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CUMULATIVE TEST-1(CT-1) Code

(JEE ADVANCED PATTERN)


TARGET : JEE (MAIN+ADVANCED) 2016

Revision Plan-2 | PAPER-2


Date : 10-04-2016

COURSE : JP, JF, JR

Time: 3 Hours

Maximum Marks : 189

1.
2.
3.
4.
5.

The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
The question paper CODE is printed on the right hand top corner of this sheet.
Use the Optical Response Sheet (ORS) provided separately for answering the question.
Blank spaces are provided within this booklet for rough work.
Write your Name and Roll Number in the space provided on the below cover.

QUESTION PAPER FORMAT AND MARKING SCHEME :


6.
7.
8.

The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
Carefully read the instructions given at the beginning of each section.
Section 1 contains 7 multiple Choice question with Only one correct option.
Marking scheme: +3 for correct answer, 0 if not attempted and 2 in all other cases.

9.

Section 2 contains 3 "paragraph" type questions. Each paragraph describes an experiment, a situation or a
problem. Two multiple choice questions will be asked based on this paragraph. Only one option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and 1 in all other cases.

10.

Section 3 contains 3 "match the following" type question and you will have to match entries in Column I with the entries
in Column-II.
Marking scheme : for each entry in Column I, +2 for correct answer, 0 if not attempted and 0 in all other cases.
OPTICAL RESPONSE SHEET :
11.
12.
13.
14.

Darken the appropriate bubbles on the original by applying sufficient pressure.


The original is machine-gradable and will be collected by the invigilator at the end of the examination.
Don not tamper with or mutilate the ORS.
Write your name, roll number and the name of the examination centre and sign with pen in the space provided for
this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble
under each digit of your roll number.

DARKENING THE BUBBLES ON THE ORS :


15. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
16. Darken the bubble COMPLETELY.
17. Darken the bubble ONLY if you are sure of the answer.
18.

The correct way of darkening a bubble is as shown here :

19.
20.

There is NO way to erase or "un-darkened bubble.


The marking scheme given at the beginning of each section gives details of how darkened and not darkened
bubbles are evaluated.

NAME OF THE CANDIDATE : ..


ROLL NO. : ..
I have read all the instructions
and shall abide by them

------------------------Signature of the Candidate

I have verified the identity, name and roll number


of the candidate.

------------------------Signature of the Invigilator

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DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %

MATHEMATICS

SECTION 1 : (Maximum Marks : 21)

This section contains SEVEN questions


Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
2 In all other cases

1.

The solution set of inequality

1
1
1
(tan x 2)(cot x) (tan x) 1 + 2 1 > lim sec 1 x is (where [.] denotes the
x

2
2
2

greatest integer function)


(A) (tan1, tan2)
(B) ( cot1, cot2)
(C) (tan1, tan2)
(D) (tan1, )

2.

tan
k 1


xk = then tan is equal to (Here 0, )
2 6

(A) tan
3.

x1, x2, x3, x4 are roots of the equation x x sin2 + x cos 2 x cos sin = 0 and if

(B) sin

(C) cot

(D) data insufficient

The domain of the function f(x) given by 3x + 3f(x) = min {min (2t3 15t2 + 36t 25), 2 + |sint|} where
2 t 4, is
(A) (, 1)
(B) (, log3e)
(C) (0, log32)
(D) (, log32)

Space for Rough Work

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P2JPCT1100416C0-1

MATHEMATICS

PART : I MATHEMATICS

MATHEMATICS

Let f(x) = x + x + cos x, being an integer and a real number. The number of ordered pairs
(, ) for which the equations f(x) = 0 and f(f(x)) = 0 have the same (non empty) set of real roots is.
(A) 0

(B) 3

(C) 4

(D) infinite

2015

5.

For all n N, let f(n + 1) = (1)n + 1 n 2f(n) and f(1) = f(2016), then

f(r) is equal to

r 1

(A) 0

6.

(B)

(C) 336

2x 1 x 2
Solution of the equation 2 sin1 x tan1
1 2x 2

1 1
(A)
,

2 2

7.

1007
3

1
(B)
,1
2

1007
3

is

(C)

1,1

Value of cos1 3x 4x 3 cos1 1 2x 2 sin1 1 x 2 =

(D)

1 1
(D) 1,1
,

2 2

a cos1 x b then value of a + b is

given 0 x
2

(A) 2 2

(B) 2 2

(C) 2

(D) 3

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P2JPCT1100416C0-2

MATHEMATICS

4.

SECTION 2 : (Maximum Marks : 18)

This section contains THREE paragraphs


Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
1 In all other cases

Paragraph for Question Nos. 8 to 9


Let f(x) and g(x) be twice differentiable functions, defined as
2

f(x) = x + xg(1) + g(2) and g(x) = f(1) x + xf (x) + f(x).

8.

The value of f(1) + g(1) is


(A) 0

9.

(B) 1

(C) 2

The number of integers in the domain of the function F(x) =


(A) 0

(B) 1

(D) 3

f(x)
g(x)

3x

(C) 2

(D) infinite

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P2JPCT1100416C0-3

MATHEMATICS

MATHEMATICS

MATHEMATICS

MATHEMATICS

Paragraph for Question Nos. 10 to 11


3

Let , and are the roots of the equation x + 6x + 3 = 0


1
1
1
1
and
A = cos (sin (( + ) + ( + ) + ( + ) ))


B = cos tan 1 sin

1
C = sec (cosec (1 )(1 )(1 )))

10.

11.

Find the value of 5A + B C


(A) 1
(B) 21

(C) 0

Find the range of the function h(x) =


(A) [0, 3]

(B) (0, 3)

(D) Can't be calculated

(5 A C)x 5 6Bx 2
x 4 (B 1)x 3 1
(C) [0, )

(D) (, )

Paragraph for Question Nos. 12 to 13


2

Consider f(x) = ax + ax + a 3, g(x) = sinx 1 and h(x) = k x

1
then
2

12.

The least positive integral value of a, say a1, for which f(x) = g(y) has no real solution for any
x and y, is equal to
(A) 4
(B) 5
(C) 6
(D) 7

13.

Value of k for which f(x) = a1x + a1x + a1 3 has exactly one real point of intersection with
y = h(x) is equal to
(where a1 is from above question)
3
3
(A) 1
(B) 2
(C)
(D)
2
4

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P2JPCT1100416C0-4

SECTION 3 : (Maximum Marks : 24)

This section contains THREE questions

Each question contains two columns, Column I and Column

Column I has four entries (A),(B), (C) and (D)


Column II has four entries (P),(Q), (R) and (S)
Match the entries in Column I with the entries in Column II
One or more entries in Column I may match with one or more entries in Column II

The ORS contains a 4 4 matrix whose layout will be similar to the one shown below :

II

(A)
(B)
(C)
(D)

For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the
ORS. Similarly, for entries (B), (C) and (D).

Marking scheme :
For each entry in Column I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 If none of the bubbles is darkened
0 In all other cases

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P2JPCT1100416C0-5

MATHEMATICS

MATHEMATICS

14.

Column-I

Column-II

(A)

(P)

[0, 1/2)

(Q)

[1, 1] {0}

(R)

(S)

{1, 0, 1}

Domain of the function


f(x) =

(B)

1
+ 2sin1 x +
x

1
x 1

is

Find the range of the function


1
f(x) =
, where [.] represents G.I.F.
[x ]

(C)

Range of the function f(x) =

{x}
1 {x}

where {.} represents fraction part function

(D)

f(x) = sin1 [x]; g(x) = 2 3x2 then domain


of the function f(g(x)), where [.] represents G.I.F.

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P2JPCT1100416C0-6

MATHEMATICS

MATHEMATICS

15.

Column-I

Column-II

(A)

(P)

(Q)

(R)

(S)

Number of values of 'x' satisfying the equation

3 sin1 1 x 2 sin1 x cos1 x 2 is

(B)

Number of integers in the range of function

f x cos1 cos 2x cos x is/are

(C)

Number of integers in the range of function


f cot 1 6 sin cos 8 cos2 is

(D)

Number of solution of equation

sin 4cos1 cot 2 tan1 x

0 is

Space for Rough Work

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P2JPCT1100416C0-7

MATHEMATICS

MATHEMATICS

16.

Column I

Column II

4x 8 3

(x 1)

72 4

3
2

(A)

If f(x) =

is defined, then x can be

(B)

The least positive integral value of x satisfying (e 2)

(P)

(Q)

(R)

(S)



sin x (x log22)(sin x cos x) < 0 is
4

(C)

The number of integral values of m for which f : R R;


f(x) =

(D)

x3
2
+(m 1)x +(m + 5)x + n is bijective is
3

The number of roots of equation


(x 1)(x 3)
(x 1)(x 3)

e x
e x x 3 cos x = 0

(x 2)(x 4)
(x 2)(x 4)

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P2JPCT1100416C0-8

MATHEMATICS

MATHEMATICS

PHYSICS

PHYSICS

PART - II : PHYSICS
SECTION 1 : (Maximum Marks : 21)

This section contains SEVEN questions

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct

For each question, darken the bubble corresponding to the correct option in the ORS

Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0

If none of the bubble is darkened

2 In all other cases

17.

AB is a uniform rod of mass M and a point mass m is placed at origin as shown in figure. The
direction of force on point mass m due to rod makes an angle with positive x-axis, where is :

(A) + 45
(B) 30
(C) + 30
(Positive angle means angle measured anti-clockwise from x-direction)

(D) + 15

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P2JPCT1100416C0-9

18.

Two rays are incident on a spherical concave mirror of radius R = 5 cm and rays are parallel to a
line AB which passes through the centre C. The rays are at perpendicular distances 3 cm and
4 cm from AB respectively as shown. Find the distance between the points at which these rays
intersect the line AB after reflection -

(A)

25
cm
24

(B)

24
cm
25

(C) zero

(D)

1
cm
3

19.

Consider a uniformly charged solid non conducting sphere of radius R and charge Q. Consider
three spherical regions centered at the centre of the uniformly charged solid non conducting
sphere, given below :
Region (1)
R1 r 0
Region (2)
R2 r R1
Region (3)
r R2
R
If electrostatic potential energy stored in each of the three regions is equal then 2 is :
R1
(A) 2
(B) 3
(C) 1
(D) 4

20.

Two satellites revolve around the Sun as shown in the figure. First satellite revolves in a circular
orbit of radius R with speed v1. Second satellite revolves in elliptical orbit, for which minimum and
R
5R
maximum distance from the sun are
and
respectively. Velocities at these positions are
3
3
v2 and v3 respectively. The correct order of speeds is :
v3

v1
5R/3Work
R Rough
Space for
Orbit(1)

R/3

Orbit(2)

Sun

v2

(A) v2 > v3 > v1

(B) v3 < v2 < v1

(C) v2 > v1 > v3

(D) v2 > v3 = v1

Space for Rough Work

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P2JPCT1100416C0-10

PHYSICS

PHYSICS

21.

A circular disc of diameter d lies horizontally inside a metallic hemispherical bowl of radius a. The
disc is just visible to an eye looking over the edge. The bowl is now filled with a liquid of refractive
index 3 . Now, the whole of the disc is just visible to the eye in the same position. If
(A) 1

22.

(B) 2

(C)

1
2

d
is equal to :
a

(D) None of these

The electric field at the centre of a uniformly charged hemispherical shell is E0. Now two portions of
the hemisphere are cut from either side and remaining portion is shown in figure. If = =

,
3

then electric field intensity at centre due to remaining portion is

(A)

23.

E0
3

(B)

E0
6

(C)

E0
2

(D) E0

A small area is removed from a uniform spherical shell of mass M and radius R. Then the
gravitational field intensity near the hollow portion is :
(A)

GM
R

(B)

GM
2R

(C)

3GM
2R 2

(D) Zero

Space for Rough Work

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P2JPCT1100416C0-11

PHYSICS

PHYSICS

SECTION 2 : (Maximum Marks : 18)


This section contains THREE paragraphs
Based on each paragraph, there will be TWO questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
For each question, darken the bubble corresponding to the correct option in the ORS
Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
1 In all other cases

Paragraph for Questions 24 and 25


Consider a hypothetical solar system, which has two identical massive suns each of mass M and
radius r, seperated by a seperation of 2 3 R (centre to centre). (R >>>r). These suns are always
at rest. There is only one planet in this solar system having mass m. This planet is revolving in
circular orbit of radius R such that centre of the orbit lies at the mid point of the line joining the
centres of the sun and plane of the orbit is perpendicular to the line joining the centres of the sun.
Whole situation is shown in the figure.

Answer the following question regarding to this solar system.


Space for Rough Work
24.

Speed of the planet is :


(A)

25.

GM
8R

(B)

GM
4R

(C)

GM
2R

Average force on the planet in half revolution is :


GMm
GMm
GMm
(A)
(B)
(C)
2
2
4 R
4R
2 R 2

(D)

(D)

GM
3R

GMm
8R 2

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P2JPCT1100416C0-12

PHYSICS

PHYSICS

PHYSICS

PHYSICS

Paragraph for Questions 26 and 27


A spherical distribution of charge varies with distance from centre as:
1from r = 0 to r = R, and 2 from r = R to r = 2R
[Relative permittivity of material of sphere is 1]
Then answer the following questions:

1
2

R
2R

26.

If the electric field at a point A at a distance R/2 from the surface of the smaller sphere is zero, find
the ratio of 1 and 2.

3R/2

2R

(A)
27.

8
19

(B)

19
8

(C)

27
8

(D)

8
27

Given the above ratio of 1 and 2 find the magnitude of electric field at a point B at the surface of
the outer sphere. (figure)

1
R

2R

(A)

37 1R
76 0

(B)

37 Space
37 R
1R
for Rough
(C) Work1
456 0
228 0

(D)

29 1R
76 0

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P2JPCT1100416C0-13

PHYSICS

Consider a situation in which a negatively charged particle of mass M and charge q revolves in
elliptical path around a fixed charge Q. the closest and farthest distance of the moving particle
from fixed charge is a and 4a respectively. (k = 1/40)
v
2a
B

28.

F
a

A
4a

The speed of revolving particle when it reaches point A is


(A)

29.

3kQq
10Ma

(B)

kQq
10Ma

(C)

kQq
2Ma

(D)

KQq
3ma 2

(D)

7kQq
10Ma

The rate of change of speed of particle at point C is :


(A) zero

(B)

KQq
4 3ma 2

(C)

KQq
4ma 2

Space for Rough Work

Space for Rough Work

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P2JPCT1100416C0-14

PHYSICS

Paragraph for Questions 28 and 29

SECTION 3 : (Maximum Marks : 24)


This section contains THREE questions

Each question contains two columns, Column I and Column

Column I has four entries (A),(B), (C) and (D)

Column II has four entries (P),(Q), (R) and (S)

Match the entries in Column

PHYSICS

PHYSICS

II

I with the entries in Column II


One or more entries in Column I may match with one or more entries in Column II

The ORS contains a 4 4 matrix whose layout will be similar to the one shown below :
(A)
(B)
(C)
(D)

For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the
ORS. Similarly, for entries (B), (C) and (D).

Marking scheme :
For each entry in Column I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 If none of the bubbles is darkened
0 In all other cases

Space for Rough Work

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P2JPCT1100416C0-15

30.

Consider a solid uniformly charged sphere of radius R1 with a spherical hole of radius R2 displaced
a distance x0 from the centre as shown in the figure. is the charge density. If column- indicates
the electric field intensity E on the x-axis as a function of distance x from centre O, at A, B, C and
D, then match the following.
R1
D

R2
O

BA
C

x0

Column-

Column-

(A) EA

(P)

x 0
3 0

(B) EB

(Q)

3 0

(C) EC

(R)

R 32

x

3 0
(x x 0 )2

(D) ED

(S)

3 0

R 32
x

(x x 0 )2

R13
R 32

(x x 0 )2
x

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P2JPCT1100416C0-16

PHYSICS

PHYSICS

31.

Consider the situation shown in column-I a real object is moving towards a fixed optical component
or an optical component is moving towards a fixed object. Match the possible direction and
magnitude of velocity of image as shown in column-II. (All velocities in column-I are equal to v0)
Column-

Column-

(A)

(P)

2f

(B)

(Q)

(C)
2f

(D)

Object is
fixed

(R) More than v0

(S) Less than v0

Space for Rough Work

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P2JPCT1100416C0-17

PHYSICS

PHYSICS

Consider an arrangement shown in Column-, a value related to arrangement is asked. Choose


the proper value from Column- and Column-
Column-
Column-
A

(A)

(P) 1

A and B are two metallic plates having charges zero and


'3Q ' Respectively now plate A is grounded by a wire then
if

Q1 is charge flown through wire and Q2 is charge on


Q2
is
Q1

right surface of A then

(B)

(Q) 2

A is a point on axis of conducting ring having charge ' Q ' .


Now another point charge of

128
Q is placed at centre of ring.
125

If E1 and E2 are Electric fields at A before and after placing point


charge then

E2
is (radius of ring is 3R and OA = 4R)
E1

(C)

(R) 3

Space mirror
for Rough
A light ray is incident on hemispherical
parallelWork
to
Principle axis. If N1 is total number of reflections when
0
light is incident. At angle of 60 and N2 is total number of
0

reflections when light is Incident at 80 then

(D)

C1

3N1
is
N2

(S) 4

C2

Spherical cavity of radius

R
is made inside a uniform sphere
2

of radius R as shown in figure. If maximum difference of


gravitation potential. Between any two points inside cavity
is

k
4R 2G
then
is : ( is density of material of sphere)
2
k
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P2JPCT1100416C0-18

PHYSICS

PHYSICS

32.

CHEMISTRY

Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION 1 : (Maximum Marks : 21)

This section contains SEVEN questions

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct

For each question, darken the bubble corresponding to the correct option in the ORS

Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
2 In all other cases

33.

50 mL of H2SO4 (sp. gravity 1.84) is mixed with 150 mL of H2SO4 (sp. gravity 1.2). If there is 20%
reduction in volume after mixing, The specific gravity of the resulting solution is:
(A) 1.9

(B) 1.62

(C) 1.7

(D) none of these

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P2JPCT1100416C0-19

CHEMISTRY

PART III : CHEMISTRY

CHEMISTRY

A 10 gm sample of "gas liquor" is boiled with an excess NaOH and resulting NH3 produced is
passed into 60 mL of 0.45 M H2SO4. The residual acid was then neutralised by 10 mL of 0.4 M
NaOH. The % ammonia in the "gas liquor" examined is:

35.

(A) 17

(B) 8.5

(C) 34

(D) none of these

A mixture of N2O and CO2 in the mole ratio of a : b has a mean molecular mass equal to M. What
would be the mean molecular mass of mixture of the same gases present in the mole ratio of
b : a?
(A)

22a 44b
M

(C) M

36.

(B)
(D)

M
ab
ab
M

0.5 g of an anhydrous organic acid silver salt leaves on ignition 0.355 g silver. In another
experiment 100 mL of 0.2 M acid solution was neutralised by 400 mL of

1
M caustic potash
10

solution. What is the approximate molecular weight of acid?


(A) 60

(B) 90

(C) 120

(D) 80

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P2JPCT1100416C0-20

CHEMISTRY

34.

CHEMISTRY

Industrially TNT (C7H5N3O6, explosive material) is synthesized by reacting toluene (C7H8) with
nitric acid in presence of sulphuric acid. Calculate the maximum weight of C7H5N3O6 which can be
produced by 140.5 gm of a mixture of C7H8 and HNO3.
(A) 140.5
(C)

38.

(B) 113.5

140.5
2

(D) 140.5 (3 18)

The ratio of coefficients of HNO3, Fe(NO3)2 and NH4NO3 in the following redox reaction:

Fe HNO3 Fe(NO3 )2 NH4NO3 H2 O is respectively-

39.

(A) 10:1:4

(B) 10:4:1

(C) 4:10:1

(D) none of these

n-caproic acid, C5H11COOH, found in coconut and palm oil is used in making artificial flavours, has
solubility in water equal to 11.6 g/L. The saturated solution has pH = 3.0. The Ka of acid is
6

(A) 10

(B) 10
5

(C) 2 10

(D) 2 10

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P2JPCT1100416C0-21

CHEMISTRY

37.

CHEMISTRY

This section contains THREE paragraphs

Based on each paragraph, there will be TWO questions.

Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct

For each question, darken the bubble corresponding to the correct option in the ORS

Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
1 In all other cases

Paragraph for Question Nos. 40 to 41


A mixture of H2C2O4 (oxalic acid) and NaHC2O4 was dissolved in water and the solution made up
to one litre. 10 mL of the solution required 3 mL of 0.1 N NaOH solution for complete
neutralization. In another experiment, 10 mL of the same solution, in hot dilute H2SO4 medium
required 4 mL of 0.1 N KMnO4 solution for complete reaction.
40.

Mass of oxalic acid in orginal mixture is


(A) 1.12 g

41.

(B) 1.8 g

(C) 0.9 g

(D) none of these

Instead of KMnO4 if K2Cr2O7 was taken for complete reaction, the volume of 0.2 M K2Cr2O7
needed was:
(A) 1mL

(B)

2
ml
3

(C)

1
ml
3

(D) none of these

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P2JPCT1100416C0-22

CHEMISTRY

SECTION 2 : (Maximum Marks : 18)

CHEMISTRY

CHEMISTRY

Paragraph for Question Nos. 42 to 43


For the reaction: Ag (aq) Cl (aq) AgCl(s). Given
Species

Gf (kJ/mol) at 25C

Ag (aq)

+77

Cl (aq)

129

AgCl(s)

109

Ag e Ag; E 0.80 V

Zn2 2e Zn; E 0.76 V

42.

The cell representantions of the above reaction and Ecell are:


+

(A) Ag(s) | AgCl(s) | Cl (aq) || Ag (aq) | Ag(s); Ecell = 0.59 V


+

(B) Ag(s) | Ag (aq) | Cl (aq) || AgCl(s) | Ag (s); Ecell = 0.59 V

(C) Ag(s) | Cl (aq) || Ag (aq) | Ag; Ecell = 0.59 V


+

(D) Ag(s) | Ag (aq) || Cl (aq) || AgCl(s) | Ag (s); Ecell =1.18 V


43.

A quantity of 6.5 x 10 g of metallic zinc is added to 100 mL of solution of AgNO3. The value of

Zn2
at equilibrium is:
log
2
Ag
(A) 5.288

(B) 52.88

(C) 26.44

(D) None of these

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P2JPCT1100416C0-23

CHEMISTRY

The dissociation constant of acetic acid is 2.0 10 . An aqueous solution of acetic acid is
3

prepared by dissolving 0.7 millimole acetic acid in sufficient water to get 10 m of solution at 25C.

44.

What is the pH of solution? (log 2 = 0.3, log 7 = 0.85, log 17 = 1.23,


(A) 7.15

45.

(B) 6.77

(C) 6.85

4.49 2.1 )
(D) 7.0

What is the concentration of unionized acetic acid in the solution?


(A) 0

10

(B) 4.9 10

(C) 7 10

10

(D) 2.45 10

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P2JPCT1100416C0-24

CHEMISTRY

Paragraph for Question Nos. 44 to 45

CHEMISTRY

This section contains THREE questions

Each question contains two columns, Column I and Column

Column I has four entries (A),(B), (C) and (D)

Column II has four entries (P),(Q), (R) and (S)

Match the entries in Column

CHEMISTRY

SECTION 3 : (Maximum Marks : 24)

II

I with the entries in Column II


One or more entries in Column I may match with one or more entries in Column II

The ORS contains a 4 4 matrix whose layout will be similar to the one shown below :
(A)
(B)
(C)
(D)

For each entry in Column I, darken the bubbles of all the matching entries. For example, if entry
(A) in Column Imatches with entries (P), (Q) and (R), then darken these three bubbles in the
ORS. Similarly, for entries (B), (C) and (D).

Marking scheme :
For each entry in Column I
+2 If only the bubble(s) corresponding to all the correct match(es) is (are) darkened
0 If none of the bubbles is darkened
0 In all other cases
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P2JPCT1100416C0-25

CHEMISTRY

H3PO4 is triprotic acid and its dissociation constants are


K1 = 10

K2 = 10

K3 = 10

12

Column-I

Column-II

(Composition of solution)

(pH of solution)

(A) 0.1 M H3PO4

(P) 8.0

(B) 0.05 M NaH2PO4

(Q) 2.5

(C) 0.05 M NaH2PO4 + 0.05 M Na3PO4

(R) 6.0

(D) 0.5 M Na2HPO4

(S) 10.0

CHEMISTRY

46.

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P2JPCT1100416C0-26

CHEMISTRY

Cl2 reacts with O2 in either of the following ways depending upon the amount of O2 supplied.

Cl2

CHEMISTRY

47.

1
O2
Cl2 O
2

Cl2 2O2
2ClO2
Cl2O may also react with O2 as per the following reaction

Cl2O

3
O2 2ClO2
2

Match composition of final mixture of the product (given in column II) for initial amount of
reactants (given in column I).
Column-I

Column-II

(Mass of initial reactants)

(Mole of final products)

(A) 142 gm of Cl2 is mixed with 64 gm of O2

(P) 0.5 (O2), 1 (ClO2)

(B) 71 gm of Cl2 is mixed with 8 gm of O2

(Q) 4 (Cl2O)

(C) 35.5 gm of Cl2 is mixed with 48 gm of O2

(R) 0.5 (Cl2), 0.5 (Cl2O)

(D) 284 gm of Cl2 is mixed with 64 gm of O2

(S)

4
4
(Cl2O), (ClO2 )
3
3

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P2JPCT1100416C0-27

CHEMISTRY

Match the following:


Column-I

Column-II

(Solution)

(Result of electrolysis using inert electrode)

(A) AgNO3(aq)

(P) pH of solution increases

(B) CuSO4(aq)

(Q) O2 gas evolved at anode

(C) CH3COONa(aq)

(R) H2 gas evolved at cathode

(D) CuCl2(aq)

(S) Metal deposited at cathode

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P2JPCT1100416C0-28

CHEMISTRY

48.