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Group 2
1 Trends N RXNs
Oxidation Numbers
Atomic Radius
Ionisation Energy
Melting/Boiling Points
Solubility
Reactivity/Reducing Power
Inorganic Chemistry
M + O2 = MO (Oxide)
Very slow, Slow, Fast, Explosive
Magnesium burns with brilliant white flame, Calcium burns with brick-red
flame, strontium burns with crimson-red flame, barium burns with green
flame
M + H2O = M(OH)2 + H2
Magnesium reacts with steam to give oxide and cold water to give hydroxide
Very slow with cold, slow with cold, vigorous with cold, very vigorous with
cold
Remember solubility of hydroxides increases down the group, so more
alkaline as well.
MO + H2O = M(OH)2
Lattice energy decreases down the group due to cation radius, reaction with
water increases
Reacts very slowly with cold water, rapidly with heat given off, vigorously
with heat given off, very vigorous reaction with a lot of heat given off
Talk about solubility as well
Inorganic Chemistry
Group 7
2 Trends N RXNs
Oxidation Numbers
Bond Energy
First IE
Electron affinity
Inorganic Chemistry
Electronegativity
F2 + H2O = HF + O2
F2 + H2O = HF + O3
Fluorine reacts EXPLOSIVELY with cold water to give HF and
oxygen/ozone
CL2 + H2O = HCL + HOCL (disproportionation)
Br2 + H2O = HBR + HOBR (To a smaller extent)
Inorganic Chemistry
Displacement (Redox)
More reactive halogen can displace less reactive one from its salt
More disproportionation redox with alkalis and metals [LO] RXN of CHLORINES
with cold and hot aq NAOH
Inorganic Chemistry
Decomposition of Hydrogen Halides [LO] Thermal stability of hydrides and
interpret in terms of bond energies
Acid Strength
Precipitation reaction with Silver Nitrate and Ammonia [LO] RXN of halides with
ammonia, Ag
CL- ions react with AGNO3 to give white ppt, Br- cream, I- yellow ppt
Ag+ + NH3 = [Ag(NH3)2]+ (Position of equilibrium shifts)
Key concept is dissolving requires ionic product to be lower
than Ksp
React with PB2+ ions to give PBX(s) which is only a yellow ppt with I
and white with rest
May be soluble upon addition of excess halides due to formation of
PB2+ + X- = [PBX4]2- complex ion
Reactions with concentrated sulfuric acid [LO] RXN with conc. Sulfuric acids
Inorganic Chemistry
Periodicity
3 Trends N RXNs
Reaction of period 3 with oxygen gas [LO] Describe rxn of elements with
oxygen
Inorganic Chemistry
Sulfur burns on gentle heating with pale blue flame to form SO2. SO2
can be further oxidized to give SO3.
Chlorine does not react.
Reaction of period 3 with chlorine gas [LO] Describe rxns of elements with
chlorine
Sodium and magnesium burn readily in chlorine gas to give white ionic
solid. Highly exothermic.
Aluminium only reacts when dry chlorine gas is passed over heated
aluminium foil. RXN is slow at room temperature. Pale yellow ALCL3
powder produced that fumes. Form AL2CL6 dimers as well.
If chlorine passed over HEATED silicon powder, can form silicon
tetrachloride.
Burns vigorously with chlorine gas to produce PCL3 and PCL5. Excess is
used to favour PCL5 (pale yellow solid)
Rest not in syllabus
General Trends
Inorganic Chemistry
Ionisation energy of non-metals high, high tendency to form
covalent bonds with oxygen
Melting Points
o Melting points of NaO and MgO high due to giant ionic lattice
with strong electrostatic forces of attraction between oppositely
charged ions
o Melting point of MgO higher due to stronger lattice energy due
to higher charge density, more energy needed to break apart
lattice
o Melting point of Al2O3 lower due to high charge density of
Aluminium cation, leading to polarization of anions electron
cloud, covalent character, weaker lattice energy
o SiO2 is a giant covalent structure, strong covalent bonds holding
atoms together. Each SI bonded to 4 O and each O bonded to 2
Si.
o Melting point of SO2 and P4O6 lower due to simple covalent
structure and weak VDW/D.F
Acidity. Fundamental concept of acidity deals with O2- ion hydrolyzing
in water to produce hydroxide ions
Ionic oxides are always basic [LO] Describe reaction of oxides with
water and acid base behavior of oxides and hydroxides
o NaO will dissolve fully and exothermically and vigorously in
water to give Na+ and OH- ions
o Strongly alkaline at PH13
o Also reacts with acids to produce Na+ and H2O
o MgO reacts slower and limited solubility with water due to higher
LE to give magnesium hydroxide/oxide in steam. PH is lower at 9
due to limited solubility
o MgO also reacts with acids to give Mg2+ and H2O
o Sodium Hydroxide, magnesium hydroxide react with acids to
give salt and water in neutralisation reaction
Amphoteric Oxides
o Al2O3 is insoluble in water (so does not react as previously
mentioned)
o Reacts with acids to form Al3+ ad H2O
o Reacts with STRONG excess bases and H2O to give [Al(OH)4]o Aluminium Hydroxide also reacts with acids to give Al3+ and
H2O
o Dissolves in excess strong bases to similarly form same ion. (No
water in equation)
Acidic Oxides
o Sio2 does not react with water
o Reacts with hot and concentrated strong bases before SiO32and h2o formed
o P4O6 reacts with cold water spontaneously to give acidic
solution of H3PO3
o
Inorganic Chemistry
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Reactions of chloride with water (Think about salt hydrolysis) [LO] RXN of
chlorides with water