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Inhibicija korozije ugljinog elika u slanim otopinama pomou glukonata, cink sulfata i eluata gline
ISSN 1330-3651 (Print), ISSN 1848-6339 (Online)
UDC/UDK 620.197.3:669.141.3
Inhibicija korozije ugljinog elika u slanim otopinama pomou glukonata, cink sulfata i eluata gline
Izvorni znanstveni lanak
U ovom je radu procijenjen utjecaj glukonata, cink sulfata i eluata zelene gline na inhibiciju korozije ugljinog elika (EN S235 JRG) u 0,5 % i 3,5 %
otopini natrij klorida pomou metode Tafelove polarizacije. Primjenom umjerenih koncentracija natrij glukonata postignuta je znaajna inhibicija ope
korozije. U tom je sluaju inhibicija uglavnom ostvarena anodnim mehanizmom inhibicije ope korozije, uz pojavu lokalne "pitting" korozije ugljinog
elika. Meutim, u sluaju kada je natrij glukonat pomijean s cinkovim sulfatom i/ili eluatom zelene gline u odgovarajuim koncentracijama, dolazi do
smanjenja i ope i lokalne korozije to ukazuje na dobro sinergijsko djelovanje izmeu uporabljenih inhibitora.
Kljune rijei: inhibicija korozije, glukonat, otopina natrij klorida, ugljini elik, zelena glina
Introduction
Experimental
Corrosion inhibition of carbon steel in saline solutions by gluconate, zinc sulphate and green clay eluate
Z=
( jni jinh )
100,
jni
O. Lahodny-arc, I. Stojanovi
(1)
Figure 2 Surface of the carbon steel specimens after electrochemical measurements in 0,5 % NaCl solution
Inhibicija korozije ugljinog elika u slanim otopinama pomou glukonata, cink sulfata i eluata gline
Figure 4 Surface of the carbon steel specimens after electrochemical measurements in 3,5 % NaCl solution - one inhibitor
Table 2 Corrosion parameters of carbon steel in 3,5 % NaCl solution-one inhibitor
Medium
Composition
Ecorr
vcorr
jcorr
RP
pH
No.
Inhibitors
gL1
mV
mmy1
Acm2
k
Without inhibitor
705
0,15
12,87
1,9
5,08
1
SG
1,5
487
0,064
5,48
4,79
5,43
2
SG
4
490
0,052
4,46
5,47
5,55
3
ZS
1
600
0,101
8,68
2,24
5,15
4
CE
1
584
0,237
20,26
1,61
7,75
Z
%
0
57,4
65,35
32,56
57,4
109
Corrosion inhibition of carbon steel in saline solutions by gluconate, zinc sulphate and green clay eluate
O. Lahodny-arc, I. Stojanovi
Table 3 Corrosion parameters of carbon steel in 3,5 % NaCl solution- two inhibitors mixture
Medium
Composition
Ecorr
vcorr
jcorr
RP
Z
pH
No.
Inhibitors
gL1
mV
mmy1
Acm2
k
%
5
SG+ZS
0,5+0,13
556
0,037
3,17
6,66 5,57 75,37
6
SG+ZS
1+0,07
515
0,038
3,27
5,69 5,77
74,6
7
SG+ZS
2+0,5
499
0,021
1,823
9,54 5,51 85,84
8
SG+ZS
4+1
529
0,022
1,868
9,61 5,58
85,5
9
SG+CE
2+0,5
489
0,047
4,029
5,64 6,32
68,7
Figure 6 Surface of the carbon steel specimens after electrochemical measurements in 3,5% NaCl solution- two inhibitors mixture
Inhibicija korozije ugljinog elika u slanim otopinama pomou glukonata, cink sulfata i eluata gline
Ecorr
vcorr
jcorr
RP
mV
608
489
494
500
507
540
520
mmy1
0,073
0,0146
0,0226
0,022
0,0225
0,0223
0,031
Acm2
6,22
1,24
1,93
1,88
1,92
1,91
2,65
k
3,39
8,6
9,83
9,46
9,23
6,36
6,57
Composition
Inhibitor
SG+ZS+CE
SG+ZS+CE
SG+ZS+CE
SG+ZS+CE
SG+ZS+CE
SG+ZS+CE
SG+ZS+CE
gL1
0,25+0,13+0,17
2,66+0,17+0,17
1+1+1
2+0,5+1
2+1+0,5
2,5+1+0,66
3+1+0,33
pH
5,74
5,86
7,11
7,06
6,85
6,5
5,96
Z
(efficiency)
%
51,67
90,37
85,00
85,39
85,08
85,16
79,41
Corrosion inhibition of carbon steel in saline solutions by gluconate, zinc sulphate and green clay eluate
O. Lahodny-arc, I. Stojanovi
Figure 8 Surface of the carbon steel specimens after electrochemical measurements in 3,5 % NaCl solution- three inhibitors mixture
Conclusion
Inhibicija korozije ugljinog elika u slanim otopinama pomou glukonata, cink sulfata i eluata gline
References
113
Corrosion inhibition of carbon steel in saline solutions by gluconate, zinc sulphate and green clay eluate
O. Lahodny-arc, I. Stojanovi
Authors addresses
Dr. sc. Franjo Ivui, dipl. ing.
Croatian Academy of Sciences and Arts,
The Institute for Corrosion Research and Desalinization
Vlaha Bukovca 14, 20000 Dubrovnik, Croatia
E-mail: fivusic@hazu.hr
Prof. dr. sc. Olga Lahodny-arc, dipl. ing.
Croatian Academy of Sciences and Arts,
The Institute for Corrosion Research and Desalinization
Vlaha Bukovca 14, 20000 Dubrovnik, Croatia
E-mail: lahodny@hazu.hr
Dr. sc. Ivan Stojanovi, dipl. ing.
University of Zagreb
Faculty of Mechanical Engineering and Naval Architecture
Ivana Luia 5, 10000 Zagreb, Croatia
E-mail: ivan.stojanovic@fsb.hr
114