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Contents
Topic
Page No.
Theory
01 - 06
Exercise - 1
07 - 24
Exercise - 2
25 - 33
Exercise - 3
34 - 38
Exercise - 4
39 - 41
Answer Key
42 - 43
Syllabus
Chemical Kinetics :
Rates of chemical reactions; Order of reactions; Rate constant; First order reactions; Temperature
dependence of rate constant (Arrhenius equation).
CHEMICAL KINETICS
Rate/Velocity of chemical reaction :
The rate of change of concentration with time of different chemical species taking part in a chemical reaction is
known as rate of reaction of that species.
c
mol / lit.
Rate =
=
= mol lit1 time1 = mol dm3 time1
t
sec
Rate is always defined in such a manner so that it is always a positive quantity.
=
Total time taken
t
t
t
Order of reaction :
Let there be a reaction m1A + m2B products.
Now, if on the basis of experiment, we find that
R [A]P [B]q
Where p may or may not be equal to m1 and similarly q may or may not be equal to m2.
p is order of reaction with respect to reactant A and q is order of reaction with respect to reactant B and
(p + q) is overall order of the reaction.
C0 Ct
' t'
or
kt = C0 Ct
or Ct = C0 kt
C0
2.303
log C
t
t
2.303 log 2
ln2
0.693
=
=
k
k
k
CHEMICAL KINETICS # 1
Ct
C 0 = kt
b(a x )
k = t (a b) log a (b x )
Table : Characteristics of Zero, First, Second and nth Order Reactions of the Type A Products
Zero Order
First-Order
[ A ]
= k[A]
t
[ A ]
= k[A]
t
In [A]t = kt + In [A]0
nth order
Second-Order
[ A ]
= k[A]2
t
1
1
=
kt
+
[A]t
[ A ]0
[ A ]
k [ A ]n
t
1
(A t )
n1
1
( A 0 )n 1
(n 1) kt
Linear graph
Half-life
[A]t v/s t
t1/2 =
In [A] v/s t
[ A ]0
2k
t1/2 =
(depends on [A]0)
0.693
k
(independent of [A]0)
1
v/s t
[A]
( A t )n1
1
t1/2 = k[ A ]
0
t 1/ 2
v/s
1
( A 0 )n1
(depends on [A]0)
if
[B] = constant
[C] = constant
r01 = k [A0]1a
r02 = k [A0]2a
r01
r02
[A ]
0 1
[ A 0 ]2
t1/2
t1 / 2
t1' / 2
1
[R0 ]n1
(R '0 )n1
(R 0 )n1
CHEMICAL KINETICS # 2
k=
nB(g)
P0 (n 1)
2.303
log nP P
t
0
t
By titration method :
By measuring the volume of titrating agent we can monitor amount of reactant remaining or amount of product
formed at any time. It is the titre value . Here the milliequivalent or millimoles are calculated using valence
factors.
V0 = vol. of titrant used at t = 0
Vt = vol. of titrant used at t
V = vol. of titrant used at t =
k=
V V0
2.303
log V V
t
t = 0, t = t and t =
Y Y0
2.303
log
t
r rt
K t 10
2 to 3 ( for most of the reactions)
Kt
Enthalpy (H)
HR
Ea1
Ea2
Threshold enthalpy
or energy
Reactants
H = Hp HR = Ea1 Ea2
HP
Products
CHEMICAL KINETICS # 3
T2
Fraction of
molecule
T2 > T1
T1
Ea
rate e E a / RT
dependence of rate on temperature is due to dependence of k on temperature.
k e Ea / RT
k Ae Ea / RT
[Arrhenius equation]
Ea
E'a
HR
HP
Products
Reaction Coordinate
For an elementary reaction, the orders in the rate law equal the coefficients of the reactants.
Mechanism of a reaction :
Reactions can be divided into
Elementary / simple / single step
Complex / multi-step
ELEMENTARY REACTION :
These reaction take place in single step without formation of any intermediate
T.S.
Ep
P.E.
Er
Reaction coordinates
For elementary reaction we can define molecularity of the reaction which is equal to no of molecules which
make transition state or activated complex because of collisions in proper orientation and with sufficient energy
CHEMICAL KINETICS # 4
COMPLEX REACTION :
Reaction which proceed in more than two steps. or having some mechanism. ( sequence of elementary reaction
in which any complex reaction procceds)
T.S.
intermediate
E
Reaction coordinates
For complex reaction each step of mechanism will be having its own molecularity but molecularity of net
complex reaction will not be defined.
CALCULATION OF RATE LAW/ ORDER
d [intermediate ]
=0
dt
1
1
1
Teff = T1 + T2
k1
[B]
= k
[C]
2
Ea
(remember)
(remember)
E a1k 1 E a 2 k 2
k1 k 2
a
a x
a xeq.
B
0
x
xeq.
CHEMICAL KINETICS # 5
kfa
x = k k
f
b
kf + kb =
1 e
( k f k b ) t
(remember)
x eq.
1
n x x
t
eq.
(remember)
t=0
t
1
2
A
B
C
a
0
0
ax
y
z
k 1a
y = k k { e k1t e k 2 t }
2
1
(remember)
k1
1
tmax. = k k n k
1
2
2
CASE-
(remember)
k1 >> k2
k
CASE :
k2 >> k1
Conc
[C]
[B]
[A]
CHEMICAL KINETICS # 6
A-2.
xA + yB zC. If
(A) 1,1, 1
A-3.
d[C]
d[B]
d[ A ]
=
= 1.5
= then x,y and z are :
dt
dt
dt
(B) 3, 2, 3
(C) 3, 3, 2
(D) 2, 2, 3
xA yB
d[B]
A-5.
Rate of formation of SO3 in the following reaction 2SO2 + O2 2SO3 is 100 g min1. Hence rate of disappearance
of O2 is :
(A) 50 g min-1
(B) 40 g min1
(C) 200 g min1
(D) 20 g min1
A-6.
A reaction follows the given concentration (M)time graph. The rate for this reaction at 20 seconds will be:
0.5
0.4
0.3
0.2
0.1
0
20 40 60 80 100
Time/second
(A) 4 103 M s1
A-7.
(B) 8 102 M s1
(C) 2 102 M s1
(D) 7 103 M s1
For the reaction : N2 + 3H2 2NH3. If the rate of disappearance of hydrogen is 1.8 103. What is the
rate of formation of ammonia. (mole per litre per sec.)
(A) 1.8 103
(B) 1.2 103
(C) 2.7 103
(D) 0.9 103
CHEMICAL KINETICS # 7
A-8.
(B) B + 3D 4A + 2C
(C) 4A + 2B 2C + 3D
(D) B + (1/2) D 4A + 3
A-9.
ln the reaction; A + 2B 3C + D, which of the following expression does not describe changes in the
concentration of various species as a function of time :
(A) {d [C] / dt} = {3d [A] / dt}
(B) {3d [D] / dt} = {d [C] / dt}
(C) {3d [B] / dt} = {2d [C] / dt}
(D) {2d [B] / dt} = {d [A] / dt}
A-10.
For a chemical reaction 2X + Y Z, the rate of appearance of Z is 0.05 mol L1 per min. The rate of
disappearance of X will be (A) 0.05 mol L1 per hour
(B) 0.05 mol L1 per min
1
(C) 0.1 mol L
per min
(D) 0.25 mol L1 per min
B-2.
B-3.
(C) 1/2
(D) 3/2
(C) 2
dA
= K [A] [B]1/3
dt
(D) 13/12
B-4.
B-5.
For which of the following, the units of rate constant and rate of the reaction are same (A) First order reaction
(B) Second order reaction
(C) Third order reaction
(D) Zero order reaction
B-6.
For a chemical reaction, 2A + 2B C + D, the order of reaction is one with respect to A and one with
respect to B. The initial rate of the reaction is 4 102 mol L1 s1. When 50% of the reactants are converted
into products, the rate of the reaction would become(A) 2 102 mol L1s1
(B) 1 102 mol L1s1
2
1
1
(C) 4 10 mol L s
(D) 2 101 mol L1 s1
B-7.
For a gaseous reaction the rate equation is v = k[A][B]. If the volume of the gaseous system is suddenly
reduced to 1/3 of initial volume. The rate would become
(A) 1/9 times
(B) 9 times
(C) 1/6 times
(D) 6 times
B-8.
aA + bB Product, dx/dt = k [A]a [B]b . If concentration of A is doubled, rate is four times. If concentration
of B is made four times, rate is doubled. What is relation between rate of disappearance of A and that of B ?
(A) {d [A] / dt} = {d [B] / dt}
(B) {d [A] / dt} = {4 d [B] / dt}
(C) {4 d [A] / dt} = {d [B]/ dt}
(D) None of these
CHEMICAL KINETICS # 8
B-9.
For the reaction, 2NO(g) + 2H2(g) N2(g) + 2H2O(g) the rate expression can be written in the following
ways :
{d [N2] / dt} = k1 [NO][H2] ; {d[H2O] / dt} = k[NO][H2] ; { d[NO] / dt} = k1 [NO] [H2] ; {d[H2] / dt} = k1 [NO][H2]
The relationship between k, k1 , k1 and k1. is :
(A) k = k1 = k1 = k1
(B) k = 2k1 = k1 = k1
(C) k = 2k1 = k1 = k1
(D) k = k1 = k1 = 2 k1
B-10.
For rate constant is numerically the same for three reactions of first, second and third order respectively.
Which of the following is correct :
(A) if [A] = 1 then r1 = r2 = r3
(B) if [A] < 1 then r1 > r2 > r3
(C) if [A] > 1 then r3 > r2 > r1
(D) All
B-11.
In acidic medium the rate of reaction between (BrO3) and Br ions is given by the expression.
[d (BrO3) /dt] = K [BrO3 ] [Br] [H+]2 It means :
(A) Rate constant of overall reaction is 4 sec1
(B) Rate of reaction is independent of the concentration of acid
(C) The changes in pH of the solution will not affect the rate
(D) Doubling the concentration of H+ ions will increase the reaction rate by 4 times.
B-12.
For the irreversible process, A + B products, the rate is firstorder w.r.t. A and secondorder w.r.t. B. If 1.0
mol each of A and B introduced into a 1.0 L vessel, and the initial rate was 1.0 102 mol L1 s1 , rate when half
reactants have been turned into products is :
(A) 1.25 103 mol L1 s1
(B) 1.0 102 mol L1 s1
(C) 2.50 103 mol L1 s1
(D) 2.0 102 mol L1 s1
k 1t
= C0
(B) Ct = C0 e k 1t
(C) ln
C0
= k 1t
Ct
(D) ln
Ct
= k 1t
C0
C-2.
C-3.
C-4.
C-5.
What is the half life of a radioactive substance if 75% of any given amount of the substance disintegrates
in 60 minutes
(A) 2 Hours
(B) 30 Minutes
(C) 45 Minutes
(D) 20 Minutes
C-6.
For an elementary reaction X (g) Y (g) + Z (g) the half life periods is 10 min. In what period of time
would the concentration of X be reduced to 10% of original concentration (A) 20 Min.
(B) 33 Min
(C) 15 Min
(D) 25 Min
C-7.
99% of a first order reaction was completed in 32 min. When will 99.9% of the reaction complete
(A) 50 Min
(B) 46 Min
(C) 49 Min
(D) 48 Min
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F-106, Road No.2 Indraprastha Industrial Area, End of Evergreen Motor,
BSNL Lane, Jhalawar Road, Kota, Rajasthan (324005) Tel. : +91-744-242-5022, 92-14-233303
CHEMICAL KINETICS # 9
C-8.
In the presence of an acid, the initial concentration of cane sugar was reduced from 0.20 to 0.10 molar
in 5 hours and from 0.2 to 0.05 molar in 10 hours. The reaction is of
(A) Zero order
(B) First order
(C) Second order
(D) Third order
C-9.
For a second order reaction, if the conc. of a reactant decreases from 0.08M to 0.04M in ten minutes,
what would be the time taken for the conc. to decreases to 0.01M
(A) 20 minutes
(B) 30 minutes
(C) 50 minutes
(D) 70 minutes
C-10.
The rate constant for a second order reaction 8.0 104 litre mol1min1. How long will it take a 0.5M
solution to be reduced to 0.25M in reactant
(A) 8.665 102 min
(B) 8.0 104 min
(C) 2.50 103 min
(D) 4.0 104 min
C-11.
A radioactive isotope decomposes according to the first order with half life period of 15 hrs. 80% of the
sample will decompose in (A) 15 0.8 hr.
(B) 15 (log 8) hr.
(C) 15 (log5 / log2) hr. (or 34.83) hr.
(D) 15 10/ 8 hr.
C-12.
C-13.
C-14.
The rate constant of reaction 2 A + B C is 2.57 105 It mole1 sec1 after 10 sec. 2.65 105 It.
mole1 sec1 after 20 sec. and 2.55 105 It. mole1 sec1 after 30 sec. The order of the reaction is:
(A) 0
(B) 1
(C) 2
(D) 3
C-15.
For a first order reaction, the plot of log C against t (logC vs 't') gives a straight tine with slope equal to :
(A) (k / 2.303)
(B) ( k / 2.303)
(C) (ln k / 2.303)
(D) k.
C-16.
In a certain reaction, 10% of the reactant decomposes in one hour, 20 % in two hours, 30% in three hours and
so on the dimensions of the rate constant is :
(A) hour1
(B) mole litre1 sec1
(C) litre mole1 sec1
(D) mole sec1
C-17.
In presence of HCl, sucrose gets hydrolysed into glucose and fructose. The concentration of sucrose was found
to reduce from 0.4 M to 0.2 M in 1 hour and to 0.1 M in total of 2 hours. The order of the reaction is :
(A) zero
(B) one
(C) two
(D) None of these
C-18.
In a first order reaction the reacting substance has half-life period of ten minutes. What fraction of the substance
will be left after an hour the reaction has occurred ?
(A) 1/6 of initial concentration
(B) 1/64 of initial concentration
(C) 1/12 of initial concentration
(D) 1/32 of initial concentration
C-19.
K1
K2
In the following first order reactions (A)
Product, (B)
Product, the ratio k1 /k2 if 90% of (A) has
been reacted in time 't' while 99% of(B) has been reacted in time 2t is :
(A) 1
(B) 2
(C) 1/2
C-20.
Two substances A (t1/2 = 5 min) and B (t1/2 = 15 min) are taken in such a way that initially [A] = 4[B]. The time
after which both the concentration will be equal is : (Assume that reaction is first order)
(A) 5 min
(B) 15 min
(C) 20 min
(D) concentration can never be equal
CHEMICAL KINETICS # 10
C-21.
If a I-order reaction is completed to the extent of 60% and 20% in time intervals, t1 and t2, what is the ratio,
t1 : t2 ?
(A) 6.32
(B) 5.58
(C) 4.11
(D) 8.33
C-22.
For a reaction A Products, the concentration of reactant are C0 , aC0 , a2C0, a3C0 ........... after time interval
0, t, 2t ........where 'a' is constant. Then :
(A) reaction is of 1st order and K = (1/1) ln a
(B) reaction is of 2nd order and K = (1/tC0)(1a)/a
(C) reaction is of 1st order and K =
C-23.
1 1
ln
t a
The rate constant for the reaction A B is 2 104 It. mol1 min1. The concentration of A at which rate of the
reaction is (1/12) 105 M sec1 is :
(B) (1/20) 5 / 3 M
(A) 0.25 M
C-24.
1
1
ln a
t
(C) 0.5 M
Graph between concentration of the product and time of the reaction A B is of the type
Hence graph
(A)
(B)
(C)
(D)
Time
C-25.
A graph plotted between log t50% vs. log concentration is a straight line. What conclusion can you draw from this
graph.
(A) n = 1 ; t1/2 a
(C) n = 1 ; t1/2 = (0.693 / k)
C-26.
What will be the order of reaction and rate constant for a chemical change having log t50% vs log concentration
of (A) curves as :
(A) 0, 1/2
(B) 1, 1
(C) 2, 2
(D) 3, 1
C-27.
A drop of solution (volume 0.05 mL) contains 3.0 106 moles of H+. If the rate constant of disappearance of H+
is 1.0 107 mole litre1 sec1. How long would it take for H+ in drop to disappear :
(A) 6 108 sec
(B) 6 107 sec
(C) 6 109 sec
(D) 6 1010 sec
D-2.
initial rate
1
2
3
4
0.10
0.80
0.10
0.80
(A) r = k [B]3
0.012
0.024
0.012
0.024
0.035
0.035
0.070
0.070
(B) r = k [A]3
CHEMICAL KINETICS # 11
D-3.
A + B Product,
dx
=k [A]a [B]b
dt
dx
= k, then order is :
dt
If
(A) 4
(B) 2
(C) 1
(D) 0
D-4.
One litre of 2M acetic acid and one litre of 3M ethyl alcohol were mixed. The esterification takes place
according to the reaction:
CH3COOH + C2H5OH CH3COOC2H5 + H2O
If each solution is diluted by one litre water the rate would become
(A) 4 times
(B) 2 times
(C) 0.5 times
(D) 0.25 times
D-5.
In the reaction : A + 2B + C D + 2E
Ther rate of reaction remains unchanged if the conc. of B is doubled and that of A and C is kept constant.
What is the order with respect to B.
(A) 0
(B) 1/2
(C) 1
(D) 3
D-6.
D-7.
Using the data given below the order and rate constant for the reaction : CH3CHO(g) CH4(g) + CO(g) would
be
Experiment no.
Initial conc.
Initial rate
[mol/]
[mol.lit1sec 1]
I
0.10
0.020
II
0.20
0.080
III
0.30
0.180
IV
0.40
0.320
Answer is
(A) 2,[k = 2.0 /mol sec]
(B) 0,[k = 2.0 mol/ sec]
(C) 2,[k = 1.5 /mol sec]
(D) 1,[k = 1.5 sec1]
D-8.
For the reaction 2A + 3B products, A is in excess and on changing the concentration of B from 0.1 M to
0.4 M, rate becomes doubled, Thus, rate law is :
(A)
D-9.
dx
= k[A]2 [B]2
dt
(B)
dx
= k[A] [B]
dt
0
20 mol
5 min
18 mol
(C)
dx
= k[A]0 [B]2
dt
(D)
dx
= k[B]1/2
dt
d [A]
= k and at different time interval, [A] values are :
dt
10 min
16 mol
15 min
14 mol
(C) 8 mol/min
CHEMICAL KINETICS # 12
D-10.
dx
dx
= k[A]2 . If log
is plotted against log [A], then graph is of the type :
dt
dt
A Product and
(A)
(B)
(C)
(D)
D-11.
If a is the initial concentration of reaction, then the half life period of a reaction of nth order is directly
propotional to (A) an
(B) an1
(C) a1n
(D) an+1
D-12.
The half-life period for a reaction at initial concentrations of 0.5 and 1.0 moles litre-1 are 200 sec and 100
sec respectively. The order of the reaction is (A) 0
(B) 1
(C) 2
(D) 3
D-13.
Consider the reaction 2A(g) 3B(g) + C(g). Starting with pure A initially, the total pressure doubled in 3 hrs.
The order of the reaction might possibly be
(A) zero
(B) first
(C) second
(D) unpredictable from this data
E-2.
Formation of NO2F from NO2 and F2 as per the reaction 2NO2(g) + F2(g) 2NO2F(g) is a second order
reaction, first order with respect to NO2 and first order with respect to F2. If NO2 and F2 are present in a closed
vessel in ratio 2 :1 maintained at a constant temperature with an initial total pressure of 3 atm, what will be the
total pressure in the vessel after the reaction is complete?
(A) 1atm
(B) 2 atm
(D) 3 atm
E-3.
In a gaseous state reaction, A2 (g) B(g) + (1/2)C (g), The increase in pressure from 100 mm to 120 mm
is notices in 5 minutes. The rate of disapearance of A2 in mm min1 is :
(A) 4
(B) 8
(C) 16
(D) 2
E-4.
The decomposition of a gaseous substance (A) to yield gaseous products (B), (C) follows First order kinetics.
If initially only (A) is present and 10 minutes after the start of the reaction the pressure of (A) is 200 mm Hg and
that of over all mixture is 300 mm Hg, then the rate constant for 2A B + 3 C is :
(A) (1/1200) ln 1.25 sec1
(B) (2.303 /10) log 1.5 min1
1
(C) (1/10) ln 1.25 sec
(D) None of these
E-5.
In the reaction NH4NO2 (aq.) N2 (g) + 2 H2O (l) the volume of N2 after 20 min and after a long time is 40 ml and
70 ml respectively. The value of rate constant is :
(A) (1/20) In (7/4) min1
(B) (2.303 /1200) log (7/3) sec1
1
(C) (1/20) log (7/3) min
(D) (2.303 / 20) log (11/7) min1
E-6.
/ Cu
N2Cl
volume of N2 gas is 10 L and after complete reaction it is 50 L. Hence rate constant is:
(A) (2.303 /10) log 5 min1
(B) (2.303 /10) log 1.25 min1
1
(C) (2.303 /10) log 2 min
(D) (2.303 /10) log 4 min1
CHEMICAL KINETICS # 13
The activation energies of the forward and backward reactions in the case of a chemical reaction are 30.5
and 45.4 KJ/mol respectively. The reaction is
(A) Exothermic
(B) Endothermic
(C) Neither exothermic nor endothermic
(D) Independent of temperature
F-2.
Chemical reaction occurs as a result of collisions between reacting molecules. Therefore, the reaction rate
is given by (A) Total number of collisions occurring in a unit volume per second
(B) Fraction of molecules which possess energy less than the threshold energy
(C) Total number of effective collisions
(D) None of the above
F-3.
The chemical reactions in which reactants require high amount of activation energy are generally (A) Slow
(B) Fast
(C) Instantaneous
(D) Spontaneous
F-4.
For a reaction for whi ch the activation energies of forward and reverse reactions are equal (A) H = 0
(B) S = 0
(C) The order is zero (D) There is no catalyst
F-5.
The activation energy of reaction is equal to(A) Threshold energy for the reaction
(B) Threshold energy + Energy of the reactants
(C) Threshold energy Energy of the reactants
(D) Threshold energy + Energy of the products
F-6.
Which of the following explains the increase of the reaction rate by catalyst (A) Catalyst decreases the rate of backward reaction so that the rate of forward reaction increases
(B) Catalyst provides extra energy to reacting molecules so that they may reduce effective collisions
(C) Catalyst provides an alternative path of lower activation energy to the reactants
(D) Catalyst increases the number of collisions between the reacting molecules.
F-7.
F-8.
F-9.
F-10.
F-11.
The first order rate constant k is related to temp. as log k = 15.0 (106 /T) Which of the following pair of value is
correct ?
(A) A = 1015 and E = 1.9 104 KJ
(B) A = 1015 and E = 40 KJ
(C) A = 1015 and E = 40 KJ
(D) A = 1015 and E = 1.9 104 KJ.
F-12.
The decomposition of N2O into N2 & O2 in presence of gaseous argon follow second order kinetics with
k = (5.0 1011 L mol1 s1) e
(A) 5.0 x 1011 J
41570 K
T
(B) 41570 J
(D) 345612.98 J
CHEMICAL KINETICS # 14
F-13.
How much faster would a reaction proceed at 25C than at 0C if the activation energy is 65 kJ?
(A) 2 times
(B) 5 times
(C) 11 times
(D) 16 times
F-14.
The rate constant, the activation energy and the frequency factor of a chemical reaction at 25C are
3.0 104 s1, 104.4 KJ mol1 and 6.0 1014 s1 respectively. The value of the rate constant as T is :
(A) 2.0 1018 s1
(B) 6.0 1014 s1
(C) infinite
(D) 3.6 1030 s1
F-15.
For a given reaction, energy of activation for forward reaction (Eaf) is 80kJ.mol1. H = 40kJ.mol1 for the
reaction. A catalyst lowers Eaf to 20 kJ.mol1. The ratio of energy of activation for reverse reaction before and
after addition of catalyst is :
(A) 1.0
(B) 0.5
(C) 1.2
(D)2.0
For the reaction H2 (g) + Br2 (g) 2HBr (g) the experiment data suggested that r = k[H2][Br2]1/2
The molecularity and order of the reaction are respectively :
(A) 2, 3/ 2
(B) 3/2 , 3/2
(C) Not defined, 3/2
(D) 1,1/2
G-2.
G-3.
dc
= k[NO2]2 the number of
dt
(A) only
G-4.
G-5.
In the Lindemann theory of unimolecular reactions, it is shown that the apparent rate constant for such a
reaction is kapp =
k1C
where C is the concentration of the reactant k1 and are constants. Calculate the
1 C
value of C for which kapp has 90% of its limiting value at C tending to infinitely large values, given = 9 x 105.
(A) 106 mole/litre
(B) 104 mol/litre
(C) 105 mole/litre
(D) 5 x 105 mol/litre
G-6.
G-7.
CHEMICAL KINETICS # 15
dx
For an elementary reaction, net rate is dt = k[A]2 k'[C] [B]2 then, select the correct statement :
(A)
d[C]
d[ A ]2 d [B]
=
=
is the relation among (B) 2A
dt
dt
dt
Consider the elementary reaction sequence shown in figure. Which of the following
equations are correct ?
H-3.
(A)
d[A]
= k1[A] + k4[D]
dt
(B)
d [ C]
= k2[B] k3[C]
dt
(C)
d [D]
= k4[D] + k3[D]
dt
(A) 2A +
H-4.
1
B
(B) 2A + B
(C) 2A
C + B1
H-5.
C+D
dx
dt = k1 [A] [B] k2[C] [D] in which set of the concentration reaction ceases?
[A]
[B]
[C]
[D]
[A]
[B]
(A)
0.1 M
0.2 M
0.3 M
0.4 M
(B)
0.4 M
0.25 M 0.2 M
[C]
[D]
0.5 M
(C)
0.2 M
0.2 M
0.3 M
0.2 M
(D)
0.2 M
0.2 M
0.2 M
0.4 M
The substance undergoes first order decomposition. The decomposition follows two parallel first order reactions
as :
H-6.
The rate constant for two parallel reactions were found reactions were found to be 1.0 102dm3 mol-1 s1 and
3.0 102 dm3 mol1 s1. If the corresponding energies of activation of the parallel reactions are 60.0 kJ mol1
and 70.0 kJ mol1 respectively, what is the apparent overall energy of activation ?
(A) 130.0 kJ mol1
CHEMICAL KINETICS # 16
At t = t1 pressure of gas B is :
(A) 2.5 bar
2.
3.
(B) 1.5 s
(C) 2.3 s
(D) 1.15 s
(C) 1 : 3 : 5
(D) 1 : 3 : 5
(B) 1 : 1 : 1
Comprehension # 2
4.
(C) if T1 > T2, k1 < k2 (for endothermic reaction) (D) Ea1 Ea2
5.
if T1 > T2
if T1 > T2
if T2 < T1 (endothermic)
if T2 > T1 (exothermic)
CHEMICAL KINETICS # 17
Comprehension # 3
A reaction is said to be first order if it's rate is proportional to the concentration of reactant. Let us consider a
reaction
A(g) B(g) + C(g)
At t = 0
a
0
0
At time t
ax
x
x
The rate of reaction is given by the expression
represented as k =
dx
= k(a x) and integrated rate equation for a given reaction is
dt
1 a
where a = initial concentration and (a x) = concentration of A after time t.
ln
t
ax
7.
Thermal decomposition of compound X is a first order reaction. If 75% of X is decomposed in 100 min. How long
will it take for 90% of the compound to decompose?
Given : log 2 = 0.30
(A) 190 min
(B) 176.66 min
(C) 166.66 min
(D) 156.66 min
8.
Consider a reaction A(g) 3B(g) + 2C(g) with rate constant 1.386 102 min1. Starting with
2 moles of A in 12.5 litre vessel initially, if reaction is allowed to takes place at constant pressure & at 298K then
find the concentration of B after 100 min.
(A) 0.04 M
(B) 0.36 M
(C) 0.09 M
(D) None of these
Comprehension # 4
Competing First-Order Reactions
Frequently a species can react in different ways to give a variety of products. For example, toluene can be
nitrated at the ortho, meta, or para positions, We shall consider the simplest case, that of two competing
irreversible first-order reactions :
k
k2 D
A 1 C and A
where the stoichiometric coefficients are taken as unity for simplicity. The rate law is
d[A]
d [C]
For C, we have
= k1[A] = k1[A]0 e (k1 k 2 )t . Multiplication by dt and integration from time 0
dt
k [A]
( k k ) t
(where [C]0 = 0) to an arbitary time t gives
[C] = 1 0 (1 e 1 2 )
k1 k 2
d [D]
gives
Similarly, integration of
dt
[D] =
k 2 [ A ]0
(1 e (k 1 k 2 )t )
k1 k 2
The sum of the rate constants k1 + k2 appears in the exponentials for both [C] and [D].
At any time we also have
9.
k1
[C]
= k
[D]
2
[C] t
[B] t
+
3
2
2
[A]t +[B]t + [C]t
3
CHEMICAL KINETICS # 18
10.
[ X] t
starting with only 'X', ratio [ Y ] [ Z]
t
t
11.
(B)
(e kt 1)
At high temperature acetic acid decomposes into CO2 & CH4 and simultaneously into CH2CO (ketene) and H2O
1
k1 3s
(i) CH3COOH
CH4 + CO2
k 2 4s
(ii) CH3COOH
CH2CO + H2O
12.
3
4
(B)
For A
3
7
(C)
4
7
Comprehension # 5
For the given sequential reaction
k
2
1
A
B
C
the concentration of A, B & C at any time 't' is given by
[A]t =
[A]0 e k1t
[B]t =
k1[ A ]0
e k1t e k 2 t
( k 2 k1 )
(B)
1
k
ln 1
k 2 k1 k 2
(C)
1
k
ln 1
k1 k 2 k 2
(D)
k2
k 2 k1
[B]t
[A]t
(B)
[C]t
Conc.
(A)
[C]t
conc.
[B] t
time
[A]t
time
(C)
[C]t
(D)
[B]t
time
Conc.
14.
k1
k 2 k1
Conc.
13.
[C]t
[B]t
[A] t
[A]t
time
CHEMICAL KINETICS # 19
16.
17.
The polarimeter readings in an experiment to measure the rate of inversion of cane suger (1st order reaction)
were as follows
time (min)
:
0
30
angle (degree) :
30
20
15
Then match the following. (Use : log 35 = 1.54, log 3 = 0.48, log 2 = 0.3)
Column - I
Column - II
(A)
(p)
120 min.
(B)
(q)
7.5
(C)
(r)
75.2 min.
(D)
(s)
laevorotatory
Column - II
(A)
A + B C + D
r = k1 [A] [B]
(p)
(B)
A + B C + D
r = k2 [A] [B]
(q)
(C)
A + B C + D
r = k3 [A] [B]
(r)
(D)
2A + B 2C + 3D
r = k3 [A] [B]
(s)
Column - II
(A)
d[ B]
d[A ]
vs
for first order
dt
dt
(p)
(B)
(q)
(C)
(r)
(D)
(s)
CHEMICAL KINETICS # 20
18.
Column-II
(A)
(p)
(B)
(q)
Zero
(C)
11
(D)
30
(s)
0.136
480
0.272
960
ASSERTION / REASON
Directions :
Each question has 5 choices (A), (B), (C), (D) and (E) out of which ONLY ONE is correct.
(A) Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.
(B) Statement-1 is True, Statement-2 is True; Statement-2 is NOT a correct explanation for Statement-1.
(C) Statement-1 is True, Statement-2 is False.
(D) Statement-1 is False, Statement-2 is True.
(E) Statement-1 and Statement-2 both are False.
19.
Statement-1
Statement-2
20.
Statement-1
: The time of completion of reactions of type A product (order <1) may be determined.
Statement-2
: Reactions with order 1 are either too slow or too fast and hence the time of completion can
not be determined.
21.
Statement-1
Statement-2
22.
Statement-1
Statement-2
: The overall rate of a reversible reaction may decrease with the increase in temperature.
: When the activation energy of forward reaction is less than that of backward reaction, then the
increase in the rate of backward reaction is more than that of forward reaction on increasing
the temperature.
23.
Statement-1
: In a reversible endothermic reaction, Eact of forward reaction is higher than that of backward
reaction
: The threshold energy of forward reaction is more than that of backward reaction
Statement-2
24.
Statement-1
Statement-2
: A catalyst provides an alternative path to the reaction in which conversion ofreactants into
products takes place quickly
: The catalyst forms an activated complex of lower potential energy, with thereactants by which
more number of molecules are able to cross the barrier per unit of time.
CHEMICAL KINETICS # 21
25.
Statement-1
26.
Statement-2
Statement-1
: For A + 2B C (rate= K[A]1[B]0), the half life time of reaction is only defined when conc.
of A and B are in stoichiometric ratio
Statement-2
: For above given order half life of reaction is directly proportional to conc. of A and not to conc.
of B due to its zero order.
27.
28.
Statement-1
Statement-2
Au
: N2 O(g)
N2 (g) 1/ 2O 2 ; rate = k[N2O]0 = k = constant is a zero order reaction.
Statement-1
: Half life of a certain radioactive element is 100 days. After 200 days, fraction left undecaye
will be 25%.
n
29.
30.
Ct 1
, where symbols have standard meaning.
C0 2
Statement-2
Statement-1
: Time taken for the completion of 75% of a st order reaction is double than its t.
Statement-2
: Time taken for completion of any fraction of a st order reaction is a constant value.
Statement-1 : If the activation energy of reaction is zero temperature will have no effect on the rate constant
Statement-2 : Lower the activation energy faster is the reaction
TRUE / FALSE
31.
32.
In a complex reaction the rate of overall reaction is governed by the slowest step.
33.
If t1/2 for a first order reaction is 6.93 s, the value of rate constant for the reaction would be 10s1.
34.
35.
Order and molecularity of a single step reaction may or may not be same.
36.
The activation energy of a catalysed reaction is more than the activation energy of the uncatalysed reaction.
37.
For a zero order reaction t3/4 is related to t1/2 as t3/4 = 1.5 t1/2
38.
39.
40.
41.
CHEMICAL KINETICS # 22
42.
43.
If the partial orders are equal to corresponding coefficients in the balanced reaction, the reaction must be
elementary.
44.
Every species that appears in the rate law of reaction must be a reactant or product in that reaction.
45.
46.
Product can form only when the required orientation and energy conditions are met.
47.
48.
The pre-exponential factor A has the same units for all reactions.
49.
50.
If the partial orders differ from the coefficients in the balanced reaction, the reaction must be complex.
51.
The rate of the reaction A B having the rate law dt k [ A ] [B] when plotted against time will exhibit a
d[A]
For a firstorder reaction, the time required to reduce successively the concentration of reactant by a constant
fraction is always same.
53.
As a first order reaction proceeds at a constant temperature, the rate remains constant.
54.
If concentration of catalyst appear in rate law (rate = k [catalyst]1 [reactant]1) then it may becomes pseudo first
order reaction during the reaction.
55.
Larger the value of Ea , greater is the effect on the value of k for a given temperature change.
56.
A catalyst in a chemical reaction decreases the activation energy of the forward reaction and increases the
activation energy of the reverse reaction
57.
A catalyst in a chemical reaction increases the forward Ea and decreases the backward Ea
58.
59.
At lower temperature, increase in temperature cause more change in the value of k than at higher temperature.
60.
Molecularity of a reaction may includes the number of product molecules taking part in the reaction.
CHEMICAL KINETICS # 23
For collision to be effective the energy possessed by the colliding molecules should be equal to or greater than
the ____________.
62.
In the reaction, H2 + I2 2HI, the rate of disappearance of H2 is _______ the rate of appearance of HI.
63.
For an endothermic process, the minimum value of activation energy can be _______.
64.
65.
The rate constant for the zero order reaction has the dimensions___________.
66.
67.
68.
69.
70.
71.
The ratio t7/8 / t1/2 for a first order reaction would be equal to _________.
72.
For a zero order reaction, the rate of the reaction is equal to the ______ of the reaction.
73.
74.
For a certain reaction, xM yL, the rate of reaction increases by 4 times when the concentration of M is
doubled. The rate law is _________.
75.
The rate equation r = k [A][B]1/2 suggests that order of overall reaction is _______.
76.
A plot of [A] vs t for a certain reaction A B with r = k [A]0 will be a straight line with slope equal to ________.
77.
78.
In the Arrhenius equation k = Aexp (E/RT), A may be termed as the rate constant at __________.
79.
For a ______ order reaction the half-life (t1/2) is independent of the initial conc. of the reactants.
80.
For a first order reaction A P, a graph of log [A] vs t has a slope equal to __________.
81.
82.
The order of a reaction is the ________ of the _________ of all the concentration terms in the rate equation.
CHEMICAL KINETICS # 24
d[ B]
= k[A], then half life (t1/2 ) is
dt
If decomposition reaction A (g) B (g) follows first order kinetics then the graph of rate of formation (R) of B
against time t will be
(A)
(B)
(C)
(D)
3.
(B) 50 min
-2
-3
(A) 0.2
4.
The rate constant for the forward reaction A (g) + 2B(g) is 1.5 103 s1 at 100 K. If 105 moles of A and 100
moles of B are present in a 10 litre vessel at equilibrium then rate constant for the backward reaction at this
temperature is :
(A) 1.50 104 L mol1 s1
(B) 1.5 1011 L mol1 s1
10
1
1
(C) 1.5 10 L mol s
(D) 1.5 1011L mol1 s1
5.
k [A]
1
1
2 [ B] 2 . Starting with initial conc. of 1 M of
A and B each, what is the time taken for concentration of A of become 0.25 M.
Given : k = 2.303 103 sec1.
(A) 300 sec.
(B) 600 sec.
(C) 900 sec.
(D) 1200 sec.
6.
The reaction A (g) B(g) + 2C (g) is a first order reaction with rate constant 3465 106 s1. Starting with
0.1 mole of A in 2 litre vessel, find the concentration of A after 200 sec., when the reaction is allowed to take
place at constant pressure and temperature.
(A) 0.05 M
(B) 0.025 M
(C) 0.0125 M
(D) None of these
CHEMICAL KINETICS # 25
The variation of concentration of A with time in two experiments starting with two different initial concentration of
A is given in the following graph. The reaction is represented as A(aq) B(aq). What is the rate of reaction
(M/min) when concentration of A in aqueous solution was 1.8 M?
Concentration(M)
7.
1.5
1.2
1
0.8
Experiment-1
Experiment-2
0.6
5
10
15
20
time(min.)
(D) 1 M min1
8.
In respect of the equation k = A exp ( Ea / RT), which one of the following statements is correct?
(A) R is Rydberg's constant
(B) k is equilibrium constant
(C) A is adsorption factor
(D) Ea is the energy of activation
9.
10.
The rate constant, the activation energy and the Arrhenius parameter (A) of a chemical reaction at 25C are
3.0 104 s1, 104.4 kJ mol1 and 6.0 1014s1 respectively. The value of the rate constant at T is
(A) 2.0 1018 s1
(B) 6.0 1014 s1
(C) infinity
(D) 3.6 1030 s1
11.
A first order reaction is 50% completed in 20 minutes at 27C and in 5 min at 47C. The energy of activation of
the reaction is
(A) 43.85 kJ/mol
(B) 55.14 kJ/mol
(C) 11.97 kJ/mol
(D) 6.65 kJ/mol
12.
For the first order reaction A B + C, carried out at 27 C if 3.8 1016 % of the reactant molecules exists
in the activated state, the Ea (activation energy) of the reaction is [log 3.8 = 0.58]
(A) 12 kJ/mole
(B) 831.4 kJ/mole
(C) 100 kJ/mole
(D) 88.57 kJ/mole
13.
For a certain reaction of order n, the time for half change, t1/2, is given by t1/2 =
constant and C0 is the initial concentration. What is n?
(A) 1
(B) 2
(C) 0
14.
( 2 2 ) 1/ 2
xC0 where k is
k
(D) 0.5
Given that for a reaction of order n, the integrated form of the rate equation is k =
1 1
1
where C0
t(n 1) Cn 1 Cn1
0
and C are the values of the reactant concentration at the start and after time t. What is the relationship between
t3/4 and t1/2 where t3/4 is the time required for C to become 1/4 C0?
(A) t3/4 = t1/2 [2n1 + 1]
(B) t3/4 = t1/2 [2n1 1]
n+1
(C) t3/4 = t1/2 [2 1]
(D) t3/4 = t1/2 [2n+1 + 1]
CHEMICAL KINETICS # 26
15.
In three different reactions, involving a single reactant in each case, a plot of rate of the reaction on the yaxis,
versus concentration of the reactant on the xaxis, yields three different curves shown below.
(i)
(ii)
(iii)
What are the possible orders of the reactions (i), (ii), (iii).
(A) 1, 2, 3
(B) 2, 1, 1/2
(C) 0, 1, 2
(D) 0, 1, 1/2
16.
The time elapsed of a certain between 33% and 67% completion of a first order reaction is 30 minutes. What is
the time needed for 25% completion?
(A) 150.5 minutes
(B) 12.5 minutes
(C) 180.5 minutes
(D) 165.5 minutes
17.
A reaction 2A + B C + D is first order with respect to A and 2nd order with respect to B. Initial conc.
(B) R = 27 C03 k / 32
(D) R = 49 k C03 / 32
18.
For a certain reaction, a plot of {[C0 C] / [C]} against the time t, yields a straight line. C0 = initial conc. of the
reactant and C is the reactant concentration after time t. What is the order of the reaction :
(A) 3
(B) zero
(C) 1
(D) 2
19.
In a I order reaction A products, the concentration of the reactant decrease to 6.25% of its initial value in 80
minutes. What is (i) the rate constant and (ii) the rate of the reaction, 100 minutes after the start, if the initial
concentration is 0.2 mole/litre?
(A) 2.17 102 min1, 3.47 104 mol.litre1 min1
(B) 3.465 102 min1, 2.166 104 mol.litre1 min1
(C) 3.465 103 min1, 2.17 103 mol.litre1 min1
(D) 2.166 103 min1, 2.667 104 mol.litre1 min1
20.
At 373 K, a gaseous reaction A 2B + C is found to be of first order. Starting with pure A, the total pressure at
the end of 10 min. was 176 mm and after a long time when A was completely dissociated, it was 270 mm. The
pressure of A at the end of 10 minutes was :
(A) 94 mm
(B) 47 mm
(C) 43 mm
(D) 90 mm
21.
The reaction A(s) 2 B(g) + C(g) is first order. The pressure after 20 min. and after very long time are 150 mm
Hg and 225 mm Hg. The value of rate constant and pressure after 40 min. are :
(A) 0.05 In 1.5 min1, 200 mm
(B) 0.5 ln 2 min1 ,300 mm
1
(C) 0.05 In 3 min , 300 mm
(D) 0.05 In 3 min1 , 200 mm
22.
The reaction [Co (NH3)5Br]2 + H2O [Co(NH3)5(H2O)]3+ + Br is followed by measuring a property of the
solution known as the optical density of the solution which may be taken to be linearly related to the concentration
of the reactant. The values of optical density are 0.80, 0.35 and 0.20 at the end of 20 minutes, 40 minutes and
infinite time after the start of the reaction which is first order. Calculate the rate constant.
(A) 6.93 x 103 min1
23.
The inversion of cane sugar proceeds with half life of 50 minute at pH = 5 for any concentration of sugar. However
if pH = 6, the half life changes to 500 minute of any concentration of sugar . The law expression for sugar
inversion can be written as :
(A) r = K [sugar]2 [H+]0
CHEMICAL KINETICS # 27
24.
The reaction A Products, is zero order while the reaction B Products, is 1st order. For what initial
concentration of A the half lives of the two reactions are equal.
(A) 2 M
(B) ln 2 M
(C) 2 log 2 M
(D) 2 ln 2 M
25.
For the reaction 3A Products the value of k = 1 103 / (molmin) the value of d[A] / dt in
mol/lt-sec when [A] = 2M is :
(A) 6.67 103
(B) 1.2 102
(C) 2 104
(D) 4 103
26.
Two I-order reactions have half-lives in the ratio 3 : 2. Calculate the ratio of time intervals t1 : t2. Where t1 is the
time period for 25% completion of the first reaction and t2, for 75% completion of the second reaction.
(A) 0.311 : 1
(B) 0.420 : 1
(C) 0.273 : 1
(D) 0.199 : 1
27.
The Arrhenius relationship of two different reactions is shown below. Which reaction is
faster at a lower temperature and which is more sensitive to changes of temperature ?
(A) B faster, A more sensitive
(B) B in both cases
(C) A in both cases
(D) A faster, B more sensitive
28.
When a graph between log K and 1/T is drawn a straight line is obtained. The point at which line cuts y -axis and
x -axis respectively correspond to the temp :
(A) 0, Ea / 2.303 R log A
(B) , Ea / (R ln A)
(C) 0, log A
(D) None of these
29.
A B
KA = 1015 e2000/T ;
CD
KC = 1014 e1000/T
Temperature T K at-which (KA = KC) is :
(A) 1000K
(B) 2000K
30.
The rate of a reaction gets doubled when the temperature changes from 7C to 17C. By what factor will it
change for the temperature change from 17C to 27C?
(A) 1.81
(B) 1.71
(C) 1.91
(D) 1.76
31.
For the reaction A + 2B products(started with concentrations taken in stoichiometric proportion), the
experimentally determined rate law is
(A)
32.
0.693
k
(B)
d [A]
= k [A]
dt
0.693
1/ k
(C)
0.693
2k
d[ A ]
1
= k[A]. At a time when t = , concentration of the reactant
dt
k
33.
C0
e
(B) C0e
C0
e
34.
(C)
(D)
1
e2
1
C0
1
)
K
If for a reaction in which A(g) converts to B(g) the reaction carried out at const.
V & T results into the following graph.
(A) then the reaction must be A(g) 3B(g) and is a first order reaction.
(B) then the reaction must be A(g) 3B(g) and is a second order reaction.
(C) then the reaction must be A(g) 3B(g) and is a zero order reaction.
(D) then the reaction must be A(g) 3B(g) and is a first order reaction.
CHEMICAL KINETICS # 28
35.
The instantaneous rate of disappearance of the MnO4 ion in the following reaction is 4.56 103 ms1. Then the
rate of appearance of 2 is :
2MnO4 + 10 + 16H+ 2Mn2+ + 52 + 8H2O
2MnO4 + 10 + 16H+ 2Mn2+ + 52 + 8H2O
(A) 1.14 103 Ms1
(B) 5.7 103 Ms1
(C) 4.56 104 Ms1
(D) 1.14 102 Ms1
36.
catalyst
Consider the following reactions at 300 K. A B (uncatalysed reaction). A
B (catalyst reaction)
1
The activation energy is lowered by 8.314 KJ mol for the catalysed reaction. How many times the rate of this
catalysed reaction greater than that of uncatalysed reaction ?
(Given e3.33 = 28)
(A) 15 times
(B) 38 times
(C) 22 times
(D) 28 times
37.
38.
A substance A' decomposes in solution following the first order kinetics. Flask contains 1 L of 1 M solution of
A and flask contains 100 ml of 0.6 M solution. After 8 hr, the conc. of A in flask 1 becomes 0.25 M. What will
be time for cone. of A in flask to become 0.3 M ? :
(A) 0.4 hr
(B) 2.4 hr
(C) 4.0 hr
(D) unpredictable as rate constant is not given
39.
A simple mechanism for enzyme-catalyzed reaction is given by the following set of equations
E
+
(enzyme)
S
(reactant)
ES
(intermediate-1)
ES
(intermediate-1)
EP
(intermediate-2)
EP
E
+
P
(intermediate-2)
(enzyme)
(product)
This is known as the MichaelisMenten mechanism. The potential energy diagram is shown in the fig. Which
of the following sets of identifications is correct ? (Assume that the temperature and pressure are constant).
(1)
(2)
(3)
(4)
(A)
E + P.
EP
ES
E+S
(B)
ES
Activated complex
EP
Activated complex
(C)
EP
Activated complex
ES
Activated complex
(D)
E+S
ES
EP
E+P
d[A ]
= k [A]1/2. If initial concentration of [A] is [A]0, then
dt
2 1/ 2
( A A1 / 2 )
t 0
A Vs t will be
K
2[A]10/ 2
[A]0
k
CHEMICAL KINETICS # 29
41.
42.
E1
2
In a consecutive reaction system A
B
C when E1 is much greater than E2, the yield of
B increase with
(A) increase in temperature
(B) decreases in temperature
(C) increase in initial concentration of A
(D) decrease in initial concentration of A
43.
44.
45.
Consider the decay of P to A and B by two parallel first order reactions as shown in Fig. Given
Reaction
Rate constant
Energy of activation
PA
HA
kA
EA
PB
HB
kB
EB
(C) HA = b d
(D) HB = c a
The oxidation of iodide ion by peroxy disulphate ion is described by the equation :
3 (aq) + S2O82 (aq) 3 (aq) + 2SO42 (aq)
(a) If
[S2O82 ]
t
= 1.5 103 Ms1 for a particular time interval, what is the value of
[ ]
for the same time
t
interval ?
(b) What is the average rate of formation of SO42 during that time interval ?
2.
In the following reaction 2H2O2 (aq) 2H2O () + O2 (g) rate of formation of O2 is 36 g min1 ,
(a) What is rate of formation of H2O.
(b) What is rate of disappearance of H2O2.
3.
The reaction 2NO(g) + Cl2(g) 2NOCl(g) is second order in NO and first order in Cl2. In a volume of
2 dm3, 5 mole of nitric oxide and 2 mol of Cl2 were brought together, and the initial rate was 2.4 10 3 mole
dm3 s. What will be the rate when half of the chlorine has reacted ?
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CHEMICAL KINETICS # 30
4.
BrO3 (aq) + 2Br (aq) in alkaline solution, the value of rate constant at
For the reaction 3BrO(aq)
0
80 C in the rate law for [BrO ]/t was found to be 0.057 L.mol1.s1. What is the rate constant when the rate
law is written for (a) [BrO3]/t (b) + [Br ] / t ?
5.
6.
d [N2 ]
d [H2 ]
and
denote?
dt
dt
(c) If the decomposition is zero order then what are the rate of production of N2 and H2 if k = 2.5 104 Ms1 ?
(d) If the rate obeys
k1 [NH3 ]
d [NH3 ]
= 1 k [NH ] , what will be the order for decomposition of NH3 if (i) [NH3] is very
dt
2
3
very less and (ii) [NH3] is very very high K1 and K2 are constant.
7.
Substance A reacts according to a first order rate law with k = 5 x 105 s1.
(a)
(b)
8.
Consider the following data on the hypothetical reaction between the reactants (A) and (B) give products
2A + 2B C + 3D
[A]
[B]
Rate r
[mol 1]
[mol 1]
[mol 1 s1]
1.
6.0 x 10-3
1.0 x 10-3
0.012
2.
6.0 x 10-3
2.0 x 10-3
0.024
-3
-3
3.
2.0 x 10
1.4 x 10
0.0020
4.
4.0 x 10-3
1.4 x 10-3
0.0080
If the reaction rate given by r = [A]a[B]b, then,
(i) What is the order of the reaction with respect to A.
(ii) What is the order of the reaction with respect to B.
(iii) What is the overall order.
(iv) Write the rate law equation.
(v) Calculate the rate constant.
9.
The reaction A + 2B C + 2D is run three times. In the second run, the initial concentration of A is double that
in the first run, and the initial rate of the reaction is double that of the first run. In the third run, the initial
concentration of each reactant is double the respective concentrations in the first run, and the initial rate is
double that of the first run. What is the order of the reaction with respect to each reactant?
10.
In a kinetic study of the reduction of nitric oxide with hydrogen, the initial pressure of 340 mm, an equimolar
mixture of gases was reduced to half the value in 102 seconds. In another experiment, the initial pressure of 288
mm, under the same conditions was reduced to half the value in 140 sec. Calculate the order of the reaction.
11.
(a)
The half life period and initial concentration for a reaction are as follows. What is order of reaction?
Initial concentration
350
540
158
t1/2
425
275
941
(b)
The half-life period for the thermal decomposition of PH3 at three different pressures are given below
Initial pressure (mm Hg)
707
79
37.5
Half--life (seconds)
84
84
83
What is the order of the reaction ?
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CHEMICAL KINETICS # 31
12.
The decomposition of Cl2O7 at 400 K in gaseous phase to Cl2 and O2 is of order reaction. After 55 sec at 400
K, the pressure of reaction mixture increases from 0.62 to 1.88 atm. Calculate the rate constant of given
reaction, also calculate the pressure of reaction mixture after 100 second.
[Given : n
13.
31
= 0.869, e1.58 = 4.858]
13
CI2 (g) +
CI2O7(g)
7
O (g)
2 2
For a homogeneous gaseous phase reaction 2A 3B + C the initial pressure was P0 while pressure after time
't' was P. Find the pressure after time '2t'. Assume first order reaction.
14.
The kinetic of hydrolysis of methyl acetate in excess dilute HCl at 25C were followed by withdrawing 2 mL of the
reaction mixture at intervals of (t), adding 50 mL water and titrating with baryta water. Determine the velocity
constant of hydrolysis.
t (in minute)
75
119
259
19.24
24.20
26.60
32.23
42.03
[ln
15.
22.79
22.79
22.79
= 0.2454, ln
= 0.39, ln
= 0.8439]
17.83
15.43
9. 8
D
A
B+C
Time
Volume of reagent
V1
V2
V3
A first order reaction, A B, requires activation energy of 70 kJ mol1. When a 20% solution of A was kept at
250C for 20 minutes, 25% decomposition took place. What will be the percent decomposition in the same time
in a 30% solution maintained at 40 0C? Assume that activation energy remains constant in this range of
temperature.
17.
slow
N2O5
NO2 + NO3
Step -
fast
N2O5 + NO3
3NO2 + O2
4NO2 + O2
2N2O5
18.
The reaction 2NO (g) + Br2 (g) 2NOBr (g), obeys the following mechanism.
(i) NO (g) + Br2 (g)
NOBr2 (g)
Slow
(ii) NOBr2 (g) + NO (g)
2NOBr (g)
CHEMICAL KINETICS # 32
19.
(fast)
D + E
B + C
slow)
A + E
D + F
fast)
CH3COOC2H5 + H2O
is 2.8 at room temperature, and the velocity constant of the forward reaction is 0.002. When a catalyst is added
this velocity constant is increased to 0.0045. What is now the velocity constant of the backward reaction?
22.
respectively. If concentrations at equilibrium are [A]eq. and [B]eq. derive an expression for the time taken by B to
attain concentration equal to [B]eq/2 .
CHEMICAL KINETICS # 33
The rate constant for the reaction,2N2O5 4NO2+ O2, is 3 105 s1. If the rate is 2.4 105 mol L1 s1, then
the concentration of N2O5 (in mol L1) is :
[JEE-2000, 1/35]
(A) 1.4
(B) 1.2
(C) 0.04
(D) 0.8
2.
A hydrogenation reaction is carried out at 500 K. If the same reaction is carried out in the presence of a catalyst
at the same rate, the temperature required is 400 K. Calculate the activation energy of the reaction if the catalyst
lowers the activation barrier by 20 kJ mol1.
[JEE-2000, 3/100]
3.
If '' is the intensity of absorbed light and 'C' is the concentration of AB for the photochemical process,
AB + hv AB * , the rate of formation of AB * is directly proportional to
(A) C
(B)
(C) 2
[JEE-2001, 1/35]
(D) C.
4.
The rate of a first order reaction is 0.04 mole litre1 s1 at 10 minutes and 0.03 mol litre1 s1 at 20 minutes after
initiation. Find the half life of the reaction.
[JEE-2001, 5/100]
5.
d [N2 ]
1 d [H2 ] 1 d [NH3 ]
dt
3 dt
2 dt
d [N2 ]
1 d [H2 ] 1 d [NH3 ]
dt
3 dt
2 dt
(B) Rate =
d [N2 ]
d [H2 ]
d [NH3 ]
3
2
dt
dt
dt
(D) Rate =
d [N2 ]
d [H2 ] d [NH3 ]
dt
dt
dt
6.
In the biologically-catalysed oxidation of ethanol, the concentration of ethanol decreases in a first order reaction
from 800 mol dm3 to 50 mol dm3 in 2 104 s. The rate constant (s1) of the reaction is : [JEE-2003, 3/84]
(A) 3.45 105
(B) 1.38 104
(C) 1.00 104
(D) 5.00 105
7.
Given
conc
0.01 0.0025
(mol/lit)
time (min) 0
40
Initial rate of reaction is in mol //min.
(A) 3.43 104
(B) 1.73 104
8.
[JEE-2004, 3/84]
(C) 3.43 105
Initial rates, r0, of the A + B P at different initial concentrations of A and B ([A]0 and [B]0) are given below:
[A]0
[B]0
r0
(a)
(b)
(mol L1)
(mol L1)
(mol L1 s1)
0.1
0.1
0.05
0.2
0.1
0.10
0.1
0.2
0.05
[JEE-2004, 2/60]
CHEMICAL KINETICS # 34
9.
Px (mm of Hg)
(Partial pressure of X)
800
400
200
Find order with respect to X, rate constant of the reaction, time taken for 75% completion and find the total
pressure when partial pressure of X, Px = 700 mm of Hg.
[JEE-2005, 2/60]
10.
Consider a reaction aG + bH Products. When concentration of both the reactants G and H is doubled, the
rate increases by eight times. However, when concentration of G is doubled keeping the concentration of H
fixed, the rate is doubled. The overall order of the reaction is :
[JEE-2007, 3/81]
(A) 0
(B) 1
(C) 2
(D) 3
11.
Under the same reaction conditions, initial concentration of 1.386 mol dm3 of a substance becomes half in 40
k1
seconds and 20 seconds through first order and zero order kinetics, respectively. Ratio of the rate
k0
constant for first order (k1) and zero order (k0) of the reaction is.
(A) 0.5 mol1 dm3
(B) 1.0 mol dm3
(C) 1.5 mol dm3
[JEE-2008, 3/82]
(D) 2.0 mol1 dm3
12.
For a first order reaction A P, the temperature (T) dependent rate constant (k) was found to follow the equation
1
log k = (2000)
+ 6.0. The pre-exponential factor A and the activation energy Ea, respectively, are :
T
[JEE-2009, 3/80]
6 1
1
1
1
(A) 1.0 10 s and 9.2 kJ mol
(B) 6.0 s and 16.6 kJ mol
(C) 1.0 106 s1 and 16.6 kJ mol1
(D) 1.0 106 s1 and 38.3 kJ mol1
13.
Plots showing the variation of the rate constant (k) with temperature (T) are given below. The plot that follows
Arrhenius equation is :
(A)
14.
[JEE-2010, 3/163]
(B)
(C)
(D)
The concentration of R in the reaction R P was measured as a function of time and the following data is
obtained :
[JEE-2010, 3/163]
235
92 U
142
54 Xe
and
90
38 Sr
is :
[JEE-2010, 3/163]
CHEMICAL KINETICS # 35
16.
Bombardment of aluminum by -particle leads to its artificial disintegration into two ways, (i) and (ii) as shown.
Products X, Y and Z respectivey are :
[JEE-2011, 3/163]
17.
18.
An organic compound undergoes first-order decomposition. The time taken for its decompositionto 1/8 and 1/10
of its initial concentration are t1/8 and t1/10 respectively. What is the value of
[JEE-2011, 4/163]
[ t 1/ 8 ]
10? (take log10 2 = 0.3).
[ t1 / 10 ]
[IIT-JEE-2012]
Units of rate constant of first and zero order reactions in terms of molarity M unit are respectively
[AIEEE- 2002]
(1) sec1, M sec1
(2) sec1, M
(3) M.sec1, sec1
(4) M, sec1
2.
For the reaction A + 2B C, rate is given by R = [A] [B]2 then the order of the reaction is : [AIEEE- 2002]
(1) 3
(2) 6
(3) 5
(4) 7
3.
4.
1 dH2 1 d[I2 ]
d[HI]
2 dt
2 dt
dt
(2)
dt
dt
2 dt
(4) 2
dH2
d[I ]
d[HI]
2 2
dt
dt
dt
The rate law for a reaction between the substances A and B is given by rate = k [A]n [B]m. On doubling the
concentration of A and halving the concentration of B, the ratio of the new rate to the earlier rate of the reaction
will be as
[AIEEE- 2003]
(1)
2
5.
dH2
d[I ]
d[HI]
2
dt
dt
dt
[AIEEE- 2002]
mn
(2) (m + n)
(3) (n m)
For the reaction system: 2NO(g) + O2(g) 2NO2(g), volume is suddenly reduced to half its value by increasing
the pressure on it. If the reaction is of first order with respect to O2 and second order with respect to NO, the rate
of reaction will :
[AIEEE- 2003]
(1) diminish to one-fourth of its initial value
(2) diminish to one-eighth of its initial value
(3) increase to eight times of its initial value
(4) increase to four times of its initial value.
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CHEMICAL KINETICS # 36
6.
In the respect of the equation k = Ae Ea/RT in chemical kinetics, which one of the following statements is correct :
[AIEEE- 2003]
7.
In a first order reaction, the concentration of the reactant, decreases from 0.8 M to 0.4 M in 15 minutes. The time
taken for the concentration to change from 0.1 M to 0.025 M is :
(1) 30 minutes
8.
(2) 15 minutes
[AIEEE- 2004]
(4) 60 minutes
The rate equation for the reaction 2A + B C is found to be : rate = k[A] [B]. The correct statement in
relation to this reaction is that the :
[AIEEE- 2004]
The half - life of a radioisotope is four hours. If the initial mass of the isotope was 200 g, the mass remaining after
24 hours undecayed is :
(1) 1.042 g
10.
[AIEEE- 2004]
(2) 2.084 g
(3) 3.125 g
(4) 4.167 g.
Consider an endothermic reaction X Y with the activation energies Eb and Ef for the backward and forward
reaction, respectively. In general
(1) Eb < Ef
11.
12.
(2) H = U
[AIEEE- 2005]
(3) H < U
(4) H > U
[AIEEE- 2005]
A reaction was found to be second order with respect to the concentration of carbon monoxide. If the concentration
of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will be : [AIEEE- 2006]
13.
(2) tripled
(4) doubled
The following mechanism has been proposed for the reaction of NO with Br2 to form NOBr.
NO (g) + Br2 (g)
If the second step is the rate determining step, the order of the reaction with respect to NO(g) is
[AIEEE- 2007, 3/120]
(1) 1
14.
(2) 0
(3) 3
(4) 2
200 kJ mol1 respectively. The presence of a catalyst lowers the activation energy of both (forward and reverse)
reactions by 100 kJ mol1. The enthalpy change of the reaction (A2 + B2 2AB) in the presence of catalyst will be
(in kJ mol1).
(1) 280
(3) 300
(4) 120
CHEMICAL KINETICS # 37
15.
A radioactive element gets spilled over the floor of a room. Its half-life period is 30days. If the initial activity is ten
times the permissible value, after how many days will it be safe to enter the room :
[AIEEE- 2007, 3/120]
(1) 10 days
16.
For a reaction
1
A 2B, rate of disappearance of 'A' related to the rate of appearance of 'B' by the
2
expression.
(1)
17.
d [ A ] 1 d [B]
dt
4 dt
(2)
d [ A ] d [B]
dt
dt
(3)
d[A]
d [B]
4
dt
dt
(4)
d [ A ] 1 d [B]
dt
2 dt
The half life period of a first order chemical reaction is 6.93 minutes. Time required for the completion of 99% of
the chemical reaction will be (log 2 = 0.301) :
(1) 23.03 minutes
18.
The time for half life period of a certain reaction A Products is 1 hour. When the initial concentration of the
reactant A, is 2.0 mol L1 , how much time does it take for its concentration to come from 0.50 to 0.25 mol L1. If
it is a zero order reaction?
(1) 4 h
19.
(2) 0.5 h
(3) 0.25 h
(4) 1 h
B.
(1) B only
20.
(4) A only
The rate of a chemical reaction doubles for every 10 C rise of temperature. If the temperature is raised by 50 C,
the rate of the reaction increases by about :
(1) 10 times
21.
(2) 24 times
[AIEEE-2011]
(3) 32 times
(4) 64 times
For a first order reaction, (A) products, the concentration of A changes from 0.1 M to 0.025 M in 40
minutes. The rate of reaction when the concentration of A is 0.01 M, is
(1) 1.73 10 M/min
3
[AIEEE-2012, 4/120]
(4) 1.73 104 M/min
CHEMICAL KINETICS # 38
PART-NCERT QUESTIONS
1.
From the rate expression for the following reactions, determine their order of reaction and the dimensions of the
rate constants.
(i) 3NO(g) N2O (g)
Rate = k[NO]2
2.
3.
The decomposition of NH3 on platinum surface is zero order reaction. What are the rates of production of N2 and
H2 if k = 2.5 104 mol1 L s1?
4.
The decomposition of dimethyl ether leads to the formation of CH4, H2 and CO and the reaction rate is given by
Rate = k [CH3OCH3]3/2
The rate of reaction is followed by increase in pressure in a closed vessel, so the rate can also be expressed in
terms of the partial pressure of dimethyl ether, i.e.,
Rate = k (PCH3OCH3)3/2
If the pressure is measured in bar and time in minutes, then what are the units of rate and rate constants?
5.
6.
A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of
the reactant is
(i) doubled
(ii) reduced to half ?
7.
What is the effect of temperature on the rate constant of a reaction? How can this effect of temperature on rate
constant be represented quantitatively?
8.
In a pseudo first order hydrolysis of ester in water, the following results were obtained :
(i) Calculate the average rate of reaction between the time interval 30 to 60 seconds.
(ii) Calculate the pseudo first order rate constant for the hydrolysis of ester.
9.
10.
In a reaction between A and B, the initial rate of reaction (r0) was measured for different initial concentrations of
A and B as given below :
CHEMICAL KINETICS # 39
11.
The following results have been obtained during the kinetic studies of the reaction :
2A + B C + D
Determine the rate law and the rate constant for the reaction.
12.
The reaction between A and B is first order with respect to A and zero order with respect to B. Fill in the blanks
in the following table:
13.
Calculate the half-life of a first order reaction from their rate constants given below :
(i) 200 s1
(ii) 2 min1
(iii) 4 years1
14.
The half-life for radioactive decay of 14C is 5730 years. An archaeological artifact containing wood had only 80%
of the 14C found in a living tree. Estimate the age of the sample.
15.
The rate constant for a first order reaction is 60 s1. How much time will it take to reduce the initial concentration
of the reactant to its 1/16th value?
17.
During nuclear explosion, one of the products is 90Sr with half-life of 28.1 years. If 1g of 90Sr was absorbed in the
bones of a newly born baby instead of calcium, how much of it will remain after 10 years and 60 years if it is not
lost metabolically.
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CHEMICAL KINETICS # 40
18.
For a first order reaction, show that time required for 99% completion is twice the time required for the completion
of 90% of reaction.
19.
A first order reaction takes 40 min for 30% decomposition. Calculate t1/2.
20.
For the decomposition of azoisopropane to hexane and nitrogen at 543 K, the following data are obtained.
Calculate the rate constant.
21.
The following data were obtained during the first order thermal decomposition of SO2Cl2 at a constant volume.
SO2 Cl2 (g) SO2 (g) + Cl2 (g)
Calculate the rate of the reaction when total pressure is 0.65 atm.
22.
The rate constant for the decomposition of N2O5 at various temperatures is given below :
Draw a graph between ln k and 1/T and calculate the values of A and Ea. Predict the rate constant at 30 and
50C.
23.
The rate constant for the decomposition of hydrocarbons is 2.418 105 s1 at 546 K. If the energy of activation
is 179.9 kJ/mol, what will be the value of pre-exponential factor.
24.
Consider a certain reaction A Products with k = 2.0 102 s1. Calculate the concentration of A remaining after
100 s if the initial concentration of A is 1.0 mol L1.
25.
Sucrose decomposes in acid solution into glucose and fructose according to the first order rate law, with
t1/2 = 3.00 hours. What fraction of sample of sucrose remains after 8 hours ?
26.
The decomposition of hydrocarbon follows the equation k = (4.5 1011s1) e28000K/T. Calculate Ea.
k = (4.5 1011s1) e28000K/T
27.
The rate constant for the first order decomposition of H2O2 is given by the following equation :
log k = 14.34 1.25 104K/T
Calculate Ea for this reaction and at what temperature will its half-period be 256 minutes?
28.
The decomposition of A into product has value of k as 4.5 103 s1 at 10C and energy of activation
60 kJ mol1. At what temperature would k be 1.5 104 s1?
29.
The time required for 10% completion of a first order reaction at 298K is equal to that required for its 25%
completion at 308K. If the value of A is 4 1010 s1. Calculate k at 318 K and Ea.
30.
The rate of a reaction quadruples when the temperature changes from 293 K to 313 K. Calculate the energy of
activation of the reaction assuming that it does not change with temperature.
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CHEMICAL KINETICS # 41
EXERCISE # 1
A-1.
A-8.
B-5.
B-12.
C-7.
C-14.
C-21.
D-1.
D-8.
E-2.
F-3.
F-10.
G-2.
H-2.
(B)
(B)
(D)
(A)
(D)
(C)
(C)
(B)
(D)
(B)
(A)
(B)
(D)
(B)
A-2.
A-9.
B-6.
C-1.
C-8.
C-15.
C-22.
D-2.
D-9.
E-3.
F-4.
F-11.
G-3.
H-3.
(C)
(D)
(B)
(A)
(B)
(B)
(C)
(B)
(D)
(B)
(A)
(A)
(B)
(B)
1.
8.
15.
17.
19.
26.
33.
40.
47.
54.
61.
65.
70.
(A*)
2.
(D*)
3.
(C*)
9.
(C*)
10.
(A) r ; (B) p ; (C) s; (D) q 16.
(A) s, (B) r, (C) p, (D) q 18.
(C)
20.
(C)
21.
(A)
27.
(B)
28.
F
34.
T
35.
T
41.
T
42.
T
48.
T
49.
T
55.
T
56.
threshold energy
62.
mol L1s1
66.
rare
increases
71.
3
74.
rate = k[M]2
78.
82.
sum, exponents
1.
8.
15.
22.
29.
36.
43.
(C)
(D)
(B)
(C)
(D)
(D)
(ABC)
75.
A-3.
A-10.
B-7.
C-2.
C-9.
C-16.
C-23.
D-3.
D-10.
E-4.
F-5.
F-12.
G-4.
H-4.
1
2
PART # I
A-4.
(A)
B-1.
(B)
B-8.
(B)
C-3.
(B)
C-10. (C)
C-17. (B)
C-24. (C)
D-4.
(D)
D-11. (C)
E-5.
(B)
F-6.
(C)
F-13. (C)
G-5.
(C)
H-5.
(B)
(B)
(C)
(B)
(D)
(D)
(B)
(C)
(D)
(C)
(A)
(C)
(D)
(D)
(B)
A-5.
B-2.
B-9.
C-4.
C-11.
C-18.
C-25.
D-5.
D-12.
E-6.
F-7.
F-14.
G-6.
H-6.
(D)
(D)
(B)
(D)
(C)
(B)
(C)
(A)
(C)
(B)
(D)
(B)
(A)
(B)
A-6.
B-3.
B-10.
C-5.
C-12.
C-19.
C-26.
D-6.
D-13.
F-1.
F-8.
F-15.
G-7.*
(D)
A-7.
(D)
B-4.
(D)
B-11.
(B)
C-6.
(C)
C-13.
(A)
C-20.
(A)
C-27.
(C)
D-7.
(B)
E-1.
(A)
F-2.
(A)
F-9.
(D)
G-1.
(ABCD) H-1.
PART # II
(B*)
4.
(A*)
5.
(C*)
6.
(A*)
7.
(B*)
11.
(B*)
12.
(A*)
13.
(C*)
14.
(A) p, q, r, s ; (B) q, r, s ; (C) p, q, r, s ; (D) p, r, s
(A) r ; (B) s ; (C) p ; (D) q
(D)
22.
(A)
23.
(C)
24.
(A)
25.
(A)
29.
(A)
30.
(B)
31.
F
32.
F
36.
F
37.
T
38.
T
39.
T
43.
F
44.
F
45.
F
46.
F
50.
T
51.
T
52.
T
53.
F
57.
F
58.
T
59.
T
60.
half
63.
equal to H
64.
directly proportional
67.
lowering
68.
fast
69.
slowest
72.
rate constant
73.
2 and 3
76.
77.
79.
first
80.
k
2.303
81.
unchanged
6.
13.
20.
27.
34.
41.
(B)
(D)
(B)
(A)
(C)
(ACD)
(B)
(C)
(D)
(B)
(B)
(B)
(C)
(A)
(A)
(C)
(A)
(C)
(B)
(C*)
(C*)
(C)
T
F
T
F
F
EXERCISE # 2
2.
9.
16.
23.
30.
37.
44.
(C)
(C)
(B)
(C)
(C)
(C)
(CD)
3.
10.
17.
24.
31.
38.
45.
(C)
(B)
(D)
(D)
(C)
(C)
(ABC)
4.
11.
18.
25.
32.
39.
(D)
(B)
(D)
(C)
(A)
(D)
5.
12.
19.
26.
33.
40.
(B)
(C)
(B)
(A)
(B)
(AD)
7.
14.
21.
28.
35.
42.
(A)
(A)
(D)
(B)
(D)
(AC)
SUBJECTIVE
1.
3.
5.
6.
7.
2.
4.
CHEMICAL KINETICS # 42
8.
9.
10.
(i) 2nd order, (ii) 1st order, (iii) Third order, (iv) r = K[A]2[B] (v) k = 3.33 105 mole2 +2 sec1
order with respect to A = 1, order with respect to B = 0
3
11.
(a)
n = 2,
(b)
First Order
12.
13.
2P0
15.
( V3 V1)
1
ln ( V V )
t
3
2
16.
% decomposition = 67.10%
18.
19.
(a) 2 B+F 2E; (b) A; (c) C,D; (d) rate = k [B][C]; (e) rate = k'[A][B] (f) 2.
21.
0.001607
22.
t=
(2 P0 P)2
P0
14.
k [N2O5]
0.693
K f Kb
EXERCISE # 3
PART-I
1.1
1.7
1.9
1.10
1.16
1.5
(A)
1.6
(B)
1.14
1.15
(3)
(3)
(4)
2.6
2.13
2.20
(3)
(4)
(3)
2.7
2.14
2.21
n2
= 6.93 103 min1.
t1/ 2
PART-II
2.1
2.8
2.15
(1)
(4)
(2)
2.2
2.9
2.16
(1)
(3)
(1)
2.3
2.10
2.17
(4)
(1)
(2)
2.4
2.11
2.18
(4)
(1)
(3)
2.5
2.12
2.19
(1)
(2)
(2)
EXERCISE # 4
1.
3.
4.
5.
9.
1.471 1019
2.
6.
1.925 104 s1
8.
Ea = 52.897 kJ mol1
CHEMICAL KINETICS # 43