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a,*
a
Escola de Engenharia de Lorena, Universidade de Sao Paulo, P.O. Box 116, CEP 12602-810 Lorena/SP, Brazil
Divisao de Materiais, Instituto de Aeronautica e Espaco, Comando Tecnico Aeroespacial, Pc Mal do Ar Eduardo Gomes,
50, Vila das Acacias, 12228-904, Sao Jose dos Campos, SP, Brazil
Received 28 December 2004; received in revised form 23 November 2006; accepted 14 January 2007
Abstract
The compression and injection molding processes were performed in order to evaluate the better mixer method for ber (sugarcane
bagasse, bagasse cellulose and benzylated bagasse) and matrix (polypropylene). The samples (composites and polypropylene plates) were
cut and submitted to mechanical tests in order to measure exural and tensile properties. The morphological and microstructural analyses of fracture surface and specimens from composites can be easily evaluated by microscopic techniques. The fracture surface was evaluated by SEM and selected specimens from composites were analyzed by reected light in OM. The better tested method for composites
obtainment was the injection molding under vacuum process, by which composites were obtained with homogeneous distribution of
bers and without blisters. The mechanical properties show that the composites did not have good adhesion between ber and matrix;
on the other hand, the ber insertion improved the exural modulus and the material rigidity.
2007 Elsevier Ltd. All rights reserved.
Keywords: A. Polymermatrix composite (PMCs); B. Microstructure; D. Mechanical testing; E. Injection molding
1. Introduction
Polymeric composites may be understood as the combination of two or more materials, for example, reinforcement elements or ller involved by a polymeric matrix
[1]. The introduction of bers (treated or in natura) into a
polymer is known to cause substantial changes in the
resulting composites [2,3], which may result, dierently
from the original materials, in good mechanical properties
and rigidity [4].
In recent years, studies about the utilization of lignocellulosic materials as reinforcement in polymeric composites
are increasing due to the improvements that natural bers
can provide to the product, such as low density and biodegradability, besides the fact that these materials are from
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lms, polymer in powder or granules, utilizing the mechanisms of compression molding by heating and injection
molding [1,11,12]. In these two mechanisms, the bers are
placed in intimate contact with the matrix.
Thermoplastic polymers are materials thoroughly used
in emergent technologies having low processing cost and
density, among other properties, such as transparency
and possibility of recycling [13]. Polypropylene (PP) was
the thermoplastic polymer used in this work, being a
semi-crystalline polymer and an important engineering
thermoplastic with various industrial applications [14],
but it is also a commodity polymer by the low cost, low
level of mechanical resistance, processing facility and larger
production [15]. Therefore, the combination of lignocellulosic material with thermoplastic matrix can present a considerable problem: incompatibility between the polar and
hygroscopic ber and the non-polar and hydrophobic
matrix. The possible solution for this problem has been
studied through the chemical modication of bers due
to the presence of hydroxyl groups, very reactive and susceptible to chemical reactions. Non-polar groups can be
inserted in the bers, resulting in hydrophobic characteristics compatibles with thermoplastic matrices [1,16,17].
Other alternative to improve the compatibility between
ber and matrix is to modify the matrix, for example, with
maleic anhydride [18].
Recent studies in respect to mechanical behavior of reinforcement bers in composites show that these materials
can present structural and non-structural applications.
The synergetic characteristics of composite materials
depend on the initial characteristics of the reinforcement
or the matrix [2]. Damage in the composites is associated
to matrix crack, failed interfacial bond between ber and
matrix, ber break and delamination. Composites fracture
surfaces have been studied by scanning electron microscopy (SEM), due to the great depth of focus exhibited by
this technique. Specimens are fractured by normal physical
testing procedures and SEM is used to evaluate size, distribution and adhesion of the ller bers or particles. The nature of adhesion between the matrix and the reinforcement
and information relating the structure of mechanical properties can be obtained by SEM assessment of the composite
fracture surface [19].
Reected light microscopy is a typical optical microscopy (OM), which provides an overview of composite
microstructure. Specimens are polished and examined in
reected light, generally at magnications about 30500
[19]. The strength of ber-reinforced composite depends
on the ber length and orientation, on the proportion of
bers in the matrix and on interfacial bond between the
ber and matrix [19].
This work aimed to evaluate the mechanical characteristics of PP-composites obtained by compression and
injection molding processes utilizing the bagasse, benzylated bagasse and bagasse cellulose as reinforcement. Some
composites were analyzed by SEM and OM techniques in
order to evaluate the morphological characteristics of
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Table 1
Properties of the materials obtained by compression molding
Samples
Polypropylene (PP)
Bagasse (5.0%)/PP composite
7.2 1.2
3.0 0.3
27.4 1.6
18.7 2.2
991.6 57.8
1001.9 95.7
7.9 0.4
6.9 0.5
25.3 1.0
19.2 3.1
Polypropylene (PP)
Bagasse (5.0%)/PP composite
Reinforcement in wt%.
241.9 18.4
223.8 21.4
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Tensile
Sawdust (20%)/PP
Flexural
10
11
12
13
Tensile
Sawdust (20%)/PP
Flexural
12
16
20
24
28
32
Strength (MPa)
Sawdust (20%)/PP
Cellulose bagasse (6.7%)/PP
Benzylated bagasse (10%)/PP
Bagasse (10%)/PP
Bagasse (8.7%)/PP
Tensile
Polypropylene (PP)
0
Flexural
200
400
600
800
1000
1200
1400
Modulus (MPa)
Fig. 2. SEM of fracture surfaces of injected polypropylene: (a) lateral detail exhibits classical brittle fracture, and (b) detail of extremity of specimens
fracture exhibits a ductile fracture.
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Fig. 3. SEM of fracture surfaces of bagasse/polypropylene composite injected under vacuum. (a) Morphology of composite fracture surfaces towards the
bagasse the presence exhibits of brittle fracture. (b) Morphology of composite fracture surfaces exhibits the limit region between ber and matrix (brittle
fracture). (c and d) Higher magnication of limit region between ber and matrix.
Fig. 4. Optical micrograph with reected light of composite polished surface (bagasse/polypropylene). (a) 50 Magnied micrograph exhibits the bagasse
forms and distribution within the matrix. (b) 100 Magnied micrograph shows the detail of limit region between ber and matrix.
decreased 50% and 42%, when compared to the polypropylene. In the composite with sawdust/polypropylene
industrially produced, the tensile strength decreased 62.3%.
The modied ber (benzylated bagasse)/matrix interface
is shown in Fig. 5a. The bers presented circular cross-section shapes. In a recent work [20], in the chemical modication process, the lignin (natural ber component) was
partially removed by NaOH addition and the morphology
of benzylated bagasse was dierent in respect to in natura
bagasse as shown in Fig. 5b. In Fig. 5a, the bers are transversally aligned to the fracture. The higher magnied
micrograph of ber and matrix interface (Fig. 5c) exhibits
the pulled-out bers of the matrix by tensile stress. The
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Fig. 5. SEM composite fracture surface injected under vacuum: (a) benzylated bagasse/polypropylene interface showing the clumping and morphological
bers; (b) the micrograph shows the shapes of benzylated bagasse; (c) higher magnied micrograph shows the detail of region interface between ber and
matrix; and (d) bagasse cellulose and matrix interface showing the morphology of their composites.
exural strength decreased about 54% in respect to the polypropylene, due to larger amount of failed points.
The tensile and exural moduli are related to the material rigidity, and as previously mentioned, the Youngs
modulus was higher for the bers than for thermoplastics.
If the bers are distributed and aggregated to the matrix, a
higher exural modulus for the material can be resulted.
Comparing the values of tensile modulus between the
composites (Fig. 1), bagasse (10 wt%)/PP and sawdust
(20 wt%)/PP, the composites presented values very similar
to the neat polypropylene. The tensile modulus values for
the bagasse (8.7 wt%)/PP, benzylated bagasse (10 wt%)/
PP and cellulose from bagasse composites are smaller due
to the disadvantageous presence of defects.
For the composites, the exural modulus increased in
relation to that of the neat polypropylene (Fig. 1; except
for the composite with benzylated bagasse). As the exural
tests were made by the four-points method, the composite
with random distribution of the bers had a better performance. Better performance of composites with random distribution into the matrix is attained due to homogeneous
distribution of bers. The stress transference between ber
and matrix is more eective, aecting positively the
performance.
4. Conclusions
The best molding process is the injection under vacuum,
which leads to materials with homogeneous distribution of
bers and free of blisters. The exural and tensile tests show
that the obtained composites did not present good exural
and tensile strengths. The blisters and/or the non-homogeneity of the bers are defects in the material that directly
interfere in the mechanical properties, harming the obtainment of a material with high resistance. The composites did
not present, in general, a good interfacial contact between
ber and matrix. However, the bers insertion caused an
increase in the exural modulus, turning the materials more
rigid. The mechanical properties of the obtained composites
are comparable to the commercial material with 20 wt%
sawdust and PP. The composites utilizing bagasse (treated
or in natura) can be investigated, seeking a similar application, for example, in coatings of pieces of automobiles. The
SEM and OM techniques permit the study of the morphology and microstructure of composites.
Acknowledgements
The authors acknowledge FAPESP, Capes and CNPq
for fellowships and nancial support.
References
[1] Nogueira CL, Marlet JMF, Rezende MC. Processo de Obtencao de
Pre-Impregnados Polimericos Termoplasticos Via Moldagem por
Compressao a Quente. Pol Cienc e Tecnol 1999(3):1827.
[2] Khalil HPSA, Ismail H, Rozman HD, Ahmad MN. The eect of
acetylation on interfacial shear strength between plant bres and
various matrices. Europ Polym J 2001;37:103745.
1461
[15] Canevarolo SV. Ciencia dos Polmeros. Sao Paulo: Artliber; 2002.
[16] Rowell RM, Sanadi AR, Cauleld DF, Jacobson RE. Utilization of
natural composites: problems and opportunities. In: Leao AL,
Carvalho FX, Frollini E, editors. Lignocellulosic Plastics Composites. Sao Paulo; 1997. p. 2352.
[17] Hon DN-S. Functional Natural Polymers: A New Dimensional
Creativity in Lignocellulosic Chemistry. In: Hon DN-S, editor.
Chemical Modication of Lignocellulosic Materials. New
York: Dekker; 1996. p. 110.
[18] Joseph PV, Joseph K, Thomas S, Pillai CKS, Prasad VS, Groeninckx
G, et al. The thermal and crystallisation studies of short sisal bre
reinforced polypropylene composites. Compos Part A 2003;34:
25366.
[19] Sawyer LC, Grubb DT. Polymer Microscopy. London: Chapman &
Hall; 1996.
[20] Luz SM, Goncalves AR. Evaluation of soda/Aq pulping for
sugarcane bagasse and straw. In: Proceedings of 7th Brazilian
Symposium on the Chemistry of Lignins and other Wood Components. Belo Horizonte; September 2001. p. 1316.
[21] Luz SM, Goncalves AR, DelArco Jr AP. Evaluation of mechanical
properties of sugarcane bagasse/polypropylene composites. In: Leao
AL, Carvalho FX, Frollini E, editors. Natural Polymers and
Composites IV, Sao Carlos; 2002. p. 52327.
[22] ASTM D 638. Association standards testing materials. Standard test
method for tensile properties of plastics. Philadelphia; 1988.
[23] ASTM D 790. Association standards testing materials. Standard test
method for exural properties of unreinforced and reinforced plastics
and electrical insulating materials. Philadelphia; 1988.
[24] Luz SM, Goncalves AR. Evaluation of chemically modied sugarcane bagasse by weight variation and FT-IR analysis. In: Leao AL,
Carvalho FX, Frollini E, editors. Natural Polymers and Composites
IV, Sao Carlos; 2002. p. 1494497.