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03.01.2011 | Khazrai, F. , Chagalesh Consulting Engineers, Tehran, Iran; Haghighi, H. B. , Chagalesh Consulting
Engineers, Tehran, Iran; Kordabadi, H. , Chagalesh Consulting Engineers, Tehran, Iran
Key points identify effects from auto-refrigeration on steel vessels
Keywords:
During an emergency, equipment failure or a planned maintenance event, hydrocarbon-processing industry (HPI) pressure
vessels are normally depressurized. This action may cause auto-refrigeration and low-metal temperature situations in which
the likelihood of brittle fracture may occur in steel vessels and reactors. This case history describes the results from a
simulation regarding auto-refrigeration effects on HPI reactors. The study also included investigation on brittle-fracture
phenomenon and recommendations for a proactive engineering approach to mitigate such failures. Key points highlighted
from the study are:
Although the process-fluid temperature from auto-refrigeration drops to 86C, considering the vessels metal-mass heat
capacity and ambient temperature, the short-term vessel minimum metal temperature does not become colder than 28C.
Therefore, selecting expensive material of construction can be avoided.
Complying with the ASME rules or other internationally recognized codes for minimum requirements is crucial to the
structural integrity of a pressure vessel. However, proactive engineering practices and precautions pertaining to the design,
materials, fabrication, nondestructive examinations and operation are also required to ensure that the vessels are resistant
to brittle fracture.

Process engineering
This case study focuses on a gas field production facility, which uses several separation vessels and a stabilization unit to
obtain dew-point control for the natural gas products and Rvp-controlled condensate products. The process vessels operate
as three-phase separators containing vapor, light-liquid hydrocarbons and heavy-liquid phase. The study focused on the
simulation and design of three interconnected separation vesselsV-100, V-101 and V-102 (Fig. 1).

Fig. 1. Flow diagram of three vessels for the

separation process of the gas plant.

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Since in accordance with API 521, all process equipment with operating pressure higher than 18 barg must be depressurized
in case of an incidence, the fluid pressure should be reduced to 6.9 barg and the blowdown lines including the restricted
orifice were designed based on depressurizing to 6.9 barg within 15 minutes.4 In practice during depressurization and
blowdown events, the actual vessel-fluid pressure drops from operating pressure (initial pressure) down to almost
atmospheric pressure (final pressure). The general assumptions and process design basis parameters used in the simulation
include:
Minimum ambient temperature of 13C is the minimum outer metal-wall temperature of the vessels
PV work term contribution is defined as isentropic expansion efficiency and assumed as 100% (a conservative
assumption)
Construction material is carbon steel
Other design basis parameters are listed in Table 1.

The first simulation was done without including the vessels metal mass. In other words, the control volume of
depressurization study was limited to the fluid inside the vessel, and the metal-wall temperature was assumed to be the same
as the inventory fluid temperature. Also, the temperature difference between vapor and liquid was assumed to be negligible.
Table 2 lists the final fluid temperatures obtained in the first simulation.
In the second depressurization simulation, the metal mass of each vessel was included in the control volume of the model.
Table 3 shows the results of the second simulation based on the metal mass values. As shown in Table 3, the calculated
inner-wall temperatures are considerably higher than the calculated fluid final temperatures listed in Table 2 from the first
simulation.

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The simulation work indicates that including the metal-mass heat capacity into evaluation increases the accuracy of
estimated minimum metal temperature of the vessels. Consequently, more accurate vessel wall temperatures aid
cost-effective selection of construction materials for the separation vessels.

Mechanical engineering
All three separation vessels were designed using ASME Code Section VIII , Division 2. Table 4 lists the design data for the
separation vessles.5

MDMT of vessels.
The minimum design metal temperature (MDMT) of a vessel is the minimum metal temperature in which the vessel can
sustain its full design pressure without having to be impact tested. When the vessel operates at pressures less than its full
design pressure, concessions on MDMT are allowed based on ASME Section VIII. Table 5 lists the result of MDMT
calculations for this studys vessels based on ASME, Section VIII, Div. 2.
Minimum allowable temperature (MAT), as defined in API 579, is the lowest (coldest) permissible metal temperature
for a given material and thickness based on its resistance to brittle fracture. It may be a single temperature or an envelope of
allowable operating temperatures as a function of pressure.6 The MAT is derived from mechanical design information and
material specification. MAT at design pressure is MDMT.
Lowest metal temperature (LMT). LMT as defined and used in this article is the lowest metal temperature due to the
operating condition and minimum ambient temperature. The LMT may be a single temperature at an operating pressure or
an envelope of temperatures and coincident pressures. Actually, the LMT, in this case, is derived from the calculated inner
wall temperature due to the contained process fluid temperature and also the minimum ambient temperature. The LMTs of
the vessels coincident with final pressures (after depressurization and blowdown) are shown in Table 6.

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As shown in Figs. 24 and Table 6, the LMTs for all of the vessels at the final pressure as well as other coincident pressures
are on the safe side based on the rules and design philosophy of ASME Section VIII Div. II. Although the code requirements
have been satisfied, further considerations and precautions are required to ensure the design and construction of the vessels
are resistant against brittle fracture. Several key factors in combination can contribute to brittle fracture of steel vessels; a
proactive engineering approach is recommended.

Fig. 2. LMT curve for vessel, V-100, during

depressurization event.

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Fig. 3. LMT curve for vessel, V-101, during

depressurization event.

Fig. 4. LMT curve for vessel, V-102, during

depressurization event.

Brittle fracture phenomena

The major concern for low-temperature vessels is brittle-fracture phenomenon, which can be a cause for vessel failure. Many
metals loose their ductility and toughness; they become susceptible to brittle fracture as the metal temperature decreases. At
normal or higher temperatures, a warning is normally given by plastic deformation (bulging, stretching or leaking) as signs
of potential vessel failure. However, under low-temperature conditions, no such warnings of plastic deformation are given.
Unfortunately, an abrupt fracture can cause a catastrophic event.
Only materials that have been impact tested to ensure metal toughness at or above a specified metal temperature should be
used. However, certain paragraphs in the ASME Pressure Vessel Code applying to low-temperature vessels indicate when
impact testing may not be required for a pressure-vessel component material (impact test exemptions). In general, four
main factors, in combination, can cause brittle fracture of steel vessels. These factors are represented in the form of brittle
fracture square as shown in Fig. 5. The factors that contribute to the brittle fracture of carbon or low-alloy steel pressure
vessels are reviewed briefly here:

Fig. 5. Brittle fracture square affecting carbon

and low-alloy steels at low temperatures.

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Low temperature.
A metal depending on its toughness property has a transition temperature range within which it is in a semi-brittle condition
(ductile to brittle transition). Within this range, a notch or crack may cause brittle fracture (notch brittleness). Above the
transition range (warmer), brittle fracture will not happen even if a notch exists. Below the transition range (colder), brittle
fracture can happen even though no notches or cracks may exist.3 Although the transition from ductile to brittle fracture
actually occurs over a temperature range, a point within this range is selected as the transition temperature to delineate
the boundaries of ductile and brittle zones. One of the ways to determine this temperature is by performing many impact
tests on the construction material.
Loading.
The type and level of mechanical/thermal loading will affect the vessels susceptibility to brittle fracture. Dynamic loading
associated with cyclic mechanical/thermal or impact loading, as opposed to quasi-static loading, is a brittle-fracture
contributing factor. Furthermore, shock-chilling effects, defined as rapid decreases in equipment temperatures, can be a
cause for brittle fracture.6 Based on the stress levels applied (in a quasi-static loading), component material, effective
thickness and minimum metal temperature, ASME Section VIII, Divisions 1 and 2 present criteria for vessel-component
material-impact test requirements and/or exemptions.
Susceptible steel.
Susceptibility of steels depends on several parameters such as poor toughness, material flaws (cracks and notches),
corrosion vulnerability, large thickness, etc.:
Steel composition. Steels with lower carbon content (C) are proven to have higher toughness at lower temperatures.
Also, phosphorous (P) present in steels decreases the transition temperature of steel and improves weldability. In general,
steel-transition temperature is a function of carbon content percent plus 20 times the percentage of phosphorous.
Furthermore, adding nickel to steel can increase steel toughness and decrease its transition temperature. Stainless steel 304
with 8% nickel can resist impact loads at 320F. Furthermore, sufficiently low carbon equivalents contribute to the
weldability of the material (reducing hardness and cold-cracking susceptibility) and, thus, making metal crack-free girth
welds.4 Selecting the appropriate welding material also is a determining factor to ensure a crack-free weld.3
Steel structure. A correlation was developed between steel structure (microstructure and grain size) and fracturetoughness by numerous fracture toughness tests at different low temperatures. Based on this correlation, steels with coarsegrained microstructures have lower toughness at low temperatures as compared to steels with the fine-grained
microstructure. During an 1999 incidence with a high-density polyethylene (HDPE) reactor, a brittle fracture occurred at a
temperature of 12C in a 24-in. flange of ASTM A105 material that had a coarse-grain microstructure (ASTM grain size
number 5 to 6 ferrite-pearlite microstructure ).1a
Hydrogen cracks (hydrogen-induced cracks or so-called flakes). When hydrogen atoms diffuse into the metal during
material manufacturing operations such as forming, forging and welding or when hydrogen is introduced to the metal
through a galvanic or hydrogen sulfide (H2S) corrosion process, the metal is prone to hydrogen cracks.
There are various techniques to prevent hydrogen cracks, including appropriate heat treatments or slow cooling after
forging, in which the hydrogen within the metal diffuses out. In the case of welding, usually pre-heating and post-heating are
applied to diffuse out the hydrogen and to prevent any cracks and brittleness.
Environmental stress fracture. Steels exposed to corrosive fluids such as wet H2S, moist air or sea water are prone to
premature fracture under tensile stresses, considerably below their fracture toughness threshold. Suitable steel materials
should be used when exposure to corrosive fluids is possible.
Crack/stress risers.

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Steel vessels with thicker walls have a greater probability potential for brittle fracture due to the larger thermal gradient
across the wall thickness. Thicker metal walls can result in differential expansion of material across the wall thickness and
could possibly lead to a crack occurrence and eventually brittle fracture.
Stress raisers such as sharp or abrupt transitions or changes of sections, corners or notches (as may be found in weld
defects) as a result of design or fabrication processes are all stress risers, which can cause stress intensification. The weak
points are prone to brittle fracture when other susceptible conditions exist.

Proactive engineering
Based on the brief technical information given here, several proactive measures can ensure resistance of carbon or low-alloy
steel vessels against brittle fracture under quasi-static loading:
Design pressure vessels, if justifiable, by analysis in accordance with the ASME Section VIII, Div 2 part 5, or other
internationally recognized codes that result in lower wall thicknesses.
Order vessel materials from reliable and capable manufacturers. Key vessel components still require attention to proper
heat treatment, avoiding hydrogen cracks, quality control, etc.
Specify fine-grain steel materials with appropriate specifications and require production tests for plate/piece (from the
same heat) if an impact test is not requested. Ensure that the steel with fine-grain microstructure/toughness is supplied; do
not rely just on the material certificates. Also, conduct impact tests on test pieces to verify required toughness.
Take benefit of the recommendations contained in the document indicated in reference 1 for ordering pipe flanges made in
forged steel complying with ASTM A105.
Ask the material manufacturer for effective construction/fabrication methods such as vacuum degassing to prevent
hydrogen-crack formation in the metal and require stringent nondestructive examinations and quality control.
Do nondestructive testing (NDT) to identify cracks or reject materials with detectable cracks.
Eliminate stress risers, at the design and fabrication stages
Verify full-penetration welds with adequate toughness using appropriate welding material/processes and require
weld-procedure qualification and production-weld test specimens for both the weld and heat-affected zone for each weld
process.c
Conduct proper vessel post-weld heat treatment (PWHT), preferably in a furnace in one piece whenever practical, and
examine heat-affected zone hardness to ensure the beneficial effects of the performed PWHT.d
Perform the vessel hydrostatic test in accordance with the rules of the ASME Section VIII Code or other internationally
recognized codes.b
Apply control of operation proactively, whenever practical, (e.g., after a depressurizing to ensure that the vessel metal
temperature is sufficiently warm prior to re-pressurization).
A proactive engineering program, as envisioned in Fig. 6, can incorporate the listed measures during vessels design,
procurement and construction stages. HP

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Fig. 6. Proactive engineering program in

designing and manufacturing vessels to avoid
brittle fracture from auto-refrigeration.

NOTES
a

Research was conducted by the Belgian Institute for Welding Techniques on pipe flanges made in forged steel complying
with ASTM A105. In June 2002, the study produced a series of recommendations for new flanges as well as flanges already
in service.1

The beneficial effect of a hydrostatic test is that crack-like flaws located in the component are blunted resulting in an
increase in brittle fracture resistance.6

Requiring full penetration would minimize any highly localized stresses (especially at Category C and D joints) that can
have deleterious effect on the vessels ability to resist brittle fracture.2

Carbon equivalent in terms of welding is a rate of weldability related to different alloying elements including carbon,
manganese, chromium, molybdenum, vanadium, nickel and carbon content, which affect hardness of the steel being welded.

Fracture toughness is an important property of any material for virtually all design applications; it indicates the ability of a
material containing a crack to resist fracture.
f

Proper PWHT reduces residual stresses, improves the resistance of the hard heat affected zone to environmental cracking,
and improves the toughness.
LITERATURE CITED

Recommendations for pipe flanges made in forged steel complying with ASTM A105, July 2002, Chemical Risks
Directorate, Technical Inspectorate, Administration of Labor Safety, Federal Ministry of Employment and Labor.
2 Rao, K. R., Companion guide to the ASME Boiler & Pressure Vessel Code.
3 Brownwell, L. E. and E. H. Young, Process Equipment Design.
4 Pressure-relieving and Depressuring Systems, ANSI/API STANDARD 521, Fifth Edition, January 2007.
5 2007 ASME Boiler and Pressure Vessel Code, Section VIII, Division 2, Alternative Rules for Construction of Pressure
Vessels.

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Fitness-For-Service, API 579 -1/ASME FFS-1, June 5, 2007, Part 3.

The authors

Faramarz Khazrai has worked as a mechanical engineer for over 30 years in the areas of piping, static
equipment and machinery. In 1986, he joined Chagalesh Consulting Engineers, Tehran, Iran, and supervised
mechanical engineering activities of several hydrocarbon processing projects. Currently, he is the machinery
department head. He graduated from the Sharif University of Technology with BS degree in mechanical
engineering in 1972.

Hamed Basir Haghighi is a mechanical engineer specializing in the area of static equipment engineering.
He has participated in various hydrocarbon processing projects at Chagalesh Consulting Engineers since
2001. Currently, he is the static equipment project specialty leader and also project engineering manager.
His fields of specialization are detail design of static equipment, composite material selection and finite
element method. He graduated from Azad University of Tehran with BS and MS degrees in mechanical
engineering.

Hojat Kordabadi, as a process engineer, has participated in the design of various process plants
pertaining to the hydrocarbon processing industry. He joined Chagalesh Consulting Engineers in 2007 and
has worked in the process engineering department as a project specialty leader. He is the author of three
technical paper published in the Chemical Engineering Journal (April 2005, December 2007, September
2008). He holds a BS degree in chemical engineering from Amir Kabir University and a M.S. degree in
chemical engineering from Shiraz University, Shiraz, Iran.

Moemen
04.13.2016
I need advice for below vessel case to calc. inner wall temp. C:
Composition: C1=77.98,C2=10.96 C3=5.3.IC4=0.8,NC4=0.99,C5=0.2
Initial conditions , P= 31kg/cm2 T= -84C
Final pressure 1 kg/cm2
Vessel material SA-240 304L
Weight 58.18 Ton Without fluid
Volume 64 m3
Thickness 49 mm
design pressure 36 kg/cm2
Liquid molar flow = 7292.15 kmole/hr
Vapor molar flow = 2393.41 kmole/hr
your advice is highly appreciated
Abtin
01.21.2016

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Good Article thanks for sharing the knowledge.

I think, in Fig6, LMT>MAT is correct, since both of them are negative numbers.
Abtin
Antoinette Renouf
02.21.2015
Dear Faramarz
Iain and I are so glad to hear that you have a successful career in engineering. You were always a good student. Perhaps you
could email me for a personal chat?
Robert
09.20.2014
We are trying to identify if it is possible to convert a S stamped pressure vessel which is NB registered for a application in
which it would be used for hydrocarbon processing (conversion to a separator)
the vessels in question are new units and are rated for high temperature applications. Is their anything in the Code that
prevents S stamped vessels from being used for hydro carbon application specifically. Does the ASME S Stamp meet or
exceed the ASME U stamp or are they both designed for separate application ?
Mounir
05.01.2013
referring to the article, my understanding is that ordinary carbon steel is still recommended for low temperature service of
-28C. i need a confirmation.
Flow Tech Equipments
04.12.2013
I have registered my company profile in your company only in the near past. But results are very fruitful and productive.
Thanks to your great service.
My company Site-http://www.flowtechequipments.com

04.15.2011
As one of the authors of this article I would like to mention that the article actually does not claim A105 is a suitable
material for low temperature application. ASTM standard states that A105 is to be used for ambient temperature and
higher, but it does not indicate which ambient temperature on our earth. AS far as low temperature is concerned I believe
the article is quite more conservative than ASME section 8 or ASTM A105. Reading the reference 1 (literature cited) of the
article is highly recommended.
Faramarz Khazrai

04.12.2011
I appreciate the comments.
I would be pleased to summarize my understanding from "ASME VIII Division 2" for this case in paragraph below:
As explained in section 3.11.2.7, "Vessels or components may be operated at temperatures colder than the MDMT stamped
on the name- plate", but not lower than -104C and under specific conditions. Actually, MDMT is a function of "Design
Load" which includes pressure and several other items. As I see it, the decreasing the Design Load, the MDMT reduces.

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I agree that review the dynamic of Design Load would be over-collaborated as a general procedure; also, some
considerations in Design Philosophy (i.g. Re-pressurizing) do not allow pressured systems to be operated below MDMT
stamped on the name-plate. Indeed, this paper is a review for a more sophisticated material selection that is applicable in
special cases such as Brownfield projects.
H Kordabadi

04.09.2011
As one of the authors of this article I would like to mention that the article actually does not claim A105 is a suitable
material for low temperature application. ASTM standard states that A105 is to be used for ambient temperature and
higher, but it does not indicate which ambient temperature on our earth. As far as low temperature application is concerned
I believe the article(in proactive engineering part) is quite more conservative than ASME Section 8 code or ASTM A105.
Reading the reference 1 (literature cited) of the article is highly recommended.

04.06.2011
Regarding the comments of D.M. Barny on this article, though the ASTM standard directly indicates A105 specification
covers ambient and higher-temperature service in pressure system , the ambient temperature of many facilities during
winter time may reach as low as -30oC or lower. ASTM does not indicate which ambient temperature.

04.06.2011
concise ,clear and to the point
Good article for a mechanicalengineer like me ... to understand what the process is cooking

03.25.2011
Gentlemen:
The definition of MDMT given in the article is not with the ASME Code definition.
Otherwise - very interesting article, thank you!
Regards,
Oleg A. Barsky, P.E.

03.21.2011
I had a free time to read the content of this article and decided to write following comments:
1-How the authors can claim that A105 is a suitable material for low temperature applications? I bring their attention to the
ASTM standard where it directly indicate A105 can be only used for ambient or above temperature and not low temperature.
2-The authors have specified some conditions for using A105 in "proactive engineering part" . I should note if we are to use a
material with these conditions then we surely use a low temperature one and not a simple carbon steel!
3- I do not know if the authors have seen the impact test results for the ordinary carbon steel materials in the laboratory?
The results show the absorbed energy of between 3-7 J for the temperature in the range of -5 to -10 degree. Therefore, I am
really in doubt if we can use A105 or equivalent material for low temperature applications.
Thank you and I remain with:
Kind Regards,
D.M.Barny

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03.21.2011
I had a free time to read the content of this article and decided to write following comments:
1-How the authors can claim that A105 is a suitable material for low temperature applications? I bring their attention to the
ASTM standard where it directly indicate A105 can be only used for ambient or above temperature and not low temperature.
2-The authors have specified some conditions for using A105 in "proactive engineering part" . I should note if we are to use a
material with these conditions then we surely use a low temperature one and not a simple carbon steel!
3- I do not know if the authors have seen the impact test results for the ordinary carbon steel materials in the laboratory?
The results show the absorbed energy of between 3-7 J for the temperature in the range of -5 to -10 degree. Therefore, I am
really in doubt if we can use A105 or equivalent material for low temperature applications.
Thank you and I remain with:
Kind Regards,
D.M.Barny

03.08.2011
thanks mr bassir haghighi,hamed

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