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1.
1.1
Product identifiers
Product name
Product Number
Brand
:
:
L3771
Sigma
1.2
1.3
Relevant identified uses of the substance or mixture and uses advised against
Identified uses
1.4
1.5
Telephone
Fax
:
:
2.
HAZARDS IDENTIFICATION
2.1
GHS Classification
Flammable solids (Category 2)
Acute toxicity, Oral (Category 4)
Acute toxicity, Dermal (Category 3)
Skin irritation (Category 2)
Serious eye damage (Category 1)
Specific target organ toxicity - single exposure (Category 3), Respiratory system
2.2
Danger
Hazard statement(s)
H228
Flammable solid.
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H302
H311
H315
H318
H335
Harmful if swallowed.
Toxic in contact with skin.
Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation.
Precautionary statement(s)
Prevention
P210
P240
P241
P261
Response
P305 + P351 + P338
P310
P361
P370 + P378
Storage
P403 + P233
Disposal
P501
2.3
Other hazards
Possible sensitizer.
3.
COMPOSITION/INFORMATION ON INGREDIENTS
3.1
Substances
Synonyms
Formula
Molecular Weight
CAS-No.
EC-No.
:
:
:
:
C12H25NaO4S
288.38 g/mol
151-21-3
205-788-1
Component
Classification
Concentration
<=100%
For the full text of the H-Statements mentioned in this Section, see Section 16.
4.
4.1
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If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.
Consult a physician.
4.2
4.3
5.
FIREFIGHTING MEASURES
5.1
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
5.2
5.3
5.4
Further information
Use water spray to cool unopened containers.
6.
6.1
6.2
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the
environment must be avoided.
6.3
6.4
7.
7.1
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7.2
7.3
8.
8.1
Control parameters
Occupational Exposure Limits
We are not aware of any national exposure limit.
8.2
Exposure controls
Appropriate engineering controls
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the
product.
Personal protective equipment
Eye/face protection
Face shield and safety glasses Use equipment for eye protection tested and approved under
appropriate government standards such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the
standard EN 374 derived from it.
Full contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
Splash contact
Material: Nitrile rubber
Minimum layer thickness: 0.11 mm
Break through time: 480 min
Material tested:Dermatril (KCL 740 / Aldrich Z677272, Size M)
data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test
method: EN374
If used in solution, or mixed with other substances, and under conditions which differ from EN 374,
contact the supplier of the CE approved gloves. This recommendation is advisory only and must be
evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated
use by our customers. It should not be construed as offering an approval for any specific use
scenario.
Body Protection
Complete suit protecting against chemicals, Flame retardant antistatic protective clothing, The type
of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Where risk assessment shows air-purifying respirators are appropriate use a full-face particle
respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering
controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use
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respirators and components tested and approved under appropriate government standards such as
NIOSH (US) or CEN (EU).
9.
9.1
Appearance
Form: solid
Colour: white
b)
Odour
no data available
c)
Odour Threshold
no data available
d)
pH
7.2
e)
Melting point/freezing
point
f)
no data available
g)
Flash point
180 C
h)
Evapouration rate
no data available
i)
Flammability (solid, gas) The substance or mixture is a flammable solid with the category 2.
j)
Upper/lower
flammability or
explosive limits
no data available
k)
Vapour pressure
no data available
l)
Vapour density
no data available
m) Relative density
0.370 g/cm3
n)
Water solubility
soluble
o)
p)
Auto-ignition
temperature
no data available
q)
Decomposition
temperature
no data available
r)
Viscosity
no data available
s)
Explosive properties
no data available
t)
Oxidizing properties
no data available
9.2
10.
10.1
Reactivity
no data available
10.2
Chemical stability
Stable under recommended storage conditions.
10.3
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10.4
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
10.5
Incompatible materials
Oxidizing agents
10.6
11.
TOXICOLOGICAL INFORMATION
11.1
No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
no data available
Specific target organ toxicity - single exposure
Inhalation - May cause respiratory irritation.
Specific target organ toxicity - repeated exposure
no data available
Aspiration hazard
no data available
Additional Information
RTECS: WT1050000
sneezing, The sodium salt of dodecyl sulfate has been reported to cause pulmonary sensitization resulting in
hyperactive airway dysfunction and pulmonary allergy accompanied by fatigue, malaise, and aching.
Significant symptoms of exposure can persist for more than two years and can be activated by a variety of
nonspecific environmental stimuli such as automobile exhaust, perfumes, and passive smoking.
sneezing, The sodium salt of dodecyl sulfate has been reported to cause pulmonary sensitization resulting in
hyperactive airway dysfunction and pulmonary allergy accompanied by fatigue, malaise, and aching.
Significant symptoms of exposure can persist for more than two years and can be activated by a variety of
nonspecific environmental stimuli such as automobile exhaust, perfumes, and passive smoking.
Liver - Irregularities - Based on Human Evidence
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12.
ECOLOGICAL INFORMATION
12.1
Toxicity
Toxicity to fish
Toxicity to algae
12.2
12.3
95.9 %
Bioaccumulative potential
Bioaccumulation
Cyprinus carpio (Carp) - 72 h
Mobility in soil
no data available
12.5
12.6
13.
DISPOSAL CONSIDERATIONS
13.1
14.
TRANSPORT INFORMATION
14.1
UN number
ADR/RID: 2926
IMDG: 2926
IATA-DGR: 2926
14.2
14.3
Packaging group
ADR/RID: II
IMDG: II
IATA-DGR: II
Environmental hazards
ADR/RID: no
IATA-DGR: no
14.4
14.5
14.6
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15.
REGULATORY INFORMATION
15.1
Safety, health and environmental regulations/legislation specific for the substance or mixture
Standard for the Uniform Scheduling of Medicines and Poisons
Schedule 6
Carcinogen classification under WHS Regulation 2011, Schedule 10
Not listed
Notification status
16.
AICS:
DSL:
ENCS:
IECSC:
ISHL:
KECI:
NZIoC:
PICCS:
OTHER INFORMATION
Full text of H-Statements referred to under sections 2 and 3.
Acute Tox.
Eye Dam.
Flam. Sol.
H228
H302
H311
H315
H318
H335
Skin Irrit.
STOT SE
Acute toxicity
Serious eye damage
Flammable solids
Flammable solid.
Harmful if swallowed.
Toxic in contact with skin.
Causes skin irritation.
Causes serious eye damage.
May cause respiratory irritation.
Skin irritation
Specific target organ toxicity - single exposure
Further information
Copyright 2013 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information in this document is based on the present state of our knowledge and is
applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See www.sigmaaldrich.com and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.
Sigma - L3771
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