Академический Документы
Профессиональный Документы
Культура Документы
R. V. ARSOV
University of Architecture, Civil Engineering and Geodesy
1 Chr.Smirnensky blvd., 1046 Sofia, Bulgaria
1. Introduction
Wastewater sludge treatment and disposal have always created more problems than
wastewater treatment itself. This is rooted in the fact that in contrast to wastewater,
which continuously passing the wastewater treatment plants (WWTPs) inflows
unaffectedly (in quantitative sense) the natural hydrological cycle, sludge entirely
accumulates there. Due to its specific properties, the accumulated sludge inclusion in
the natural cycles of mass transfer in an economically and environmentally acceptable
manner [14] is more difficult. This is because sludge management is associated with
overcoming of serious technological and economical problems, some of which have not
received satisfactory solution yet. Biological stabilisation of municipal wastewater
sludge is one of them, irrespectively of the availability of significant experience and the
long historical development of this issue.
Classical technologies for municipal wastewater sludge anaerobic stabisisation
proved to be reliable, adequate to the contemporary technological and ecological
requirements and are still intensively used in the current sanitary engineering practice.
They are applied both for separate or for mixed primary and waste activated sludge
stabilisation and usually include the following units: high-rate (heated) anaerobic
digesters (methane-tanks), low-rate (conventional, open-air, unheated) anaerobic
digesters and Imhoff-tanks (Emscher-wells, two-stage settlers). Despite the biological,
chemical and physical processes taking place in these units are now well known and are
subject of intensive modelling, adequate generic design procedures for more of them are
still missing.
Irrespectively of the remarkable scientific and applied research achievements in this
field, out-of-date design methods and parameters, some of which have been established
empirically more than 60 years [10, 11] are still intensively use in the current practice
for technological design of sludge anaerobic digestion units. Lack of knowledge about
the kinetics and mutual impact of relevant biological, chemical and physical processes
undoubtedly is not among the reasons for this somewhat strange situation. The
problem is more complex but its discussion is out of the scope of this paper.
It is than not surprising that in response to the questionnaire, prepared and
distributed by IAWQ TG on Anaerobic Digestion Modelling and concerning
establishing of new generic model for anaerobic processes in sanitary engineering [13],
68 % of respondents require the future model to be applicable mainly for sludge
digestion and 80 % of them want it to perform design procedures.
*Submited to Water Research, IWA in 2000
V t.(Q X QSX ) .
(1)
Different design models distinguish each to the other by the way they define
X
the values of t and Q S , with later in the case if sludge thickening and supernatant
X
withdrawal take place. The supernatant flow rate QS depends on the BVSS degree of
destruction and sludge thickening kinetics (respectively on HRT at some anaerobic
digesters with cyclic feeding/withdrawing). In turn the hydraulic retention time t
1
1 .
X
.
(2)
(3a)
1
k dX
(3b)
(3c)
1' is
range 0,5 0,7. The values of the kinetic parameters Y and kb are usually fixed around
0,06 and 0,03 d-1, respectively.
Following relationships are valid in respect of the correction factors for actual
raw sludge BVSS content X , associated with the relevant kinds of wastewater sludge
[1, 3]):
PS 1 . 2 /[1' 1 (1 2 )] ;
WAS
1 0,48
0 , 415
(5a)
.( 1) ;
(5b)
(5c)
(6)
definite period t and temperature , are known. Taking into account the data,
published by Pruss [18], Fair et al. [10], Dimovski [7], Imhoff and Imhoff [11] and
PS
Tourovski [20], the following values could be accepted: W0 95%;
t = 60 d;
W0WAS 98%
W1WAS 87% ;
WtWAS 94% at = 15o C and t = t = 60 d. The values of W0MS and W1MS for
mixed sludge, generated in Imhoff-tanks with simultaneous precipitation of PS and
MS
WAS are 95,5% and 79 %, respectively [7, 11, 20]. The values of W0
and W1MS
for low-rate anaerobic digesters, where PS and WAS inflow as a separately generated
suspensions, could be obtained by formulas (7) and (8) respectively, based on the SSmass balance:
W0MS [100 100 (100 W0WAS ) /(100 W0PS ) (100 W0WAS )( 1)] /
/[1 (100 W0WAS ) /(100 W0PS )];
(7)
W1MS [100 100 (100 W1WAS ) /(100 W1PS ) (100 W1WAS )( 1)] /
/[1 (100 W1WAS ) /(100 W1PS )].
(8)
Taking into account the above quoted parameters, the following values of the
sludge thickening rate coefficients have been obtained:
(9a)
(0,0153 0,00753).1,027
( 15 )
(9b)
/(1 ) .
(9c)
Q SX 0 .
(10)
regulation ATV [4] or the ones published by Ekama et al. [8], with the graphical
appearance of the exponential relationship (6), taking into account the sludge SS and
X
water content Wt relation. Based on the above assumption, the mean sludge water
X
content - Wm along SS depth profile could be defined as follows:
X
m
W0X W1X
1 m X
Wt dt
[1 exp( kWX .t m ] W1X
X
tm 0
kW .t m
(11)
V WAS Q WAS .C WAS .t.[1 3 ( 4 . WAS 4 1). RWAS / s .(1 WmWAS / 100)
;
(13)
V S S d e s tru c tio n d e g re e R
PS
0 ,8
0 ,6
1 = 0 ,7 0
1 = 0 ,6 0
1 = 0 ,5 0
0 ,4
D e s ig n m e th o d o f U S
( 1 9 7 8 ) w i t h = 0 . 2 0
E x p e rim e n ta l d a ta o f
M c K in e y (1 9 6 3 )
0 ,2
0
0
200
400
600
800
1000
1200
1400
1600
1800
2000
Figure 1. Proposed design model graphical comparison with pilot-plant data of McKiney [17] and design
0 ,6
t= 2 d
t = 5 d
t= 10 d
0 ,4
d
V S S d e s t r u c t u in d e g r e e , R
0 ,8
0 ,2
D e s ig n m e th o d o f
U S E P A ( 1 9 7 8 ) a t = 0 . 2 0
E x p e r im e n t a l d a t a o f
M a lin a (1 9 6 2 )
0
0
400
200
600
1000
800
1400
1200
1600
1800
2000
2200
T e m p e r a tu r e , x T im e , d
method, recommended by US EPA [9] for primary sludge anaerobic digestion at 1 = 0,75 and 2 = 0,65
Figure 2. Proposed design model graphical comparison with pilot-scale data of Malina [15] and the design
method, recommended by US EPA [9] for waste activated sludge anaerobic digestion. at 3 = 0,9, 4 =
0,8
Despite the available data (Malina [9, 15], McKiney [17] and EPA [9])
represented by dots in Fig. 1 and Fig. 2 dont fully characterise the sludge quality to
allow precise calibration of the proposed model, they could be fitted quite well by the
later (with continuous black lines), if it is run with proper combination of available and
default data.
0 ,7
= 0 ,7
= 0 ,6 5 0
0 ,6
P S
= 0 ,7 5
= 0 ,6 2 1
V S S d e s t r u c t io n d e g r e e , R
0 ,5
= 0 ,7
= 0 ,6
= 0 ,4 3 8
= 0 ,4 9 1
= 0 ,6
1
0 ,4
0 ,3
D a ta fro m
S o f ia W W T P
1
= 0 ,6
1
10
12
14
16
D im o v sk i (1 9 7 8 )
C E R (1 9 8 5 )
U S E PA (1 9 7 8 )
Im h o ff (1 9 7 9 )
K a r p in s k i (1 9 5 9 )
= 0 ,5
= 0 ,4
A c c o r d in g t o t h e
d e s ig n m e t h o d s o f :
= 0 ,4
0 ,1
0 ,2
= 0 ,5
= 0 ,5
,1 0
= 0
= 0 ,4 9 4
18
20
22
24
26
28
T im e , d
Figure 3. Graphical comparison of the proposed design model for primary sludge anaerobic digestion with
other design methods and data from Sofia WWTP. At
0 ,7
V S S d e s tru c tio n d e g re e , R
M S
= 0 ,7
0 ,6
1 = 0 ,5 1 0
1= 0 ,5 8 4
1 = 0 ,4 9 0
0 ,5
1 = 0 ,6 0 1
1 = 0 ,5 5 9
1 = 0 , 4 9 2
0 ,4
1 = 0 , 4 9 3
1 = 0 ,4 9 2
1 = 0 ,5 8 5
D a ta fr o m th e
S o fia W W T P :
D a ta a c c o rd in g to
th e d e s ig n m e th o d s o f :
D im o v s k i (1 9 7 8 )
C E R (1 9 8 5 )
= 0 , 5 ; = 1 5 d
U S E P A (1 9 7 8 )
= 0 , 1 ; = 1 5 d
Im h o ff (1 9 7 9 )
= 0 , 3 ; = 1 5 d
K a rp in s k i (1 9 5 9 )
0 ,2
d 1
0 ,1
d 1
10
12
14
16
18
20
22
d 1
d 1
d 1 d
1
d 1
d
= 0 ,5
= 0 ,6
0 ,3
= 0 ,6
d 1
= 0 ,4
24
26
28
30
32
34
36
38
T im e , t
40
42
Figure 4. Graphical comparison of the proposed design model for mixed sludge anaerobic digestion
with other design methods and data from Sofia WWTP.
Data presented in Fig. 3 and Fig. 4 show that most of the illustrated design
methods (Karpinski [12], Dimovski [7], EPA 625/4-78-012 [9], CER 2.04.03-85
[6], Imhoff and Imhof [11]) applying classical (or similar) approaches, as well as the
field data from the Sofia WWTP [1, 3] reflect only one study-state (one point) of the
relevant systems, excluding the method of Karpinski, which cover some range of the
t RX domain, but with fixed default sludge quality. Most of the data points are
located on the left side of the lines with = 0,1 which shows that the relevant systems
do not perform digestion processes up to the classical technical degree of digestion
(90% reduction of BVSS) and that this is the more usual practice [2, 3]. Since the
proposed design method is based on biological processes lump kinetics and consider the
main sludge quality parameters, it allows positioning of the designed system in an
arbitrary study-state point of the t RX domain, chosen by proper analysis and
considerations. The relevant analysis performed by the STAB package are discussed
elsewhere [2, 3].
4. Conclusions
The necessity of a new approach in design (bioreactors volumes sizing) of the
municipal wastewater sludge digesters motivates the research reported in this paper and
the main reasons for this is discussed.
10
The proposed model is founded on the kinetics of the relevant physical and
biological processes (the later taken in lump) and needs only few basic sludge quality
parameters as input. It allows positioning of the designed digesting system in arbitrary
study-state, motivated according to the local environment (hygienic) and economical
requirements and conditions. Considering of the different rates of aerobic and anaerobic
digestion of primary, waste activated and mixed sludge, along with the relevant
hydrodynamic conditions and processes of thickening taking place in some anaerobic
digesters are among the unique features and main advantages of the model.
The software package STAB based on the proposed model proved to be useful
tool not only for design but also for various technical and economical investigations,
concerning determination of the optimal technological scheme and degree of municipal
wastewater sludge stabilisation, and costs minimisation.
5. Nomenclature
5.1. ABBREVIATIONS
BVSS
CSTR
HRT
MS
PS
SS
VSS
WAS
WWTP
X
5.2. SIMBOLS
C PS , C WAS and C MS suspended solids concentrations in PS, WAS and MS, respectively
kb
decay coefficient of the active anaerobic biomass, incorporated in the digested sludge, d-1
k dX
rate coefficient of sludge BVSS anaerobic destruction (with the superscript meanings
X PS or X WAS or X MS)
X
W
digesting sludge thickening rate coefficient, depending on the temperature, d-1 (with the superscript
meanings X PS or X WAS or X MS)
QS
supernatant volumetric flow rate, m3/d (at anaerobic digesters where sludge thickening and
QX
RX
actual degree of VSS reduction, % (with the superscript meanings X PS or X WAS or X MS)
t
tm
digester volume, relevant to PS, WAS or MS stabilisation, respectively, m3 (with the superscript
11
Wt
sludge water content at the moment t of thickening processes, associated with definite temperature,
% (with the superscript meanings X PS or X WAS or X MS)
X
0
W1X
first critical sludge water content, defined as a break-point between the content of free water
VSS fraction in an ideal raw primary sludge (unaffected by digestion processes usually taking
place in the primary settlers and/or in the sludge accumulation chambers); In the model
1 is
1'
2
actual VSS fraction in the primary sludge at the digester inlet; In the model it is involved as an
input parameter
BVSS fraction in an ideal raw primary sludge (unaffected by digestion processes usually taking
place in the primary settlers and/or in the sludge accumulation chambers); In the model
3 is assumed as a
4 is assumed as a constant
residual fraction of the BVSS, remaining at the end (or at a definite moment) of stabilisation
process
temperature in the digester, grad C
correction factor for the actual raw sludge BVSS content (with the superscript meanings X PS or
X WAS or X MS) ;
1 d ; In the model
1 d; In the model
2 is
place in the primary settlers and/or in the sludge accumulation chambers; It is defined analytically
by equations (5a), (5b) and (5c), respectively
age of the waste activated sludge, d
6. References
1.
2.
3.
Arsov R. (1999a) On the kinetics of the biological processes in design of municipal wastewater sludge
anaerobic digestion units. Annuals of UACEG 40 (6), Sofia.
Arsov R. (1999b) On the reasonable degree of sludge stabilisation at the municipal wastewater
treatmentplants. Proceedings of the Specialised Conference on Disposal and Utilisation of Sewage
Sludge: Treatment Methods and Application Modalities, Oct. 13 15, Athens, Greece.
Arsov R. (1999c) Investigations on Rational Technological Flow Sheets and Design Methods for
Biological Stabilisation of Municipal Sludge. D.Sc. Thesis, University of Architecture, Civil Engineering
and Geodesy (UACEG), Sofia (in Bulgarian)
12
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
ATV Abwassertechnische Vereinigung (1991) Dimensioning of single stage activated sludge plants
upwards from 5000 total inhabitants and population equivalents - A 131. ATV rules and Standards.
Wastewater-waste, UDC 628.356:628.32-001.2(083).
Blunk H. (1925) Contribution to the calculation of digesting wastes removal. Gesundheits Ingeieur 4 (in
German).
CER 2.04.03-85 (1986) - Civil Engineering Regulations. Sewerage and Wastewater Treatment. Russian
State Committee on Civil Engineering, Moscow (in Russian).
Dimovski C. (1978) Treatment and utilisation of wastewater sludge. Technika, Sofia, 327 pp (in
Bulgarian).
Ekama G., J. Barnard, F. Gunthert, P. Krebs, J. McCorquodale, D. Parker and E. Wahlberg (1997)
Secondary settling tanks: theory modelling design and operation. Scientific and technical report 6.
IAWQ, London, 216 pp.
EPA 625/4-78-012 (1978) Sludge treatment and disposal I. US EPA Technology Transfer, Washington
DC.
Fair G., J. Geyer and D. Ocun (1968) Water and wastewater engineering 2. J. Wiley & Sons Inc., N.Y.
Imhoff K. and K. Imhoff (1979) Manual of Urban Sewarage 25. R. Oldendurg Verlag, Munich Vienna
(inGerman).
Karpinski A. (1959) New achievements in wastewater sludge digestion. Academy of Public Works
atRussian Federation, Moscow (in Russian).
Keller J. (1999) Report from Anaerobic Digestion Task Group. Newsletter 5. IAWQ Specialist group on
Anaerobic Digestion, London.
Lue-Hing C., P. Matthews, J. Namer, N. Okuno and L. Spinosa (1996) Sludge management in highly
urbanised areas. IAWQ Scientific and Technical Report 4. IAWQ, London, 7 12.
Malina J. (1962) The effect of temperature on high rate digestion of activated sludge. Proceedings of 16
thPardue Industrial Wastes Conference, p. 232.
Malina J. (1964) Thermal effect on completely mixed anaerobic digestion. Water and Sewage Works 1,
p.52.
McKiney R. (1963) Advances in biological waste treatment. Pergamon Press, N.Y.
Pruss M. (1928) Progress in the wastewater sludge thickening. R. Oldenbourg Verlag, Munchen (in
German).
Rudolph K. (1999) A low-cost approach to tackling odours. Water Quality International 1/2. IAWQ,
London, 28 31.
Tourovski I. (1982) Treatment of wastewater sludge. Stroyizdat, Moscow (in Russian).
13