Luprintol Multifunction SL-S MSDS

Safety Data Sheet in accordance with
Regulation (EU) No.453/2010

Luprintol Multifunction SL-S
Substance key: B0174
Version : 1 - 1 / EU
Page 1(13)
Revision Date: 25.06.2015
Date of printing : 16.11.2015
SECTION 1: Identification of the substance/mixture and of the

company/undertaking
1.1. Product identifier
Trade name
Material number: 281301
1.2. Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses of the substance or mixture
Industry sector :
Textile processing industry
Type of use :
Auxiliary for the textile industry
1.3. Details of the supplier of the safety data sheet
Identification of the company
Archroma Management GmbH
Neuhofstrasse 11
4153 Reinach, Switzerland
Telephone no. : +41 61 716 3401
Information about the substance/mixture
Product Stewardship +41 61 716 3401
e-mail: PS.MSDS-Europe@archroma.com
1.4. Emergency telephone number
+44 (0) 1235 239 670
(24 h)
SECTION 2: Hazards identification

2.1. Classification of the substance or mixture
Classification according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
Not a dangerous substance according to GHS.
2.2. Label elements
Labelling according CLP regulation (Regulation (EC) No. 1272/2008, as amended)
Not a dangerous substance according to GHS.
Sensitizing components / contains :
Formaldehyde
May produce an allergic reaction.
2.3. Other hazards
No additional hazards are known except those derived from the labelling.

Page 2(13)


SECTION 3: Composition/information on ingredients

3.2. Mixtures
Chemical characterization
in aqueous/organic dispersion
Polycondensed
Nonionic surfactants
Hazardous ingredients
Diethylene glycol
Concentration :
CAS number :
EC number:
Index Number
>= 1 - < 3 %
111-46-6
203-872-2
603-140-00-6
Classification hazard substance EC

Xn
Harmful
GHS classification EC
Acute toxicity
Specific target organ
toxicity - repeated
exposure
Propan-2-ol
Concentration :
CAS number :
EC number:
Index Number
Category 4
Category 2
Methanol
Concentration :
CAS number :
EC number:
Index Number
Category 2
Category 2
Category 3
R11
R36
R67
H225
H319
H336
> 0,1 - < 1 %

67-56-1
200-659-6
603-001-00-X

F
Highly flammable
T
Toxic
Flammable liquids
H302
H373
>= 0,1 - < 1 %

67-63-0
200-661-7
603-117-00-0

F
Highly flammable
Xi
Irritant
Flammable liquids
Eye irritation
toxicity - single exposure
R22
Category 2
R11
R23/24/25
R39/23/24/25
H225

Page 3(13)

Acute toxicity
Acute toxicity
Acute toxicity
toxicity - single exposure
Formaldehyde
Concentration :
CAS number :
EC number:
Index Number

Category
Category
Category
Category
3
3
3
1
< 0,1 %
50-00-0
200-001-8
605-001-00-5

Carc.Cat.3
Carcinogenic Category 3
T
Toxic
C
Corrosive
Acute toxicity
Acute toxicity
Acute toxicity
Skin corrosion
Skin sensitisation
Carcinogenicity
H301
H331
H311
H370
Category
Category
Category
Category
Category
Category
3
3
3
1B
1
2
R40
R23/24/25
R34
R43
H301
H331
H311
H314
H317
H351
The text of the R-phrases is shown in section 16.

The text of the H-phrases is shown in section 16.
SECTION 4: First aid measures

4.1. Description of first aid measures
General information
Remove/Take off immediately all contaminated clothing.
After inhalation
Remove person to fresh air. If signs/symptoms continue, get medical attention.
After contact with skin
After contact with skin, wash immediately with plenty of soap and water.
Get medical attention immediately if irritation persists.
After contact with eyes
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
If eye irritation persists, consult a specialist.
After ingestion
Rinse out mouth and give plenty of water to drink.
4.2. Most important symptoms and effects, both acute and delayed

Page 4(13)
Symptoms
The possible symptoms known are those derived from the labelling (see section 2).
No symptoms known currently.
Hazards
No additional hazards are known except those derived from the labelling.
4.3. Indication of any immediate medical attention and spe cial treatment needed
Treatment
There is no specific antidote available.
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media
Water spray
Dry powder
Foam
5.2. Special hazards arising from the substance or mixture
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
5.3. Advice for firefighters
Further information
The degree of risk is governed by the burning substance and the fire conditions
Extinguishing water is to be disposed of in accordance with local aut hority regulations
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Use personal protective equipment.
Self-contained breathing apparatus
6.2. Environmental precautions
The product should not be allowed to enter drains, water courses or the soil.
6.3. Methods and material for containment and cleaning up
Pump up larger quantities.
Pick up rest with absorbent material (e.g. sand, sawdust).
Dispose of absorbed material in accordance with the regulations.
6.4. Reference to other sections
Additional information
Information regarding Safe handling, see chapter 7.

Page 5(13)


SECTION 7: Handling and storage

7.1. Precautions for safe handling
Advice on safe handling
No special measures necessary if stored and handled as prescribed.
Hygiene measures
Do not eat, drink or smoke when using this product.
7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers
Keep containers tightly closed in a cool, well-ventilated place.
Should not be released into the environment.
Advice on storage compatibility
Keep away from food, drink and animal feeding stuffs.
Further information on storage conditions
Keep tightly closed in a dry, cool and well-ventilated place.
Storage stability
Storage temperature: 5 - 40 C
7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is
to be observed.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Exposure limit values
methanol
EC number:
CAS number :
200-659-6
67-56-1
Regulatory basis / Regulatory list

Europe. Indicative occupational exposure
limit values
EU. Commission Directive 2006/15/EC
Revision
2006-02-09
Type of value
Limit Value eight hours
Values
260 mg/m3
200 ppm
Remarks
DNEL/DMEL values
Formaldehyde
EC number:
CAS number :
200-001-8
50-00-0
Route of exposure
Inhalation
Personnel
Workers
Exposure time/Effect
Acute systemic effects
Inhalation
Workers
Acute local effects
Inhalation
Workers
Long-term systemic effects
Value
1 mg/m3
0,8 ppm
1 mg/m3
0,8 ppm
0 mg/m3
0,4 ppm
Remarks
DNEL
DNEL
DNEL

Page 6(13)


Inhalation
Workers
Long-term local effects
Dermal
Dermal
Oral
Dermal
Inhalation
Inhalation
Workers
Consumers
Consumers
Consumers
Consumers
Consumers

0 mg/m3
0,4 ppm
240 mg/kg
102 mg/kg
4,1 mg/kg
0,012 mg/cm2
3,2 mg/l
0,1 mg/m3
DNEL
DNEL
DNEL
DNEL
DNEL
DNEL
DNEL
PNEC values
Formaldehyde
EC number:
CAS number :
Environmental
compartment
Fresh water
salt water
Water (intermittent
release)
Fresh water
sediment
Marine sediment
Soil
Sewage treatment
plant
200-001-8
50-00-0
Personnel/Exposure time/Effect
Value
0,47 mg/l
0,47 mg/l
4,7 mg/l
2,44 mg/l
2,44 mg/l
0,21 mg/l
0,19 mg/l
8.2. Exposure controls

Respiratory protection :
Protection necessary if aerosols or vapors should develop.

P2 filter
Hand protection :
Chemical resistant gloves

Take note of the information given by the producer concerning
permeability and break through times, and of special
workplace conditions (mechanical strain, duration of contact).
Eye protection :
Safety glasses with side-shields conforming to EN166
Body protection :
The choice of skin protection should be based on the job

activity and potential for exposure to the skin.
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state :
liquid ( 20 C )
Form :
liquid
Particle size :
not applicable
Colour :
white yellowish
Odour :
Product specific
Odour threshold :
not applicable

Page 7(13)


pH value :
approx. 8 - 10 (20 C)
(undiluted)
Melting point :
not applicable
Boiling point :
not determined
Sublimation point :
not applicable
Flash point :
> 100 C
Method : DIN 51758
Evaporation rate :
Value can be approximated from Henry's Law Constant or

vapor pressure.
Flammability :
The product is not flammable.

Method : Flash point
Lower explosion limit :
Not relevant
The lower explosion point may be 5 - 15 C below the flash
point.
Upper explosive limit :
Not relevant
Combustion number :
not applicable
Minimum ignition energy :
not tested.
Vapour pressure :
not applicable
Solubility in water :
soluble
Octanol/water partition
coefficient (log Pow) :
Study scientifically not justified.
Ignition temperature :
not determined
Self-ignition temperature :
not auto-flammable
Thermal decomposition :
No decomposition if used as directed.
Viscosity (dynamic) :
not determined
Explosive properties :
Explosive according to EU supply regulations : Not explosive

Explosive according transport regulation : Not explosive
Oxidizing properties :
Type of oxidizing effect : not oxidizing
9.2. Other information

Density :
approx. 1,1 g/cm3 (20 C)
SECTION 10: Stability and reactivity

10.1. Reactivity
No dangerous reaction known under conditions of normal use.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions

Page 8(13)


No dangerous reaction known under conditions of normal use.

10.4. Conditions to avoid
Avoid Heat, Open Flames And Sparks.
10.5. Incompatible materials
Strong acids
Strong bases
Strong oxidizing agents
10.6. Hazardous decomposition products
No hazardous decomposition products are known.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Information related to the product itself:
Acute oral toxicity :
LD50 > 2.000 mg/kg (rat)
Acute dermal toxicity :
not tested.
Acute inhalation toxicity :
not tested.
Irritant effect on skin :
No skin irritation (rabbit)

Method : OECD Test Guideline 404
Irritant effect on eyes :
No eye irritation (rabbit)

Method : OECD Test Guideline 405
Sensitization :
not tested.
Repeated dose toxicity:
not tested.
Genetic toxicity in vitro :
not tested.
Assessment of mutagenicity : Based on the ingredients, there is no suspicion of a mutagenic

effect.
Assessment of
carcinogenicity :
The whole of the information assessable provides no

indication of a carcinogenic effect.
Specific target organ toxicity

(STOT) - repeated exposure :
According to experience and to the information available, the

product has no harmful effects on health if used correctly and
for the intended purpose.
The product has not been tested. The information is derived
from the properties of the individual components.
Aspiration hazard :
No aspiration toxicity classification
Remarks
The product has not been tested. The information is derived from the properties of the
individual components.

Page 9(13)


Information related to the component: Propan-2-ol

LD50 5.280 mg/kg (rat)
LD50
12.800 mg/kg (rabbit)
Acute inhalation toxicity :
LC50
72,6 mg/l (4 h, rat)
Information related to the component: Methanol

LD0 428 mg/kg (Humans)

Acute toxicity estimate 100 mg/kg
Method : Converted acute toxicity point estimate

Information related to the component: Formaldehyde

LD50 800 mg/kg (rat)

SECTION 12: Ecological information

12.1. Toxicity
Fish toxicity :
LC50 > 100 mg/l (96 h, Leuciscus idus (Golden orfe))
Daphnia toxicity :
not tested.
Algae toxicity :
not tested.
Bacteria toxicity :
not tested.

Fish toxicity :
Test data for the substance are not available.

Fish toxicity :
LC50 19.000 mg/l (96 h, Oncorhynchus mykiss (rainbow

trout))
Daphnia toxicity :
LC50 > 10.000 mg/l (24 h)
Bacteria toxicity :
IC50 > 1.000 mg/l (3 h, activated sludge)
12.2. Persistence and degradability

Biodegradability :
20 - 70 % (28 d)
Moderately/partially eliminated from water.
Method : Zahn-Wellens Test

Page 10(13)

Biodegradability :

95 %
Readily biodegradable.

Biodegradability :
99 % (28 d)
Method : OECD Test Guideline 301D
12.3. Bioaccumulative potential

Bioaccumulation:
not tested.

Bioaccumulation:

Bioaccumulation:
Due to the low logPow bioaccumulation is not expected
12.4. Mobility in soil

Behaviour in environmental compartments
no data available
Transport and distribution
between environmental
compartments :
12.5. Results of PBT and vPvB assessment

According to Annex XIII of Regulation (EC) No.1907/2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH):The product does not
contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or t he vPvB
(very persistent/very bioaccumulative) criteria.

no data available
12.6. Other adverse effects

Page 11(13)


Additional ecotoxicological remarks

Product must not be released into water without pre-treatment.
If handled correctly it causes no disturbance in treatment plants.
Additional ecotoxicological remarks
slightly water endangering
SECTION 13: Disposal considerations

13.1. Waste treatment methods
Product
Product should be be taken to a suitable and authorized waste disposal site in
accordance with relevant regulations and if necessary after consultation with the waste
disposal operator and/or the competent Authorities
Uncleaned packaging
Uncontaminated packaging may be reused
Packaging material which cannot be cleaned is to be disposed of in the same way as
the substance.
SECTION 14: Transport information

Section 14.1. to 14.5.
ADR
ADN
RID
IATA
IMDG
not restricted
not restricted
not restricted
not restricted
not restricted
14.6. Special precautions for user

See sections 6 to 8 of this Safety Data Sheet.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code (International
Bulk Chemicals Code)
No transport as bulk according IBC - Code.
SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or
mixture

Page 12(13)
Other regulations
Apart from the data/regulations specified in this chapter, no further information is available
concerning safety, health and environmental protection.
15.2. Chemical safety assessment
No Chemical Safety Assessment (CSA) is yet available for the substance, or for the
component substances, contained in this product.
SECTION 16: Other information

Product should be stored, handled and used in accordance with good industrial hygiene practices
and in conformity with legal regulations. The information contained herein is based on the present
state of our knowledge and is intended to describe our produc ts from the point of view of safety
requirements. It should therefor not be construed as garanteeing specific properties.
Text of the R-phrases assigned to the ingredients/components mentioned in section 3 :
R11
R22
R23/24/25
R34
R36
R39/23/24/25
R40
R43
R67
Highly flammable.
Harmful if swallowed.
Toxic by inhalation, in contact with skin and if swallowed.
Causes burns.
Irritating to eyes.
Toxic: danger of very serious irreversible effects through inhalation, in
contact with skin and if swallowed.
Limited evidence of a carcinogenic effect.
May cause sensitisation by skin contact.
Vapours may cause drowsiness and dizziness.
List of the text of the hazard statements mentioned section 3 (H-phrases) :

H225
H301
H302
H311
H314
H317
H319
H331
H336
H351
H370
H373
Highly flammable liquid and vapour.

Toxic if swallowed.
Harmful if swallowed.
Toxic in contact with skin.
Causes severe skin burns and eye damage.
May cause an allergic skin reaction.
Causes serious eye irritation.
Toxic if inhaled.
May cause drowsiness or dizziness.
Suspected of causing cancer.
Causes damage to organs.
May cause damage to organs through prolonged or repeated exposure if
swallowed.
Legend
ADN
ADR
AOX
CAS
DMEL
European Agreement concerning the International Carriage of Dangerous

Goods by Inland Waterways
European Agreement concerning the International Carriage of Dangerous
Goods by Road
Adsorbable organic bound halogens
Chemical Abstracts Service
Derived Minimal Effect Level (genotoxic substances)

DNEL
EC50
GHS
IATA
IMDG
LC50
LD50
MARPOL
NOAEC
NOAEL
NOEC
OEL
PBT
PEC
PNEC
REACH
RID
SVHC
vPvB
Page 13(13)
Derived No Effect Level

Half maximal effective concentration
Globally Harmonized System
International Air Transport Association
International Maritime Dangerous Goods
Lethal Concentration 50%
Lethal Dose 50%
International Convention for the Prevention of Pollution From Ships
No Observed Adverse Effect Concentration
No Observed Adverse Effect Level
Non Observed Effect Concentration
Occupational Exposure Limit
Persistent, Bioaccumulative, Toxic
Predicted Environmental Concentration
Predicted No Effect Concentration
Registration, Evaluation, Authorisation and Restriction of Chemicals
International Rule for Transport of Dangerous Substances by Railway
Substances of Very High Concern
very Persistent and very Bioaccumulative
This information corresponds to the present state of our knowledge and is intended as a general
description of our products and their possible applications. Archroma makes no warranties, express or
implied, as to the information's accuracy, adequacy, sufficiency or freedom from defect and assumes
no liability in connection with any use of this information. Any user of this product is responsible for
determining the suitability of Archroma's products for its particular application. Nothing included in this
information waives any of Archroma's General Terms and Conditions of Sale, which control unless it
agrees otherwise in writing. Any existing intellectual/industrial property rights must be observed. Due
to possible changes in our products and applicable national and international regulations and laws, the
status of our products could change. Material Safety Data Sheets providing safety precautions, that
should be observed when handling or storing Archroma products, are available upon request and are
provided in compliance with applicable law. You should obtain and review the applicable Material
Safety Data Sheet information before handling any of these products. For additional information,
please contact Archroma.

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Safety Data Sheet in accordance with

Regulation (EU) No.453/2010

SECTION 1: Identification of the substance/mixture and of the

SECTION 2: Hazards identification

Safety Data Sheet in accordance with

Substance key: B0174

Revision Date: 25.06.2015

SECTION 3: Composition/information on ingredients

Classification hazard substance EC

> 0,1 - < 1 %

Classification hazard substance EC

>= 0,1 - < 1 %

Classification hazard substance EC

Safety Data Sheet in accordance with

Substance key: B0174

Revision Date: 25.06.2015

Classification hazard substance EC

The text of the R-phrases is shown in section 16.

SECTION 4: First aid measures

Safety Data Sheet in accordance with

SECTION 5: Firefighting measures

SECTION 6: Accidental release measures

Safety Data Sheet in accordance with

Substance key: B0174

Revision Date: 25.06.2015

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

Regulatory basis / Regulatory list

Acute local effects

Long-term systemic effects

Safety Data Sheet in accordance with

Substance key: B0174

Revision Date: 25.06.2015

Long-term local effects

Long-term systemic effects

8.2. Exposure controls

Protection necessary if aerosols or vapors should develop.

Chemical resistant gloves

Safety glasses with side-shields conforming to EN166

The choice of skin protection should be based on the job

SECTION 9: Physical and chemical properties

Safety Data Sheet in accordance with

Substance key: B0174

Revision Date: 25.06.2015

Value can be approximated from Henry's Law Constant or

The product is not flammable.

Lower explosion limit :

Upper explosive limit :

Minimum ignition energy :

Study scientifically not justified.

No decomposition if used as directed.

Explosive according to EU supply regulations : Not explosive

Type of oxidizing effect : not oxidizing

9.2. Other information

approx. 1,1 g/cm3 (20 C)

SECTION 10: Stability and reactivity

Safety Data Sheet in accordance with

Substance key: B0174

Revision Date: 25.06.2015

No dangerous reaction known under conditions of normal use.

SECTION 11: Toxicological information

LD50 > 2.000 mg/kg (rat)

Acute dermal toxicity :

Acute inhalation toxicity :