxy haemoglobin. The affinity between haemoglobin and carbon monoxide
is 240 times stronger than the affinity between haemoglobin and oxygen,
so haemoglobin binds to carbon monoxide in preference to oxygen.
The person dies due to suffocation, as little oxygen will actually be
released in the tissues, as there is decrease in the amount of oxygen
carried by the haemoglobin, thus this causes hypoxic tissue injury
resulting in relative functional anemia.
Sources of
Carbon
Monoxide
Carbon
monoxide is
produced
when fuels such
as gas, oil, coal
and
wood do
not
burn
fully. Burning
charcoal, running cars and the smoke from cigarettes also produce carbon
monoxide gas.
The following are the sources
boilers
gas fires
water heaters
cookers
open fires
Explosives
Oil Lamps
Mines
blocked
flues
and
chimneys this
can
stop
monoxide escaping, allowing it to reach dangerous levels
carbon
Auto Emissions of CO
In cities, about ; two-thirds of the carbon monoxide emissions come from
transportation sources, with the largest contribution coming from highway
motor vehicles. In urban areas, the motor vehicle contribution to carbon
monoxide pollution can exceed 90 percent. In 1992, carbon monoxide
levels exceeded the Federal air quality standard in 20 U.S. cities, home to
more than 14 million people.
Carbon monoxide results from incomplete combustion of fuel and is
emitted directly from vehicle tailpipes. Incomplete combustion is most
likely to occur at low air-to-fuel ratios in the engine. These conditions are
common during vehicle starting when air supply is restricted ("choked"),
when cars are not tuned properly, and at altitudes where "thin" air
reduces the amount of oxygen available for combustion (except in cars
that are designed or adjusted to compensate for altitude).
By 1975, most new cars were equipped with catalytic converters that
convert carbon monoxide to carbon dioxide. In the 1980's, automakers
improved CO conversion with computers and oxygen sensors that
increased the efficiency of catalytic converters. Carbon monoxide
emissions from automobiles increase in cold weather because cars need
more fuel to start at cold temperatures, and because some emission
control devices (such as oxygen sensors and catalytic converters) operate
less efficiently when they are cold.
4 ://www.nhs.uk/Conditions/Carbon-monoxide-poisoning/Pages/Causes.asp
Symptoms of CO Poisoning
On average, about 170 people in the United States die every year from CO
produced by non-automotive consumer products. These products include
malfunctioning fuel-burning appliances such as furnaces, ranges, water
heaters and room heaters; engine-powered equipment such as portable
generators; fireplaces; and charcoal that is burned in homes and other
enclosed areas. In 2005 alone, CPSC staff is aware of at least 94
generator-related CO poisoning deaths. Forty-seven of these deaths were
known to have occurred during power outages due to severe weather,
including Hurricane Katrina. Still others die from CO produced by nonconsumer products, such as cars left running in attached garages. The
Centres
for Disease Control and Prevention estimates that several
thousand people go to hospital emergency rooms every year to be treated
for CO poisoning.
The Symptoms depend on the limit of blood saturation1. Below 10% - a little inconvenience is felt.
2. 10 to 20% - Lassitude, headache, shortness of breath.
3. 20 to 30% - Giddiness, faintness, severe throbbing, headache,
muscular weakness, nausea, rapid heart beat, hurried respiration,
defective memory.
4. 30 to 40% - In-coordinated movement, mental confusion, defective
sight and hearing, palpitation, dyspnoea.
5. 40 to 50% - Behaviour like a drunk person and loss of power of
movement increasing confusion, hallucination, ataxia.
6. At 50 to 60% - Syncope or coma followed by convulsion. Weak, rapid
pulse. Skin- pinkish or reddish.
7. 60 to 70% - Deep coma. Often painless death due to deprivation of
Oxygen. There may be in-continuance of urine or stool.
oxide haemoglobin. Froths in the air passages, mouth and nostrils are
conspicuous.
Remedy for Carbon Monoxide Poisoning 1. The persons should be brought into the open air and should be
provided with artificial respiration.
2. The person should be made to inhale Carbogen, a mixture of 95%
oxygen and 5% carbon dioxide.
Treatment
1.
2.
3.
4.
5.
6.
Prevention of CO Poisoning
Make sure wood burning stoves comply with local regulations and
meet current EPA emissions standards.
Don't use a gas kitchen oven to heat your home. Keep gas
appliances properly adjusted and serviced.
Don't use paint remover that has methylene chloride in it, especially
when children are around. (Methylene chloride converts to carbon
monoxide in the body.)8
The largest group that suffers from CO poisonings are homeowners. You
can reduce your familys exposure to CO by following the
recommendations below.
Fuel-Burning Appliances
All fuel-burning appliances (eg, gas water heaters, gas stoves, gas
clothes dryers) should be checked professionally once a year or as
recommended by the manufacturer.
Gas cooking stove tops and ovens should not be used for
supplemental heat.
Space Heaters
8 www.cdc.gov/co/guidelines.htm
Barbecue Grills/Hibachis
when
operating
Boats
Be aware that CO poisoning can mimic symptoms of sea sickness.
Schedule regular engine and exhaust system maintenance.
Consider installing a CO detector in the accommodation space on
the boat.
Never swim under the back deck or swim platform as CO builds up
near exhaust vents.
9 www.healthychildren.org/English/safety-prevention/all-around/Pages/How-toPrevent-Carbon-Monoxide-Poisoning.aspx
Effects on Breathing
CO Alarms/ Detectors
10 http://www.netwellness.org/question.cfm/1230.htm
11 http://www.ehow.com/info_7873237_effects-carbon-monoxide-respiratorysystem.html
CO alarms always have been and still are designed to alarm before
potentially life-threatening levels of CO are reached. The safety standards
for CO alarms have been continually improved and currently marketed CO
alarms are not as susceptible to nuisance alarms as earlier models.
Consumers should follow the manufacturer's instructions. Using a test
button tests whether the circuitry is operating correctly, not the accuracy
of the sensor. Alarms have a recommended replacement age, which can
be obtained from the product literature or from the manufacturer.
Light-emitting diodes (LEDs) use lights to let you know how the
unit is functioning and whether the battery needs to be replaced.
Some detectors also have a liquid crystal display (LCD) panel that
shows a readout of CO levels.
12 www.cpsc.gov/en/Safety-Education/Safety-Education-Centers/CarbonMonoxide-Information-Center/Carbon-Monoxide-Questions-and-Answers-/
13 http://home.howstuffworks.com/home-improvement/householdsafety/tips/carbon-monoxide-detector3.htm
If the source of the CO is determined to be a malfunctioning
appliance, DO NOT operate that appliance until it has been properly
serviced by trained personnel.
ACKNOWLEDGEMENT
This project would be incomplete without expressing my gratitude towards
the people who made it possible for me to finish it on time and with
accuracy.
Firstly, I would like to thank my Forensic Science teacher, Professor Ajay
Ranga for giving me the requisite guidelines and helping me in fulfilling
the loopholes of my project.
Secondly, I would like to thank my friends who constantly gave me advice
on the quality of information and helped me in completing my project.
Lastly, I would like to thank our library staff for helping me in collecting
the material and the required books for the project.
BIBLIOGRAPHY
WEBLIOGRAPHY
1. www.cpsc.gov/en/Safety-Education/Safety-EducationCenters/Carbon-Monoxide-Information-Center/Carbon-MonoxideQuestions-and-Answers-/
2. http://www.ehow.com/info_7873237_effects-carbon-monoxiderespiratory-system.html
3. www.healthychildren.org/English/safety-prevention/allaround/Pages/How-to-Prevent-Carbon-Monoxide-Poisoning.aspx
4. www.nutramed.com/environment/monoxide.htm
5. http://home.howstuffworks.com/home-improvement/householdsafety/tips/carbon-monoxide-detector3.htm
6. http://www.carbonmonoxide.ie/splash.html