Chemistry Retake ch 10 & 11

13 Which statements about exothermic and endothermic reactions are correct?

1 During an exothermic reaction, heat is given out.
2 The temperature of an endothermic reaction goes up because heat is taken in.
3 Burning methane in the air is an exothermic reaction.
A 1, 2 and 3
B 1 and 2 only
C 1 and 3 only
D 2 and 3 only
14 A power station was designed to burn gaseous fuels only. Which two substances could be
used?
A carbon dioxide and hydrogen
B carbon dioxide and 235U
C hydrogen and methane
D methane and 235U
D 2 and 3 only
15 The rate of a reaction depends on temperature, concentration, particle size and catalysts.
Which statement is not correct?
A Catalysts can be used to increase the rate of reaction.
B Higher concentration decreases the rate of reaction.
C Higher temperature increases the rate of reaction.
D Larger particle size decreases the rate of reaction.
16 The diagram shows the change from an anhydrous salt to its hydrated form. forward
reverse
Which statement is correct?
A forward reaction requires heat and water
B forward reaction requires water only
C reverse reaction requires heat and water
D reverse reaction requires water only
anhydrous salt
11 D 31 C 12 A 32 B 13 C 33 D 14 C 34 A 15 B 16 B
4 A fuel cell produces electrical energy by the oxidation of a fuel by oxygen.
The fuel is usually hydrogen but methane and methanol are two other fuels which may be used. A
diagram of a hydrogen fuel cell is given below.
(a) When the fuel is hydrogen, the only product is water.
What additional product would be formed if methane was used?
.............................................................................................................................................. [1]
(b) Write the equation for the chemical reaction that takes place in a hydrogen fuel
cell. .............................................................................................................................................. [1]
(c) (i) At which electrode does oxidation occur? Explain your
choice. ....................................................................................................................................... [1]
(ii) Write an ionic equation for the reaction at this
electrode. ....................................................................................................................................... [2]
(d) Fuel cells are used to propel cars.
Give two advantages of a fuel cell over a gasoline-fuelled engine.
.................................................................................................................................................... ........
...................................................................................................................................... [2]
[Total: 7]

5 (a)
Sodium chlorate(I) decomposes to form sodium chloride and oxygen. The rate of this reaction is
very slow at room temperature provided the sodium chlorate(I) is stored in a dark bottle to prevent
exposure to light.
2NaClO 2NaCl + O2
The rate of this decomposition can be studied using the following experiment.
20 40 60 80 100
oxygen collects in syringe
sodium chlorate(I) solution
Sodium chlorate(I) is placed in the flask and 0.2 g of copper(II) oxide is added. This catalyses the
decomposition of the sodium chlorate(I) and the volume of oxygen collected is measured every
minute. The results are plotted to give a graph of the type shown below.

(ii)
Explain why the gradient (slope) of this graph decreases with
time. ............................................................................................................................................. ......
................................................................................................................................. [2]

Cobalt(II) oxide is a more efficient catalyst for this reaction than copper(II) oxide. Sketch, on the
grid, the graph for the reaction catalysed by cobalt(II) oxide.
All other conditions were kept constant. [2]
(b)
7
(iii) What can you deduce from the comment that sodium chlorate(I) has to be shielded from
light? ............................................................................................................................................. ......
................................................................................................................................. [1]
(iv) Explain, in terms of collisions between particles, why the initial gradient would be steeper if the
experiment was repeated at a higher temperature.
............................................................................................................................................. ...............
.............................................................................................................................. ..............................
............................................................................................................... .............................................
.......................................................................................... [3]
The ions present in aqueous sodium chloride are Na+(aq), Cl (aq), H+(aq) and OH(aq).
The electrolysis of concentrated aqueous sodium chloride forms three products. They are
hydrogen, chlorine and sodium hydroxide.
UCLES 2014
0620/33/O/N/14
[Turn over
(i)
Explain how these three products are formed. Give ionic equations for the reactions at the
electrodes.
............................................................................................................................................. ...............
.............................................................................................................................. ..............................
............................................................................................................... .............................................
................................................................................................ ............................................................
........................................................................... [4]
If the solution of the electrolyte is stirred, chlorine reacts with sodium hydroxide to form sodium
chlorate(I), sodium chloride and water.
Write an equation for this reaction.
(ii)
Cl2 + ...NaOH ..................... + ..................... + .....................
[2]
[Total: 14]
13 When anhydrous copper(II) sulfate is added to water a solution is formed and heat is given out.
Which row correctly shows the temperature change and the type of reaction taking place?

A
B
C

14 Which fuel does not produce carbon dioxide when it burns? A coal
B hydrogen C methane D petrol
15 A student investigates the rate of reaction between zinc and an excess of sulfuric acid. The
graph shows the results of two experiments, X and Y.
volume of hydrogen

Which change explains the difference

between X and Y?
A A catalyst is added in Y.
B A lower temperature is used in Y.
C Larger pieces of zinc are used in Y.
D Less concentrated acid is used in Y.

16 Anhydrous copper(II) sulfate can be made by heating hydrated copper(II) sulfate.

CuSO4.5H2O CuSO4 + 5H2O
What can be added to anhydrous copper(II) sulfate to turn it into hydrated copper(II) sulfate?
A concentrated sulfuric acid
B sodium hydroxide powder
C sulfur dioxide
D water
16 When hydrated copper(II) sulphate is heated in the apparatus shown, solid X and liquid Y are
produced.
hydrated copper(II)
sulphate