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Mohammed Evuti Abdullahi, Mohd Ariffin Abu Hassan*, Zainura Zainon Noor
and Raja Kamarulzaman Raja Ibrahim
1 Introduction
There is an increasing public concern on the need to
remove volatile organic compounds (VOCs) from groundwater and wastewater because certain VOCs are known to
be hazardous to human health and the environment (Goldstein and Galbally 2007). Some VOCs have been identified
as odorous, ozone precursors, carcinogenic, and potential
air toxicants (Inoue etal. 2011). About 189 hazardous air
pollutants (HAPs) have been identified by U.S. Environmental Protection Agency (USEPA), out of which 97 are
VOCs (USEPA 1990). There also exists mounting evidence
that long-time exposure to low concentrations of certain
organic chemicals can be an important factor in the development and manifestation of some chronic diseases. It
is further believed that between 80% and 90% of cancer
cases are of environmental origin; therefore, the contaminants present in potable water supplies come under suspicion (Bedding etal. 1982). More also, certain VOCs are also
known as greenhouse gases (Derwent 1995, Wuebbles and
Hayhoe 2002, IPCC 2006, Lelieveld etal. 2009). Because
these gases effectively absorb radiated energy from the
Earth, the rise in their concentrations within the Earths
atmosphere has been associated with the global warming
phenomena (AEA Group 2007, Mohammed etal. 2012). In
addition, the presence of VOCs in wastewater reduces the
possibility of water reuse, such as in irrigation, thereby
placing a higher demand on the limited existing primary
water resources (Bedding etal. 1982).
This increasing concern is also due to the increase
in the numbers and quantities of VOCs in use, which
have made the water resources used for portable supply
to have become increasingly susceptible to contamination by VOCs from various sources. Abdullahi and Chian
(2011), in their study of VOCs in drinking water in peninsular Malaysia, detected 54 different VOCs species in
samples analyzed from 11 states, which were attributed
to improper disposal practice. The result showed that
the number of significant compounds detected increased
with the extent of infrastructure growth in the state, with
2M.E. Abdullahi etal.: A packed column air stripper for VOC removal
M.E. Abdullahi etal.: A packed column air stripper for VOC removal3
in higher concentrations of valuable VOCs through recovery. Over 99% VOC recovery using air stripping has
been reported in the literature (Chuang et al. 1992, Nirmalakhandan et al. 1993, Negrea et al. 2008, Zareei and
Ghoreyshi 2011). Air stripping has also been used along
with other treatment methods such as adsorption, catalytic oxidation, pervaporation, and nonthermal plasma as
an integrated system for the treatment of VOCs (Chuang
etal. 1992, Worrall and Zuber 1996, Zareei and Ghoreyshi
2011, Abdullahi et al. 2013a). Although some reviews on
air stripping are available (Kutzer etal. 1995, Brown etal.
1997, Berenjian et al. 2012), this paper presents further
elaborations and new information on some topics in the
application of a packed column air stripper in VOC treatment from wastewater. These include a review of the
physical and chemical properties of the VOCs and how
they affect the air stripping process. Second, the summary
tables of the various applications containing information
on process variables provided by this paper (Tables 1 and
2) will serve as an easy and ready access to the literature.
The review will also cover available works on the modeling and simulation of a packed column air stripper.
Chlorobenzene
Chloroform
1,2-DCE
1,2-Dibromo-3-chloropropane
TCE
1,1,2,2-Tetrachloroethane
Pollutant
concentration
110 mg/l
50300 g/l
NA
NA
440 g/l
350 g/l
A/W
ratio
Removal
efficiency (%)
NA
20:1
40:1
762.1
NA
NA
99
87.4
90.6
89.2
99
9498
References
4M.E. Abdullahi etal.: A packed column air stripper for VOC removal
Table 2Treatment of VOCs from wastewater using a combination of technologies.
Researcher
Technologies
Pollutants
Findings
TCE
groundwater, VOCs can remain there for years, decomposing slowly because of the cool, dark environment. These
chemicals move with the groundwater and pose a threat
to the nearby drinking water. The USEPA estimates that
VOCs are present in one fifth of the nations water supplies
(Moran etal. 2006). Several factors increase the likelihood
that a water supply will be contaminated. These factors
are illustrated in Figure 1.
One factor is the distance between a well and a source
of contamination. Many wells contaminated with VOCs
are located near industrial or commercial areas, gas stations, landfills, or railroad tracks. A second factor is the
amount of VOCs dumped or spilled. Some spills are small
and localized. Others occur over a long period of time or
involve large quantities of contaminants. When a large
quantity of chemicals has leaked or spilled, as may occur
with leaking underground tanks or industrial spills, a
large geographical area may be affected. Third, the depth
of a well can be a factor. Shallow wells are often affected
sooner and more severely than deep wells when contaminants have been spilled on surface soils. A fourth factor is
local geology. Groundwater covered by thin, porous soil
or sand layers is most vulnerable. Dense, thickly layered
soils may slow down the movement of contaminants and
may help to absorb them. The fifth factor affecting contamination of water is time. Groundwater typically moves
very slowly. A spill may take years to reach nearby wells,
so wells may not be contaminated until months or years
M.E. Abdullahi etal.: A packed column air stripper for VOC removal5
Diesel
storage
Homestead
with
septic field
Barn
Water table
Ground water
Shallow aquifer
Clay
(aquitard)
Bedrock aquifer
Flow meter
Air stripper
Air compressor
Flow meter
Heater
Pump
Feed tank
Collection tank
Driving
shed
6M.E. Abdullahi etal.: A packed column air stripper for VOC removal
the contact surface area between the water and the air.
Equilibrium is reached when the two phases are brought
into contact. This means that the water in contact with
air evaporates until the air is saturated with water vapor,
and the air is absorbed by the water until it becomes saturated with the individual gases. The equilibrium relationship is linear and it is defined by Henrys law. Henrys law
states that for a low concentration of volatile compound
a, at equilibrium, the partial pressure of a gas (Pa) above
a liquid is directly proportional to the mole fraction of the
gas (xa) dissolved in the liquid. This can be mathematically stated in Equation (1):
Pa = H a xa
(4)
G xin -xout
=
L yout
(5)
(1)
E=
The proportionality constant Ha is known as Henrys constant. It is a dimensionless partition coefficient expressed
as the ratio of the mass (or molar) concentration in the gas
phase to that in the liquid phase (Robert etal. 1985). This
constant is a primary indicator of a compounds potential for removal by air stripping and it increases with the
increase in temperature. The application of air stripping is
limited to compounds with Henrys constant values > 100
atmospheres (Richardson etal. 2002, Mourad etal. 2012).
Applying Henrys law, a mass balance of VOCs in and
out of Figure 3 will be as follows:
Lout xout + Gout yout = Lin xin + Gin yin
(2)
where G is the gas flux, L is the water flow, x is the VOCs concentration in water, and y is the VOCs concentration in air.
Assuming an uncontaminated air supply,
Yin = 0; Lin = Lout = L and Gin = Gout = G
Liquid in
Lin
Xin
Gas out
Gout
Yout
Liquid out
Lout
Xout
xin -xout
xin
100(%)
(6)
(7)
Stripping
column
(3)
u0
Lm
=
K L a ( L K L a )
(8)
Gas in
Gin
Yin
CL , 2 -CG , 1
( S-1) + 1
S Hc
ln
NTU =
CL , 1 -CG , 1
S-1
H S
c
(9)
M.E. Abdullahi etal.: A packed column air stripper for VOC removal7
QG H c
(10)
QL
L , 2 ( S-1) + 1
Lm S CL , 1
Z =
ln
( L K L a ) S-1
(11)
8M.E. Abdullahi etal.: A packed column air stripper for VOC removal
Air out
Cover
Air outlet
screen
Mist eliminator
Water in
Distribution
tray
Pipe
Packing
material
Air
Column
Water
Flowmeter
Packing
material
Pipe
Redistributor
(Typical)
Manometer
device
Packing
material
Support
plate
Valve
Water
Flowmeter
Air in
Influent
water
Water outlet
Air duct
Damper
Centrifugal blower
Concrete pad
Centrifugal pump
water flow rate to the column decreases, the air flow rate
will also decrease. This will reduce the cost of treating air
emissions.
Henrys constant, a primary indicator of a compounds potential for removal in an air stripper, increases
with the increase in temperature. Also, compounds with
low volatility at ambient temperature may require preheating to achieve high removal efficiency. In addition, different VOCs also have different values of Henrys constant
(Chuang etal. 1992, Nehra etal. 2008). Packed column air
strippers exhibit lower pressure drop characteristics than
the pressure drop through a sieve tray air stripper. This
M.E. Abdullahi etal.: A packed column air stripper for VOC removal9
allows for a smaller blower and motor, with reduced electrical operating costs. In general, packed column air strippers are generally less expensive and easier to construct.
They are also preferred for liquids that have a tendency to
foam, since they have significant interference on the efficiency of a tray air stripper. However, tray strippers have
shorter heights and smaller diameters than an equivalent
packed column stripper.
From a thermodynamic analysis, the temperature dependence of Henrys constant can be modeled by a Vant Hofftype relation, given in the integrated form by (Hand etal.
2011)
- H 0
+C
log( H ) =
RT
(13)
4.0
3.5
3.0
KL (min-1)
(12)
2.5
2.0
1.5
1.0
0.5
0.0
10
15
20
25
30
Temperature (C)
10M.E. Abdullahi etal.: A packed column air stripper for VOC removal
Rashing
ring
Lessing
ring
Partition
ring
Beri saddle
Intalox saddle
Tellerette
Pall ring
Nor pac
ring
Tri-pac
Figure 6Examples of packing material for air stripping towers (Hand etal. 2011).
Reproduced with permission from McGraw-Hill Education Ltd., UK.
M.E. Abdullahi etal.: A packed column air stripper for VOC removal11
Table 3Equilibrium vapor pressure of water at four different temperatures (Lowe 1990).
T (C)
0
10
20
30
P(mm Hg)
4.85
9.21
17.54
31.82
4.63
8.33
14.28
(14)
Bass and Sylvia (1992) reported that the Henrys constant for methyl tert-butyl ether (MTBE) is doubled by a
17C temperature increase, from 12C to 29C. Therefore,
heating the wastewater by this amount before treatment
would reduce the stripping air requirement by half.
12M.E. Abdullahi etal.: A packed column air stripper for VOC removal
C0=10 mg/l
10
C0=7 mg/l
C0=5 mg/l
CB concentration (mg/l)
C0=3 mg/l
6
C0=1 mg/l
curve fitted
temperature 15C
air flow rate 2.5 l/min
0
0
8
10
Time (min)
12
14
16
channels and a relatively high surface area. Packing material provides a large A/W interfacial area resulting in an
efficient transfer of the volatile contaminant from the
water to the air (Wang etal. 2006, Alam and Hossain 2009,
El-Behlil etal. 2012). Packing materials normally employ
at least one of the following mechanisms (Ali 2012):
1. Dividing the gas into small bubbles in a continuous
liquid phase.
2. Spreading the liquid into thin film that flow through a
continuous gas phase.
3. Forming the liquid into small drops in a continuous
gas phase.
There are several different varieties of commercially
available packing material with their physical properties
usually provided by the manufacturers (Hand etal. 2011).
Some examples are displayed in Figure 6. The types and
shape of packing materials determine the pressure drop
in the air stripper. Packing offers resistance to flow under
given air and water loading rates. The packing media
hold up a certain amount of liquid depending on the
relative amount of space (gap) left between them, which is
referred to as voidage (Nirmalakhandan etal. 1993).
The choice of packing materials should therefore be
based on the ratio of their absolute pressure drop to avoid
the phenomenon of flooding. Modern plastic lattice packings are superior to classic packings such as stainless-steel
pall rings or ceramic saddles due to its high voidage, which
reduces the tendency of plugging. To minimize the pressure
drop of packings, many manufacturers offer large random
packings up to a nominal size of 90mm (Kutzer etal. 1995,
El-Behlil et al. 2012). However, ceramic random column
packing is highly suitable for the conditions of higher and
M.E. Abdullahi etal.: A packed column air stripper for VOC removal13
14M.E. Abdullahi etal.: A packed column air stripper for VOC removal
(15)
where KLa is the overall (liquid-phase-based) mass transfer coefficient and H is the Henrys law constant expressed
as the ratio of the VOC mass concentration in the gas
M.E. Abdullahi etal.: A packed column air stripper for VOC removal15
gas- and liquid-phase resistance. The Onda model predicted the transfer rate constants within an average standard deviation of 21%. Also, a comparison of empirically
generated mass transfer coefficient using Onda correlation to actual mass transfer coefficients in an air stripping
tower for the removal of dissolved gasoline constituents
from groundwater by Wolf etal. (1989) gave 31% standard
deviation.
16M.E. Abdullahi etal.: A packed column air stripper for VOC removal
Developers/Source
Description
TOTM
BATE
ASAP
ASAP Features:
Hand 1991
NN prediction of
KLa (NN model)
ASDC
AirStrip v.1.2
Development mass
transfer coefficient
for different
packing materials
References
Raschig Jaeger
Technologies 2006
Kim and Deshusses
2008
M.E. Abdullahi etal.: A packed column air stripper for VOC removal17
6 Conclusion
The packed column air stripper is a proven, effective means
of removing VOCs from groundwater and wastewater. It
has been used in many sites, either alone or in conjunction with other methods with effective results. As shown
in the present review, extensive experimental and theoretical researches have been carried out by a lot of researchers, and a large volume of knowledge on the application
of a packed column air stripper in the removal of VOCs
from wastewater has been collected. Various models have
been developed to determine the overall mass transfer
coefficient. Empirically generated and actual mass transfer coefficients in air stripping towers for the removal of
various compounds are available. In addition, different air
stripper design software have been developed. However, a
knowledge gap still exists in the synthesis of this knowledge to formulate practically applicable mathematical
relationships for the general description of the process.
Mathematical models capable of effectively describing
the air stripping of VOCs in packed columns are useful
tools for the design and scaleup of air stripping process.
Predictive models make it possible to assess process feasibility preliminarily and/or to validate experimental data
for process scaleup. Further attention is therefore required
in the area of air stripper performance optimization. There
has been no research on the development of a mathematical model and optimization of an air stripper using statistical experimental design method. Such a determination
is critical to the understanding of the interactive effect
of process variables such as temperature, A/W ratio, and
height of packing on an air stripper performance.
Acknowledgments: The authors would like to express
their sincere appreciation to Universiti Teknologi Malaysia
(UTM) for the financial support under the exploratory
research grant scheme (ERGS) and international doctorate fellowship.
References
Abdullahi MP, Chian SS. Chlorinated and non-chlorinated-volatile
organic compounds (VOCs) in drinking water of peninsular
Malaysia. Sains Malaysiana 2011; 40: 12551261.
Abdullahi ME, Abu Hassan MA, Zainura ZN, Raja Ibrahim RK. Volatile
organic compounds abatement from industrial wastewater:
selecting the appropriate technology. Aust J Basic Appl Sci
2013a; 7: 103113.
Abdullahi ME, Abu Hassan MA, Zainura ZN, Raja Ibrahim RK.
Simulation of the effect of process variables on packed
column air stripper performance. World Appl Sci J 2013b; 25:
11001106.
Abdullahi ME, Abu Hassan MA, Zainura ZN, Raja Ibrahim RK.
Temperature and air-water ratio influence on the air stripping
of benzene, toluene and xylene. Desal Water Treat 2014. doi:
10.1080/19443994.2014.903209.
AEA Group. Climate change consequences of VOC emission controls.
A report to the Department for Environment, Food and Rural
Affairs, Welsh Assembly Government, the Scottish Executive
and the Department of the Environment for Northern Ireland,
2007.
Aeration System Analysis Program (ASAP). A publication of
Sustainable Futures Institute, Michigan Technological
University. Available from: http://cpas.mtu.edu/etdot/
brochures/etdot_asap_brochure.pdf. Accessed October 18,
2013.
Alam R, Hossain MD. Effect of packing materials and other
parameters on the air stripping process for the removal of
ammonia from the wastewater of natural gas fertilizer factory.
J Water Resources Protect 2009; 3: 210215.
Ali I. Catalytic method utilizing an alkaline and acidic liquid catalyst
for the removal of siloxane from biogas (landfill methane gas).
An unpublished Masters thesis submitted to the Department
of Chemical and Biological Engineering Chalmers University of
Technology, Goteborg, Sweden, 2012: 120.
Anders S, Teich TH, Heinzle E, Hungerbhler K. VOC treatment with
non-thermal plasma. Lecture given at the 4th International
18M.E. Abdullahi etal.: A packed column air stripper for VOC removal
Conference on Advanced Oxidation Technologies for Water and
Air Remediation AOTs-4, Orlando, FL, 1997: 60.
Bansode RR, Losso JN, Marshall WE, Rao RM, Portier RJ. Adsorption
of volatile organic compounds by pecan shell-and almond
shell-based granular activated carbons. Bioresource Technol
2003; 90: 175184.
Bass DH, Sylvia TE. Heated air stripping for the removal of MTBE
from recovered ground water. Groundwater Technol 1992:
1726.
Bedding ND, McIntyre AE, Perry R, Lester JN. Organic contaminants
in aquatic environment I. Source and occurrence. Sci Total
Environ 1982; 25: 143147.
Beranek D. Engineering and design air stripping: Design Guide No.
1110-13. Washington, D.C. Department of Army, U.S. Army
Corps of Engineers, 2001: A1-1 to D18.
Berenjian A, Chan N, Malmiri HJ. Volatile organic compounds
removal methods: a review. Am J Biochem Biotechnol 2012; 8:
220229.
Bravo JL. Design steam stripper for wastewater. Chem Eng Progress
1994: 5663.
Brown A, Devinny JS, Davis MK, Browne TE, Rodriguez RA. A
review of potential technologies for the treatment of methyl
tertiary butyl ether (MtBE) in drinking water. 1997 NGWA/API
Conference on Petroleum Hydrocarbon and Organic Chemical
in Ground Water: Prevention Detection and Remediation, USA,
1997: 126147.
Butillo JV, Pulido AD, Reese NM, Lowe MA. Removal efficiency of
MTBE in water: confirmation of a predictive model through
applied technology. Proceedings of the API/NGWA Petroleum
Hydrocarbons and Organic Chemicals in Groundwater:
Prevention, Detection and Remediation, Houston, TX,
November 24, 1994: 91105.
Byer WD, Morton CM. Removing VOCs from groundwater; pilot,
scale-up, and operating experience. Environ Progress 1985; 4:
112118.
Cameron GM, Chang I. Sizing of packed towers in acid plants.
Presented at The Chemical Engineers Resource Page 2010:
121.
Cho LD, Chung CD, Kim G. Decomposition and solidification of
hazardous volatile organic compounds through plasma
chemical reactions. J Ind Eng Chem 2007; 13: 287297.
Chuang KT, Cheng S, Tong S. Removal and destruction of benzene,
toluene and xylene from wastewater by air stripping and
catalytic oxidation. Ind Eng Chem Res 1992; 31: 24662472.
Creyghton B. Direct plasma treatment of polluted water. 4th Int.
Conf. on Advanced Oxidation Technologies for Water and Air
Remediation AOTs-4, Orlando, FL, 1997: 58.
Derwent RG. Sources, distributions and fates of VOCs in the
atmosphere. In: Hester RE, Harrison RM, Derwent RG, editors.
Volatile organic compounds in the atmospheres. UK: The Royal
Society of Chemistry, 1995: 115.
Djebbar Y, Narbaitz RM. Neural network prediction of air stripping
KLa. J Environ Eng 2002; 128: 451460.
Dwivedi P, Gaur V, Sharma A, Verma N. Comparative study
of removal of volatile organic compounds by cryogenic
condensation and adsorption by activated carbon fiber. Separ
Purif Technol 2004; 39: 2327.
Dzombak DA, Fang H, Roy SB. ASDC: a micro-computer based
program for Air Stripper Design and Costing. CE Report No.
92-204 [USAF Report No. ESL-TR-91-40] 1991: 1167.
M.E. Abdullahi etal.: A packed column air stripper for VOC removal19
20M.E. Abdullahi etal.: A packed column air stripper for VOC removal
in aqueous media via UV light, nano titania hydrogen peroxide
and potassium persulfate. Chem Eng J 2011; 167: 172182.
Samadi MT, Nasseri S, Mesdaghinia AR, Alizadefard MR. Removal of
chloroform (CHCl3) from Tehran drinking water by GAC and air
stripping columns. Iran J Environ Health Sci Eng 2004; 1: 512.
Schultz TE. Biotreating process waste water: airing the options.
Chem Eng Mag 2005. Available from: http://www.che.com.
Simpson H, Conant, Myslik J. Protecting the quality of groundwater
supplies. Fact sheet Ministry of Agriculture, Food and Rural
Affairs, Ontario, 2006: 14.
Slater CS, Savelski MJ, Hesketh RP, Frey E. The selection and
reduction of organic solvents in pharmaceutical manufacture.
American Chemical Society 10th Green Chemistry and
Engineering Conference Washington, 2006.
Spencer C, Witco J. Evaluation and assessment of removal
technology for specific organic contaminant in NJ drinking
water. Black & Veatch Project No. 161096, 2008: 147.
Available from: www.nj.gov/dep/watersupply/.../
treatment_b&v_final08_rpt. Accessed April 7, 2014.
Srinivasan A, Chowdhudry P, Viraraghavan T. Air stripping in industrial
wastewater in water and wastewater treatment technologies.
Volume 1. London: UNESCO and EOLSS, 2011; 88110.
Subrahmanyam C, Renken L, Kiwi-Minsker L. Novel catalytic
non-thermal plasma reactor for the abatement of VOCs. Chem
Eng J 2007; 134: 7883.
Surinder PS, James HW, Robert MC, John FV, Andrew JL, Gregory DR,
Richard AA, Mike GE. Removal of volatile organic compounds
from groundwater using a rotary air stripper. Ind Eng Chem Res
1992; 31: 574580.
Suthersan SS. Pump and treat systems, remediation engineering:
design concepts. USA: CRC Press, 1999: 136.
USEPA. Federal Cleaning Air Act amended 1990. U.S. Environmental
Protection Agency, Washington, DC, 1990. Available from:
http://www.epa.gov/dfe/pubs/.
M.E. Abdullahi etal.: A packed column air stripper for VOC removal21